CN108927290B - Coal dressing collector and preparation method thereof - Google Patents
Coal dressing collector and preparation method thereof Download PDFInfo
- Publication number
- CN108927290B CN108927290B CN201711378210.4A CN201711378210A CN108927290B CN 108927290 B CN108927290 B CN 108927290B CN 201711378210 A CN201711378210 A CN 201711378210A CN 108927290 B CN108927290 B CN 108927290B
- Authority
- CN
- China
- Prior art keywords
- coal
- raw materials
- glyceride
- oil
- squalene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000003245 coal Substances 0.000 title claims abstract description 60
- 238000002360 preparation method Methods 0.000 title abstract description 16
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims abstract description 56
- 239000002994 raw material Substances 0.000 claims abstract description 33
- 239000004215 Carbon black (E152) Substances 0.000 claims abstract description 28
- BHEOSNUKNHRBNM-UHFFFAOYSA-N Tetramethylsqualene Natural products CC(=C)C(C)CCC(=C)C(C)CCC(C)=CCCC=C(C)CCC(C)C(=C)CCC(C)C(C)=C BHEOSNUKNHRBNM-UHFFFAOYSA-N 0.000 claims abstract description 28
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N dodecahydrosqualene Natural products CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 claims abstract description 28
- 229930195733 hydrocarbon Natural products 0.000 claims abstract description 28
- 150000002430 hydrocarbons Chemical class 0.000 claims abstract description 28
- 229940031439 squalene Drugs 0.000 claims abstract description 28
- TUHBEKDERLKLEC-UHFFFAOYSA-N squalene Natural products CC(=CCCC(=CCCC(=CCCC=C(/C)CCC=C(/C)CC=C(C)C)C)C)C TUHBEKDERLKLEC-UHFFFAOYSA-N 0.000 claims abstract description 28
- 238000003756 stirring Methods 0.000 claims abstract description 20
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 17
- 239000000203 mixture Substances 0.000 claims abstract description 17
- 229930182558 Sterol Natural products 0.000 claims abstract description 16
- 235000003702 sterols Nutrition 0.000 claims abstract description 16
- 238000005303 weighing Methods 0.000 claims abstract description 10
- 239000003921 oil Substances 0.000 claims description 29
- 235000019198 oils Nutrition 0.000 claims description 29
- 235000015112 vegetable and seed oil Nutrition 0.000 claims description 15
- 239000008158 vegetable oil Substances 0.000 claims description 15
- -1 squalene fatty ester Chemical class 0.000 claims description 8
- 235000019438 castor oil Nutrition 0.000 claims description 7
- 239000004359 castor oil Substances 0.000 claims description 7
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims description 7
- 238000010438 heat treatment Methods 0.000 claims description 7
- 235000019483 Peanut oil Nutrition 0.000 claims description 4
- 235000019774 Rice Bran oil Nutrition 0.000 claims description 4
- 238000004821 distillation Methods 0.000 claims description 4
- 238000000605 extraction Methods 0.000 claims description 4
- 125000005456 glyceride group Chemical group 0.000 claims description 4
- 239000000312 peanut oil Substances 0.000 claims description 4
- 239000003208 petroleum Substances 0.000 claims description 4
- 239000008165 rice bran oil Substances 0.000 claims description 4
- 239000002253 acid Substances 0.000 claims description 2
- 238000000034 method Methods 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 11
- 238000011084 recovery Methods 0.000 abstract description 10
- 239000008396 flotation agent Substances 0.000 abstract description 3
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 3
- 230000007613 environmental effect Effects 0.000 abstract description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 19
- 229930195729 fatty acid Natural products 0.000 description 19
- 239000000194 fatty acid Substances 0.000 description 19
- 125000003976 glyceryl group Chemical group [H]C([*])([H])C(O[H])([H])C(O[H])([H])[H] 0.000 description 11
- 238000005188 flotation Methods 0.000 description 7
- VZJHQHUOVIDRCF-BIGJJFBESA-N dnc014787 Chemical compound C1CCC(C)(C)[C@H]2[C@@H]3CC[C@H]2[C@@]1(C)[C@H]3CO VZJHQHUOVIDRCF-BIGJJFBESA-N 0.000 description 5
