CN108912950A - A kind of anti-rotten water-base epoxy priming paint peculiar to vessel - Google Patents

A kind of anti-rotten water-base epoxy priming paint peculiar to vessel Download PDF

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Publication number
CN108912950A
CN108912950A CN201810552211.4A CN201810552211A CN108912950A CN 108912950 A CN108912950 A CN 108912950A CN 201810552211 A CN201810552211 A CN 201810552211A CN 108912950 A CN108912950 A CN 108912950A
Authority
CN
China
Prior art keywords
parts
oxide
vessel
paint
base epoxy
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810552211.4A
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Chinese (zh)
Inventor
岳晓清
钱晓平
杨尧
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Wuxi Hailun Paint Co Ltd
Original Assignee
Wuxi Hailun Paint Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Wuxi Hailun Paint Co Ltd filed Critical Wuxi Hailun Paint Co Ltd
Priority to CN201810552211.4A priority Critical patent/CN108912950A/en
Publication of CN108912950A publication Critical patent/CN108912950A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16Antifouling paints; Underwater paints
    • C09D5/1687Use of special additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2296Oxides; Hydroxides of metals of zinc
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Paints Or Removers (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)

Abstract

The invention discloses a kind of anti-rotten water-base epoxy priming paint peculiar to vessel, and comprising mian paint, secondary paint, wherein mian paint includes in parts by weight:12-18 parts of aliphatic polyester addition product, 52-60 parts of distilled water, 3-8 parts of talcum powder, 3-8 parts of mica powder, 1-2 parts of thixotropic agent, 4-8 parts of titanium dioxide, 1.5-3 parts of anti-flash rusting agent, 0.5-0.8 parts of sub-nanometer metal oxide, 5-7.5 parts of trbasic zinc phosphate, it is wax powder 0.5-1.5 parts ultra-fine, 0.05-0.4 parts of viscosity-controlling agent;Secondary enamel-cover contains in parts by weight:50-58 parts of epoxy resin, 2.2-2.8 parts of isopropanol, 38-45 parts of emulsified water.Anti- rotten water-base epoxy priming paint peculiar to vessel of the invention, has both anti-corrosion and soil resistance, and have good and consistent compactness, can form preferable mass exchange rate and interface state with seawater, long-acting durable, and process recipe is simply economical, with very high cost performance.

