CN108935460A - The Herbicidal combinations and application thereof of regional control injurious weed for corn growth - Google Patents
The Herbicidal combinations and application thereof of regional control injurious weed for corn growth Download PDFInfo
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- CN108935460A CN108935460A CN201810750196.4A CN201810750196A CN108935460A CN 108935460 A CN108935460 A CN 108935460A CN 201810750196 A CN201810750196 A CN 201810750196A CN 108935460 A CN108935460 A CN 108935460A
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/32—Ingredients for reducing the noxious effect of the active substances to organisms other than pests, e.g. toxicity reducing compositions, self-destructing compositions
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
- A01N47/36—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< directly attached to at least one heterocyclic ring; Thio analogues thereof
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- Life Sciences & Earth Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- Agronomy & Crop Science (AREA)
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- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention relates to a kind of Herbicidal combinations and application thereof of regional control injurious weed for corn growth.The Herbicidal combinations, the active constituent B comprising safener A and herbicidally effective amount is as effective component, safener A: phenyl substituted oxazoline isoxazole Carbox amide, such as following formula:
Description
Technical field
The present invention relates to herbicide technology fields, and in particular to a kind of regional control injurious weed for corn growth
Herbicidal combinations and application thereof.
Background technique
With the development of economy and society, the increase of the continuous 30 years blowouts of world population quantity, world population in 2016
7,300,000,000 high pointes are broken through.And the arable area in global range is as the reasons such as environmental degradation, soil erosion are continuous
It reduces.By effectively preventing and kill off Farmland weed, reduces agricultural losses raising grain yield and have become current agriculture field research
Hot subject.Sulfonylurea herbicide is a kind of herbicide of most widely used, kind at most, this kind of herbicide in the world today
Active height, low toxicity, low dosage and it is highly selective the advantages that, action target be the intracorporal Amino acid synthesis of plant during
Essential enzyme-acetolactate synthestase (ALS), by hindering the biosynthesis of branched-chain amino acid, and then block cell point
The synthesis for splitting period DNA causes cell to be unable to normal growth and plays the role of killing weeds.In global agrochemical market, sulphur
Sulfonylurea herbicide accounts for herbicide market share and is up to 12% as one of herbicide kind mostly important in the market.Sulphonyl
Carbamide herbicides have special efficacy to the prevention and treatment of perennial weeds or annual grassy weeds, therefore, can be applied to prevent and kill off gardens, paddy field,
Bare place, upland weeds.Wherein, the sulfonylurea that Nissan Chemical Ind Ltd develops jointly with Monsanto Company removes
Careless agent-halosulfuronmethyl was registered in the U.S. in 1994 and is produced, and is registered within 2013 and is produced in China, with its high activity, Gao Xuan
The features such as selecting property, has obtained extensive concern.
In recent years, as in a large amount of uses in farmland, halosulfuronmethyl is also convex therewith to the harm of crop and environment
It is aobvious.Safety using farm-chemical indoor determination method research halosulfuronmethyl to different corn varieties finds halosulfuronmethyl
To the safeties of different corn varieties, there are significant differences.Part corn variety drug resistance is higher, and inhibitory effect is unobvious, but
It is more sensitive that there are also kinds, and plant height inhibiting rate reaches 10% or so.It is larger that current application rate is handled using halosulfuronmethyl
Corn variety raise beautiful No. 7, Five Sacred Mountins 18, corn, agricultural university 0638, when spending glutinous No. a kind, it is found that the corn of these kinds is raw
Length is suppressed, and aetiolation, young leaves twisted growth occurs in blade.One research in Ontario, Canada also indicates that chlorine pyrrole
For Sulfometuron Methyl to the corn plant height of Empire kind, there is apparent inhibit in cob size and yield.
In order to solve drug injury problem caused by halosulfuronmethyl, other than developing new herbicides kind, exploitation is directed to
The safener of halosulfuronmethyl is also a kind of effective method.Herbicide-safener (antidote, antagonist or protective agent)
It is the chemical substance for improving crop (but not being weeds) removing toxic substances herbicide ability.The common usage mode of safener includes at seed
Reason (for example, being used for sorghum), water process (is used for rice), or spray formulation is made together with herbicide and other auxiliary agents, it
Sprinkling uses (for corn and other cereal crops fields) afterwards.The effect of herbicide-safener is in the crop fields for having weed growth
Between herbicide can be made to show selectivity, avoid manslaughtering crop.Herbicide not of the same race and corresponding safener are mixed into application
It is the best approach for improving herbicide selective, the method for this novel mixing application reaches increasing under the premise of efficient weeding
It pretends object drug resistance and reduces herbicide to the purpose of chemical injury of crops.Therefore, it is necessary to which exploration discovery is lived for corn field, protection
The high novel halosulfuronmethyl safener of property, to cope with the drug injury problem of halosulfuronmethyl.
