CN108914610A - A kind of disposable surgical clothing water pressure resistance material - Google Patents

A kind of disposable surgical clothing water pressure resistance material Download PDF

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Publication number
CN108914610A
CN108914610A CN201810811669.7A CN201810811669A CN108914610A CN 108914610 A CN108914610 A CN 108914610A CN 201810811669 A CN201810811669 A CN 201810811669A CN 108914610 A CN108914610 A CN 108914610A
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Prior art keywords
parts
aqueous polyurethane
ether
disposable surgical
water pressure
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CN201810811669.7A
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Chinese (zh)
Inventor
刘华锋
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Wangjiang Mingda Textile Co Ltd
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Wangjiang Mingda Textile Co Ltd
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Priority to CN201810811669.7A priority Critical patent/CN108914610A/en
Publication of CN108914610A publication Critical patent/CN108914610A/en
Withdrawn legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30Low-molecular-weight compounds
    • C08G18/34Carboxylic acids; Esters thereof with monohydroxyl compounds
    • C08G18/348Hydroxycarboxylic acids
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40High-molecular-weight compounds
    • C08G18/48Polyethers
    • C08G18/4854Polyethers containing oxyalkylene groups having four carbon atoms in the alkylene group
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40High-molecular-weight compounds
    • C08G18/64Macromolecular compounds not provided for by groups C08G18/42 - C08G18/63
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/65Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
    • C08G18/66Compounds of groups C08G18/42, C08G18/48, or C08G18/52
    • C08G18/6666Compounds of group C08G18/48 or C08G18/52
    • C08G18/6692Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/34
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0002Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
    • D06N3/0011Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using non-woven fabrics
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0002Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
    • D06N3/0015Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using fibres of specified chemical or physical nature, e.g. natural silk
    • D06N3/0038Polyolefin fibres
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0043Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by their foraminous structure; Characteristics of the foamed layer or of cellular layers
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0056Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
    • D06N3/0059Organic ingredients with special effects, e.g. oil- or water-repellent, antimicrobial, flame-resistant, magnetic, bactericidal, odour-influencing agents; perfumes
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/12Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
    • D06N3/14Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00Properties of the materials
    • D06N2209/12Permeability or impermeability properties
    • D06N2209/126Permeability to liquids, absorption
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00Properties of the materials
    • D06N2209/16Properties of the materials having other properties
    • D06N2209/1671Resistance to bacteria, mildew, mould, fungi

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Professional, Industrial, Or Sporting Protective Garments (AREA)
  • Materials For Medical Uses (AREA)

Abstract

The invention discloses a kind of disposable surgical clothing water pressure resistance material, raw material includes:Polypropylene spunbondeds, aqueous polyurethane bottom material, aqueous polyurethane fretting map fabric;Wherein, aqueous polyurethane bottom material raw material includes:Polyether-ether-ketone modified aqueous polyurethane, adhesion promoter, thickener, wetting agent, defoaming agent;Aqueous polyurethane fretting map raw material of fabric includes:Polycarbonate waterborne polyurethane, foam stabilizer, antibacterial agent, thickener, wetting agent.Polyether-ether-ketone modified aqueous polyurethane is prepared using following technique:Prefabricated material is made in polytetrahydrofuran diol, hexamethylene diisocyanate, chain extender, the heating reaction of catalyst adding into acetone;End hydroxy polyether ether ketone, salt forming agent be added in prefabricated material to the reaction was continued, adds water dispersion, the obtained polyether-ether-ketone modified aqueous polyurethane of removal acetone.The resistance to hydrostatic pressure value of disposable surgical clothing material of the invention is high, soft, good anti-bacterial effect.