Description

A kind of anti-rotten water-base epoxy priming paint peculiar to vessel
Technical field
The present invention relates to a kind of coating, especially a kind of anti-rotten water-base epoxy priming paint peculiar to vessel.
Background technique
Marine fouling organism adherency is grown in the underwater shell position of ship, not only increases hull sole mass, Er Qiexian Work increases hull bottom surface roughness, increases frictional resistance when ship's navigation, in many cases, the surface flatness of paint The poor normal time, which steeps the aquatic organisms such as the seaweed in ocean in the seawater, can adhere to hull surface corrosion hull, it is often more important that corrosion resistant Corrosion can be poor, and anti-pollution is poor, and the antifouling time is short, and stability is bad.
Often ship steel structure surface covering aging dropping situations of the bubble in seawater are serious, and many coating are difficult to reach at present Technical requirements, existing ship steel structure paint are difficult to accomplish that Corrosion Protection is good simultaneously, and smoothness, compactness, surface are consistent The multiple requirements such as property, decorative performance be good, so, a kind of research and development of aqueous anti-corrosion primer seem of crucial importance.
Summary of the invention
Goal of the invention:In order to develop a kind of long life anti corrosion paint for ship, and maintain its surface depolluting properties, this hair It is bright that a kind of anti-rotten water-base epoxy priming paint peculiar to vessel is provided, to solve problems of the prior art.
Summary of the invention:A kind of anti-rotten water-base epoxy priming paint peculiar to vessel, comprising mian paint, secondary paint, wherein mian paint includes following weight The component of part:
Pair paint contains the following parts by weight component:
50-58 parts of epoxy resin
2.2-2.8 parts of isopropanol
38-45 parts of emulsified water.
Preferably, the aliphatic polyester addition product is 80% aqueous solution of the addition product.Pre-assigned aliphatic poly Ester water-base epoxy priming paint, various aspects tolerance is stronger, and the raw material that can be used as marine paint uses.
Preferably, the anti-flash rusting agent is the anti-flash rusting agent of the auspicious treasured Raybo 60 in the U.S..Anti- flash rusting agent does not allow the production of corrosion It is raw, while the comprehensive benefits such as the long-term water resistance of paint film, in-can preservation can be improved.
Preferably, the viscosity-controlling agent is viscosity-controlling agent BYK-347.Viscosity-controlling agent BYK-347 is for aqueous Coating, printing ink and coating for paper, promote the wetting of ground and reducing surface tension strongly, also promote flowing and levelling Property, have no effect on coating recoatability.
Preferably, the sub-nanometer metal oxide be manganese oxide, nickel oxide, cuprous oxide, copper oxide, zinc oxide, One of titanium oxide, cobalt oxide, ferrous oxide, iron oxide, molybdenum oxide, tin oxide, silver oxide or a combination thereof.It receives the above Asia Rice metal oxide can efficiently promote polishing certainly for paint, obtain consistency and compactness effect, and increase antiseptic property.
Preferably, the ultra-fine wax powder be low molecule polytetrafluoroethylresin, polyethylene wax, polyamide wax, haze tallow, beeswax, One of ceresine, pure lanocerin or a combination thereof.The above ultra-fine wax powder component materials are easy to get, economical, emulsifiable after addition, Flowing, the film performance of coating can be improved.
Preferably, the mian paint and secondary paint weight ratio are 55:45.It is used after mian paint, secondary paint allotment, with Good matching property, and there is the convenience converted i.e..
The beneficial effects of the present invention are:One kind of the invention anti-rotten water-base epoxy priming paint peculiar to vessel, is formulated simple, resistant. The paint ingredient on aqueous basis keeps it good with the compatibility of seawater, is formulated and is easy allotment;Thixotropic agent, anti-flash rusting agent guarantee coating Service performance is not easy to be destroyed;Sub-nanometer metal oxide enhances the smooth of lacquer painting, anti-corrosion, antifouling capacity, and increases paint film Consistency, so that it is had good mechanics and physical and chemical performance;The dispersibility of ultra-fine wax powder makes each component form good levelling And coating property.Anti- rotten water-base epoxy priming paint peculiar to vessel of the invention, has both anti-corrosion and soil resistance, and have well and consistent densification Property, preferable mass exchange rate and interface state can be formed with seawater, it is long-acting durable, and process recipe is simply economical, tool There is very high cost performance.
Specific embodiment
In order to illustrate the technical solutions in the embodiments of the present application or in the prior art more clearly, letter will be made to embodiment below Singly introduce.A kind of anti-rotten water-base epoxy priming paint peculiar to vessel, including parts by weight of component involved in the embodiment in table 1.
Component (the unit of 1 embodiment of table:Parts by weight)
Wherein, the sub-nanometer metal oxide is manganese oxide, nickel oxide, cuprous oxide, copper oxide, zinc oxide, oxidation One of titanium, cobalt oxide, ferrous oxide, iron oxide, molybdenum oxide, tin oxide, silver oxide or a combination thereof;The ultra-fine wax powder For one of low molecule polytetrafluoroethylresin, polyethylene wax, polyamide wax, haze tallow, beeswax, ceresine, pure lanocerin or its group It closes.
In use, by the mian paint and secondary paint according to parts by weight 55:45 proportions can be used after mixing evenly.
Basic performance test result is shown in Table 2, according to GB/T 9274-1988, GB/T9780-2005, GB/T 4893- 1992, GB/T 1728-1979, GB 9286-1998, ISO 2429-1992.
The basic performance indices of 2 embodiment of table
Above embodiments are only to illustrate the preferred technical solution of the present invention, it is noted that for the general of the art For logical technical staff, without departing from the principle of the present invention, several improvement made or equivalent replacement are accordingly to be regarded as this The protection scope of invention should be covered within the scope of the claims of the present invention.

