CN108914627A - A kind of chain tooth and zipper with translucent effect - Google Patents

A kind of chain tooth and zipper with translucent effect Download PDF

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Publication number
CN108914627A
CN108914627A CN201810915531.1A CN201810915531A CN108914627A CN 108914627 A CN108914627 A CN 108914627A CN 201810915531 A CN201810915531 A CN 201810915531A CN 108914627 A CN108914627 A CN 108914627A
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CN
China
Prior art keywords
owf
translucent
monofilament
zipper
preparation
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810915531.1A
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Chinese (zh)
Inventor
何卫星
何翔
赵远航
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Zhejiang Weixing Industrial Development Co Ltd
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Zhejiang Weixing Industrial Development Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Zhejiang Weixing Industrial Development Co Ltd filed Critical Zhejiang Weixing Industrial Development Co Ltd
Priority to CN201810915531.1A priority Critical patent/CN108914627A/en
Publication of CN108914627A publication Critical patent/CN108914627A/en
Pending legal-status Critical Current

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Classifications

    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/16General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using dispersed, e.g. acetate, dyestuffs
    • AHUMAN NECESSITIES
    • A44HABERDASHERY; JEWELLERY
    • A44BBUTTONS, PINS, BUCKLES, SLIDE FASTENERS, OR THE LIKE
    • A44B19/00Slide fasteners
    • A44B19/24Details
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/60General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing polyethers
    • D06P1/613Polyethers without nitrogen
    • D06P1/6138Polymerisation products of glycols, e.g. Carbowax, Pluronics
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/62General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds with sulfate, sulfonate, sulfenic or sulfinic groups
    • D06P1/621Compounds without nitrogen
    • D06P1/622Sulfonic acids or their salts
    • D06P1/625Aromatic
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/34Material containing ester groups
    • D06P3/52Polyesters
    • D06P3/54Polyesters using dispersed dyestuffs

Abstract

The present invention provides the preparation method and zipper of a kind of chain tooth with translucent effect, method includes by after polyethylene terephthalate slice dehumidifying, and melting extrusion, cooling and drawing and setting obtains transparent monofilament;Monofilament is dyed in dye bath, dyeing is contaminated by 40~60 DEG C of beginnings, and 20~60min is kept the temperature after being warming up to 125~135 DEG C, is washed after cooling, the translucent monofilament dyed;Dye bath includes 0.001~6%owf of disperse dyes;0.001~3g/L of 0.05~3g/L of pH adjusting agent and levelling agent;By the translucent monofilament heated die of dyeing, obtained continuous U-shaped element chain combination obtains the chain tooth with translucent effect.Chain tooth and strap combine to obtain the zipper with translucent effect, possess unique visual sense, promote the class of zipper;Zipper also has preferable Washing, PERSPIRATION COLOR FASTNESS and fastness to rubbing, at 4 grades or more.