Summary of the invention
The purpose of the present invention is being directed to corn crop field, a kind of regional control injurious weed for corn growth is provided
Herbicidal combinations and application thereof do not cause phytotoxicity to crop while controlling weeds.
Herbicidal combinations of the present invention adopt the following technical solutions to achieve:
A kind of Herbicidal combinations of the regional control injurious weed for corn growth include safener component A and weeding
A effective amount of active ingredient components B as effective component,
Component A: phenyl substituted oxazoline isoxazole Carbox amide, such as following formula:
R1For hydrogen or halogen；
R2For hydrogen or halogen；
R3For hydrogen or the alkyl with 1 to 3 carbon atom；
R4For hydrogen or the naphthenic base of the alkyl with 1 to 6 carbon atom or 1 to 6 carbon atom；
R5For hydrogen or the alkyl with 1 to 3 carbon atom；
R6For hydrogen, methyl, phenyl or alpha-substituted heterocycle；
Component B: halosulfuronmethyl；
Wherein the weight ratio comprising a effective amount of component A and B is 1-4:1-5.
The present invention also has following technical characteristic:
1, a kind of Herbicidal combinations of the regional control injurious weed for corn growth include weeding group as described above
Object and adjuvant component C are closed, wherein the weight ratio comprising a effective amount of component A, B, C is 1-4:1-5:2-7.
2, herbicidal composition as described above, component C auxiliary agent include carrier, emulsifier, dispersing agent, disintegrating agent, increasing
Thick dose, wetting agent, film forming agent, defoaming agent, one of antifreezing agent and colorant or a variety of.
3, herbicidal composition as described above, the dosage form of the composition are wettable powder, missible oil, suspending agent, water
Discrete particles or seed coat agent.
3, Herbicidal combinations as described above are applied to the purposes of the regional control injurious weed of corn growth.
Compared with prior art, the present invention has the following advantages:
Composition of the invention can effectively prevent most of weeds in corn field, and not damage substantially to crop,
It is not easy to bring secondary phytotoxicity, the safener contained can effectively avoid the phytotoxicity caused by corn of halosulfuronmethyl herbicide.Relatively
Degrass spectrum is not only expanded in herbicide single dose, avoids drug injury problem caused by halosulfuronmethyl herbicide, can also be delayed miscellaneous
The generation of careless drug resistance has safety for corn.The performance of Herbicidal combinations of the invention is significantly more than routine techniques
It is horizontal.
Specific embodiment
Embodiment 1
The present invention provides a kind of weeding containing phenyl substituted oxazoline isoxazole Carbox amide and halosulfuronmethyl
Composition, safener, herbicide and auxiliary agent comprising herbicidally effective amount.
Herbicidal combinations of the present invention include wherein comprising a effective amount of
A) detoxify a effective amount of Formulas I safener
R1For hydrogen or halogen；
R2For hydrogen or halogen；
R3For hydrogen or the alkyl with 1 to 3 carbon atom；
R4For hydrogen or the naphthenic base of the alkyl with 1 to 6 carbon atom or 1 to 6 carbon atom；
R5For hydrogen or the alkyl with 1 to 3 carbon atom；
R6For hydrogen, methyl, phenyl or α heterocyclic substituent.
B) halosulfuronmethyl.
C) auxiliary agent, it is characterised in that comprising carrier, emulsifier, dispersing agent, disintegrating agent, thickener, wetting agent, film forming agent,
One of defoaming agent, antifreezing agent and colorant are a variety of.
The weight ratio of described component A, B, C are 1-4:1-5:2-7.
Component C auxiliary agent used in the present invention include carrier, emulsifier, dispersing agent, disintegrating agent, thickener, wetting agent, at
One of film, defoaming agent, antifreezing agent and colorant are a variety of, are common various composition in pesticide, have no special limit
Fixed, specific ingredient and dosage are determined by experiment according to recipe requirements.
It is suitble to prepare the liquid-carrier of Herbicidal combinations of the invention to include water, aliphatic hydrocarbon (n-hexane), aromatic series
Hydro carbons (benzene, toluene, ethylbenzene, dimethylbenzene), alcohols (ethyl alcohol), esters (ethyl acetate) etc..
The solid carrier for being suitble to herbicidal composition of the invention is gypsum, diatomite, bentonite, kaolin, clay, white
Carbon black, calcium carbonate, bark powder, shuck powder, corn ear powder etc..
