CN108918504A - The system and method for Gemstone Identification is realized based on Raman spectrum and OCT - Google Patents

The system and method for Gemstone Identification is realized based on Raman spectrum and OCT Download PDF

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Publication number
CN108918504A
CN108918504A CN201811059554.3A CN201811059554A CN108918504A CN 108918504 A CN108918504 A CN 108918504A CN 201811059554 A CN201811059554 A CN 201811059554A CN 108918504 A CN108918504 A CN 108918504A
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sample
oct
raman spectrum
raman
image
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傅洪波
陈占坤
张建
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Guangzhou Medical University
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Guangzhou Medical University
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    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/62Systems in which the material investigated is excited whereby it emits light or causes a change in wavelength of the incident light
    • G01N21/63Systems in which the material investigated is excited whereby it emits light or causes a change in wavelength of the incident light optically excited
    • G01N21/65Raman scattering
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/17Systems in which incident light is modified in accordance with the properties of the material investigated
    • G01N21/41Refractivity; Phase-affecting properties, e.g. optical path length

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  • Health & Medical Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • General Physics & Mathematics (AREA)
  • Immunology (AREA)
  • Pathology (AREA)
  • Nuclear Medicine, Radiotherapy & Molecular Imaging (AREA)
  • Investigating, Analyzing Materials By Fluorescence Or Luminescence (AREA)

Abstract

The invention discloses one kind to be imaged based on Raman spectrum and optical coherence(OCT)Technology realizes the system and method for Gemstone Identification, the system comprises:Gem Samples, glass slide, magazine, mobile platform, Raman spectrometer, OCT, data, which are extracted, includes two loopholes with processing module, display, the magazine;The method includes:It obtains unloaded image when glass slide zero load by loophole with OCT first, then the sample being placed on glass slide is detected to obtain sample spectrum diagram and OCT image with OCT and Raman spectrometer respectively;Using computer software analysis image, to obtain sample boundaries and range information, and by the calculating of light path matching principle completion refractive index, analysis raman spectrum obtains sample chemical property;Final measurement is shown by display.System and method design it is simple, easy to operate, to same sample realize measurement be switched fast;Realize the physical attribute of irregular gem materials(Light refractive index)With the measurement and comprehensive analysis of the multi objectives such as chemical component;This method realizes automation, the digitlization, intelligent measuring of the light refractive index of jewel difference tomography simultaneously.