- 239000003350 kerosene Substances 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- YYGNTYWPHWGJRM-UHFFFAOYSA-N (6E,10E,14E,18E)-2,6,10,15,19,23-hexamethyltetracosa-2,6,10,14,18,22-hexaene Chemical compound CC(C)=CCCC(C)=CCCC(C)=CCCC=C(C)CCC=C(C)CCC=C(C)C YYGNTYWPHWGJRM-UHFFFAOYSA-N 0.000 description 3
- 239000002283 diesel fuel Substances 0.000 description 3
- 229940049964 oleate Drugs 0.000 description 3
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 3
- 241000196324 Embryophyta Species 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000003250 coal slurry Substances 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 239000004088 foaming agent Substances 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 239000003209 petroleum derivative Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D1/00—Flotation
- B03D1/001—Flotation agents
- B03D1/004—Organic compounds
- B03D1/008—Organic compounds containing oxygen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D2201/00—Specified effects produced by the flotation agents
- B03D2201/02—Collectors
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D2203/00—Specified materials treated by the flotation agents; Specified applications
- B03D2203/02—Ores
- B03D2203/04—Non-sulfide ores
- B03D2203/08—Coal ores, fly ash or soot
Landscapes
- Edible Oils And Fats (AREA)
- Solid Fuels And Fuel-Associated Substances (AREA)
- Fats And Perfumes (AREA)
Abstract
The invention provides a coal dressing collecting agent and a preparation method thereof, belongs to the technical field of coal flotation agents, and aims to solve the technical problems of poor dispersibility in water, poor collecting effect, low recovery rate of clean coal, danger, high production cost and the like of the conventional collecting agent. The coal dressing collecting agent consists of the following raw materials in parts by weight: 5-15% of squalene glyceride, 10-25% of sterol glyceride, 10-30% of isolongifolan ethyl ether and 30-65% of hydrocarbon oil mixture of C7-C16. The preparation method comprises the following steps: step 1, weighing the raw materials in parts by weight; step 2, putting the raw materials weighed in the step 1 into a reaction kettle for stirring, wherein the temperature in the reaction kettle is 10-40 ℃, and the rotating speed during stirring is 20-60 r/min; and 3, storing the stirred product into a finished product tank. The invention has the advantages of higher safety coefficient, convenient use, good collecting effect, high recovery rate of clean coal, capability of improving the ash content of the tail coal, environmental protection and the like.
Description
Technical Field
The invention relates to the technical field of coal flotation agents, in particular to a coal dressing collecting agent and a preparation method thereof.
Background
In the coal flotation stage, 0-0.4mm fine coal slime is contacted and adsorbed with a collecting agent and a foaming agent, the fine coal slime is throttled and aspirated by a mineralizer to form bubbles, hydrophobic coal particles are attached to the bubbles and rise to a foam tank along with the bubbles to form concentrate, and hydrophilic gangue particles are discharged from the lower part along with tailings, so that the separation effect is achieved. The collector is a flotation agent which changes the hydrophobicity of the surface of the mineral and enables floating mineral particles to be adhered to the air bubbles. The collector plays a crucial role in the flotation yield of the clean coal.
Most of the current collectors are petroleum products, mainly including kerosene, diesel oil and some artificially synthesized non-polar oil collectors. However, because of poor dispersibility of kerosene and diesel oil in water, an adsorption film formed on coal slime particles is incomplete, the hydrophobicity is not ideal, and the separation effect is poor; meanwhile, the kerosene and the diesel oil are flammable and explosive dangerous goods, so that the danger is high and the use is inconvenient; the nonpolar oil collecting agent has low activity in the coal preparation process, large medicament dosage, poor collecting effect, high production cost and low recovery rate of clean coal.