Currently preferred dosage form is missible oil, wettable powder, suspending agent, water dispersible granular, seed coat agent.
For wettable powder, corresponding auxiliary agent can be used to complete the present invention for those skilled in the art.Workable auxiliary agent
Have: alkylnaphthalene sulfonate, polycarboxylate, vegetable oil ethylene oxide adduct or aralkyl polyoxyethylene ether yuban sulphur
One or more of hydrochlorate is used as dispersing agent；In alkyl sulfate, lignosulfonates, saponin or sulfite cellulose
One or more are used as wetting agent；Diatomite or kaolin are as carrier.For missible oil, those skilled in the art be can be used
Corresponding auxiliary agent completes the present invention.Workable auxiliary agent has: phenol derivatives ethoxylate, phenol derivatives ethoxy-c oxygen
Glycolylate, calcium dodecyl benzene sulfonate, polyethers sulfate, phenethyl phenol polyethenoxy ether class, one in ethoxylated castor oil
Kind is a variety of as emulsifier.For suspending agent, corresponding auxiliary agent can be used to complete the present invention for those skilled in the art.It can make
Auxiliary agent has: alkylnaphthalene sulfonate, polycarboxylate, vegetable oil ethylene oxide adduct or aralkyl polyoxyethylene ether formaldehyde
One or more of polymer sulfates are used as dispersing agent；Castor oil polyoxyethylene ether, polyol fatty acid ester, alkylbenzene
One or more of sulfonate or agriculture breast 2201 are used as emulsifier；Alkyl sulfate, lignosulfonates, saponin or
One or more of sulfite cellulose is used as wetting agent；Gelatin, guar gum, Arabic gum, xanthan gum, aluminium-magnesium silicate, diatom
One or more of soil or sodium carboxymethylcellulose are used as thickener；One of organic silicon or fatty acid or
The a variety of defoaming agents of person；Glycerol is as antifreezing agent.For water dispersible granular, alkylnaphthalene sulfonate, polycarboxylate, vegetable oil epoxy second
One or more of alkane addition product or aralkyl polyoxyethylene ether yuban sulfate are used as dispersing agent；Alkyl sulfide
One or more of hydrochlorate, lignosulfonates, saponin or sulfite cellulose are used as wetting agent；Sodium chloride is as disintegration
Agent；Diatomite or kaolin are as carrier.
For seed coat agent, corresponding auxiliary agent can be used to complete the present invention for those skilled in the art.Alkylnaphthalene sulfonate, poly- carboxylic
One or more of hydrochlorate, vegetable oil ethylene oxide adduct or aralkyl polyoxyethylene ether yuban sulfate
As dispersing agent；Polyvinyl acetate emulsion, polyvinyl alcohol, polyacrylamide, polyethylene glycol series, in polyvinylpyrrolidone
One or more are used as film forming agent；One or more of xanthan gum, sodium alginate, sodium carboxymethylcellulose are as thickening
Agent；Basic rhodamine is as colorant.
Herbicidal combinations of the invention can use in the region for cultivating following crop: maize farming object.
In addition, the present invention can be very good the appearance of delaying drug resistance weeds.
The object of the invention is also to provide a kind of weed control methods using above-mentioned Herbicidal combinations, including will be above-mentioned
Herbicidal combinations are applied to cultivated crop, undesired plant growth region.
Specifically, weed control methods of the invention are that the real area of herbicide need to be applied according to cultivated crop, with
And a situation arises for weeds, determines the dosage for needing Herbicidal combinations to be used, selects any dosage form and be diluted to a certain concentration,
Finally it is sprayed on arable farming region.Method of administration refers to any effective common method when the applications of pesticide, including but not limited to sprays
Powder method, spray-on process, fumigating system, soil treatment method etc..
The method of the present invention is most preferably for prevention and treatment arable farming region or will be used for the weeds in the region of arable farming.When
When for crop growing loci, amount of application answers enough controlling weeds but will not generate apparent damage, Ke Yiti to crop simultaneously
High crop yield and quality has important use value.
Herbicidal combinations of the invention be suitable for but be not limited to seedling before, Miao Hou, the method for administration such as seed soaking.
Embodiment 2:10% safener A+40% halosulfuronmethyl wettable powder
Weight ratio
Each component is mixed in proportion, arrives Herbicidal Compositions Wettable pulvis after ultra-fine pulverizer disintegrating.
Embodiment 3:20% safener B+20% halosulfuronmethyl missible oil
Weight ratio
Each component is mixed in proportion, is stirred evenly to get Herbicidal combinations missible oil is arrived.