Description

A kind of chain tooth and zipper with translucent effect
Technical field
The invention belongs to zipper technology field more particularly to a kind of chain tooths and zipper with translucent effect.
Background technique
Auxiliary material on clothes combines fashion trend instantly, the zipper based on special visual effect class product also increasingly by Client welcomes, wherein a kind of effect of the salad chain as nearest prevalence is hit, it is deep to be pursued.
However more common zipper is that white zipper code dress carries out dyeing again and is made into the market, the cloth of this zipper Band, chain tooth, suture are all a kind of unified colors, give cheap sense, do not meet the need of currently popular individual requirement It wants.
Summary of the invention
In view of this, the purpose of the present invention is to provide a kind of chain tooth and zipper with translucent effect, the chain tooth are done At zipper there is translucent effect, promote zipper class, and meet color fastness requirement.
The present invention provides a kind of preparation methods of chain tooth with translucent effect, include the following steps:
After polyethylene terephthalate slice dehumidifying, melting extrusion, cooling and drawing and setting obtains transparent monofilament;
Monofilament to be dyed in dye bath, dyeing is contaminated by 40~60 DEG C of beginning, heat preservation 20 after being warming up to 125~135 DEG C~ 60min is washed after cooling, the translucent monofilament dyed;
The dye bath includes 0.001~6%owf of disperse dyes;0.05~3g/L of pH adjusting agent and levelling agent 0.001~ 3g/L;
By the translucent monofilament heated die of dyeing, continuous U-shaped element chain is obtained, combination obtains the chain with translucent effect Tooth.
Preferably, the levelling agent is selected from neopelex and/or polyethylene glycol monooleate.
Preferably, the bath raio when dyeing is 1:6~1:20.
Preferably, the temperature of the dehumidifying is 140~170 DEG C, and the time of dehumidifying is 5~7h.
Preferably, the temperature of the melting extrusion is 280~300 DEG C, and the pressure of melting extrusion is 7.5~8.5MPa;It draws The temperature for stretching sizing is 170~250 DEG C.
Preferably, dye bath includes 0.5~1g/L of 0.02~0.42%owf of disperse dyes and levelling agent.
Preferably, the dye bath includes scattered fluorescent yellow 0.05%owf, disperses color indigo plant 0.15%owf, glacial acetic acid 0.2g/L With levelling agent 0.5g/L;
Or including scattered fluorescent yellow 0.23%owf, dispersion fluorescence red 0.19%owf, glacial acetic acid 0.2g/L and levelling agent 1g/ L;
Or including disperse violet 0.06%owf, disperse brilliant blue 0.15%owf, glacial acetic acid 0.2g/L and levelling agent 0.5g/L.
Preferably, 125~135 DEG C are warming up to 1~2 DEG C/min.
The present invention provides a kind of zippers, including have translucent effect made from preparation method described in above-mentioned technical proposal Chain tooth.
The present invention provides a kind of preparation methods of chain tooth with translucent effect, include the following steps:It will be poly- to benzene After the slice dehumidifying of dioctyl phthalate second diester, melting extrusion, cooling and drawing and setting obtains transparent monofilament;Monofilament is contaminated in dye bath Color, dyeing are contaminated by 40~60 DEG C of beginnings, and 20~60min is kept the temperature after being warming up to 125~135 DEG C, is washed after cooling, half dyed Transparent monofilament;The dye bath includes 0.001~6%owf of disperse dyes;0.05~3g/L of pH adjusting agent and levelling agent 0.001 ~3g/L;By the translucent monofilament heated die of dyeing, continuous U-shaped element chain is obtained, combination obtains the chain with translucent effect Tooth.The present invention is raw material by using polyethylene terephthalate slice, in the dye bath of special formulation and under specified conditions Dyeing, obtains the chain tooth with translucent effect.Chain tooth and strap combine to obtain the zipper with translucent effect, possess uniqueness Visual sense, promote the class of zipper;Zipper also has preferable Washing, PERSPIRATION COLOR FASTNESS and fastness to rubbing.Experiment The result shows that:The Washing of zipper with translucent effect is at 4 grades or more, and PERSPIRATION COLOR FASTNESS is more than 4 ranks, antifriction Rubbing fastness is more than 4 ranks.
Detailed description of the invention
Fig. 1 is the apparent visual effect picture of zipper prepared by the embodiment of the present invention 1;
Fig. 2 is the apparent visual effect picture of zipper prepared by the embodiment of the present invention 2;
Fig. 3 is the apparent visual effect picture of zipper prepared by the embodiment of the present invention 3.
Specific embodiment
The present invention provides a kind of preparation methods of chain tooth with translucent effect, include the following steps:
After polyethylene terephthalate slice dehumidifying, melting extrusion, cooling and drawing and setting obtains transparent monofilament;
Monofilament to be dyed in dye bath, dyeing is contaminated by 40~60 DEG C of beginning, heat preservation 20 after being warming up to 125~135 DEG C~ 60min is washed after cooling, the translucent monofilament dyed;
The dye bath includes 0.001~6%owf of disperse dyes;0.05~3g/L of pH adjusting agent and levelling agent 0.001~ 3g/L;
By the translucent monofilament heated die of dyeing, continuous U-shaped element chain is obtained, combination obtains the chain with translucent effect Tooth.