Disclosure of Invention
The invention aims to solve the technical problems of poor dispersibility in water, poor collecting effect, low recovery rate of clean coal, danger, high production cost and the like of the conventional collecting agent and provides a coal dressing collecting agent and a preparation method thereof.
In order to solve the technical problems, the invention adopts the technical scheme that:
a coal dressing collecting agent is composed of the following raw materials in parts by weight: 5-15% of squalene glyceride, 10-25% of sterol glyceride, 10-30% of isolongifolan ethyl ether and 30-65% of hydrocarbon oil mixture of C7-C16.
A preparation method of a coal dressing collector comprises the following steps:
step 1, weighing the following raw materials in parts by weight: 5-15% of squalene glyceride, 10-25% of sterol glyceride, 10-30% of isolongifolan ethyl ether and 30-65% of hydrocarbon oil of C7-C16;
step 2, putting the raw materials weighed in the step 1 into a reaction kettle for stirring, wherein the temperature in the reaction kettle is 10-40 ℃, and the rotating speed during stirring is 20-60 r/min;
and 3, storing the stirred product into a finished product tank.
Further, the squalene fatty acid glyceride is a fraction extracted by heating vegetable oil to 220-270 ℃ and having a density of 0.95-0.98 g/cm 3; the sterene glyceride is a fraction extracted by heating vegetable oil to 160-190 ℃ and having a density of 0.92-0.95 g/cm 3; the isolongifolyl ethyl ether is a fraction which is extracted by heating vegetable oil to 120-150 ℃ and has a density of 0.89-0.93 g/cm 3; the mixture of the hydrocarbon oil of C7-C16 is a product extracted from petroleum, the density of the product is 0.85-0.87 g/cm3, and the distillation range of the product is 100-300 ℃.
Further, the vegetable oil is rice bran oil, peanut oil or castor oil.
The invention has the beneficial effects that:
the invention adopts non-flammable raw materials, so the safety coefficient is higher and the use is convenient. In addition, the raw materials in the invention are cheap, so that the coal dressing collector has lower cost. Industrial tests show that the coal dressing collecting effect is good, the recovery rate of clean coal is high, and the ash content of the tail coal can be improved. In addition, the invention adopts environment-friendly raw materials and has no pollution to the environment. Therefore, compared with the background art, the invention has the advantages of higher safety coefficient, convenient use, good collecting effect, high clean coal recovery rate, capability of improving the ash content of the tail coal, environmental protection and the like.
Detailed Description
The present invention will be described in further detail with reference to examples.
Example 1
The coal dressing collecting agent in the embodiment is composed of the following raw materials in parts by weight: 5-15% of squalene glyceride, 10-25% of sterol glyceride, 10-30% of isolongifolan ethyl ether and 30-65% of hydrocarbon oil mixture of C7-C16.
Wherein the squalene fatty ester is vegetable oil heated to 220-270 deg.C, and has extraction density of 0.95-0.98 g/cm3A fraction of (a); the steryl olefine acid glyceride is vegetable oil which is heated to 160-190 ℃ and the density of extraction is 0.92-0.95 g/cm3A fraction of (a); the isolongifolyl ethyl ether is extracted by heating vegetable oil to 120-150 ℃ and the density of the extracted vegetable oil is 0.89-0.93 g/cm3A fraction of (a); the mixture of the C7-C16 hydrocarbon oil is extracted from petroleum and has the density of 0.85-0.87 g/cm3And the distillation range is 100-300 ℃. Optionally, the vegetable oil is rice bran oil, peanut oil or castor oil.
