CN108935356A - A kind of degradable bionical simulation attracting plug material - Google Patents

A kind of degradable bionical simulation attracting plug material Download PDF

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Publication number
CN108935356A
CN108935356A CN201810938020.1A CN201810938020A CN108935356A CN 108935356 A CN108935356 A CN 108935356A CN 201810938020 A CN201810938020 A CN 201810938020A CN 108935356 A CN108935356 A CN 108935356A
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parts
powder
poly
degradable
attracting
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CN201810938020.1A
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Chinese (zh)
Inventor
胡文龙
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CHAOHU XIANGYU FISHING GEAR Co Ltd
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CHAOHU XIANGYU FISHING GEAR Co Ltd
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Priority to CN201810938020.1A priority Critical patent/CN108935356A/en
Publication of CN108935356A publication Critical patent/CN108935356A/en
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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01KANIMAL HUSBANDRY; AVICULTURE; APICULTURE; PISCICULTURE; FISHING; REARING OR BREEDING ANIMALS, NOT OTHERWISE PROVIDED FOR; NEW BREEDS OF ANIMALS
    • A01K85/00Artificial bait for fishing

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  • Life Sciences & Earth Sciences (AREA)
  • Environmental Sciences (AREA)
  • Marine Sciences & Fisheries (AREA)
  • Animal Husbandry (AREA)
  • Biodiversity & Conservation Biology (AREA)
  • Fodder In General (AREA)

Abstract

A kind of degradable bionical simulation attracting plug material, it is related to technical field of fishing, is composed of the following parts by weight: poly- 5 ~ 27 parts of hydroxy alkyl acid rouge, 7 ~ 31 parts of poly-epsilon-caprolactone, 11 ~ 23 parts of gelatin, 27 ~ 51 parts of modified starch, 7 ~ 19 parts of glycerol, 11 ~ 13 parts of phagostimulant, 0.5 ~ 1 part of sesame oil, 0.5 ~ 1 part of pigment, 0.5 ~ 1 part of Radix et Caulis Opuntiae Dillenii extract, 2 ~ 4 parts of calcium carbonate, 1 ~ 2 part of pearl powder, 0.5 ~ 1 part of crosslinking agent;It is disclosed by the invention, according to the feeding characteristic of fish species, the bionic fish bait of a variety of bait fishes, shrimp pattern true to nature is made, in the natural environment can complete biodegradable, small pollution of the environment.

