CN108929555A - A kind of high-performance composite materials and preparation method thereof suitable for window frame - Google Patents

A kind of high-performance composite materials and preparation method thereof suitable for window frame Download PDF

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Publication number
CN108929555A
CN108929555A CN201710374325.XA CN201710374325A CN108929555A CN 108929555 A CN108929555 A CN 108929555A CN 201710374325 A CN201710374325 A CN 201710374325A CN 108929555 A CN108929555 A CN 108929555A
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China
Prior art keywords
window frame
composite materials
parts
performance composite
weight
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Pending
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CN201710374325.XA
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Inventor
杨春才
尚祖睿
薛飞
张成勇
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Jiangsu Chong Cheng Composite Mstar Technology Ltd
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Jiangsu Chong Cheng Composite Mstar Technology Ltd
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Priority to CN201710374325.XA priority Critical patent/CN108929555A/en
Publication of CN108929555A publication Critical patent/CN108929555A/en
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
    • C08K13/04—Ingredients characterised by their shape and organic or inorganic ingredients
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C67/00—Shaping techniques not covered by groups B29C39/00 - B29C65/00, B29C70/00 or B29C73/00
    • B29C67/24—Shaping techniques not covered by groups B29C39/00 - B29C65/00, B29C70/00 or B29C73/00 characterised by the choice of material
    • B29C67/242—Moulding mineral aggregates bonded with resin, e.g. resin concrete
    • B29C67/243—Moulding mineral aggregates bonded with resin, e.g. resin concrete for making articles of definite length
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24—Acids; Salts thereof
    • C08K3/26—Carbonates; Bicarbonates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/34—Silicon-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/34—Silicon-containing compounds
    • C08K3/346—Clay
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/14—Peroxides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00—Use of ingredients characterised by shape
    • C08K7/02—Fibres or whiskers
    • C08K7/04—Fibres or whiskers inorganic
    • C08K7/10—Silicon-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2227—Oxides; Hydroxides of metals of aluminium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2237—Oxides; Hydroxides of metals of titanium
    • C08K2003/2241—Titanium dioxide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2265—Oxides; Hydroxides of metals of iron
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2296—Oxides; Hydroxides of metals of zinc
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24—Acids; Salts thereof
    • C08K3/26—Carbonates; Bicarbonates
    • C08K2003/265—Calcium, strontium or barium carbonate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/08—Stabilised against heat, light or radiation or oxydation

Abstract

A kind of high-performance composite materials suitable for window frame, each component including following parts by weight：50~100 parts of resin, 0.01~0.1 part of infrared cutoff agent, 15~35 parts of filler, 0.3~3 part of curing agent, 1~5 part of ultraviolet light screener, 60~100 parts of basalt multiaxial fabric.The present invention discloses the preparation methods of the composite material, using pultrude process, using basalt fibre multiaxial fabric as reinforcement, matrix resin is immersed by impregnation technology, preformed, shaping mould carries out gel under the conditions of temperature appropriate and traction, solidification, solidifies the obtained high-performance composite materials for being suitable for window frame afterwards.The material high-strength light has very high specific modulus and specific strength, and good weatherability, price is very cheap, and the toughness of material is very good, will not generate destruction when by high wind or external impacts.