Description

A kind of disposable surgical clothing water pressure resistance material
Technical field
The present invention relates to field of nonwoven fabric technology more particularly to a kind of disposable surgical clothing water pressure resistance materials.
Background technique
Fabric used in operating coat belongs to medical loomage, mainly barrier property emphatically, including prevents liquid and micro- life The performance of object infiltration.Operating coat is broadly divided into use repeatly operating coat and disposable surgical clothing according to service condition.Repetition makes It is that common cotton fabric, polyester of high density fabric and PE, TPU, PTFE lamination coating film are multiple that material is mainly selected with operating coat Close operating coat.Disposable surgical clothing is with polypropylene spunbondeds, polyester fiber and the compound perverse cloth of water of wood pulp and polypropylene spun-bonded-molten Based on spray-spunbond composite non-weaving cloth, can antibacterial, antistatic, wear-resisting property is good, and price is lower, and application prospect is wide, but this The hydrostatic pressure resistant of kind disposable surgical clothing material is relatively low, and also poor to virion barriering efficiency, not being able to satisfy people completely needs It asks.
Summary of the invention
Technical problems based on background technology, the invention proposes a kind of disposable surgical clothing water pressure resistance material, Resistance to hydrostatic pressure value is high, soft, good anti-bacterial effect.
The present invention proposes that a kind of disposable surgical clothing water pressure resistance material, raw material include by weight:It is polypropylene spun-bonded 90-110 parts of cloth, 5-10 parts of aqueous polyurethane bottom material, 3-6 parts of aqueous polyurethane fretting map fabric;Wherein, aqueous polyurethane bottom material Raw material includes by weight:80-100 parts of polyether-ether-ketone modified aqueous polyurethane, 1-2 parts of adhesion promoter, thickener 1-4 Part, 1-2 parts of wetting agent, 0.5-1 parts of defoaming agent;Aqueous polyurethane fretting map raw material of fabric includes by weight:Polycarbonate type 80-120 parts of aqueous polyurethane, 3-5 parts of foam stabilizer, 1-3 parts of antibacterial agent, 1-2 parts of thickener, 1-2 parts of wetting agent.
Preferably, polyether-ether-ketone modified aqueous polyurethane is prepared using following technique:By polytetrahydrofuran diol, six methylenes Prefabricated material is made in group diisocyanate, chain extender, the heating reaction of catalyst adding into acetone;By end hydroxy polyether ether ketone, at salt The reaction was continued in the prefabricated material of agent addition, adds water dispersion, and polyether-ether-ketone modified aqueous polyurethane is made in removal acetone.
Preferably, polytetrahydrofuran diol, hexamethylene diisocyanate, end hydroxy polyether ether ketone weight ratio be 20- 30:3-6:55-65:10-20.
Preferably, chain extender is dihydromethyl propionic acid and/or tartaric acid, and salt forming agent is triethylamine and/or ethylenediamine, catalysis Agent is stannous octoate.
Preferably, the expansion ratio of aqueous polyurethane fretting map fabric is 1.2-1.6.
Preferably, foam stabilizer is lauryl sodium sulfate and/or AEO carboxylic acid sodium.
Preferably, antibacterial agent is organic quaternary ammonium salt antibacterial agent and/or nano-metal antibacterial agent.
Preferably, thickener is agent for polyacrylic acid thickening and/or polyurethanes thickener.
Preferably, wetting agent is polyoxyethylated alkyl phenol and/or polyoxyethylene aliphatic alcohol ether.
3-6 parts;Wherein, aqueous polyurethane bottom material raw material includes by weight:Polyether-ether-ketone modified aqueous polyurethane 80- 100 parts, 1-2 parts of adhesion promoter, 1-4 parts of thickener, 1-2 parts of wetting agent, 0.5-1 parts of defoaming agent;The micro- hair of aqueous polyurethane Steep raw material of fabric includes by weight:80-120 parts of polycarbonate waterborne polyurethane, 3-5 parts of foam stabilizer, 1-3 parts of antibacterial agent, 1-2 parts of thickener, 1-2 parts of wetting agent
