CN108930194A - A kind of UV glazing fluid composition - Google Patents

A kind of UV glazing fluid composition Download PDF

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Publication number
CN108930194A
CN108930194A CN201710368037.3A CN201710368037A CN108930194A CN 108930194 A CN108930194 A CN 108930194A CN 201710368037 A CN201710368037 A CN 201710368037A CN 108930194 A CN108930194 A CN 108930194A
Authority
CN
China
Prior art keywords
fluid composition
glazing
glazing fluid
reaction monomers
composition
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710368037.3A
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Chinese (zh)
Inventor
徐月香
孙亚文
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hui Yue Electronic Materials (shanghai) Co Ltd
Original Assignee
Hui Yue Electronic Materials (shanghai) Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hui Yue Electronic Materials (shanghai) Co Ltd filed Critical Hui Yue Electronic Materials (shanghai) Co Ltd
Priority to CN201710368037.3A priority Critical patent/CN108930194A/en
Publication of CN108930194A publication Critical patent/CN108930194A/en
Pending legal-status Critical Current

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Classifications

    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00Coated paper; Coating material
    • D21H19/36Coatings with pigments
    • D21H19/44Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
    • D21H19/62Macromolecular organic compounds or oligomers thereof obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00Coated paper; Coating material
    • D21H19/36Coatings with pigments
    • D21H19/44Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
    • D21H19/46Non-macromolecular organic compounds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Paints Or Removers (AREA)

Abstract

The present invention relates to paper product surface treatment more particularly to a kind of glazing fluid compositions.A kind of UV glazing fluid composition, it includes following weight percents:Polyurethane acroleic acid oligomer, 40-60;Reaction monomers iso-bornyl acrylate, 20-30;Reaction monomers trimethylolpropene acid esters, 5-10;Defoaming agent, moral modest 6800,0.2-0.5;Photoinitiator 184,2-6;Levelling agent BYK-333,0.1-0.3.Composition of the invention is able to satisfy requirement, and color saturation is good and glossiness is high.