Description

A kind of high-performance composite materials and preparation method thereof suitable for window frame
Technical field
The invention belongs to structure materials, specially a kind of suitable for the high-performance composite materials of window frame and its preparation side Method.
Background technique
Door and window is a component common in building, and the public places such as office, house and market all can installation door Window.With the development of science and technology, intelligence, green building constantly cause the favor of people, this also window frame material traditional to us More stringent requirements are proposed for material.Frame material must have fire-retardant, heat preservation, the ageing-resistant and excellent performance such as high-intensitive.
Frame material mainly has three categories at present.One kind is aluminum alloy materials：The thermal conductivity of this material is very high, heat-insulated effect Fruit is bad, and the heat in winter house cracking can be lost to outdoor, and the heat outside summer room can conduct rapidly into interior, make Indoor temperature excursion.Moreover, the processing technology of aluminium alloy extrusions is more complicated, production process energy consumption is big, at high cost.It is another It is plastic material：This cost of material is low, material heat insulating ability, but its intensity is not high, anti-aging property is poor.There are also one Kind is using pultrude process, and with the composite material of glass fiber reinforcement unsaturated-resin, glass fibre is that unidirectional fibre adds glass Felt.This strength of materials is not high, and the resistance to ag(e)ing of unsaturated-resin is also not good enough, and heat insulation is general.
Summary of the invention
Poor, the plastic and glass fiber reinforcement unsaturated-resin material for solution aluminum alloy window frame heat insulation effect in the prior art The defect for the problems such as intensity of material is low, resistance to ag(e)ing is poor, the present invention provide a kind of high-performance composite materials suitable for window frame and Preparation method.
A kind of high-performance composite materials suitable for window frame, each component including following parts by weight：
Preferably, the resin is vinylite；Infrared cutoff agent is one or more of ITO, ATO, GTO.
Further, the filler is one of calcium carbonate, talcum powder, kaolin, aluminium hydroxide, mica powder or several Kind.
Further, the curing agent is methyl ethyl ketone peroxide, benzoyl peroxide, cyclohexanone peroxide, peroxidating One or more of the tert-butyl ester, isopropyl benzene hydroperoxide, tert-butyl hydroperoxide.
Further, the ultraviolet light screener is zinc oxide, iron oxide, titanium dioxide, one in UV326, UV531 Kind is several.
Further, the basalt multiaxial fabric be 2400tex, 4800tex, 9600tex biaxially, three axis To, it is four one or more of axial.
A kind of preparation method of the high-performance composite materials suitable for window frame, includes the following steps：
1), 50~100 parts by weight resin are placed in stirred tank, then thereto be added 0.3~3 parts by weight curing agent, 0.01~0.1 parts by weight infrared cutoff agent, 15-35 parts of filler material by weight, 1-5 parts by weight ultraviolet light screener fall after stirring 2~4h Enter in glue groove；
2), 60~100 parts by weight of basalt multiaxial fabric are placed on creel, warp thread plate enters glue groove dipping, later mistake After preforming tool setting into molding die, curing molding under the conditions of 60-150 DEG C.
Beneficial effect：The present invention passes through impregnation technology using basalt fibre multiaxial fabric as reinforcement using pultrude process Matrix resin is immersed, preformed mold, progress gel, solidification, rear solidification are made suitable under the conditions of temperature appropriate and traction It is suitable for the high-performance composite materials of window frame.The material high-strength light, have very high specific modulus and specific strength, good weatherability, more Estimable is that price is very cheap, and using green material basalt fibre, which is by single basalt mine Wire drawing produces after stone melts at high temperature, and it is real green product that product and production process are all nontoxic, I State's basalt ore is abundant, and lower cost for material, in addition basalt fibre anti-ultraviolet property is strong, substantially increases composite material Anti-aging property, due to having used multiaxial fabric, the toughness of material is very good, will not when by high wind or external impacts Generate destruction.
Specific embodiment
Embodiment 1
A kind of high-performance composite materials suitable for window frame, each component including following parts by weight：
The resin is vinylite；Infrared cutoff agent is ITO；The filler is kaolin；The solidification Agent is t-butylperbenzoate；The ultraviolet light screener is titanium dioxide；The basalt multiaxial fabric is 4800tex's Three axial cloth.
A kind of preparation method of the high-performance composite materials suitable for window frame, includes the following steps：
1), resin is placed in stirred tank, then curing agent, infrared cutoff agent, filler, ultraviolet screener are added thereto, It is poured into glue groove after 2~4h of stirring；
2), basalt multiaxial fabric is placed on creel, warp thread plate enters glue groove dipping, crosses preforming tool setting later Afterwards into molding die, curing molding under the conditions of 60 DEG C.
Embodiment 2
A kind of high-performance composite materials suitable for window frame, each component including following parts by weight：
Resin is vinylite；Infrared cutoff agent is the mixture of ATO and GTO；Filler is calcium carbonate and aluminium hydroxide Mixture；The curing agent is the mixture of methyl ethyl ketone peroxide and benzoyl peroxide；Ultraviolet light screener is oxidation The mixture of zinc and UV326；The basalt multiaxial fabric is mixing of the 2400tex biaxially with three axial directions of 9600tex Object.
A kind of preparation method of the high-performance composite materials suitable for window frame, includes the following steps：
1), resin is placed in stirred tank, then curing agent, infrared cutoff agent, filler, ultraviolet screener are added thereto, It is poured into glue groove after 2~4h of stirring；
2), basalt multiaxial fabric is placed on creel, warp thread plate enters glue groove dipping, crosses preforming tool setting later Afterwards into molding die, curing molding under the conditions of 150 DEG C.
Embodiment 3
A kind of high-performance composite materials suitable for window frame, each component including following parts by weight：
The resin is vinylite；Infrared cutoff agent is the mixture of ITO and GTO；The filler is carbonic acid The mixture of calcium, talcum powder and mica powder；The curing agent is the mixture of benzoyl peroxide and isopropyl benzene hydroperoxide； The ultraviolet light screener is the mixture in iron oxide and UV531；The basalt multiaxial fabric is the four of 9600tex Axial cloth.
A kind of preparation method of the high-performance composite materials suitable for window frame, includes the following steps：
1), resin is placed in stirred tank, then curing agent, infrared cutoff agent, filler, ultraviolet screener are added thereto, It is poured into glue groove after stirring 3h；
2), basalt multiaxial fabric is placed on creel, warp thread plate enters glue groove dipping, crosses preforming tool setting later Afterwards into molding die, curing molding under the conditions of 100 DEG C.