The present invention using polyether-ether-ketone modified aqueous polyurethane as base-material, cooperation adhesion promoter, thickener, wetting agent and Defoaming agent obtains aqueous polyurethane bottom material, passes through adhesive force, water resistance and the film of the modified aqueous polyurethane bottom material of polyether-ether-ketone Intensity improves, and is remarkably improved the resistance to hydrostatic pressure performance of polypropylene spunbondeds;Using polycarbonate waterborne polyurethane as base-material, match Close foam stabilizer, antibacterial agent, thickener, wetting agent obtain aqueous polyurethane fretting map fabric, soft, adsorption effect is good, can It sterilizes, is antiviral, further increasing the performance of polypropylene spunbondeds.The present invention with polypropylene spunbondeds, aqueous polyurethane bottom material, Aqueous polyurethane fretting map fabric is raw material, rationally limits the preparation work of each component content and polyether-ether-ketone modified aqueous polyurethane Skill condition, the resistance to hydrostatic pressure value for obtaining disposable surgical clothing material is high, and soft, good anti-bacterial effect can satisfy medical It is required that.
Specific embodiment
In the following, technical solution of the present invention is described in detail by specific embodiment.
Embodiment 1
A kind of disposable surgical clothing water pressure resistance material, raw material include by weight:It is 90 parts of polypropylene spunbondeds, aqueous 5 parts of polyurethane bottom material, expansion ratio is 1.2 3 parts of aqueous polyurethane fretting map fabrics.
Wherein, aqueous polyurethane bottom material raw material includes by weight:80 parts of polyether-ether-ketone modified aqueous polyurethane, adhesive force 1 part of promotor, 1 part of agent for polyacrylic acid thickening, 1 part of polyoxyethylated alkyl phenol, 0.5 part of organic silicon defoaming agent;It is aqueous poly- Urethane fretting map raw material of fabric includes by weight:80 parts of polycarbonate waterborne polyurethane, 3 parts of lauryl sodium sulfate, have 1 part of machine quaternary ammonium salt antibacterial agent, 1 part of agent for polyacrylic acid thickening, 1 part of polyoxyethylated alkyl phenol.
Polyether-ether-ketone modified aqueous polyurethane is prepared using following technique:It is by weight 20:3:55:10 weigh respectively it is poly- Erythritan, hexamethylene diisocyanate, end hydroxy polyether ether ketone, polytetrahydrofuran diol, hexa-methylene two is different Cyanate, dihydromethyl propionic acid, stannous octoate adding into acetone are heated to 50 DEG C of reaction 2h and prefabricated material are made;By end hydroxy polyether Ether ketone, triethylamine are added in prefabricated material that the reaction was continued 1h, adds water dispersion, the obtained poly- ammonia of polyether-ether-ketone modified water-soluble of removal acetone Ester.
Embodiment 2
A kind of disposable surgical clothing water pressure resistance material, raw material include by weight:110 parts of polypropylene spunbondeds, water Property 10 parts of bottom material of polyurethane, expansion ratio be 1.6 6 parts of aqueous polyurethane fretting map fabrics.
Wherein, aqueous polyurethane bottom material raw material includes by weight:100 parts of polyether-ether-ketone modified aqueous polyurethane, attachment 2 parts of power promotor, 4 parts of polyurethanes thickener, 2 parts of polyoxyethylene aliphatic alcohol ether, 1 part of organic silicon defoaming agent;Aqueous poly- ammonia Ester fretting map raw material of fabric includes by weight:120 parts of polycarbonate waterborne polyurethane, AEO carboxylic acid sodium 5 parts, 3 parts of nano-metal antibacterial agent, 2 parts of polyurethanes thickener, 2 parts of polyoxyethylene aliphatic alcohol ether.
Polyether-ether-ketone modified aqueous polyurethane is prepared using following technique:It is by weight 30:6:65:20 weigh respectively it is poly- Erythritan, hexamethylene diisocyanate, end hydroxy polyether ether ketone, polytetrahydrofuran diol, hexa-methylene two is different Cyanate, tartaric acid, stannous octoate adding into acetone are heated to 60 DEG C of reaction 4h and prefabricated material are made;By end hydroxy polyether ether ketone, Triethylamine and/or ethylenediamine are added in prefabricated material that the reaction was continued 3h, adds water dispersion, the obtained polyether-ether-ketone modified water of removal acetone Property polyurethane.