It is raw material by using polyethylene terephthalate slice, contaminates in the dye bath of special formulation and under specified conditions Color obtains the chain tooth with translucent effect.Chain tooth and strap combine to obtain the zipper with translucent effect, possess unique Visual sense promotes the class of zipper;Zipper also has preferable Washing, PERSPIRATION COLOR FASTNESS and fastness to rubbing.
By after polyethylene terephthalate slice dehumidifying, melting extrusion, cooling and drawing and setting obtains transparent the present invention Monofilament.In the present invention, the temperature of polyethylene terephthalate slice dehumidifying is preferably 140~170 DEG C, dehumidifying when Between preferably 5~7h.
Present invention preferably employs monofilament extrusion equipments to carry out melting extrusion;The temperature of the melting extrusion is preferably 280~ 300 DEG C, the pressure of melting extrusion is preferably 7.5~8.5MPa.Monofilament after extrusion is cooling preferably at 60~80 DEG C, and preferably Drawing and setting is carried out at 170~250 DEG C, obtains transparent monofilament.
After obtaining transparent monofilament, the present invention dyes the transparent monofilament in dye bath, and dyeing is contaminated by 40~60 DEG C of beginnings, rises Temperature is washed, the translucent monofilament dyed to 20~60min of heat preservation after 125~135 DEG C after cooling.The present invention preferably with 1~ 2 DEG C/min is warming up to 125~135 DEG C.In the present invention, the dye bath includes 0.001~6%owf of disperse dyes;PH value is adjusted 0.001~3g/L of 0.05~3g/L of agent and levelling agent.In the present invention, the levelling agent is preferably selected from neopelex And/or polyethylene glycol monooleate;The pH adjusting agent is preferably selected from Acetic acid-sodium acetate buffer or acetic acid;The pH value The pH value of dye bath is preferably adjusted to 4~6 by regulator.The disperse dyes carry out the selection of different dyes according to client's needs; The disperse dyes preferably include one of fluorescein, fluorescein, pink, purple, gorgeous blue, color blue and bright red or a variety of.
In the present invention, the dye bath preferably includes 0.5~1g/L of 0.02~0.42%owf of disperse dyes and levelling agent. In a particular embodiment, the dye bath includes scattered fluorescent yellow 0.05%owf, disperses color indigo plant 0.15%owf, glacial acetic acid 0.2g/L With levelling agent 0.5g/L;
Or including scattered fluorescent yellow 0.23%owf, dispersion fluorescence red 0.19%owf, glacial acetic acid 0.2g/L and levelling agent 1g/ L;
Or including disperse violet 0.06%owf, disperse brilliant blue 0.15%owf, glacial acetic acid 0.2g/L and levelling agent 0.5g/L.
In the present invention, the dye bath when dyeing is than preferably 1:6~1:20;More preferably 1:10~1:15.
If chain tooth surface has the dyestuff of attachment when dyeing, the present invention is carried out preferably after cooling using piece alkali and sodium hydrosulfite Reduction cleaning;It is washed again after reduction cleaning, the translucent monofilament dyed.
After the translucent monofilament dyed, the present invention is by the translucent monofilament heated die of the dyeing, obtained company Continuous U-shaped element chain combination, obtains the chain tooth with translucent effect.Specifically, the present invention preferably twines the translucent monofilament of dyeing It is around on center bar, temperature is heated to 100~180 DEG C, is formed by the screw extruding of two spirals, forms the element of continuous U-shaped Chain.Two plain chains obtain continuous U-shaped element chain by combination;Two continuous U-shaped element chains are combined, chain tooth is obtained.
The present invention provides a kind of zippers, including have translucent effect made from preparation method described in above-mentioned technical proposal Chain tooth.The present invention preferably sutures chain tooth and two straps to obtain zipper.
The present invention makes drawing obtained by the dyeing to polyethylene terephthalate monofilament progress special formulation and technique Chain has translucent special surface effect.
In order to further illustrate the present invention, below with reference to embodiment to provided by the invention a kind of with translucent effect The preparation method and zipper of chain tooth are described in detail, but they cannot be interpreted as limiting the scope of the present invention.
Embodiment 1
Put polyethylene terephthalate slice into dry barrel, the continuous drying 7h at 150 DEG C;
By above-mentioned steps obtain by it is dry thoroughly after, stretch, then be formed at 230 DEG C, obtain transparent at 170 DEG C Monofilament;
Transparent monofilament obtained above is wound on stain kit, send to dyeing process and is dyed;What dyeing used Dye bath includes scattered fluorescent yellow 0.05% (owf), disperses color indigo plant 0.15% (owf), glacial acetic acid 0.2g/L, levelling agent 0.5g/L; Bath raio is 1:10.Acetic acid, levelling agent, dyestuff are sequentially added in dye vat, after mixing evenly, are contaminated in 40 DEG C of beginnings, with 2 DEG C/min liter Temperature is washed, the translucent monofilament dyed in 130 DEG C of heat preservation 20min after cooling;
The translucent monofilament dyed is wound on center bar, is heated to 160 DEG C, passes through the screw extruding of two spirals Molding, forms the plain chain of continuous U-shaped;Two plain chains obtain translucent chain tooth by combination;