The preparation method of the coal dressing collector in the embodiment comprises the following steps:
step 1, weighing the following raw materials in parts by weight: 5-15% of squalene glyceride, 10-25% of sterol glyceride, 10-30% of isolongifolan ethyl ether and 30-65% of hydrocarbon oil mixture of C7-C16;
step 2, putting the raw materials weighed in the step 1 into a reaction kettle for stirring, wherein the temperature in the reaction kettle is 10-40 ℃, and the rotating speed during stirring is 20-60 r/min;
and 3, storing the stirred product into a finished product tank.
The preparation process adopts an electronic numerical control system, can automatically control parameters such as reaction temperature, time, rotating speed and the like, and is convenient for automatic control.
Example 2
The coal dressing collecting agent in the embodiment is composed of the following raw materials in parts by weight: 5% of squalene fatty acid glyceride, 10% of sterol fatty acid glyceride, 20% of isolongifolan ethyl ether and 65% of hydrocarbon oil of C7-C16.
The preparation method of the coal dressing collector in the embodiment comprises the following steps:
step 1, weighing the following raw materials in parts by weight: 5% of squalene fatty acid glyceride, 10% of sterol fatty acid glyceride, 20% of isolongifolan ethyl ether and 65% of hydrocarbon oil of C7-C16;
step 2, putting the raw materials weighed in the step 1 into a reaction kettle for stirring, wherein the temperature in the reaction kettle is 10 ℃, and the rotating speed during stirring is 20 r/min;
and 3, storing the stirred product into a finished product tank.
The squalene fatty ester is prepared by heating castor oil to 220-270 deg.C, and extracting to density of 0.95-0.98 g/cm3A fraction of (a); the steryl glyceride is castor oil which is heated to 160-190 ℃ and extracted at the density of 0.92-0.95 g/cm3A fraction of (a); the isolongifolyl ethyl ether is extracted by heating castor oil to 120-150 ℃ and has the density of 0.89-0.93 g/cm3A fraction of (a); the mixture of the C7-C16 hydrocarbon oil is extracted from petroleum and has the density of 0.85-0.87 g/cm3And the distillation range is 100-300 ℃. Optionally, the vegetable oil is rice bran oil, peanut oil or castor oil.
Example 3
The coal dressing collecting agent in the embodiment is composed of the following raw materials in parts by weight: 15% of squalene fatty acid glyceride, 25% of sterol fatty acid glyceride, 30% of isolongifolan ethyl ether and 30% of hydrocarbon oil of C7-C16.
The preparation method of the coal dressing collector in the embodiment comprises the following steps of 1:
step 1, weighing the following raw materials in parts by weight: 15% of squalene fatty acid glyceride, 25% of sterol fatty acid glyceride, 30% of isolongifolan ethyl ether and 30% of hydrocarbon oil of C7-C16;
step 2, putting the raw materials weighed in the step 1 into a reaction kettle for stirring, wherein the temperature in the reaction kettle is 40 ℃, and the rotating speed during stirring is 60 r/min;
and 3, storing the stirred product into a finished product tank.
The mixture of glyceryl squalene, glyceryl sterenoate, isolongifolol ethyl ether and hydrocarbon oil C7-C16 was the same as in example 2.
Example 4
The coal dressing collecting agent in the embodiment is composed of the following raw materials in parts by weight: 10% of glyceryl squalene oleate, 20% of glyceryl sterenoate, 20% of isolongifolan ethyl ether and 50% of a mixture of hydrocarbon oils of C7-C16.
The preparation method of the coal dressing collector in the embodiment comprises the following steps of 1:
step 1, weighing the following raw materials in parts by weight: 10% of squalene fatty acid glyceride, 20% of sterol fatty acid glyceride, 20% of isolongifolan ethyl ether and 50% of hydrocarbon oil of C7-C16;
step 2, putting the raw materials weighed in the step 1 into a reaction kettle for stirring, wherein the temperature in the reaction kettle is 30 ℃, and the rotating speed during stirring is 50 r/min;
and 3, storing the stirred product into a finished product tank.