Embodiment 3
A kind of disposable surgical clothing water pressure resistance material, raw material include by weight:100 parts of polypropylene spunbondeds, water Property 7 parts of bottom material of polyurethane, expansion ratio be 1.4 4.5 parts of aqueous polyurethane fretting map fabrics.
Wherein, aqueous polyurethane bottom material raw material includes by weight:90 parts of polyether-ether-ketone modified aqueous polyurethane, adhesive force 1.5 parts of promotor, 2.5 parts of agent for polyacrylic acid thickening, 1.5 parts of polyoxyethylene aliphatic alcohol ether, 0.7 part of organic silicon defoaming agent; Aqueous polyurethane fretting map raw material of fabric includes by weight:100 parts of polycarbonate waterborne polyurethane, lauryl sodium sulfate 4 parts, 2 parts of organic quaternary ammonium salt antibacterial agent, 1.5 parts of agent for polyacrylic acid thickening, 1.5 parts of polyoxyethylated alkyl phenol.
Polyether-ether-ketone modified aqueous polyurethane is prepared using following technique:It is by weight 5:1:12:3 weigh poly- four respectively Hydrogen furans glycol, hexamethylene diisocyanate, end hydroxy polyether ether ketone, by polytetrahydrofuran diol, two isocyanide of hexa-methylene Acid esters, dihydromethyl propionic acid, stannous octoate adding into acetone are heated to 55 DEG C of reaction 3h and prefabricated material are made;By end hydroxy polyether ether Ketone, triethylamine are added in prefabricated material that the reaction was continued 2h, adds water dispersion, the obtained poly- ammonia of polyether-ether-ketone modified water-soluble of removal acetone Ester.
Embodiment 4
A kind of disposable surgical clothing water pressure resistance material, raw material include by weight:100 parts of polypropylene spunbondeds, water Property 9 parts of bottom material of polyurethane, expansion ratio be 1.3 4 parts of aqueous polyurethane fretting map fabrics.
Wherein, aqueous polyurethane bottom material raw material includes by weight:85 parts of polyether-ether-ketone modified aqueous polyurethane, adhesive force 1.2 parts of promotor, 1.5 parts of agent for polyacrylic acid thickening, 1.8 parts of polyoxyethylene aliphatic alcohol ether, 0.6 part of organic silicon defoaming agent; Aqueous polyurethane fretting map raw material of fabric includes by weight:110 parts of polycarbonate waterborne polyurethane, lauryl sodium sulfate 3.5 parts, 1.5 parts of nano-metal antibacterial agent, 1.2 parts of agent for polyacrylic acid thickening, 1.8 parts of polyoxyethylene aliphatic alcohol ether.
Polyether-ether-ketone modified aqueous polyurethane is prepared using following technique:It is by weight 7:1:15:5 weigh poly- four respectively Hydrogen furans glycol, hexamethylene diisocyanate, end hydroxy polyether ether ketone, by polytetrahydrofuran diol, two isocyanide of hexa-methylene Acid esters, tartaric acid, stannous octoate adding into acetone are heated to 50 DEG C of reaction 4h and prefabricated material are made;By end hydroxy polyether ether ketone, second Diamines is added in prefabricated material that the reaction was continued 2.5h, adds water dispersion, the obtained polyether-ether-ketone modified aqueous polyurethane of removal acetone.
Disposable surgical clothing is made in embodiment 1-4, by its resistance to hydrostatic pressure performance of GB/T4744-1997 standard testing, is surveyed Try data such as the following table 1.
Table 1
Test item Embodiment 1 Embodiment 2 Embodiment 3 Embodiment 4
Resistance to hydrostatic pressure value/Pa 4550 4660 4580 4520
By upper table data:The resistance to hydrostatic pressure value of disposable surgical clothing of the invention reaches 4500pa or more, water pressure resistance It has excellent performance.
The foregoing is only a preferred embodiment of the present invention, but scope of protection of the present invention is not limited thereto, Anyone skilled in the art in the technical scope disclosed by the present invention, according to the technique and scheme of the present invention and its Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.