Above-mentioned translucent chain tooth and two straps are combined with suture by automatic sewing machine, drawn Chain.
It is the apparent visual effect picture of zipper prepared by the embodiment of the present invention 1 referring to Fig. 1, Fig. 1;Drawing prepared by embodiment 1 Chain has translucent effect, possesses unique visual sense, improves the class of zipper.
Washing, PERSPIRATION COLOR FASTNESS and the fastness to rubbing of zipper prepared by embodiment 1 are at 4 grades or more.
Embodiment 2
Put polyethylene terephthalate slice into dry barrel, the continuous drying 7h at 150 DEG C;
By above-mentioned steps obtain by it is dry thoroughly after, stretch, then be formed at 230 DEG C, obtain transparent at 170 DEG C Monofilament;
Transparent monofilament obtained above is wound on stain kit, send to dyeing process and is dyed;What dyeing used Dye bath includes scattered fluorescent yellow 0.23% (owf), dispersion fluorescence red 0.19% (owf), glacial acetic acid 0.2g/L, levelling agent 1.0g/ L;Bath raio is 1:12.Acetic acid, levelling agent, dyestuff are sequentially added in dye vat, after mixing evenly, are contaminated in 60 DEG C of beginnings, with 2 DEG C/min Heating, in 130 DEG C of heat preservation 30min, is washed, the translucent monofilament dyed after cooling;
The translucent monofilament dyed is wound on center bar, is heated to 160 DEG C, passes through the screw extruding of two spirals Molding, forms the plain chain of continuous U-shaped;Two plain chains obtain translucent chain tooth by combination;
Above-mentioned translucent chain tooth and two straps are combined with suture by automatic sewing machine, drawn Chain.
Referring to fig. 2, Fig. 2 is the apparent visual effect picture of zipper prepared by the embodiment of the present invention 2;Drawing prepared by embodiment 2 Chain has translucent effect, possesses unique visual sense, improves the class of zipper.
Washing, PERSPIRATION COLOR FASTNESS and the fastness to rubbing of zipper prepared by embodiment 2 are at 4 grades or more.
Embodiment 3
Put polyethylene terephthalate slice into dry barrel, the continuous drying 7h at 160 DEG C;
By above-mentioned steps obtain by it is dry thoroughly after, stretch, then be formed at 230 DEG C, obtain transparent at 170 DEG C Monofilament;
Transparent monofilament obtained above is wound on stain kit, send to dyeing process and is dyed;What dyeing used Dye bath includes disperse violet 0.06% (owf), disperse brilliant blue 0.15% (owf), glacial acetic acid 0.2g/L, levelling agent 0.5g/L;Bath raio It is 1:15.Acetic acid, levelling agent, dyestuff are sequentially added in dye vat, after mixing evenly, are contaminated in 60 DEG C of beginnings, are heated up with 2 DEG C/min, In 130 DEG C of heat preservation 20min, piece alkali and sodium hydrosulfite reduction cleaning are used after cooling, then washed, the translucent list dyed Silk;
The translucent monofilament dyed is wound on center bar, is heated to 160 DEG C, passes through the screw extruding of two spirals Molding, forms the plain chain of continuous U-shaped;Two plain chains obtain translucent chain tooth by combination;
Above-mentioned translucent chain tooth and two straps are combined with suture by automatic sewing machine, drawn Chain.
It is the apparent visual effect picture of zipper prepared by the embodiment of the present invention 3 referring to Fig. 3, Fig. 3;Drawing prepared by embodiment 2 Chain has translucent effect, possesses unique visual sense, improves the class of zipper.
Washing, PERSPIRATION COLOR FASTNESS and the fastness to rubbing of zipper prepared by embodiment 3 are at 4 grades or more.
As seen from the above embodiment, the present invention provides a kind of preparation methods of chain tooth with translucent effect, including Following steps:After polyethylene terephthalate slice dehumidifying, melting extrusion, cooling and drawing and setting obtains transparent monofilament; Monofilament is dyed in dye bath, dyeing is contaminated by 40~60 DEG C of beginnings, 20~60min is kept the temperature after being warming up to 125~135 DEG C, after cooling Washing, the translucent monofilament dyed;The dye bath includes 0.001~6%owf of disperse dyes;PH adjusting agent 0.05~ 0.001~3g/L of 3g/L and levelling agent;By the translucent monofilament heated die of dyeing, continuous U-shaped element chain is obtained, combination is had There is the chain tooth of translucent effect.The present invention is raw material by using polyethylene terephthalate slice, in the dye of special formulation Bath neutralizes to be dyed under specified conditions, obtains the chain tooth with translucent effect.Chain tooth and strap, which combine to obtain, has semi-transparent obvious results The zipper of fruit possesses unique visual sense, promotes the class of zipper;Zipper also has preferable Washing, PERSPIRATION COLOR FASTNESS And fastness to rubbing.The experimental results showed that:For the Washing of zipper with translucent effect at 4 grades or more, sweat stain color is firm Degree is more than 4 ranks, and fastness to rubbing is more than 4 ranks.
The above is only a preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art For member, various improvements and modifications may be made without departing from the principle of the present invention, these improvements and modifications are also answered It is considered as protection scope of the present invention.