Description

A kind of degradable bionical simulation attracting plug material
Technical field
The invention belongs to bait production technical fields, and in particular to a kind of degradable bionical simulation attracting plug material.
Background technique
Road Asia is a kind of fishing method, is named the transliteration that source is Lure, i.e., false bait fishing fish, is to imitate small and weak biology to draw A kind of method for attack of sending out fish big.Skill is particular about, the synthetic operation of pole, bait, wheel is needed.In the whole process, angler is to do All-around exercises, while road Asia equipment is succinct, clean environmental protection has great difference with traditional fishing method.
The fishing of road Asia is very prevailing in Europe, and road Asia is also gradually risen from China in 2007 and is fished, by more and more love of going fishing Good person is liked.It lives the predacious fish in natural water area, there is very strong autonomous prey ability, it does not depend on dead bait, It is only interested in having certain dynamic bait.Especially carnivorous fingerling, it is aggressive superpower.Overall process be all during exercise into Row, including initial stage seek fish, punctuate, and the picaroon that carries out to lower pole and in water take-up, is shaken, leads and the movement such as drag, and hold certain The characteristics of motion hardy becomes " dead bait " in water and lives, make plug present in water it is various it is similar run away, struggle with all one's might in alarm, Injured weakness, rapidly the forms such as twitch attract target fish offensive attack, instead of the waiting that traditional fishing method most of time is uninteresting. But the disadvantage is that the attracting ingredient such as the amino acid contained in conventional food bait, mineral element, protein, agent to promote food, strong food agent, difficult To be added to thermoplastic elastomer (TPE), soft PVC wherein, cause this kind of bionic fish bait small to the taste sense organ temptation of fish, Fish-catching rate is lower.And cannot degrade for a long time after such bionic fish bait use, also lead to a degree of environmental pollution. Simultaneously because containing in traditional bait, there are many chemical components, are easy to produce and eat phenomenon by mistake, dangerous.
Summary of the invention
Technical problem to be solved by the present invention lies in provide a kind of degradable bionical simulation attracting plug material.
The technical problems to be solved by the invention are realized using following technical scheme:
A kind of degradable bionical simulation attracting plug material, is composed of the following parts by weight: poly- hydroxy alkyl acid rouge 5 ~ 27 parts, 7 ~ 31 parts of poly-epsilon-caprolactone, 11 ~ 23 parts of gelatin, 27 ~ 51 parts of modified starch, 7 ~ 19 parts of glycerol, 11 ~ 13 parts of phagostimulant, sesame 0.5 ~ 1 part of sesame oil, 0.5 ~ 1 part of pigment, 0.5 ~ 1 part of Radix et Caulis Opuntiae Dillenii extract, 2 ~ 4 parts of calcium carbonate, 1 ~ 2 part of pearl powder, crosslinking agent 0.5 ~ 1 part.
Further, the phagostimulant is made of the component of following parts by weight: the food bait is fish raw meat Powder, drosophila powder, blood red worm powder, grub powder, fly pupa powder, hawkmoth powder, river snails rice noodle, earthworm powder, ginger powder, locust powder, gadfly powder, beans The dregs of rice, dried silkworm chrysalis meal, amino acid, meat maggot powder, ground cinnamon, spice, lard it is one of or several.