Description

A kind of UV glazing fluid composition
Technical field
The present invention relates to paper product surface treatment more particularly to a kind of glazing fluid compositions.
Background technique
Since facsimile art, printing technique occur, people put forward new requirements paper used, usually require Paper side is uneven surface, and another side is smooth surface.
Lamination technology is able to satisfy certain requirement, this paper can in smooth surface printing color pattern, but print Pattern, which is easy impaired dampness, to be caused lossless, requires large-scale lamination equipment, investment is huge.
Film coating technique is also a solution, this is to stamp colour image in advance on paper, then cover PE, PVC, The materials such as PU, but paper is easy to turn yellow, and encounters high temperature place, easily adhesion, the amendment in addition, this mode can not do over again, wave Fei great.
It is former gradually to start substitution for the property that there is UV oil polish at low cost, glossiness and adhesive force to increase There is mode, but the producer that existing product has adds diluent, influence performance to further reduce the cost;Some products Color saturation is insufficient, causes paper product surface gloss inadequate.
Summary of the invention
The present invention is directed to overcome the drawbacks described above of the prior art, it is to provide a kind of UV glazing fluid composition.Group of the invention It closes object and is able to satisfy requirement, color saturation is good and glossiness is high.
A kind of UV glazing fluid composition of the present invention, which is characterized in that it includes following weight percents:
Polyurethane acroleic acid oligomer, 40-60;
Reaction monomers iso-bornyl acrylate, 20-30;
Reaction monomers trimethylolpropene acid esters, 5-10;
Defoaming agent, moral modest 6800,0.2-0.5;
Photoinitiator 184,2-6;
Levelling agent BYK-333,0.1-0.3.
A kind of UV glazing fluid composition, it further includes the anti-reflection agent of 0.2-0.3.
A kind of UV glazing fluid composition, the specific gravity 0.8 ~ 1.0 of the polyurethane acroleic acid oligomer, viscosity 2000~3500CPS。
A kind of UV glazing fluid composition, the composition condition of cure are 100 ~ 110 DEG C, 40 ~ 80 seconds, are done Pencil hardness 2H or more when dry is coated with after oil polish, 130 or more clarity, 60 degree of 90 or more glossiness.
A kind of UV glazing fluid composition, the refractive index after the composition solidifies are greater than 1.6.
A kind of UV glazing fluid composition, the oil polish method of the composition includes coating, dry, solidification step Suddenly.
A kind of UV glazing fluid composition, after being coated with oil polish, AR is perplexed in the reflection for exterior light<3%, in addition Color saturation △ E>4% or more;Surface tension reaches 95 ~ 110 degree or more, 100 ~ 150 degree of dust-proof grade with On.
Composition of the invention has firmly abandoned diluent, guarantees product quality.With iso-bornyl acrylate compounding three For hydroxymethyl acrylate as reaction monomers, 184 initiator surface dryings are fast;The present composition with macromolecular 10 ~ 15% and small The ratio that molecule 30 ~ 40% adds, to reach the degree of polymerization appropriate, because it also must be noted that equilibrating to cohesive force and surface tension Effect, the phenomenon that can be only achieved Self-leveling, and the result of surface-brightening degree and hardness after solidifying.Group of the invention The index of refraction after object guarantee product solidifies is closed 1.6 or more, is more than crystal, so that sheet gloss is good, adhesive force is good, levelability Good, clarity is high, and pencil hardness reaches 2H or more, and surface tension, water proof and dust proof is antifouling, color saturation, quickly solid Change, processing procedure is not simply cumbersome.
Specific embodiment:
A kind of UV glazing fluid composition of invention, it includes following weight percents:
Polyurethane acroleic acid oligomer, 40-60;
Reaction monomers iso-bornyl acrylate, 20-30;
Reaction monomers trimethylolpropene acid esters, 5-10;
Defoaming agent, moral modest 6800,0.2-0.5;
Photoinitiator 184,2-6;
Levelling agent BYK-333,0.1-0.3.
A kind of UV glazing fluid composition, it further includes the anti-reflection agent of 0.2-0.3.
Embodiment 1:Composition of the invention includes
Polyurethane acroleic acid oligomer, 40-60;
Reaction monomers iso-bornyl acrylate, 20-30;
Reaction monomers trimethylolpropene acid esters, 5-10;
Defoaming agent, moral modest 6800,0.2-0.5;
Photoinitiator 184,2-6;
Levelling agent BYK-333,0.1-0.3.
Embodiment 2:Composition of the invention includes
Polyurethane acroleic acid oligomer, 40-60;
Reaction monomers iso-bornyl acrylate, 20-30;
Reaction monomers trimethylolpropene acid esters, 5-10;
Defoaming agent, moral modest 6800,0.2-0.5;
Photoinitiator 184,2-6;
Levelling agent BYK-333,0.1-0.3.
Embodiment 3:Composition of the invention includes
Polyurethane acroleic acid oligomer, 40-60;
Reaction monomers iso-bornyl acrylate, 20-30;
Reaction monomers trimethylolpropene acid esters, 5-10;
Defoaming agent, moral modest 6800,0.2-0.5;
Photoinitiator 184,2-6;
Levelling agent BYK-333,0.1-0.3.
Embodiment 4:Composition of the invention includes
Polyurethane acroleic acid oligomer, 40-60;
Reaction monomers iso-bornyl acrylate, 20-30;
Reaction monomers trimethylolpropene acid esters, 5-10;
Defoaming agent, moral modest 6800,0.2-0.5;
Photoinitiator 184,2-6;
Levelling agent BYK-333,0.1-0.3.
Embodiment 5:Composition of the invention includes
Polyurethane acroleic acid oligomer, 40-60;
Reaction monomers iso-bornyl acrylate, 20-30;
Reaction monomers trimethylolpropene acid esters, 5-10;
Defoaming agent, moral modest 6800,0.2-0.5;
Photoinitiator 184,2-6;
Levelling agent BYK-333,0.1-0.3..
Following table is the comparison of the coating method that composition of the invention selects and the prior art:
Each embodiment performance see the table below:
It will be clear to one skilled in the art that the technical solution of present embodiment description is only of the invention for understanding, without that should recognize To be the restriction to protection scope.Protection scope of the present invention should be defined by the following claims, any to weigh The deformation replacement done on the basis of the technical solution that sharp claim provides falls within the range that the claims in the present invention are protected.