The mixture of glyceryl squalene, glyceryl sterenoate, isolongifolol ethyl ether and hydrocarbon oil C7-C16 was the same as in example 2.
Example 5
The coal dressing collecting agent in the embodiment is composed of the following raw materials in parts by weight: 15% of squalene fatty acid glyceride, 10% of sterol fatty acid glyceride, 10% of isolongifolan ethyl ether and 65% of hydrocarbon oil of C7-C16.
The preparation method of the coal dressing collector in the embodiment comprises the following steps:
step 1, weighing the following raw materials in parts by weight: 15% of squalene fatty acid glyceride, 10% of sterol fatty acid glyceride, 10% of isolongifolan ethyl ether and 65% of hydrocarbon oil of C7-C16;
step 2, putting the raw materials weighed in the step 1 into a reaction kettle for stirring, wherein the temperature in the reaction kettle is 25 ℃, and the rotating speed during stirring is 30 r/min;
and 3, storing the stirred product into a finished product tank.
The mixture of glyceryl squalene, glyceryl sterenoate, isolongifolol ethyl ether and hydrocarbon oil C7-C16 was the same as in example 2.
Example 6
The coal dressing collecting agent in the embodiment is composed of the following raw materials in parts by weight: 10% of glyceryl squalene oleate, 25% of glyceryl sterenoate, 20% of isolongifolan ethyl ether and 45% of a mixture of hydrocarbon oils of C7-C16.
The preparation method of the coal dressing collector in the embodiment comprises the following steps:
step 1, weighing the following raw materials in parts by weight: 10% of squalene fatty acid glyceride, 25% of sterol fatty acid glyceride, 20% of isolongifolan ethyl ether and 45% of hydrocarbon oil of C7-C16;
step 2, putting the raw materials weighed in the step 1 into a reaction kettle for stirring, wherein the temperature in the reaction kettle is 20 ℃, and the rotating speed during stirring is 40 r/min;
and 3, storing the stirred product into a finished product tank.
The mixture of glyceryl squalene, glyceryl sterenoate, isolongifolol ethyl ether and hydrocarbon oil C7-C16 was the same as in example 2.
Example 7
The coal dressing collecting agent in the embodiment is composed of the following raw materials in parts by weight: 12% of glyceryl squalene oleate, 18% of glyceryl sterenoate, 30% of isolongifolan ethyl ether and 40% of a mixture of hydrocarbon oils of C7-C16.
The preparation method of the coal dressing collector in the embodiment comprises the following steps:
step 1, weighing the following raw materials in parts by weight: 12% of squalene fatty acid glyceride, 18% of sterol fatty acid glyceride, 30% of isolongifolan ethyl ether and 40% of hydrocarbon oil of C7-C16;
step 2, putting the raw materials weighed in the step 1 into a reaction kettle for stirring, wherein the temperature in the reaction kettle is 35 ℃, and the rotating speed during stirring is 50 r/min;
and 3, storing the stirred product into a finished product tank.
The mixture of glyceryl squalene, glyceryl sterenoate, isolongifolol ethyl ether and hydrocarbon oil C7-C16 was the same as in example 2.
In order to verify the flotation effect of the coal dressing collector provided by the embodiment, the applicant conducts multiple laboratory flotation searches on coal slurry in a certain coal dressing plant, and finds that the collector has ideal effect, and can achieve the purposes of improving the recovery rate of clean coal and improving the ash content of tail coal under the condition of ore pulp with the concentration of 50-150 g/L, wherein table 1 shows the test results when kerosene and the coal dressing collector provided by the invention are used for the ore pulp with the same concentration, and the selected ash content is 15.2% (flotation tank 1.5L) in the test of table 1.
Watch 1
From table 1, the coal dressing collector of the invention shows that the recovery rate of clean coal is increased, and the ash content of the tail coal is obviously improved.