Description

The system and method for Gemstone Identification is realized based on Raman spectrum and OCT
Technical field
The present invention relates to Gemstone Identification fields, more particularly to one kind is based on Raman spectrum and OCT measurement jewel physics refraction The System and method for of rate and chemical component property.
Background technique
The authenticity of jewel be in real life it is particularly important, wherein refractive index is an extremely important identification Index, measurement method include prism method, Polarization Method(Test Brewster's angle), contact pin method, Abbe refractometer method, also include light It learns coherent imaging technology (OCT).
OCT is the new skill of a kind of quick, high-resolution and the highly sensitive high-resolution tomography image for obtaining sample Art has been widely used in biologic medical and material tests, and detection method is also extremely easy, only material need to be directly put Set in scanning range, can be obtained the OCT image comprising material characteristics information, measurement it is the simplest directly, be it is a kind of quickly, Detect the new technique of refractive index.
Jewelry, ore refractive index can thus measure, but thus much an appraisal basis is relatively simple, especially rolls in sample It penetrates in situation similar in rate, is difficult to distinguish gem materials, it is therefore necessary to enrich corresponding identification of indicator;And Raman spectrum skill Art is as a kind of mature technology, using " molecular fingerprint " characteristic of Raman spectrum, can screen different chemical composition, and its conduct A kind of sxemiquantitative and non-quantitation technology, are difficult accurate quantification different chemical composition content, and refractive index can make up it is such Defect, therefore the combination of two kinds of technologies can play bigger power, form more comprehensive to jewelry ore materials, comprehensive analysis knot Fruit and report.
Apparatus of the present invention realize the combination of above-mentioned technology, and the physics and chemical property of jewelry ore materials can be achieved at the same time It measures, obtains and the comprehensive evaluating of jewel is identified, and detection is easy, quick, accurate.
Summary of the invention
It is a kind of precious based on Raman spectrum and OCT technology realization object of the present invention is to provide in view of the defects existing in the prior art The System and method for of stone identification, measurement while physics and chemical property to realize jewelry ore materials, obtains to jewel Comprehensive evaluating and identification, and detection is easy, quick, accurate.
In order to achieve the above object, the present invention adopts the following technical scheme that:
A kind of system that Gemstone Identification is realized based on Raman spectrum and OCT technology, including Gem Samples, glass slide, magazine, movement Platform, Raman spectrometer, OCT, data, which are extracted, includes two loopholes with processing module, display, the magazine.
Further, the Raman spectrometer wavelength model is optional, for measuring the Raman spectral information of Gem Samples;Institute State that OCT wavelength model is optional, principle is the light that issues of low-coherence light source after fiber optic splitter, uniformly it is divided into two beams, Reference arm and sample arm are respectively enterd, the reference light returned by the reflected sample light of sample and mirror reflection is again through light Fine beam splitter phase dry doubling is coupled on detector, herein for OCT figure in surface when obtaining glass slide zero load (for always in image Line, referred to as baseline) with place sample when Sample Scan figure.
Preferably, the sample is the jewel of surfacing.
Preferably, the slide thickness is 1 ~ 2mm, measures unloaded image and placement sample for providing OCT.
Preferably, the magazine provides environmental requirement for Raman spectrometer and OCT measurement, extraneous interference is avoided, into one With walking, the light of loophole there are two the magazine tops, Raman spectrometer and OCT are via herein into magazine.
Further, the mobile platform is for placing glass slide and sample, and horizontal can at the uniform velocity drag platform for drawing The scanning of graceful spectrometer and OCT to sample.
Preferably, the data extract the synthesis for carrying out unloaded figure and sample drawing with computer software with processing module, And optimize through median filtering, Boundary Recognition is carried out using canny operator, utilizes Hough transform (Hough Transformation Straight Line Identification) is carried out to each interface of composite diagram, the distance feature between the straight line of acquisition, according to light path Sample refractive index is calculated automatically with principle, and analysis raman spectrum obtains sample chemical property.
Further, the display is for showing final gem properties measurement result.
A method of Gemstone Identification is realized based on Raman spectrum and OCT technology, is included the following steps:
A, baseline image when first with OCT by loophole acquisition glass slide zero load;Use OCT and Raman spectrum respectively again Instrument detects the sample being placed on glass slide, i.e., at the uniform velocity drags mobile platform, makes Raman spectrometer and OCT successively to sample Product, which are scanned, obtains sample Raman spectrogram and OCT image;
B, using two image of computer software analysis, to obtain sample boundaries and characteristic information, and it is public by light path matching principle Formula completes the calculating of refractive index, and the analysis of chemical property is completed by Raman spectrum;
C, final measurement is shown by display.
The beneficial effects of the invention are as follows:(1)This system realizes Raman spectroscopy and two kinds of optical coherence imaging technique The combination of technology, reducing two kinds, technology space separation bring operation is constant and resource is overlapped.
(2)This method by computer software by arithmetic programming realize jewel difference tomography light refractive index from Dynamicization, digitlization, intelligent measuring.
(3)Apparatus of the present invention and method, design is simple, and integration ofTechnology degree is high, easy to operate, while having given full play to two kinds The qualitative and quantitative complementarity of measuring technique, to quickly, accurately, systematically complete jewelry, the common physics of ore and change Learn the comprehensive analysis and identification of property.
Detailed description of the invention
Attached drawing 1 is system and device schematic diagram of the invention.
Attached drawing 2 is measuring method flow chart provided by the invention.
Attached drawing 3 is Method And Principle schematic diagram provided by the present invention.
Attached drawing 4 is a kind of jewel embodiment Raman spectrogram provided by the invention.
Attached drawing 5 is a kind of jewel embodiment OCT figure provided by the invention, composite diagram.
Attached drawing 6 is the interaction figure provided by the invention using 5 composite diagram of attached drawing after algorithm process.
In figure, 1- sample 2- glass slide 3- magazine 301-OCT loophole 302- Raman spectrometer loophole 4- is mobile Platform 5-OCT 6- Raman spectrometer 7- data are extracted and processing module 8- display.
Specific embodiment
In order to make the foregoing objectives, features and advantages of the present invention clearer and more comprehensible, with reference to the accompanying drawing and specifically real Applying example, the invention will be further described, so that those skilled in the art can better understand technical solution of the present invention, But the embodiment of invention is without being limited thereto.
As shown in Figure 1, for a kind of system and device schematic diagram for realizing Gemstone Identification based on Raman spectrum and OCT technology, packet Gem Samples 1, glass slide 2, magazine 3, mobile platform 4, Raman spectrometer 5, OCT6, data are included to extract and processing module 7, display Device 8, the magazine include two loopholes 301,302.
It is illustrated in figure 2 a kind of method stream that Gemstone Identification is realized based on Raman spectrum and OCT technology provided by the invention Cheng Tu includes the following steps:
A, the mobile platform 4 for not placing sample 1 is placed in 301 lower section of loophole, sky when starting OCT6 acquisition glass slide 2 is unloaded Baseline chart is carried, later places the Gem Samples of surfacing 1, places it in 302 lower section of loophole, then at the uniform velocity dragging is mobile flat Platform 4, is respectively started Raman spectrometer 5 and OCT6 scanning obtains the Raman spectrum and OCT image of sample 1;
B, scanning figure acquired in two instruments is uploaded to data extraction and processing module 7 through data line connection, used here Computer software carries out the synthesis of unloaded figure and sample drawing, and optimizes through median filtering, carries out boundary knowledge using canny operator Not, Hough transform is utilized(Hough Transformation)Straight Line Identification carried out to each interface of composite diagram, acquisition it is straight Distance feature between line;If Straight Line Identification is ineffective, it may be programmed and realize same scan line(Dotted line as shown in Figure 3)With it is upper The manual interaction of lower boundary, baseline intersection point is chosen, and completes various point locations information(The coordinate value being primarily referred to as on image)It extracts, Sample refractive index is calculated according to light path matching principle automatically afterwards, analysis raman spectrum obtains sample chemical property;
C, final result is connected to display 8 by data line and is shown.
It should be noted that wherein can realize the measurement to sample refractive index, principle such as Fig. 3 based on light path matching principle It is shown:The light path matching principle and the corresponding faultage image location information of physics light path that OCT coherent measurement requires:Place sample Before, i.e., when objective table is vacant, its tomograph is scanned, the position of stage surface is y in figure0(As baseline position);It is carrying It after placing sample on object platform, is tightly attached to the lower surface of sample on objective table, carries out longitudinal scanning(At Fig. 3 algorithm process figure p0~p4It is shown);In Sample Scan tomograph, if the position of sample upper surface is y1, the lower surface of sample is for position in figure y2If sample refractive index is n, then have, then by respective image processing technique described above, extract respective distance Parameter(y0, y1, y2), refractive index can be calculated by substituting into formula.
If Fig. 4 is a kind of Raman spectrogram of Gem Samples diamond embodiment provided by the present invention, feature spectral peak is 1300cm-1 is consistent by Raman spectrum analysis with known diamond embodiment standard feature peak, and the mirror of corresponding chemical ingredient is completed It is fixed.
As shown in Figure 5,6, Fig. 5 is the OCT figure and composite diagram of above-mentioned diamond embodiment provided by the invention;Fig. 5 (a) is benefit The baseline chart of acquisition is scanned to vacant objective table with OCT technology;Fig. 5 (b) is using OCT technology to being placed on objective table Diamond be scanned the sample drawing of acquisition;Fig. 5 (c) is the synthesis of the baseline chart and sample drawing realized by programming;Fig. 6 is to close At digital picture identify that the interaction figure on boundary is scanned along longitudinal direction by the boundary identified through Hough transform(p0~p4), fortune Multiple groups up-and-down boundary distance and coboundary are obtained to parallax range parameter value i.e. with algorithmWith, light is substituted into afterwards Journey matching principle formula, and statistical disposition test result.The measuring sample refractive index is that 2.412 ± 0.013 (known this is pure 2.417) driller's industry standard refraction rate is.
In conclusion more preferred separate embodiment used herein a kind of is based on Raman to provided by the present invention Spectrum and OCT technology realize that the System and method for of Gemstone Identification is expounded, and the explanation of above example is only intended to help Understand method and core concept of the invention, it is noted that although having carried out in detail referring to aforementioned separate embodiment to the present invention Illustrate, but to those skilled in the art, without departing from the principle of the present invention, several change can also be made Into and retouching, these modifications and embellishments are also considered to be within the scope of the present invention.

Claims (10)

1. one kind is imaged based on Raman spectrum and optical coherence(OCT)The system of technology realization Gemstone Identification, which is characterized in that packet Gem Samples, glass slide, magazine, mobile platform, Raman spectrometer, OCT, data extraction and processing module, display are included, it is described Magazine includes two loopholes.
2. the system for realizing Gemstone Identification based on Raman spectrum and OCT technology as described in claim 1, which is characterized in that institute It is optional to state Raman spectrometer wavelength model, for measuring the Raman spectral information of glass material sample;The OCT wavelength model can Choosing, principle are the light of low-coherence light source sending after fiber optic splitter, are uniformly divided into two beams, respectively enter reference arm And sample arm, the reference light returned by the reflected sample light of sample with mirror reflection is again through fiber optic splitter phase dry doubling It is coupled on detector, schemes herein for surface OCT when obtaining glass slide zero load(It is a straight line, referred to as baseline in image)With put Set Sample Scan figure when sample.
3. the system for realizing Gemstone Identification based on Raman spectrum and OCT technology as described in claim 1, which is characterized in that institute Stating sample is rule of surface or irregular jewelry and ore.
4. the system for realizing Gemstone Identification based on Raman spectrum and OCT technology as described in claim 1, which is characterized in that institute Stating slide thickness is 1 ~ 2mm, measures unloaded image and placement sample for providing OCT.
5. the system for realizing Gemstone Identification based on Raman spectrum and OCT technology as described in claim 1, which is characterized in that institute It states magazine and provides environmental requirement for Raman spectrometer and OCT measurement, avoid extraneous interference;Further, at the top of the magazine There are two loophole, the light of Raman spectrometer and OCT are via herein into magazine.
6. the system for realizing Gemstone Identification based on Raman spectrum and OCT technology as described in claim 1, which is characterized in that institute Mobile platform is stated for placing glass slide and sample, and horizontal can at the uniform velocity drag platform for Raman spectrometer and OCT to sample Scanning.
7. the system for realizing Gemstone Identification based on Raman spectrum and OCT technology as described in claim 1 and 2, which is characterized in that The data extract the synthesis for carrying out unloaded figure and sample drawing with computer software with processing module, and excellent through median filtering Change, carries out Boundary Recognition using canny operator, utilize Hough transform(Hough Transformation)To each of composite diagram Interface carries out Straight Line Identification, the distance feature between the straight line of acquisition;In composite diagram when the pole out-of-flatness of jewel upper and lower interface or straight line When recognition effect is bad, mark can also be clicked by hand on the image with scan line and up-and-down boundary by programming, the three of baseline A intersection point obtains its location information, after further according to light path matching principle calculate sample refractive index automatically, analysis raman spectrum obtains Sample chemical property.
8. the system based on Raman spectrum and OCT technology measurement glass material property, feature exist as claimed in claim 7 In the light path matching principle:The light path matching principle and the corresponding tomograph image position of physics light path that OCT coherent measurement requires Confidence breath:Before placing sample, i.e., when objective table is vacant, its tomograph is scanned, the position of stage surface is y in figure0(As Baseline position);After placing sample on objective table, it is tightly attached to the lower surface of sample on objective table, is scanned;Sample Scan In tomograph, if the position of sample upper surface is y1, the lower surface of sample is that position is y in figure2If sample refractive index is n, Then have
9. the system for realizing Gemstone Identification based on Raman spectrum and OCT technology as described in claim 1, which is characterized in that institute Display is stated for showing final gem properties measurement result.
10. the method for realizing Gemstone Identification based on Raman spectrum and OCT technology as described in claim 1, which is characterized in that packet Include following steps:
A, baseline image when first with OCT by loophole acquisition glass slide zero load;Use OCT and Raman spectrum respectively again Instrument detects the sample being placed on glass slide, i.e., at the uniform velocity drags mobile platform, makes Raman spectrometer and OCT successively to sample Product, which are scanned, obtains sample Raman spectrogram and OCT image;
B, using two image of computer software analysis, to obtain sample boundaries and characteristic information, and it is public by light path matching principle Formula completes the calculating of refractive index, and the analysis of chemical property is completed by Raman spectrum;
C, final measurement is shown by display.
CN201811059554.3A 2018-09-12 2018-09-12 The system and method for Gemstone Identification is realized based on Raman spectrum and OCT Pending CN108918504A (en)

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Application publication date: 20181130