Claims (9)

1. a kind of disposable surgical clothing water pressure resistance material, which is characterized in that its raw material includes by weight:Polypropylene spunbondeds 90-110 parts, 5-10 parts of aqueous polyurethane bottom material, 3-6 parts of aqueous polyurethane fretting map fabric;Wherein, aqueous polyurethane bottom material is former Material include by weight:80-100 parts of polyether-ether-ketone modified aqueous polyurethane, 1-2 parts of adhesion promoter, 1-4 parts of thickener, 1-2 parts of wetting agent, 0.5-1 parts of defoaming agent;Aqueous polyurethane fretting map raw material of fabric includes by weight:Polycarbonate type is aqueous 80-120 parts of polyurethane, 3-5 parts of foam stabilizer, 1-3 parts of antibacterial agent, 1-2 parts of thickener, 1-2 parts of wetting agent.
2. disposable surgical clothing water pressure resistance material according to claim 1, which is characterized in that polyether-ether-ketone modified water-soluble is poly- Urethane is prepared using following technique:Polytetrahydrofuran diol, hexamethylene diisocyanate, chain extender, catalyst are added third Prefabricated material is made in heating reaction in ketone;End hydroxy polyether ether ketone, salt forming agent be added in prefabricated material to the reaction was continued, adds water point It dissipates, polyether-ether-ketone modified aqueous polyurethane is made in removal acetone.
3. disposable surgical clothing water pressure resistance material according to claim 2, which is characterized in that polytetrahydrofuran diol, six Methylene diisocyanate, end hydroxy polyether ether ketone weight ratio be 20-30:3-6:55-65:10-20.
4. disposable surgical clothing water pressure resistance material according to claim 2, which is characterized in that chain extender is dihydroxymethyl third Acid and/or tartaric acid, salt forming agent are triethylamine and/or ethylenediamine, and catalyst is stannous octoate.
5. disposable surgical clothing water pressure resistance material according to claim 1, which is characterized in that aqueous polyurethane fretting map face The expansion ratio of material is 1.2-1.6.
6. disposable surgical clothing water pressure resistance material according to claim 1, which is characterized in that foam stabilizer is dodecyl sulphur Sour sodium and/or AEO carboxylic acid sodium.
7. disposable surgical clothing water pressure resistance material according to claim 1, which is characterized in that antibacterial agent is organic quaternary ammonium salt Class antibacterial agent and/or nano-metal antibacterial agent.
8. disposable surgical clothing water pressure resistance material according to claim 1, which is characterized in that thickener is polyacrylic Thickener and/or polyurethanes thickener.
9. disposable surgical clothing water pressure resistance material according to claim 1, which is characterized in that wetting agent is polyoxyethylene alkane Base phenolic ether and/or polyoxyethylene aliphatic alcohol ether.
CN201810811669.7A 2018-07-23 2018-07-23 A kind of disposable surgical clothing water pressure resistance material Withdrawn CN108914610A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111745952A (en) * 2020-07-06 2020-10-09 福建华峰运动用品科技有限公司 Waterborne polyurethane primer, 3D (three-dimensional) pattern fabric using primer and manufacturing method of fabric
WO2021001445A1 (en) 2019-07-01 2021-01-07 Chemical Intelligence Limited Antimicrobial dyes for healthcare apparel

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2021001445A1 (en) 2019-07-01 2021-01-07 Chemical Intelligence Limited Antimicrobial dyes for healthcare apparel
CN111745952A (en) * 2020-07-06 2020-10-09 福建华峰运动用品科技有限公司 Waterborne polyurethane primer, 3D (three-dimensional) pattern fabric using primer and manufacturing method of fabric
CN111745952B (en) * 2020-07-06 2021-12-10 福建华峰运动用品科技有限公司 3D (three-dimensional) pattern fabric using waterborne polyurethane primer and manufacturing method thereof

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