Further, the modified starch is starch through 105 DEG C of dry 4h, weigh 36 parts of dried starch samples in In mouth bottle, it is made into the starch milk of mass concentration 40%, is placed in constant temperature blender with magnetic force and is stirred continuously, with weight concentration 3.0% Sodium hydroxide solution controls pH value of reaction system and is initially added into acetic anhydride after 8.0 ~ 8.4, about 30min, in 10min slowly It is homogeneously added into the acetic anhydride of 4ml, is mixed well, is kept stirring, reaction after a certain period of time, is neutralized to the hydrochloric acid of 0.5mo/L Then pH=6.5 are filtered in bottle,suction with Buchner funnel, are washed with distilled water filter cake, after being examined with silver nitrate without chloride ion, It removes filter cake to be dissolved in 500mL beaker with distilled water, refilter after mixing evenly, 3 times repeatedly, put 45 DEG C of people's constant temperature oven drying For 24 hours, it crushes, screen obtains modified starch.
Further, the pearl powder is the mixture of mica titanium perlatolic powder, pearl powder, zinnwaldite powder.
A kind of degradable bionical simulation attracting plug material, preparation method includes the following steps: (1) the poly- hydroxyl of precise 5 ~ 27 parts of base alkyl acid rouge, 7 ~ 31 parts of poly-epsilon-caprolactone, 11 ~ 23 parts of gelatin, 27 ~ 51 parts of modified starch, 7 ~ 19 parts of glycerol, food calling 11 ~ 13 parts of agent, 0.5 ~ 1 part of sesame oil, 0.5 ~ 1 part of pigment, 0.5 ~ 1 part of Radix et Caulis Opuntiae Dillenii extract, 2 ~ 4 parts of calcium carbonate, pearl powder 1 ~ 2 Part, 0.5 ~ 1 part of crosslinking agent;(2) by load weighted poly- hydroxy alkyl acid rouge, poly-epsilon-caprolactone, gelatin, modified starch, glycerol, lure Agent, sesame oil, pigment, calcium carbonate are eaten, mixed powder is obtained;(3) mixed powder and Radix et Caulis Opuntiae Dillenii extract, calcium carbonate, pearl powder, friendship Mixing 5 ~ 10 minutes in mixer are put into connection agent, and mixer set temperature is 100 DEG C ~ 160 DEG C;(4) material that will be kneaded Hot-forming in compression molding agent, molding temperature is set as 130 DEG C ~ 160 DEG C, and molding pressure is 25MPa ~ 55MPa.
The beneficial effects of the present invention are:
Modified starch, gelatin and Radix et Caulis Opuntiae Dillenii extract are added in formula as major ingredient, so that product has good degradability, Use process is safe and reliable, not can cause environmental pollution;The formula of phagostimulant has been changed simultaneously, drosophila powder, blood red worm are increased Powder, grub powder, fly pupa powder, hawkmoth powder, river snails rice noodle, earthworm powder, ginger powder, locust powder, gadfly powder, dregs of beans, dried silkworm chrysalis meal, amino Acid, meat maggot powder, ground cinnamon, smell is good, is easy to attract fish, and convenient for fishing, and cost is not high.
The present invention compared with prior art the advantages of:
It is prepared using Wholly-degradable material, simple process and low cost, can reach fully bio-degradable, thus the fishes and shrimps shape of material preparation The bait of state, Analogous fish bait travelling swings the motion state escaped due to magneticaction in water, reaches state bionic fish bait living Effect, it is environmentally protective, it is easy to operate, there is experience abundant without angler, it is easy to learn, bionic fish bait is put into and fishes point, is not necessarily to Adjustment plays fishing rod, saves the time to fish bite, improves fish quantity of the catch, greatly improves and catch fishing efficiency.
Specific embodiment
In order to be easy to understand the technical means, the creative features, the aims and the efficiencies achieved by the present invention, tie below Specific embodiment is closed, the present invention is further explained.
Embodiment 1
A kind of degradable bionical simulation attracting plug material, is composed of the following parts by weight: poly- hydroxy alkyl acid rouge 25 Part, 27 parts of poly-epsilon-caprolactone, 19 parts of gelatin, 38 parts of modified starch, 16 parts of glycerol, 12 parts of phagostimulant, 0.8 part of sesame oil, pigment 0.8 part, 0.8 part of Radix et Caulis Opuntiae Dillenii extract, 3 parts of calcium carbonate, 1.5 parts of pearl powder, 0.8 part of crosslinking agent.