The invention can also show better clean coal recovery rate and higher tailing ash when the concentration of the ore pulp is higher, such as when the concentration of the ore pulp is increased to 120 g/L, see table 2, the ash content of the selected coal slime in table 2 is 15.2% (flotation tank 1.5L).
Watch two
In addition, experiments show that the coal dressing collector disclosed by the invention is used for carrying out flotation on the coal which is extremely difficult to be dressed and has 14-17% of ash content in the Dongqu coal dressing plant, the obtained refined coal is about 11%, and the recovery rate of the refined coal can reach 85-90% in the experiment under the condition that the concentration of ore pulp is 60-140 g per liter.
It will be understood that the above embodiments are merely exemplary embodiments taken to illustrate the principles of the present invention, which is not limited thereto. It will be apparent to those skilled in the art that various modifications and improvements can be made without departing from the spirit and substance of the invention, and these modifications and improvements are also considered to be within the scope of the invention.
Claims (3)
1. The coal dressing collecting agent is characterized by comprising the following raw materials in parts by weight:
5-15% of squalene glyceride, 10-25% of sterol glyceride, 10-30% of isolongifolan ethyl ether and 30-65% of hydrocarbon oil mixture of C7-C16; wherein the squalene fatty ester is vegetable oil heated to 220-270 deg.C, and has extraction density of 0.95-0.98 g/cm3A fraction of (a); the steryl olefine acid glyceride is vegetable oil which is heated to 160-190 ℃ and the density of extraction is 0.92-0.95 g/cm3A fraction of (a); the isolongifolyl ethyl ether is extracted by heating vegetable oil to 120-150 ℃ and the density of the extracted vegetable oil is 0.89-0.93 g/cm3A fraction of (a); the mixture of the C7-C16 hydrocarbon oil is extracted from petroleum and has the density of 0.85-0.87 g/cm3And the distillation range is 100-300 ℃.
2. A coal dressing collector according to claim 1, wherein the vegetable oil is rice bran oil, peanut oil or castor oil.
3. A method of preparing the coal dressing collector according to claim 1 or 2, characterized by comprising the following steps:
step 1, weighing the following raw materials in parts by weight: 5-15% of squalene glyceride, 10-25% of sterol glyceride, 10-30% of isolongifolan ethyl ether and 30-65% of hydrocarbon oil of C7-C16;
step 2, putting the raw materials weighed in the step 1 into a reaction kettle for stirring, wherein the temperature in the reaction kettle is 10-40 ℃, and the rotating speed during stirring is 20-60 r/min;
and 3, storing the stirred product into a finished product tank.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711378210.4A CN108927290B (en) | 2017-12-19 | 2017-12-19 | Coal dressing collector and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711378210.4A CN108927290B (en) | 2017-12-19 | 2017-12-19 | Coal dressing collector and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN108927290A CN108927290A (en) | 2018-12-04 |
| CN108927290B true CN108927290B (en) | 2020-08-07 |
Family
ID=64449219
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711378210.4A Expired - Fee Related CN108927290B (en) | 2017-12-19 | 2017-12-19 | Coal dressing collector and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108927290B (en) |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2177838C2 (en) * | 1999-08-09 | 2002-01-10 | Институт химии нефти СО РАН | Coal flotation collector |
| CN101385996B (en) * | 2008-09-10 | 2012-12-19 | 中国矿业大学(北京) | Preparation method of flotation promoter |
| CN103203289B (en) * | 2013-05-09 | 2015-05-20 | 中煤科工集团淮北爆破技术研究院有限公司 | Flotation promoter of coal slime and method for preparing flotation reagent |
| CN105750092A (en) * | 2016-03-10 | 2016-07-13 | 徐州工程学院 | Novel coal preparation collecting agent and preparation method thereof |