Claims (8)

1. a kind of high-performance composite materials suitable for window frame, which is characterized in that each component including following parts by weight：
2. being suitable for the high-performance composite materials of window frame as described in claim 1, which is characterized in that the resin is ethylene Base resin.
3. being suitable for the high-performance composite materials of window frame as claimed in claim 1 or 2, which is characterized in that described infrared section Only agent is one or more of ITO, ATO and GTO.
4. being suitable for the high-performance composite materials of window frame as claimed in claim 3, which is characterized in that the filler is carbonic acid One or more of calcium, talcum powder, kaolin, aluminium hydroxide and mica powder.
5. being suitable for the high-performance composite materials of window frame as described in claim 1, which is characterized in that the curing agent was Methyl Ethyl Ketone Oxidation, benzoyl peroxide, cyclohexanone peroxide, t-butylperbenzoate, isopropyl benzene hydroperoxide and t-butyl peroxy Change one or more of hydrogen.
6. being suitable for the high-performance composite materials of window frame as described in claim 4 or 5, which is characterized in that the ultraviolet light Screener is one or more of zinc oxide, iron oxide, titanium dioxide, UV326 and UV531.
7. being suitable for the high-performance composite materials of window frame as described in claim 1, which is characterized in that the basalt multiaxis To cloth be 2400tex, 4800tex and 9600tex biaxially, it is three axial, four one or more of axial.
8. a kind of preparation method of the high-performance composite materials suitable for window frame, which is characterized in that include the following steps：
1), 50~100 parts by weight resin are placed in stirred tank, then thereto be added 0.3~3 parts by weight curing agent, 0.01~ 0.1 parts by weight infrared cutoff agent, 15-35 parts of filler material by weight, 1-5 parts by weight ultraviolet light screener pour into glue groove after stirring 2~4h In；
2), 60~100 parts by weight of basalt multiaxial fabric are placed on creel, warp thread plate enter glue groove dipping, later excessively in advance at After pattern tool setting into molding die, curing molding under the conditions of 60-150 DEG C.
CN201710374325.XA 2017-05-24 2017-05-24 A kind of high-performance composite materials and preparation method thereof suitable for window frame Pending CN108929555A (en)

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Publication number Priority date Publication date Assignee Title
CN1421310A (en) * 2001-11-28 2003-06-04 周献刚 Method of producing door and window with basalt fiber reinforced material
CN102514306A (en) * 2011-12-12 2012-06-27 青岛科瑞新型环保材料有限公司 Composite sheet material and preparation method thereof
CN103819886A (en) * 2014-01-16 2014-05-28 安徽梦谷纤维材料科技有限公司 Hybrid fiber composite material door/window section and preparation process thereof
CN104328841A (en) * 2014-09-23 2015-02-04 青岛文创科技有限公司 Anti-radiation vacuum insulation panel and preparation method
CN104761880A (en) * 2015-03-17 2015-07-08 哈尔滨工程大学 Short-fiber-reinforced pultrusion composite material solar energy assembly frame and preparation method thereof
CN106243631A (en) * 2016-07-30 2016-12-21 山西晋投玄武岩开发有限公司 The basalt fibre of a kind of pultrusion strengthens composite of thermosetting resin and preparation method thereof
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CN102514306A (en) * 2011-12-12 2012-06-27 青岛科瑞新型环保材料有限公司 Composite sheet material and preparation method thereof
CN103819886A (en) * 2014-01-16 2014-05-28 安徽梦谷纤维材料科技有限公司 Hybrid fiber composite material door/window section and preparation process thereof
CN104328841A (en) * 2014-09-23 2015-02-04 青岛文创科技有限公司 Anti-radiation vacuum insulation panel and preparation method
CN104761880A (en) * 2015-03-17 2015-07-08 哈尔滨工程大学 Short-fiber-reinforced pultrusion composite material solar energy assembly frame and preparation method thereof
CN106243631A (en) * 2016-07-30 2016-12-21 山西晋投玄武岩开发有限公司 The basalt fibre of a kind of pultrusion strengthens composite of thermosetting resin and preparation method thereof
CN106589839A (en) * 2017-02-21 2017-04-26 东南大学 High-alkali-salt-corrosion-resistance basalt fiber composite

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