CN108912525A - A kind of fire-retardant packaging material of compression-resistant type and preparation method thereof - Google Patents
A kind of fire-retardant packaging material of compression-resistant type and preparation method thereof Download PDFInfo
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- CN108912525A CN108912525A CN201810956772.0A CN201810956772A CN108912525A CN 108912525 A CN108912525 A CN 108912525A CN 201810956772 A CN201810956772 A CN 201810956772A CN 108912525 A CN108912525 A CN 108912525A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/04—Homopolymers or copolymers of styrene
- C08L25/06—Polystyrene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2227—Oxides; Hydroxides of metals of aluminium
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Polymers & Plastics (AREA)
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Abstract
The invention discloses fire-retardant packaging material of a kind of compression-resistant type and preparation method thereof, the fire-retardant packaging material of compression-resistant type includes the raw material of following parts by weight：25-40 parts of polystyrene, 20-35 parts of polyurethane, 6-12 parts of dilauryl thiodipropionate, 7-14 parts of polymethylacrylic acid, 3-8 parts of propylene glycol monomethyl ether, 3-10 parts of aluminium hydroxide, 4-8 parts of kayexalate, poly- acetimide 2-6 parts, 5-12 parts of carbon nano-fiber, 8-12 parts of talcum powder, 7-15 parts of cumyl peroxide, 4-10 parts of alumina silicate fibre, 3-7 parts of sodium-based montmorillonite, 2-6 parts of phenyl silane, 5-10 parts of poly (propylene carbonate).The fire-retardant packaging material of compression-resistant type in the present invention has many advantages, such as that compression strength is high, anti-flammability is strong.
Description
Technical field
The present invention relates to a kind of packaging materials, more particularly to fire-retardant packaging material of a kind of compression-resistant type and preparation method thereof.
Background technique
Packaging material, which refers to, meets product packaging for manufacturing packing container, packing and decorating, packages printing, packed and transported etc.
Material used in it is required that, it both includes metal, plastics, glass, ceramics, paper, bamboo sheet, wild mushroom class, natural fiber, chemistry fibre
The main packaging material such as dimension, composite material, and including auxiliary materials such as coating, adhesive, strapping, decoration, printing materials.So
And with the industrialized development of society, the packaging material that all trades and professions need to be related to is multifarious, many kinds of while right
The demand of corresponding packaging material steeply rises.However, the compressive property and anti-flammability of existing packaging material are generally all poor,
It is easy to be damaged when being hit, to realize the good protection being difficult to packaging product.
Summary of the invention
The object of the present invention is to provide a kind of fire-retardant packaging materials of compression-resistant type, strong etc. with compression strength height, anti-flammability
Advantage.
To achieve the above object, the present invention provides the following technical solutions：
A kind of fire-retardant packaging material of compression-resistant type comprising the raw material of following parts by weight：25-40 parts of polystyrene, poly- ammonia
20-35 parts of ester, 6-12 parts of dilauryl thiodipropionate, 7-14 parts of polymethylacrylic acid, 3-8 parts of propylene glycol monomethyl ether, hydroxide
3-10 parts of aluminium, 4-8 parts of kayexalate, poly- acetimide 2-6 parts, 5-12 parts of carbon nano-fiber, 8-12 parts of talcum powder, mistake
Diisopropylbenzene (DIPB) 7-15 parts of oxidation, 4-10 parts of alumina silicate fibre, 3-7 parts of sodium-based montmorillonite, 2-6 parts of phenyl silane, polymerized thylene carbonate third
5-10 parts of ester.
Preferably, the fire-retardant packaging material of the compression-resistant type includes the raw material of following parts by weight：40 parts of polystyrene, poly- ammonia
30 parts of ester, 8 parts of dilauryl thiodipropionate, 11 parts of polymethylacrylic acid, 7 parts of propylene glycol monomethyl ether, 7 parts of aluminium hydroxide, polyphenyl
5 parts of vinyl sulfonic acid sodium, 3 parts of poly- acetimide, 9 parts of carbon nano-fiber, 8 parts of talcum powder, 13 parts of cumyl peroxide, alumina silicate
6 parts of fiber, 4 parts of sodium-based montmorillonite, 3 parts of phenyl silane, 7 parts of poly (propylene carbonate).