Embodiment 4:20% safener C+20% halosulfuronmethyl water dispersion granule
Weight ratio
Each component is mixed and crushed in proportion, after being soaked with water, extrusion granulation and drying, it is 2-6 millimeters that partial size, which is made,
Herbicidal combinations water dispersion granule.
Embodiment 5:20% safener D+20% halosulfuronmethyl missible oil
Weight ratio
Each component is mixed in proportion, is stirred evenly to get Herbicidal combinations missible oil is arrived.
Embodiment 6:10% safener E+20% halosulfuronmethyl suspending agent
Weight ratio
Embodiment 7:40% safener F+30% halosulfuronmethyl seed coat agent
Weight ratio
Each component is mixed in proportion and is ground to get Herbicidal combinations seed coat agent is arrived.
For seed coat agent, corresponding auxiliary agent can be used to complete the present invention for those skilled in the art.Alkylnaphthalene sulfonate, poly- carboxylic
One or more of hydrochlorate, vegetable oil ethylene oxide adduct or aralkyl polyoxyethylene ether yuban sulfate
As dispersing agent；Polyvinyl acetate emulsion, polyvinyl alcohol, polyacrylamide, polyethylene glycol series, in polyvinylpyrrolidone
One or more are used as film forming agent；One or more of xanthan gum, sodium alginate, sodium carboxymethylcellulose are as thickening
Agent；Basic rhodamine is as colorant.
In above-mentioned example of formulations 2- embodiment 7, the present invention is individually disclosed with phenyl substituted oxazoline isoxazole formamide
The different dosage forms of class compound and halosulfuronmethyl as the Herbicidal combinations of effective component, but the present invention be not limited to it is above-mentioned
Embodiment, in other feasible embodiments, the proportion of each effective component of Herbicidal combinations, preparation condition can be adjusted accordingly
It is whole.
Embodiment 8
Biological activity test example
It is tested before seedling:
Under greenhouse experiment, use standard soil as cultivation matrix, test plant is seeded in seedling alms bowl (diameter 8cm, depth
In 12cm), it is covered with the soil with a thickness of 0.5cm.In the seedling last stage, Herbicidal combinations are administered to soil surface.Dosage depends on
In optium concentration identified under greenhouse experiment.(100% effect=plant is completely dead for evaluation test after 2-4 weeks；0%
Effect=plant-less toxicity effect).The Herbicidal combinations used in this test show good result.
It is tested after seedling:
Herbicidal Testing Trials are carried out for different types of weeds
Five kinds of reagents are prepared according to constant weight percentage:
1. safener A (3- (2 '-fluoro- 6 '-chloro- phenyl) -4- (2 '-cyclopenta -1 ', 3 '-oxazoles) -5- methyl-isoxazole
Formamide)+halosulfuronmethyl；
2. safener B (3- phenyl -4- (2 '-cyclohexyl -1 ', 3 '-oxazoles) -5- methyl-isoxazole formamide)+chlorine pyrrole is phonetic
Sulphur is grand；
3. safener C (3- (phenyl) -4- (2 ', 2 '-dipropyl -1 ', 3 '-oxazoles) -5- methyl -- 5- methyl-isoxazole
Formamide)+halosulfuronmethyl；
4. safener D (3- phenyl 4- (2 '-methyl -2 '-ethyl -1 ', 3 '-oxazoles) -5- methyl-isoxazole formamide)+
Halosulfuronmethyl；
5. safener E (3- phenyl 4- (2 '-methyl -2 '-isobutyl group -1 ', 3 '-oxazoles) -5- methyl-isoxazole formamide)
+ halosulfuronmethyl；
6. safener F (3- (2 '-fluorophenyl) -4- (2 '-(4 '-methylcyclohexyl) -1 ', 3 '-oxazole) -5- methyl-different evil
Azoles formamide)+halosulfuronmethyl.Above-mentioned each reagent is diluted with water after a certain period of time, is observed respectively to rice barnyard grass, semen euphorbiae, duck
Tongue grass, angustifolia arrowhead herb, Procumbent Falsepimpernel, difformed galingale herb herbicidal effect.
Test method: 300g standard soil is filled in seedling alms bowl (diameter 8cm, deep 12cm), stands after adding water, sows after 2 days
Weed seed is simultaneously covered with 0.5cm soil, adds water plantation a period of time.When weed growth to 3-4 leaf, by Herbicidal combinations to spray
Mist form is administered on test weeds, and dosage depends on the identified optium concentration under greenhouse experiment.Evaluation test after 5 weeks
(100% effect=plant is completely dead；0% effect=plant-less toxicity effect).The Herbicidal combinations used in this test
Show good result.