Further, the phagostimulant is made of the component of following parts by weight: the food bait is fish raw meat Powder, drosophila powder, blood red worm powder, grub powder, fly pupa powder, hawkmoth powder, river snails rice noodle, earthworm powder, ginger powder, locust powder, gadfly powder, beans The dregs of rice, dried silkworm chrysalis meal, amino acid, meat maggot powder, ground cinnamon, spice, lard it is one of or several.
Further, the modified starch is starch through 105 DEG C of dry 4h, weigh 36 parts of dried starch samples in In mouth bottle, it is made into the starch milk of mass concentration 40%, is placed in constant temperature blender with magnetic force and is stirred continuously, with weight concentration 3.0% Sodium hydroxide solution controls pH value of reaction system and is initially added into acetic anhydride after 8.0 ~ 8.4, about 30min, in 10min slowly It is homogeneously added into the acetic anhydride of 4ml, is mixed well, is kept stirring, reaction after a certain period of time, is neutralized to the hydrochloric acid of 0.5mo/L Then pH=6.5 are filtered in bottle,suction with Buchner funnel, are washed with distilled water filter cake, after being examined with silver nitrate without chloride ion, It removes filter cake to be dissolved in 500mL beaker with distilled water, refilter after mixing evenly, 3 times repeatedly, put 45 DEG C of people's constant temperature oven drying For 24 hours, it crushes, screen obtains modified starch.
Further, the pearl powder is the mixture of mica titanium perlatolic powder, pearl powder, zinnwaldite powder.
A kind of degradable bionical simulation attracting plug material, preparation method includes the following steps: (1) the poly- hydroxyl of precise 25 parts of base alkyl acid rouge, 27 parts of poly-epsilon-caprolactone, 19 parts of gelatin, 38 parts of modified starch, 16 parts of glycerol, 12 parts of phagostimulant, sesame Oily 0.8 part, 0.8 part of pigment, 0.8 part of Radix et Caulis Opuntiae Dillenii extract, 3 parts of calcium carbonate, 1.5 parts of pearl powder, 0.8 part of crosslinking agent;(2) will claim Measured poly- hydroxy alkyl acid rouge, poly-epsilon-caprolactone, gelatin, modified starch, glycerol, phagostimulant, sesame oil, pigment, calcium carbonate, Obtain mixed powder;(3) mixed powder and Radix et Caulis Opuntiae Dillenii extract, calcium carbonate, pearl powder, crosslinking agent put into mixing 5 in mixer ~ 10 minutes, mixer set temperature was 100 DEG C ~ 160 DEG C;(4) by the material being kneaded in compression molding agent hot-forming, mould Pressure temperature is set as 130 DEG C ~ 160 DEG C, and molding pressure is 25MPa ~ 55MPa.
Embodiment 2
A kind of degradable bionical simulation attracting plug material, is composed of the following parts by weight: poly- hydroxy alkyl acid rouge 22 Part, 24 parts of poly-epsilon-caprolactone, 19 parts of gelatin, 31 parts of modified starch, 12 parts of glycerol, 12 parts of phagostimulant, 1 part of sesame oil, pigment 1 Part, 1 part of Radix et Caulis Opuntiae Dillenii extract, 3 parts of calcium carbonate, 1.5 parts of pearl powder, 0.8 part of crosslinking agent.
Further, the phagostimulant is made of the component of following parts by weight: the food bait is fish raw meat Powder, drosophila powder, blood red worm powder, grub powder, fly pupa powder, hawkmoth powder, river snails rice noodle, earthworm powder, ginger powder, locust powder, gadfly powder, beans The dregs of rice, dried silkworm chrysalis meal, amino acid, meat maggot powder, ground cinnamon, spice, lard it is one of or several.