Preferably, the fire-retardant packaging material of the compression-resistant type includes the raw material of following parts by weight：33 parts of polystyrene, poly- ammonia
26 parts of ester, 12 parts of dilauryl thiodipropionate, 11 parts of polymethylacrylic acid, 7 parts of propylene glycol monomethyl ether, 10 parts of aluminium hydroxide, gather
6 parts of sodium styrene sulfonate, 6 parts of poly- acetimide, 11 parts of carbon nano-fiber, 10 parts of talcum powder, 10 parts of cumyl peroxide, silicon
8 parts of sour aluminum fiber, 4 parts of sodium-based montmorillonite, 3 parts of phenyl silane, 5 parts of poly (propylene carbonate).
Preferably, the fire-retardant packaging material of the compression-resistant type includes the raw material of following parts by weight：28 parts of polystyrene, poly- ammonia
35 parts of ester, 10 parts of dilauryl thiodipropionate, 11 parts of polymethylacrylic acid, 7 parts of propylene glycol monomethyl ether, 8 parts of aluminium hydroxide, polyphenyl
6 parts of vinyl sulfonic acid sodium, 4 parts of poly- acetimide, 8 parts of carbon nano-fiber, 11 parts of talcum powder, 12 parts of cumyl peroxide, silicic acid
7 parts of aluminum fiber, 6 parts of sodium-based montmorillonite, 5 parts of phenyl silane, 6 parts of poly (propylene carbonate).
Preferably, the fire-retardant packaging material of the compression-resistant type includes the raw material of following parts by weight：35 parts of polystyrene, poly- ammonia
27 parts of ester, 9 parts of dilauryl thiodipropionate, 10 parts of polymethylacrylic acid, 5 parts of propylene glycol monomethyl ether, 5 parts of aluminium hydroxide, polyphenyl
7 parts of vinyl sulfonic acid sodium, 4 parts of poly- acetimide, 8 parts of carbon nano-fiber, 10 parts of talcum powder, 12 parts of cumyl peroxide, silicic acid
6 parts of aluminum fiber, 5 parts of sodium-based montmorillonite, 5 parts of phenyl silane, 8 parts of poly (propylene carbonate).
Preferably, the fire-retardant packaging material of the compression-resistant type includes the raw material of following parts by weight：36 parts of polystyrene, poly- ammonia
27 parts of ester, 8 parts of dilauryl thiodipropionate, 11 parts of polymethylacrylic acid, 6 parts of propylene glycol monomethyl ether, 6 parts of aluminium hydroxide, polyphenyl
7 parts of vinyl sulfonic acid sodium, 3 parts of poly- acetimide, 11 parts of carbon nano-fiber, 9 parts of talcum powder, 13 parts of cumyl peroxide, silicic acid
6 parts of aluminum fiber, 6 parts of sodium-based montmorillonite, 3 parts of phenyl silane, 5 parts of poly (propylene carbonate).
The preparation method of the fire-retardant packaging material of the compression-resistant type, includes the following steps：
(1) according to parts by weight than weighing each raw material component；
(2) each raw material component having had been prepared in step (1) is added in blender and is stirred, rabble furnace is heated to 178-
186 DEG C, mixing speed is 310-335 revs/min, persistently stirs 45-60 minutes, obtains material magma；
(3) the material magma in step (2) is squeezed；
(4) material obtained to extruding carries out cooling, dry, then draws high plastotype, as finished product.
Compared with prior art, the beneficial effects of the invention are as follows：
The fire-retardant packaging material of compression-resistant type in the present invention adds thio using polystyrene and polyurethane as primary raw material
Dipropionic acid dilauryl, propylene glycol monomethyl ether, aluminium hydroxide, kayexalate, carbon nano-fiber, alumina silicate fibre, sodium base
The auxiliary materials such as montmorillonite and poly (propylene carbonate) make it have compression strength height, flame retardant property by each raw material component rational proportion
The advantages that good.
Specific embodiment
Below with reference to the embodiment technical solution that the present invention will be described in detail, but protection scope is not limited thereto.
Embodiment one：
A kind of fire-retardant packaging material of compression-resistant type comprising the raw material of following parts by weight：40 parts of polystyrene, polyurethane 30
Part, 8 parts of dilauryl thiodipropionate, 11 parts of polymethylacrylic acid, 7 parts of propylene glycol monomethyl ether, 7 parts of aluminium hydroxide, polystyrene
5 parts of sodium sulfonate, 3 parts of poly- acetimide, 9 parts of carbon nano-fiber, 8 parts of talcum powder, 13 parts of cumyl peroxide, alumina silicate fibre
6 parts, 4 parts of sodium-based montmorillonite, 3 parts of phenyl silane, 7 parts of poly (propylene carbonate).