The herbicidal effect table observed after handling 5 weeks
According to test result as can be seen that Herbicidal combinations of the invention herbicidal effect in the case where low usage amount is bright
It is aobvious, there is good control efficiency to weeds.
Embodiment 9
To the safety effect of crop
Under greenhouse experiment, by trial crops, culture is to 4 leaf phases in seedling alms bowl (diameter 8cm, deep 12cm), by Herbicidal combination
Object is administered in test crop (corn) with Sprayable, and dosage depends on the identified optium concentration under greenhouse experiment.5 weeks
(100% effect=crop is completely dead for evaluation test afterwards；0% effect=without crop toxic effect).
Concrete condition is as follows:
| Crop damage (%) | |
| Safener A+ halosulfuronmethyl | 3.5 |
| Safener B+ halosulfuronmethyl amine | 5.4 |
| Safener C+ halosulfuronmethyl | 4.7 |
| Safener D+ halosulfuronmethyl | 2.1 |
| Safener E+ halosulfuronmethyl | 3.7 |
| Safener F+ halosulfuronmethyl | 4.0 |
According to test result as can be seen that Herbicidal combinations of the invention have good protecting effect to crop, do not make
At apparent phytotoxicity.
Claims (5)
1. a kind of Herbicidal combinations of the regional control injurious weed for corn growth, have comprising safener component A and weeding
The active ingredient components B of effect amount is as effective component, it is characterised in that:
Component A: phenyl substituted oxazoline isoxazole Carbox amide, such as following formula:
R1For hydrogen or halogen；
R2For hydrogen or halogen；
R3For hydrogen or the alkyl with 1 to 3 carbon atom；
R4For hydrogen or the naphthenic base of the alkyl with 1 to 6 carbon atom or 1 to 6 carbon atom；
R5For hydrogen or the alkyl with 1 to 3 carbon atom；
R6For hydrogen, methyl, phenyl or alpha-substituted heterocycle；
The active ingredient components B: halosulfuronmethyl of herbicidally effective amount；
Wherein the weight ratio comprising a effective amount of component A and B is 1-4:1-5.
2. a kind of Herbicidal combinations of the regional control injurious weed for corn growth, which is characterized in that include claim 1
The Herbicidal combinations and adjuvant component C, wherein the weight ratio comprising a effective amount of component A, B, C is 1-4:1-5:2-7.
3. herbicidal composition according to claim 1 or 2, which is characterized in that its component C auxiliary agent includes carrier, emulsification
One of agent, dispersing agent, disintegrating agent, thickener, wetting agent, film forming agent, defoaming agent, antifreezing agent and colorant are a variety of.
4. herbicidal composition according to claim 1 or 2, which is characterized in that the dosage form of the composition is wettable
Pulvis, missible oil, suspending agent, water dispersible granular or seed coat agent.
5. a kind of Herbicidal combinations according to claim 1 or 2 are applied to the regional control injurious weed of corn growth
Purposes.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810750196.4A CN108935460B (en) | 2018-07-10 | 2018-07-10 | Weeding composition for preventing and controlling harmful weeds in corn growing area and application thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810750196.4A CN108935460B (en) | 2018-07-10 | 2018-07-10 | Weeding composition for preventing and controlling harmful weeds in corn growing area and application thereof |
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| Publication Number | Publication Date |
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| CN108935460A true CN108935460A (en) | 2018-12-07 |
| CN108935460B CN108935460B (en) | 2020-03-17 |
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Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1168083A (en) * | 1995-01-09 | 1997-12-17 | 泽尼卡有限公司 | Herbicidal composition of 4-benzoylisoxazole or 2-cyano-1,3-dione herbicides and antidotes therefor |
| CN105532657A (en) * | 2015-12-28 | 2016-05-04 | 东北农业大学 | Weeding composition for monocotyledon crops and application thereof |
-
2018
- 2018-07-10 CN CN201810750196.4A patent/CN108935460B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1168083A (en) * | 1995-01-09 | 1997-12-17 | 泽尼卡有限公司 | Herbicidal composition of 4-benzoylisoxazole or 2-cyano-1,3-dione herbicides and antidotes therefor |
| CN105532657A (en) * | 2015-12-28 | 2016-05-04 | 东北农业大学 | Weeding composition for monocotyledon crops and application thereof |
Non-Patent Citations (2)
| Title |
|---|
| AIYING GUAN,ET AL: "Application of the Intermediate Derivatization Approach in Agrochemical Discovery", 《CHEM REV》 * |
| 杨婧: "除草剂安全剂研究进展", 《现代农业科技》 * |
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