Further, the modified starch is starch through 105 DEG C of dry 4h, weigh 36 parts of dried starch samples in In mouth bottle, it is made into the starch milk of mass concentration 40%, is placed in constant temperature blender with magnetic force and is stirred continuously, with weight concentration 3.0% Sodium hydroxide solution controls pH value of reaction system and is initially added into acetic anhydride after 8.0 ~ 8.4, about 30min, in 10min slowly It is homogeneously added into the acetic anhydride of 4ml, is mixed well, is kept stirring, reaction after a certain period of time, is neutralized to the hydrochloric acid of 0.5mo/L Then pH=6.5 are filtered in bottle,suction with Buchner funnel, are washed with distilled water filter cake, after being examined with silver nitrate without chloride ion, It removes filter cake to be dissolved in 500mL beaker with distilled water, refilter after mixing evenly, 3 times repeatedly, put 45 DEG C of people's constant temperature oven drying For 24 hours, it crushes, screen obtains modified starch.
Further, the pearl powder is the mixture of mica titanium perlatolic powder, pearl powder, zinnwaldite powder.
A kind of degradable bionical simulation attracting plug material, preparation method includes the following steps: (1) the poly- hydroxyl of precise 22 parts of base alkyl acid rouge, 24 parts of poly-epsilon-caprolactone, 19 parts of gelatin, 31 parts of modified starch, 12 parts of glycerol, 12 parts of phagostimulant, sesame Oily 1 part, 1 part of pigment, 1 part of Radix et Caulis Opuntiae Dillenii extract, 3 parts of calcium carbonate, 1.5 parts of pearl powder, 0.8 part of crosslinking agent;It (2) will be load weighted Poly- hydroxy alkyl acid rouge, poly-epsilon-caprolactone, gelatin, modified starch, glycerol, phagostimulant, sesame oil, pigment, calcium carbonate, must mix Powder;(3) mixed powder and Radix et Caulis Opuntiae Dillenii extract, calcium carbonate, pearl powder, crosslinking agent put into 5 ~ 10 points of mixing in mixer Clock, mixer set temperature are 100 DEG C ~ 160 DEG C;(4) material being kneaded is hot-forming in compression molding agent, molding temperature Degree is set as 130 DEG C ~ 160 DEG C, and molding pressure is 25MPa ~ 55MPa.
Comparative example 1
This comparative example compared with Example 2, weighs in step in raw material, saves modified starch component, method and step in addition to this It is all the same.
Comparative example 2
This comparative example compared with Example 2, weighs in step in raw material, saves food bait ingredient, method step in addition to this It is rapid all the same.
Comparative example 3
This comparative example compared with Example 2, weighs in step in raw material, saves poly- hydroxy alkyl acid rouge ingredient, side in addition to this Method step is all the same.
Comparative example 4
This comparative example compared with Example 2, weighs in step in raw material, saves poly-epsilon-caprolactone ingredient, method step in addition to this It is rapid all the same.
The performance test results of bionic fish bait material prepared by each embodiment and comparative example of table 1
Note: above-mentioned obtained each group fishnet line Compost Biodegradation experiment: is subjected to compost degradation according to GB/T 19277.2-2013 It tests, strict temperature control, moisture is wanted in experimentation, and test period is 40 days.Fish, which lures, draws rate use, launches into static state The number of the various type fishes of bait accounts for the waters total species purpose percentage, can be calculated.
The biodegradability of bionic fish bait made from treatment process of the present invention has obtained effectively it can be seen from upper table 1 Improvement, while its tensile strength, elongation at break, control are preferably, can be very nearly the same with originality.Fish are easier to rise to the bait, temptation Power is strong, and effect is obvious.It is prepared using Wholly-degradable material, simple process and low cost, can reach fully bio-degradable, thus material system The bait of standby fishes and shrimps form, it is environmentally protective, it is easy to operate, there is experience abundant without angler, it is easy to learn, by bionic fish bait Investment fishes point, saves the time, improves fish quantity of the catch, greatly improves and catch fishing efficiency.