Claims (7)

1. a kind of anti-rotten water-base epoxy priming paint peculiar to vessel, which is characterized in that comprising mian paint, secondary paint, wherein mian paint includes following weight The component of part:
12-18 parts of aliphatic polyester addition product
52-60 parts of distilled water
3-8 parts of talcum powder
3-8 parts of mica powder
1-2 parts of thixotropic agent
4-8 parts of titanium dioxide
1.5-3 parts of anti-flash rusting agent
0.5-0.8 parts of sub-nanometer metal oxide
5-7.5 parts of trbasic zinc phosphate
Ultra-fine wax powder 0.5-1.5 parts
0.05-0.4 parts of viscosity-controlling agent;
Pair paint contains the following parts by weight component:
50-58 parts of epoxy resin
2.2-2.8 parts of isopropanol
38-45 parts of emulsified water.
2. a kind of anti-rotten water-base epoxy priming paint peculiar to vessel as described in claim 1, which is characterized in that the aliphatic polyester addition Object is 80% aqueous solution of the addition product.
3. a kind of anti-rotten water-base epoxy priming paint peculiar to vessel as described in claim 1, which is characterized in that the anti-flash rusting agent is beauty The anti-flash rusting agent of the auspicious treasured Raybo 60 of state.
4. a kind of anti-rotten water-base epoxy priming paint peculiar to vessel as described in claim 1, which is characterized in that the viscosity-controlling agent is glutinous Spend regulator BYK-347.
5. a kind of anti-rotten water-base epoxy priming paint peculiar to vessel as described in claim 1, which is characterized in that the sub-nanometer metal oxidation Object is manganese oxide, nickel oxide, cuprous oxide, copper oxide, zinc oxide, titanium oxide, cobalt oxide, ferrous oxide, iron oxide, oxidation One of molybdenum, tin oxide, silver oxide or a combination thereof.
6. a kind of anti-rotten water-base epoxy priming paint peculiar to vessel as described in claim 1, which is characterized in that the ultra-fine wax powder is low point One of sub- polytetrafluoroethylene (PTFE), polyethylene wax, polyamide wax, haze tallow, beeswax, ceresine, pure lanocerin or a combination thereof.
7. a kind of anti-rotten water-base epoxy priming paint peculiar to vessel as described in claim 1, which is characterized in that the mian paint and secondary paint weight The ratio between part is 55:45.
CN201810552211.4A 2018-05-31 2018-05-31 A kind of anti-rotten water-base epoxy priming paint peculiar to vessel Pending CN108912950A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810552211.4A CN108912950A (en) 2018-05-31 2018-05-31 A kind of anti-rotten water-base epoxy priming paint peculiar to vessel

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810552211.4A CN108912950A (en) 2018-05-31 2018-05-31 A kind of anti-rotten water-base epoxy priming paint peculiar to vessel

Publications (1)

Publication Number Publication Date
CN108912950A true CN108912950A (en) 2018-11-30

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101955718A (en) * 2009-07-16 2011-01-26 上海船舶工艺研究所 High-permeability epoxy resin primer as well as preparation method and application thereof
CN105038464A (en) * 2015-09-10 2015-11-11 广州慧谷化学有限公司 Water-based high-corrosion-resistance coating with excellent stamping performance and preparing method and application of water-based high-corrosion-resistance coating
CN106700821A (en) * 2016-11-10 2017-05-24 青岛益群漆业集团有限公司 Water-borne automobile oil tank paint
CN108084843A (en) * 2017-12-13 2018-05-29 成都拜迪新材料有限公司 Applied to face composite bed water paint in the bottom in container field and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101955718A (en) * 2009-07-16 2011-01-26 上海船舶工艺研究所 High-permeability epoxy resin primer as well as preparation method and application thereof
CN105038464A (en) * 2015-09-10 2015-11-11 广州慧谷化学有限公司 Water-based high-corrosion-resistance coating with excellent stamping performance and preparing method and application of water-based high-corrosion-resistance coating
CN106700821A (en) * 2016-11-10 2017-05-24 青岛益群漆业集团有限公司 Water-borne automobile oil tank paint
CN108084843A (en) * 2017-12-13 2018-05-29 成都拜迪新材料有限公司 Applied to face composite bed water paint in the bottom in container field and preparation method thereof

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Application publication date: 20181130