The preparation method of the fire-retardant packaging material of the compression-resistant type, includes the following steps：
(1) according to parts by weight than weighing each raw material component；
(2) each raw material component having had been prepared in step (1) is added in blender and is stirred, rabble furnace is heated to 178-
186 DEG C, mixing speed is 310-335 revs/min, persistently stirs 45-60 minutes, obtains material magma；
(3) the material magma in step (2) is squeezed；
(4) material obtained to extruding carries out cooling, dry, then draws high plastotype, as finished product.
Embodiment two：
A kind of fire-retardant packaging material of compression-resistant type comprising the raw material of following parts by weight：33 parts of polystyrene, polyurethane 26
Part, 12 parts of dilauryl thiodipropionate, 11 parts of polymethylacrylic acid, 7 parts of propylene glycol monomethyl ether, 10 parts of aluminium hydroxide, polyphenyl second
6 parts of alkene sodium sulfonate, 6 parts of poly- acetimide, 11 parts of carbon nano-fiber, 10 parts of talcum powder, 10 parts of cumyl peroxide, alumina silicate
8 parts of fiber, 4 parts of sodium-based montmorillonite, 3 parts of phenyl silane, 5 parts of poly (propylene carbonate).
The preparation method of the fire-retardant packaging material of the compression-resistant type, includes the following steps：
(1) according to parts by weight than weighing each raw material component；
(2) each raw material component having had been prepared in step (1) is added in blender and is stirred, rabble furnace is heated to 178-
186 DEG C, mixing speed is 310-335 revs/min, persistently stirs 45-60 minutes, obtains material magma；
(3) the material magma in step (2) is squeezed；
(4) material obtained to extruding carries out cooling, dry, then draws high plastotype, as finished product.
Embodiment three：
A kind of fire-retardant packaging material of compression-resistant type comprising the raw material of following parts by weight：28 parts of polystyrene, polyurethane 35
Part, 10 parts of dilauryl thiodipropionate, 11 parts of polymethylacrylic acid, 7 parts of propylene glycol monomethyl ether, 8 parts of aluminium hydroxide, polystyrene
6 parts of sodium sulfonate, 4 parts of poly- acetimide, 8 parts of carbon nano-fiber, 11 parts of talcum powder, 12 parts of cumyl peroxide, aluminium silicate fiber
7 parts, 6 parts of sodium-based montmorillonite, 5 parts of phenyl silane, 6 parts of poly (propylene carbonate) of dimension.
The preparation method of the fire-retardant packaging material of the compression-resistant type, includes the following steps：
(1) according to parts by weight than weighing each raw material component；
(2) each raw material component having had been prepared in step (1) is added in blender and is stirred, rabble furnace is heated to 178-
186 DEG C, mixing speed is 310-335 revs/min, persistently stirs 45-60 minutes, obtains material magma；
(3) the material magma in step (2) is squeezed；
(4) material obtained to extruding carries out cooling, dry, then draws high plastotype, as finished product.
Example IV：
A kind of fire-retardant packaging material of compression-resistant type comprising the raw material of following parts by weight：35 parts of polystyrene, polyurethane 27
Part, 9 parts of dilauryl thiodipropionate, 10 parts of polymethylacrylic acid, 5 parts of propylene glycol monomethyl ether, 5 parts of aluminium hydroxide, polystyrene
7 parts of sodium sulfonate, 4 parts of poly- acetimide, 8 parts of carbon nano-fiber, 10 parts of talcum powder, 12 parts of cumyl peroxide, aluminium silicate fiber
6 parts, 5 parts of sodium-based montmorillonite, 5 parts of phenyl silane, 8 parts of poly (propylene carbonate) of dimension.
The preparation method of the fire-retardant packaging material of the compression-resistant type, includes the following steps：
(1) according to parts by weight than weighing each raw material component；
(2) each raw material component having had been prepared in step (1) is added in blender and is stirred, rabble furnace is heated to 178-
186 DEG C, mixing speed is 310-335 revs/min, persistently stirs 45-60 minutes, obtains material magma；
(3) the material magma in step (2) is squeezed；
(4) material obtained to extruding carries out cooling, dry, then draws high plastotype, as finished product.
Embodiment five：
A kind of fire-retardant packaging material of compression-resistant type comprising the raw material of following parts by weight：36 parts of polystyrene, polyurethane 27
Part, 8 parts of dilauryl thiodipropionate, 11 parts of polymethylacrylic acid, 6 parts of propylene glycol monomethyl ether, 6 parts of aluminium hydroxide, polystyrene
7 parts of sodium sulfonate, 3 parts of poly- acetimide, 11 parts of carbon nano-fiber, 9 parts of talcum powder, 13 parts of cumyl peroxide, aluminium silicate fiber
6 parts, 6 parts of sodium-based montmorillonite, 3 parts of phenyl silane, 5 parts of poly (propylene carbonate) of dimension.
The preparation method of the fire-retardant packaging material of the compression-resistant type, includes the following steps：
(1) according to parts by weight than weighing each raw material component；
(2) each raw material component having had been prepared in step (1) is added in blender and is stirred, rabble furnace is heated to 178-
186 DEG C, mixing speed is 310-335 revs/min, persistently stirs 45-60 minutes, obtains material magma；
(3) the material magma in step (2) is squeezed；
(4) material obtained to extruding carries out cooling, dry, then draws high plastotype, as finished product.
Embodiment six：
A kind of fire-retardant packaging material of compression-resistant type comprising the raw material of following parts by weight：25 parts of polystyrene, polyurethane 20
Part, 6 parts of dilauryl thiodipropionate, 7 parts of polymethylacrylic acid, 3 parts of propylene glycol monomethyl ether, 3 parts of aluminium hydroxide, polystyrene sulphur
4 parts of sour sodium, 2 parts of poly- acetimide, 5 parts of carbon nano-fiber, 8 parts of talcum powder, 7 parts of cumyl peroxide, alumina silicate fibre 4
Part, 3 parts of sodium-based montmorillonite, 2 parts of phenyl silane, 5 parts of poly (propylene carbonate).
The preparation method of the fire-retardant packaging material of the compression-resistant type, includes the following steps：
(1) according to parts by weight than weighing each raw material component；
(2) each raw material component having had been prepared in step (1) is added in blender and is stirred, rabble furnace is heated to 178-
186 DEG C, mixing speed is 310-335 revs/min, persistently stirs 45-60 minutes, obtains material magma；
(3) the material magma in step (2) is squeezed；
(4) material obtained to extruding carries out cooling, dry, then draws high plastotype, as finished product.
Embodiment seven：
A kind of fire-retardant packaging material of compression-resistant type comprising the raw material of following parts by weight：40 parts of polystyrene, polyurethane 35
Part, 12 parts of dilauryl thiodipropionate, 14 parts of polymethylacrylic acid, 8 parts of propylene glycol monomethyl ether, 10 parts of aluminium hydroxide, polyphenyl second
8 parts of alkene sodium sulfonate, 6 parts of poly- acetimide, 12 parts of carbon nano-fiber, 12 parts of talcum powder, 15 parts of cumyl peroxide, alumina silicate
10 parts of fiber, 7 parts of sodium-based montmorillonite, 6 parts of phenyl silane, 10 parts of poly (propylene carbonate).
The preparation method of the fire-retardant packaging material of the compression-resistant type, includes the following steps：
(1) according to parts by weight than weighing each raw material component；
(2) each raw material component having had been prepared in step (1) is added in blender and is stirred, rabble furnace is heated to 178-
186 DEG C, mixing speed is 310-335 revs/min, persistently stirs 45-60 minutes, obtains material magma；
(3) the material magma in step (2) is squeezed；
(4) material obtained to extruding carries out cooling, dry, then draws high plastotype, as finished product.
Finally, it is stated that the above examples are only used to illustrate the technical scheme of the present invention and are not limiting, although referring to compared with
Good embodiment describes the invention in detail, those skilled in the art should understand that, it can be to skill of the invention
Art scheme is modified or replaced equivalently, and without departing from the objective and range of the technical program, should all be covered in the present invention
Scope of the claims in.
Claims (7)
1. a kind of fire-retardant packaging material of compression-resistant type, which is characterized in that the raw material including following parts by weight：Polystyrene 25-40
Part, 20-35 parts of polyurethane, 6-12 parts of dilauryl thiodipropionate, 7-14 parts of polymethylacrylic acid, 3-8 parts of propylene glycol monomethyl ether,
3-10 parts of aluminium hydroxide, 4-8 parts of kayexalate, poly- acetimide 2-6 parts, 5-12 parts of carbon nano-fiber, talcum powder 8-
12 parts, 7-15 parts of cumyl peroxide, 4-10 parts of alumina silicate fibre, 3-7 parts of sodium-based montmorillonite, 2-6 parts of phenyl silane, poly- carbon
Sour 5-10 parts of the propyl ester in Asia.
2. the fire-retardant packaging material of compression-resistant type according to claim 1, which is characterized in that the raw material including following parts by weight：
40 parts of polystyrene, 30 parts of polyurethane, 8 parts of dilauryl thiodipropionate, 11 parts of polymethylacrylic acid, 7 parts of propylene glycol monomethyl ether,
7 parts of aluminium hydroxide, 5 parts of kayexalate, 3 parts of poly- acetimide, 9 parts of carbon nano-fiber, 8 parts of talcum powder, peroxidating two
13 parts of isopropylbenzene, 6 parts of alumina silicate fibre, 4 parts of sodium-based montmorillonite, 3 parts of phenyl silane, 7 parts of poly (propylene carbonate).
3. the fire-retardant packaging material of compression-resistant type according to claim 1, which is characterized in that the raw material including following parts by weight：
33 parts of polystyrene, 26 parts of polyurethane, 12 parts of dilauryl thiodipropionate, 11 parts of polymethylacrylic acid, propylene glycol monomethyl ether 7
Part, 10 parts of aluminium hydroxide, 6 parts of kayexalate, 6 parts of poly- acetimide, 11 parts of carbon nano-fiber, 10 parts of talcum powder, mistake
10 parts of diisopropylbenzene (DIPB), 8 parts of alumina silicate fibre, 4 parts of sodium-based montmorillonite, 3 parts of phenyl silane, 5 parts of poly (propylene carbonate) of oxidation.
4. the fire-retardant packaging material of compression-resistant type according to claim 1, which is characterized in that the raw material including following parts by weight：
28 parts of polystyrene, 35 parts of polyurethane, 10 parts of dilauryl thiodipropionate, 11 parts of polymethylacrylic acid, propylene glycol monomethyl ether 7
Part, 8 parts of aluminium hydroxide, 6 parts of kayexalate, 4 parts of poly- acetimide, 8 parts of carbon nano-fiber, 11 parts of talcum powder, peroxide
Change 12 parts of diisopropylbenzene (DIPB), 7 parts of alumina silicate fibre, 6 parts of sodium-based montmorillonite, 5 parts of phenyl silane, 6 parts of poly (propylene carbonate).
5. the fire-retardant packaging material of compression-resistant type according to claim 1, which is characterized in that the raw material including following parts by weight：
35 parts of polystyrene, 27 parts of polyurethane, 9 parts of dilauryl thiodipropionate, 10 parts of polymethylacrylic acid, 5 parts of propylene glycol monomethyl ether,
5 parts of aluminium hydroxide, 7 parts of kayexalate, 4 parts of poly- acetimide, 8 parts of carbon nano-fiber, 10 parts of talcum powder, peroxidating two
12 parts of isopropylbenzene, 6 parts of alumina silicate fibre, 5 parts of sodium-based montmorillonite, 5 parts of phenyl silane, 8 parts of poly (propylene carbonate).
6. the fire-retardant packaging material of compression-resistant type according to claim 1, which is characterized in that the raw material including following parts by weight：
36 parts of polystyrene, 27 parts of polyurethane, 8 parts of dilauryl thiodipropionate, 11 parts of polymethylacrylic acid, 6 parts of propylene glycol monomethyl ether,
6 parts of aluminium hydroxide, 7 parts of kayexalate, 3 parts of poly- acetimide, 11 parts of carbon nano-fiber, 9 parts of talcum powder, peroxidating two
13 parts of isopropylbenzene, 6 parts of alumina silicate fibre, 6 parts of sodium-based montmorillonite, 3 parts of phenyl silane, 5 parts of poly (propylene carbonate).
7. the preparation method of the fire-retardant packaging material of compression-resistant type according to claim 1 to 6, which is characterized in that packet
Include following steps：
(1) according to parts by weight than weighing each raw material component；
(2) each raw material component having had been prepared in step (1) is added in blender and is stirred, rabble furnace is heated to 178-186
DEG C, mixing speed is 310-335 revs/min, persistently stirs 45-60 minutes, obtains material magma；
(3) the material magma in step (2) is squeezed；
(4) material obtained to extruding carries out cooling, dry, then draws high plastotype, as finished product.
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| CN106280259A (en) * | 2016-08-24 | 2017-01-04 | 安徽顺彤包装材料有限公司 | A kind of compression-resistant type packaging material and preparation method thereof |
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| CN106280259A (en) * | 2016-08-24 | 2017-01-04 | 安徽顺彤包装材料有限公司 | A kind of compression-resistant type packaging material and preparation method thereof |
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Application publication date: 20181130 |