Claims (7)

1. a kind of UV glazing fluid composition, which is characterized in that it includes following weight percents:
Polyurethane acroleic acid oligomer, 40-60;
Reaction monomers iso-bornyl acrylate, 20-30;
Reaction monomers trimethylolpropene acid esters, 5-10;
Defoaming agent, moral modest 6800,0.2-0.5;
Photoinitiator 184,2-6;
Levelling agent BYK-333,0.1-0.3.
2. a kind of UV glazing fluid composition according to claim 1, which is characterized in that it further includes the anti-reflective of 0.2-0.3 Penetrate agent.
3. a kind of UV glazing fluid composition according to claim 1, which is characterized in that the polyurethane acroleic acid oligomer Specific gravity 0.8 ~ 1.0,2000 ~ 3500CPS of viscosity.
4. a kind of UV glazing fluid composition according to claim 1, which is characterized in that the composition condition of cure is 100 ~ 110 DEG C, 40 ~ 80 seconds, pencil hardness 2H or more when dry was coated with after oil polish, 130 or more clarity, 60 degree of 90 or more glossiness.
5. a kind of UV glazing fluid composition according to claim 1, which is characterized in that the composition solidify after refraction Rate is greater than 1.6.
6. a kind of UV glazing fluid composition as described in claim 1, which is characterized in that the oil polish method packet of the composition Coating is included, dry, curing schedule.
7. a kind of UV glazing fluid composition as claimed in claim 6, which is characterized in that after coating oil polish, for exterior light Reflection perplex AR<3%, other color saturation △ E>4% or more;Face tension reaches 95 ~ 110 degree, dust-proof 100 ~ 150 degree of grade.
CN201710368037.3A 2017-05-23 2017-05-23 A kind of UV glazing fluid composition Pending CN108930194A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710368037.3A CN108930194A (en) 2017-05-23 2017-05-23 A kind of UV glazing fluid composition

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710368037.3A CN108930194A (en) 2017-05-23 2017-05-23 A kind of UV glazing fluid composition

Publications (1)

Publication Number Publication Date
CN108930194A true CN108930194A (en) 2018-12-04

Family

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Family Applications (1)

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CN201710368037.3A Pending CN108930194A (en) 2017-05-23 2017-05-23 A kind of UV glazing fluid composition

Country Status (1)

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CN (1) CN108930194A (en)

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102964969A (en) * 2012-11-14 2013-03-13 京东方科技集团股份有限公司 Ultraviolet curing light oil and preparation method and curing method thereof as well as touch screen
CN103074802A (en) * 2013-01-24 2013-05-01 陕西科技大学 Preparation method for ultraviolet curing water-based paper varnish
CN103146291A (en) * 2013-03-28 2013-06-12 京东方科技集团股份有限公司 Ultraviolet light solidification gloss oil and preparation method thereof
CN103194105A (en) * 2013-03-27 2013-07-10 佛山市天进塑胶有限公司 UV (Ultraviolet) gloss oil, high-gloss scrap-resisting decorative film prepared from same and preparation method of decorative film

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102964969A (en) * 2012-11-14 2013-03-13 京东方科技集团股份有限公司 Ultraviolet curing light oil and preparation method and curing method thereof as well as touch screen
CN103074802A (en) * 2013-01-24 2013-05-01 陕西科技大学 Preparation method for ultraviolet curing water-based paper varnish
CN103194105A (en) * 2013-03-27 2013-07-10 佛山市天进塑胶有限公司 UV (Ultraviolet) gloss oil, high-gloss scrap-resisting decorative film prepared from same and preparation method of decorative film
CN103146291A (en) * 2013-03-28 2013-06-12 京东方科技集团股份有限公司 Ultraviolet light solidification gloss oil and preparation method thereof

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Application publication date: 20181204