| CN105925381A (en) * | 2016-04-14 | 2016-09-07 | 淮阴师范学院 | High value utilization method of gutter oil |
-
2017
- 2017-12-19 CN CN201711378210.4A patent/CN108927290B/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| CN108927290A (en) | 2018-12-04 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| ES2899580T3 (en) | Methods of use of mixtures of glycerides and fatty acids | |
| CA2830489C (en) | Chemical additives and use thereof in stillage processing operations | |
| EP2007523B1 (en) | Fatty acid by-products and methods of using same | |
| CN107107075B (en) | Composition of N-acyl derivatives of fatty acids and sarcosine for improved flotation of non-sulphide minerals | |
| AU2007328929B2 (en) | Normal and iso parafines with low content of aromatics, sulphur and nitrogen as collector for froth flotation | |
| WO2014055502A1 (en) | Depressants for mineral ore flotation | |
| CN103406210B (en) | Fatty acid by-products and methods of using same | |
| WO2016065189A1 (en) | Polyamidoamine cationic collectors and methods for making and using same | |
| WO2021008324A1 (en) | Liquid-solid composite collector for coal slime flotation and preparation method therefor | |
| US20160114338A1 (en) | Cationic collectors with mixed polyamidoamines and methods for making and using same | |
| CN108927290B (en) | Coal dressing collector and preparation method thereof | |
| NO165482B (en) | PROCEDURE FOR ENCOURAGING COALS BY FOAM FLOTION. | |
| CN112044604A (en) | Low-sulfur high-efficiency composite flotation agent for coal slime | |
| CN204746622U (en) | Laboratory is with hanging slot type flotation device | |
| CN107335546A (en) | A kind of low-rank coal flotation method based on positively charged bubble | |
| WO2018145146A1 (en) | Biodiesel compositions and methods of use thereof | |
| CN111589590B (en) | Flotation method for oxidized coal slime | |
| CN115106200A (en) | Coal dressing compound collecting agent, preparation method thereof and coal slime flotation method | |
| CN113843048A (en) | Polyhydroxy fatty acid sodium soap and preparation method and application thereof | |
| CN109201341B (en) | Low-rank coal slime flotation collecting agent compounded with acid aldehyde ether and preparation method and application thereof | |
| CN109201342B (en) | Low-rank coal slime flotation collecting agent compounded with acid ester ether and preparation method thereof | |
| CN109604069A (en) | A kind of coal flotation agent | |
| CN111558464B (en) | Low-copper high-molybdenum ore collecting agent and preparation method thereof | |
| CN114887773B (en) | Flotation collector and preparation method and application thereof | |
| US1995915A (en) | Flotation of minerals |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20200420 Address after: 030082 unit 202, No. 10, haitangjiayuan, Tanghuai Park, Shanxi comprehensive reform demonstration zone, Taiyuan City, Shanxi Province Applicant after: Shanxi Jinmei Technology Co.,Ltd. Address before: 125100 Coastal Economic Zone of Xingcheng City, Huludao City, Liaoning Province Applicant before: LIAONING DEBAS INDUSTRIAL Co.,Ltd. |
|
| TA01 | Transfer of patent application right | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20201105 Address after: 030082 unit 202, No. 10, haitangjiayuan, Tanghuai Park, Shanxi comprehensive reform demonstration zone, Taiyuan City, Shanxi Province Patentee after: Shanxi Jinmei Technology Co.,Ltd. Patentee after: LIAONING DEBAS INDUSTRIAL Co.,Ltd. Patentee after: SHANXI COKING COAL GROUP Co.,Ltd. Patentee after: XISHAN COAL ELECTRICITY GROUP Co.,Ltd. Address before: 030082 unit 202, No. 10, haitangjiayuan, Tanghuai Park, Shanxi comprehensive reform demonstration zone, Taiyuan City, Shanxi Province Patentee before: Shanxi Jinmei Technology Co.,Ltd. |
|
| TR01 | Transfer of patent right | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20200807 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |