CN108917411A - A kind of method of lead skim recycling and UTILIZATION OF VESIDUAL HEAT IN in lead smelting process - Google Patents

A kind of method of lead skim recycling and UTILIZATION OF VESIDUAL HEAT IN in lead smelting process Download PDF

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Publication number
CN108917411A
CN108917411A CN201810343304.6A CN201810343304A CN108917411A CN 108917411 A CN108917411 A CN 108917411A CN 201810343304 A CN201810343304 A CN 201810343304A CN 108917411 A CN108917411 A CN 108917411A
Authority
CN
China
Prior art keywords
lead
mine
lead skim
skim
tank body
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810343304.6A
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Chinese (zh)
Inventor
田继涛
徐诗艳
吴国庆
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Anhui Huabo Renewable Resources Technology Co Ltd
Original Assignee
Anhui Huabo Renewable Resources Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Anhui Huabo Renewable Resources Technology Co Ltd filed Critical Anhui Huabo Renewable Resources Technology Co Ltd
Priority to CN201810343304.6A priority Critical patent/CN108917411A/en
Publication of CN108917411A publication Critical patent/CN108917411A/en
Pending legal-status Critical Current

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Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27DDETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
    • F27D17/00Arrangements for using waste heat; Arrangements for using, or disposing of, waste gases
    • F27D17/004Systems for reclaiming waste heat
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B13/00Obtaining lead
    • C22B13/02Obtaining lead by dry processes
    • C22B13/025Recovery from waste materials
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B7/00Working up raw materials other than ores, e.g. scrap, to produce non-ferrous metals and compounds thereof; Methods of a general interest or applied to the winning of more than two metals
    • C22B7/04Working-up slag
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27DDETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
    • F27D17/00Arrangements for using waste heat; Arrangements for using, or disposing of, waste gases
    • F27D17/004Systems for reclaiming waste heat
    • F27D2017/006Systems for reclaiming waste heat using a boiler
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/20Recycling
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/25Process efficiency

Abstract

The present invention relates in a kind of lead smelting process lead skim recycling and UTILIZATION OF VESIDUAL HEAT IN method, the invention mainly includes:It smelts lead skim using lead hot exhaust gas is fitted into vertical closed tank body, then the oxygen being evenly distributed is passed through from the apparatus of oxygen supply of tank base, it is sufficiently cooled so that smelting lead skim mine, the sensible heat of lead skim mine is almost all carried by air and is discharged by top of the tank simultaneously, carries out waste heat recycling heat supply power generation later.The present invention recycles compared with using technology with existing secondary lead smelting waste heat, its heat recovery rate with higher, and lead is effectively reduced and smelts subsequent handling energy consumption, this method is reasonable, efficiently, equipment is succinctly easy to operate, compares and is conducive to generate electricity in secondary lead smelting process waste heat resource reclaim and utilize technical field popularization and application.

Description

A kind of method of lead skim recycling and UTILIZATION OF VESIDUAL HEAT IN in lead smelting process
Technical field
The present invention relates to reviver technical field, in specially a kind of slag waste heat removal process based on energy-saving and emission-reduction, The high efficiente callback of cryogenic waste heat resource and the method and device thereof utilized.
Background technique
Currently, China or even in the world, the design of the structural parameters and operating parameter of cooler is based only on cold to slag But monomer effect, and almost without the recycling considered to lead ore residue sensible heat;In other words, the structure of cooler and behaviour at present Make parameter to be difficult to adapt to the high efficiente callback and utilization of lead ore residue sensible heat, there is not in Exposure degree and on for cooler Surmountable drawback, is mainly shown as:
(1) presence that cooler leaks out makes lead skim sensible heat largely scatter and disappear, while making for air-blast cooled air blower Power consumption increases.
(2) cooler band type structure only recycles temperature compared with lower part (generally at 300 DEG C or less) lead ore residue sensible heat, The slag sensible heat resource of temperature upper section is slatterned.
Summary of the invention
The present invention for existing cooler there is leak out, slag sensible heat can only be partially recycled etc. drawbacks, propose one kind Comprehensively utilize new process using secondary lead smelting lead skim, the purpose is to which previous cooler can be overcome to leak out caused by it is cooling and return Receive thermal resource efficiency reduce the problem of, and can overcome the problems, such as previous cooler can only recovery section heat source, solve tank body in Portion's charging, air feed problem.The present invention provides the following technical solutions:
A kind of method of lead skim recycling and UTILIZATION OF VESIDUAL HEAT IN in lead smelting process, it is specific as follows:
S1. red-hot lead skim mine is encased in a vertical closed tank body by feeding system, the temperature of lead skim mine is 950 DEG C~1200 DEG C;
S2. it is uniformly given on entire tank body cross section from the apparatus of oxygen supply of the tank base and is passed through cryogenic oxygen, oxygen stream The ratio of amount and lead skim mine treating capacity, i.e.,:Gas-solid ratio is 2000:2500Nm3/ t makes red-hot lead skim mine in the tank body and oxygen Gas, which comes into full contact with, to be cooled down;
S3. lead skim mine after cooling is discharged by tank base, and the carrying lead skim mine after coming into full contact with lead skim mine is whole The air of sensible heat is then discharged from tank body top, and carries out waste heat boiler recycling, generates steam heating, power generation.
Lead skim mine import is provided at the top of the vertical closed tank body, bottom is provided with cold mine outlet and external oxygen Air inlet;
The inside of the vertical closed tank body, which is divided into, prestores band and cooling zone, and the upper of cooling zone is arranged in the band that prestores Side;
The top of the vertical closed tank body is located at the feed system that lead skim mine entrance is provided with bell and lower bell System;
The exit Leng Kuang of the vertical closed tank body is provided with rotary seal valve.
The feeding system includes upper bell and lower bell, and when work, red-hot lead skim mine is poured into upper bell by truck Interior, often once upper bell rotates 60 °, and automatically opens downwards, falls into furnace charge in lower bell, is then shut off, fills in this way After material six times, lower bell is open, and furnace charge just equably falls on tank body surrounding.
The apparatus of oxygen supply includes that blast cap, cross air duct, upper cone bucket and lower cone bucket, cryogenic oxygen respectively enter apparatus of oxygen supply Upper and lower gas chamber in, the periphery air-supply of oxygen in upper chamber between upper and lower cone bucket, the oxygen of lower chamber is sent along central blast cap Wind.
Compared with prior art, the beneficial effects of the invention are as follows:Secondary lead smelting is utilized the invention particularly discloses a kind of Lead skim comprehensively utilizes new process, effectively overcomes the inadequate natural endowment of existing cooler, it is possible to prevente effectively from the leaking out of cooler Problem;It overcomes the lower lead of traditional cooler recovered temperature and smelts lead skim residual heat resources drawback, realize lead ore residue sensible heat Most recycling;Improve the uniformity and circulating air of uniformity, the lead ore residue decline that lead ore residue is distributed in vertical tank body The uniformity that body rises is realized most of recycling of lead ore residue sensible heat, was both considered to improve the cooling efficiency of vertical tank body The cooling of lead ore residue, it is contemplated that the high efficiente callback of lead ore residue sensible heat.This method is reasonable, and efficiently, equipment is succinctly easy to operate, than Relatively it is conducive to residual heat resources recycling during secondary lead smelting slag to promote and apply with using technical field.
Detailed description of the invention
Fig. 1 is schematic structural view of the invention.
Specific embodiment
Following will be combined with the drawings in the embodiments of the present invention, and technical solution in the embodiment of the present invention carries out clear, complete Site preparation description, it is clear that described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.It is based on Embodiment in the present invention, it is obtained by those of ordinary skill in the art without making creative efforts every other Embodiment shall fall within the protection scope of the present invention.
In description of the invention, it should be noted that the orientation of the instructions such as term "vertical", "upper", "lower", "horizontal" or Person's positional relationship is orientation based on the figure or positional relationship, is merely for convenience of this practical and simplified description of description, Rather than the device or element of instruction or hint meaning must have a particular orientation, and are constructed and grasped with specific orientation Make, therefore is not considered as limiting the invention.In addition, " first ", " second ", " third ", " the 4th " are only used for description mesh , and should not be understood as indicating or implying relative importance.
In description of the invention, it is also necessary to explanation, unless otherwise specific regulation and limitation, term " setting ", " peace Dress ", " connected ", " connection " shall be understood in a broad sense, for example, it may be being fixedly connected, may be a detachable connection, or integrally Connection, can be mechanical connection, is also possible to be electrically connected, can be and be directly connected to, and be also possible to be connected by intermediary, can To be the connection inside two elements.For the ordinary skill in the art, can understand as the case may be above-mentioned The concrete meaning of term in the present invention.
Embodiment 1
Referring to Fig. 1, a kind of method of lead skim recycling and UTILIZATION OF VESIDUAL HEAT IN in lead smelting process, specific as follows:
S1. red-hot lead skim mine is encased in a vertical closed tank body by feeding system, the temperature of lead skim mine is 950 DEG C~1200 DEG C;
S2. it is uniformly given on entire tank body cross section from the apparatus of oxygen supply of the tank base and is passed through cryogenic oxygen, oxygen stream The ratio of amount and lead skim mine treating capacity, i.e.,:Gas-solid ratio is 2000:2500Nm3/ t makes red-hot lead skim mine in the tank body and oxygen Gas, which comes into full contact with, to be cooled down;
S3. lead skim mine after cooling is discharged by tank base, and the carrying lead skim mine after coming into full contact with lead skim mine is whole The air of sensible heat is then discharged from tank body top, and carries out waste heat boiler recycling, generates steam heating, power generation.
The top of the vertical closed tank body 1 is provided with lead skim mine import 2, and bottom is provided with cold mine outlet 3, in tank body 1 bottom side is provided with cryogenic oxygen air outlet 4, which connects apparatus of oxygen supply, described vertical closed The inside of tank body 1, which is divided into, prestores band 5 and cooling zone 6, the top for prestoring band 5 and cooling zone 6 being arranged in, the cooling zone 6 Lower section is burner hearth 7, and described prestore is communicated between band 5 and cooling zone 6 by cross air duct 8, is provided with prestoring 5 side of band Gas chamber outlet 9,6 side of cooling zone be provided with lower chamber outlet 10, the top of the vertical closed tank body 1 be located at lead skim mine into 2 lower parts of mouth are provided with feeding system;Rotary seal valve is provided at the cold mine outlet 3 of the vertical closed tank body.The confession Material system includes upper bell 11 and lower bell 12, and when work, red-hot lead skim mine is poured into upper bell 11 by truck, and often one Secondary upper bell 11 rotates 60 °, and automatically opens downwards, falls into furnace charge in lower bell 12, is then shut off, in this way charging six After secondary, lower bell 12 is open, and furnace charge just equably falls on tank body surrounding.
The apparatus of oxygen supply includes blast cap 13, cross air duct 8, upper chamber and lower chamber, and cryogenic oxygen respectively enters oxygen supply In the upper and lower gas chamber of device, the oxygen in upper chamber is blown along the periphery of upper and lower gas chamber, and the oxygen of lower chamber is along central blast cap 13 air-supplies;Wherein upper chamber, which is located at, prestores 5 position of band, and lower chamber is located at 6 position of cooling zone;Blast cap 13 is mounted on 1 bottom of tank body Grate pedestal 14 on.
The above shows and describes the basic principles and main features of the present invention and the advantages of the present invention.The technology of the industry Personnel are it should be appreciated that the present invention is not limited to the above embodiments, and the above embodiments and description only describe this The principle of invention, without departing from the spirit and scope of the present invention, various changes and improvements may be made to the invention, these changes Change and improvement all fall within the protetion scope of the claimed invention.The claimed scope of the invention by appended claims and its Equivalent thereof.

Claims (1)

1. a kind of method of lead skim recycling and UTILIZATION OF VESIDUAL HEAT IN in lead smelting process, it is characterised in that specific as follows:
S1. red-hot lead skim mine is encased in a vertical closed tank body by feeding system, the temperature of lead skim mine is 950 DEG C ~1200 DEG C;
S2. uniformly given on entire tank body cross section from the apparatus of oxygen supply of the tank base and be passed through cryogenic oxygen, oxygen flow with The ratio of lead skim mine treating capacity, i.e.,:Gas-solid ratio is 2000:2500Nm3/ t fills red-hot lead skim mine in the tank body with oxygen Tap touching is cooled down;
S3. lead skim mine after cooling is discharged by tank base, and the carrying lead skim mine complete sensible heat after coming into full contact with lead skim mine Air be then discharged from tank body top, and carry out waste heat boiler recycling, generate steam heating, power generation.
CN201810343304.6A 2018-04-17 2018-04-17 A kind of method of lead skim recycling and UTILIZATION OF VESIDUAL HEAT IN in lead smelting process Pending CN108917411A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810343304.6A CN108917411A (en) 2018-04-17 2018-04-17 A kind of method of lead skim recycling and UTILIZATION OF VESIDUAL HEAT IN in lead smelting process

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Application Number Priority Date Filing Date Title
CN201810343304.6A CN108917411A (en) 2018-04-17 2018-04-17 A kind of method of lead skim recycling and UTILIZATION OF VESIDUAL HEAT IN in lead smelting process

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CN108917411A true CN108917411A (en) 2018-11-30

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Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101655320A (en) * 2009-09-15 2010-02-24 东北大学 Grading recycling and cascade utilization method of residual heat resources in sintering process and device thereof
CN202141346U (en) * 2011-06-27 2012-02-08 东北大学 High efficiency recovery unit of sintering waste heat resource
CN102345981A (en) * 2010-08-03 2012-02-08 刘柏谦 Sintering ore cooling device and waste heat recovery system thereof
CN205156639U (en) * 2015-07-30 2016-04-13 中冶长天国际工程有限责任公司 Vertical cooling system of sintering deposit
CN106433700A (en) * 2016-11-11 2017-02-22 中冶焦耐(大连)工程技术有限公司 Coke dry quenching dust removal system and process capable of efficiently recovering heat energy
CN106556258A (en) * 2015-09-28 2017-04-05 宝钢工程技术集团有限公司 Sintering mine sensible heat retracting device and its using method
CN106766950A (en) * 2016-11-23 2017-05-31 北京天朗致达节能环保科技有限公司 A kind of high temperature pelletizing heat recovering device and recovery method
CN206219613U (en) * 2016-11-22 2017-06-06 九源天能(北京)科技有限公司 A kind of dry type blast-furnace cement sensible heat recovery system
CN106989610A (en) * 2017-05-18 2017-07-28 中冶华天南京工程技术有限公司 Heat power generating system based on coke-oven plant's heat recovery
CN107014218A (en) * 2017-05-18 2017-08-04 中冶华天南京工程技术有限公司 Heat power generating system based on coke-oven plant's residual heat and energy integrated utilization
JP2017137531A (en) * 2016-02-04 2017-08-10 Jfeスチール株式会社 Drying method of blast furnace feed

Patent Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101655320A (en) * 2009-09-15 2010-02-24 东北大学 Grading recycling and cascade utilization method of residual heat resources in sintering process and device thereof
CN102345981A (en) * 2010-08-03 2012-02-08 刘柏谦 Sintering ore cooling device and waste heat recovery system thereof
CN202141346U (en) * 2011-06-27 2012-02-08 东北大学 High efficiency recovery unit of sintering waste heat resource
CN205156639U (en) * 2015-07-30 2016-04-13 中冶长天国际工程有限责任公司 Vertical cooling system of sintering deposit
CN106556258A (en) * 2015-09-28 2017-04-05 宝钢工程技术集团有限公司 Sintering mine sensible heat retracting device and its using method
JP2017137531A (en) * 2016-02-04 2017-08-10 Jfeスチール株式会社 Drying method of blast furnace feed
CN106433700A (en) * 2016-11-11 2017-02-22 中冶焦耐(大连)工程技术有限公司 Coke dry quenching dust removal system and process capable of efficiently recovering heat energy
CN206219613U (en) * 2016-11-22 2017-06-06 九源天能(北京)科技有限公司 A kind of dry type blast-furnace cement sensible heat recovery system
CN106766950A (en) * 2016-11-23 2017-05-31 北京天朗致达节能环保科技有限公司 A kind of high temperature pelletizing heat recovering device and recovery method
CN106989610A (en) * 2017-05-18 2017-07-28 中冶华天南京工程技术有限公司 Heat power generating system based on coke-oven plant's heat recovery
CN107014218A (en) * 2017-05-18 2017-08-04 中冶华天南京工程技术有限公司 Heat power generating system based on coke-oven plant's residual heat and energy integrated utilization

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Application publication date: 20181130