Claims (5)

1. a kind of degradable bionical simulation attracting plug material, which is characterized in that be composed of the following parts by weight: poly- hydroxyl 5 ~ 27 parts of base alkyl acid rouge, 7 ~ 31 parts of poly-epsilon-caprolactone, 11 ~ 23 parts of gelatin, 27 ~ 51 parts of modified starch, 7 ~ 19 parts of glycerol, food calling 11 ~ 13 parts of agent, 0.5 ~ 1 part of sesame oil, 0.5 ~ 1 part of pigment, 0.5 ~ 1 part of Radix et Caulis Opuntiae Dillenii extract, 2 ~ 4 parts of calcium carbonate, pearl powder 1 ~ 2 Part, 0.5 ~ 1 part of crosslinking agent.
2. a kind of degradable bionical simulation attracting plug material according to claim 1, which is characterized in that the food calling Agent is made of the component of following parts by weight: the food bait is fish raw meat powder, drosophila powder, blood red worm powder, grub powder, fly Pupa powder, hawkmoth powder, river snails rice noodle, earthworm powder, ginger powder, locust powder, gadfly powder, dregs of beans, dried silkworm chrysalis meal, amino acid, meat maggot powder, cortex cinnamomi Powder, spice, lard it is one of or several.
3. a kind of degradable bionical simulation attracting plug material according to claim 1, the modified starch is starch Through 105 DEG C of dry 4h, 36 parts of dried starch samples are weighed in mouth bottle, the starch milk of mass concentration 40% is made into, is placed on perseverance It is stirred continuously on warm magnetic stirring apparatus, pH value of reaction system is controlled 8.0 with the sodium hydroxide solution of weight concentration 3.0% ~ It is initially added into acetic anhydride after 8.4, about 30min, the acetic anhydride of 4ml is slowly homogeneously added into 10min, is mixed well, is kept Stirring, reaction after a certain period of time, are neutralized to pH=6.5 with the hydrochloric acid of 0.5mo/L, are then filtered in bottle,suction with Buchner funnel, It is washed with distilled water filter cake, after being examined with silver nitrate without chloride ion, filter cake is removed and is dissolved in 500mL beaker with distilled water, is stirred It is refiltered after uniformly, 3 times repeatedly, puts 45 DEG C of people's constant temperature oven drying for 24 hours, crush, screen obtains modified starch.
4. a kind of degradable bionical simulation attracting plug material according to claim 1, the pearl powder is mica titanium Pearl powder, pearl powder, zinnwaldite powder mixture.
5. a kind of degradable bionical simulation attracting plug material according to claim 1, which is characterized in that preparation method The following steps are included: 5 ~ 27 parts of the poly- hydroxy alkyl acid rouge of (1) precise, 7 ~ 31 parts of poly-epsilon-caprolactone, 11 ~ 23 parts of gelatin, changing Property 27 ~ 51 parts of starch, 7 ~ 19 parts of glycerol, 11 ~ 13 parts of phagostimulant, 0.5 ~ 1 part of sesame oil, 0.5 ~ 1 part of pigment, Radix et Caulis Opuntiae Dillenii extract 0.5 ~ 1 part, 2 ~ 4 parts of calcium carbonate, 1 ~ 2 part of pearl powder, 0.5 ~ 1 part of crosslinking agent;(2) by load weighted poly- hydroxy alkyl acid rouge, poly- 6-caprolactone, gelatin, modified starch, glycerol, phagostimulant, sesame oil, pigment, calcium carbonate, obtain mixed powder;(3) mixed powder Mixing 5 ~ 10 minutes in mixer, mixer set temperature are put into Radix et Caulis Opuntiae Dillenii extract, calcium carbonate, pearl powder, crosslinking agent It is 100 DEG C ~ 160 DEG C;(4) material being kneaded is hot-forming in compression molding agent, molding temperature is set as 130 DEG C ~ 160 DEG C, molding pressure is 25MPa ~ 55MPa.
CN201810938020.1A 2018-08-17 2018-08-17 A kind of degradable bionical simulation attracting plug material Pending CN108935356A (en)

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101525480A (en) * 2008-07-20 2009-09-09 集伍国际控股集团有限公司 Biodegradable synthetic bait and preparation method thereof
CN104304205A (en) * 2014-09-03 2015-01-28 界首市猎钓渔具有限公司 Food-grade safe biomimetic simulated fish bait capable of being completely degraded
CN106398067A (en) * 2016-08-30 2017-02-15 界首市猎钓渔具有限公司 Green degradable water-soluble PVA (Polyvinyl Acetate) bionic bait
CN108285497A (en) * 2017-12-26 2018-07-17 吉林中粮生化有限公司 A kind of preparation method of acetate starch

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101525480A (en) * 2008-07-20 2009-09-09 集伍国际控股集团有限公司 Biodegradable synthetic bait and preparation method thereof
CN104304205A (en) * 2014-09-03 2015-01-28 界首市猎钓渔具有限公司 Food-grade safe biomimetic simulated fish bait capable of being completely degraded
CN106398067A (en) * 2016-08-30 2017-02-15 界首市猎钓渔具有限公司 Green degradable water-soluble PVA (Polyvinyl Acetate) bionic bait
CN108285497A (en) * 2017-12-26 2018-07-17 吉林中粮生化有限公司 A kind of preparation method of acetate starch

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