Claims (9)

1. a kind of preparation method of the chain tooth with translucent effect, includes the following steps:
After polyethylene terephthalate slice dehumidifying, melting extrusion, cooling and drawing and setting obtains transparent monofilament;
The transparent monofilament to be dyed in dye bath, dyeing is contaminated by 40~60 DEG C of beginning, heat preservation 20 after being warming up to 125~135 DEG C~ 60min is washed after cooling, the translucent monofilament dyed;
The dye bath includes 0.001~6%owf of disperse dyes;0.001~3g/ of 0.05~3g/L of pH adjusting agent and levelling agent L;
By the translucent monofilament heated die of dyeing, obtained continuous U-shaped element chain combination obtains the chain with translucent effect Tooth.
2. preparation method according to claim 1, which is characterized in that the levelling agent is selected from neopelex And/or polyethylene glycol monooleate.
3. preparation method according to claim 1, which is characterized in that the bath raio when dyeing is 1:6~1:20.
4. preparation method according to claim 1, which is characterized in that the temperature of the dehumidifying is 140~170 DEG C, dehumidifying Time be 5~7h.
5. preparation method according to claim 1, which is characterized in that the temperature of the melting extrusion is 280~300 DEG C, The pressure of melting extrusion is 7.5~8.5MPa;The temperature of drawing and setting is 170~250 DEG C.
6. preparation method according to claim 1, which is characterized in that dye bath includes 0.02~0.42%owf of disperse dyes With 0.5~1g/L of levelling agent.
7. preparation method according to claim 1, which is characterized in that the dye bath includes scattered fluorescent yellow 0.05%owf, Disperse color indigo plant 0.15%owf, glacial acetic acid 0.2g/L and levelling agent 0.5g/L;
Or including scattered fluorescent yellow 0.23%owf, dispersion fluorescence red 0.19%owf, glacial acetic acid 0.2g/L and levelling agent 1g/L;
Or including disperse violet 0.06%owf, disperse brilliant blue 0.15%owf, glacial acetic acid 0.2g/L and levelling agent 0.5g/L.
8. preparation method according to claim 1, which is characterized in that be warming up to 125~135 DEG C with 1~2 DEG C/min.
9. a kind of zipper, including the chain tooth with translucent effect made from any one of claim 1~8 preparation method.
CN201810915531.1A 2018-08-13 2018-08-13 A kind of chain tooth and zipper with translucent effect Pending CN108914627A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810915531.1A CN108914627A (en) 2018-08-13 2018-08-13 A kind of chain tooth and zipper with translucent effect

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Application Number Priority Date Filing Date Title
CN201810915531.1A CN108914627A (en) 2018-08-13 2018-08-13 A kind of chain tooth and zipper with translucent effect

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Publication Number Publication Date
CN108914627A true CN108914627A (en) 2018-11-30

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CN105421114A (en) * 2015-12-21 2016-03-23 深圳市联星服装辅料有限公司 PBT resin dyed zipper and production method
CN106317759A (en) * 2016-08-30 2017-01-11 道晟拉链科技(太仓)有限公司 Antibacterial resin zipper

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Application publication date: 20181130