CN108912470A - A kind of smooth type CABLE MATERIALS and preparation method thereof - Google Patents
A kind of smooth type CABLE MATERIALS and preparation method thereof Download PDFInfo
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0846—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
- C08L23/0853—Vinylacetate
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2217—Oxides; Hydroxides of metals of magnesium
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2227—Oxides; Hydroxides of metals of aluminium
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/38—Boron-containing compounds
- C08K2003/387—Borates
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/20—Applications use in electrical or conductive gadgets
- C08L2203/202—Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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Abstract
The present invention provides a kind of smooth type CABLE MATERIALSs and preparation method thereof.The CABLE MATERIALS includes the component of following parts by weight：20-50 parts of polyolefin resins, 10-30 parts of low friction resins, 2-10 parts of polyurethane, 2-10 parts of compatilizers, 40-60 parts of fire-retardant fillers and 2-4 parts of slipping agents.The CABLE MATERIALS is to be prepared by first mixing each component of formula ratio by mixer mixing, then by the method that extruder squeezes out.CABLE MATERIALS provided by the invention has lower coefficient of friction, surface is smooth, is made into electric wire adhesion, being capable of light sliding extension while keeping good mechanical performance.
Description
Technical field
The invention belongs to cable insulation material technical fields, and in particular to a kind of smooth type CABLE MATERIALS and preparation method thereof.
Background technique
Since polyolefin has, relative density is small, chemical resistance, water-tolerant, good mechanical strength, electrical isolation
Property the advantages that, there is elasticity to be able to maintain the polyolefin composition of good thermoplastic property simultaneously and have been widely used for various fields
In, such as film, tubing, plate, various moulded products and wire and cable etc..
It, would generally since the flame retardant property of cable material is more demanding when polyolefin is applied in wire and cable
It is next fire-retardant that a large amount of inorganic type fire proofing, such as magnesium hydroxide, aluminium hydroxide are filled in polyolefin.But it is a large amount of inorganic fire-retarded
The addition of material will lead to the mechanical degradation of CABLE MATERIALS, and skin-friction coefficient is higher.In actual application, electric
Line cable is easy to cause surface layer to occur to scratch or peeling phenomenon because the reasons such as rubbing or colliding, and brings security risk.Moreover, excessively high
Coefficient of friction can also make wire and cable surfaces stick, sliding is difficult, is unfavorable for being routed.
In the prior art in order to improve the wear-resisting property of CABLE MATERIALS, prevent its mantle friction impaired, the method generallyd use
It is to improve its surface strength, reduces the loss generated by friction.If CN 104292688A discloses a kind of wear-resistant cable material, i.e.,
It is merged by using anti-abrasion-resistant powder with high temperature plasticization agent, enhances the hardness and superficial density of cable, to play anti-friction effect
Fruit.But the coefficient of friction of the CABLE MATERIALS of this method preparation is not improved, however it remains telescopic slide is difficult to be lacked
It falls into；And additional abrasion-resistant powder is usually inorganic matter, is affected for the mechanical strength of CABLE MATERIALS.
Therefore, how to reduce the coefficient of friction of CABLE MATERIALS, while its being made to keep good mechanical performance, be this field urgently
It solves the problems, such as.
Summary of the invention
In view of the deficiencies of the prior art, the present invention intends to provide a kind of smooth type CABLE MATERIALS and its preparation side
Method.The advantages of CABLE MATERIALS also has coefficient of friction low while keeping good mechanical performance, adhesion.
For this purpose, the present invention uses following technical scheme：
On the one hand, the present invention provides a kind of smooth type CABLE MATERIALS, the component including following parts by weight：
In the present invention, low friction resin has the function of cooperateing with reduction material friction coefficient with slipping agent, and the present invention utilizes
The two cooperates under specific ratio, in conjunction with other components, thus make CABLE MATERIALS while keeping good mechanical performance,
Coefficient of friction is reduced.
In the present invention, the parts by weight of the polyolefin resin can be 20 parts, 22 parts, 23 parts, 25 parts, 26 parts, 28 parts,
30 parts, 32 parts, 33 parts, 35 parts, 36 parts, 38 parts, 40 parts, 42 parts, 43 parts, 45 parts, 46 parts, 48 parts or 50 parts etc..
The parts by weight of the low friction resin can be 10 parts, 11 parts, 12 parts, 13 parts, 14 parts, 15 parts, 16 parts, 17
Part, 18 parts, 19 parts, 20 parts, 21 parts, 22 parts, 23 parts, 24 parts, 25 parts, 26 parts, 27 parts, 28 parts, 29 parts or 30 parts etc..
The parts by weight of the polyurethane can be 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6
Part, 6.5 parts, 7 parts, 7.5 parts, 8 parts, 8.5 parts, 9 parts, 9.5 parts or 10 parts etc..
The parts by weight of the compatilizer can be 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6
Part, 6.5 parts, 7 parts, 7.5 parts, 8 parts, 8.5 parts, 9 parts, 9.5 parts or 10 parts etc..
The parts by weight of the fire-retardant filler can be 40 parts, 41 parts, 42 parts, 43 parts, 44 parts, 45 parts, 46 parts, 47 parts,
48 parts, 49 parts, 50 parts, 51 parts, 52 parts, 53 parts, 54 parts, 55 parts, 56 parts, 57 parts, 58 parts, 59 parts or 60 parts etc..
The parts by weight of the slipping agent can be 2 parts, 2.1 parts, 2.2 parts, 2.3 parts, 2.4 parts, 2.5 parts, 2.6 parts, 2.7
Part, 2.8 parts, 2.9 parts, 3 parts, 3.1 parts, 3.2 parts, 3.3 parts, 3.4 parts, 3.5 parts, 3.6 parts, 3.7 parts, 3.8 parts, 3.9 parts or 4 parts
Deng.
As the preferred technical solution of the present invention, the polyolefin resin be selected from ethylene-vinyl acetate copolymer (EVA),
One of vinyl-acrylate copolymer (AEM) or ethylene-octene copolymer (POE) or at least two combination；Described group
Closing typical but non-limiting example has：The combination of EVA and AEM, the combination of EVA and POE, the combination of AEM and POE.
Preferably, the vinyl-acrylate copolymer is ethylene-ethyl acrylate copolymer (EEA).
As the preferred technical solution of the present invention, the low friction resin is high density polyethylene (HDPE) (HDPE) and/or poly- third
Alkene (PP).
Preferably, the compatilizer is selected from POE-g-MAH (ethylene-octene copolymer of maleic anhydride grafting), EVA-g-
One in MAH (ethylene-vinyl acetate copolymer of maleic anhydride grafting) or PE-g-MAH (polyethylene of maleic anhydride grafting)
Kind or at least two combination；The combination is typical but non-limiting example has：The combination of POE-g-MAH and EVA-g-MAH,
Combination, combination of EVA-g-MAH and PE-g-MAH of POE-g-MAH and PE-g-MAH etc..
As the preferred technical solution of the present invention, the fire-retardant filler is magnesium hydroxide and/or aluminium hydroxide.
As the preferred technical solution of the present invention, the slipping agent be selected from methyl vinyl silicone rubber, dimethicone or
One of ptfe micropowder or at least two combination；The combination is typical but non-limiting example has：Ethylene methacrylic
Combination, methyl vinyl silicone rubber and ptfe micropowder, the dimethicone and poly- four of base silicon rubber and dimethicone
The combination etc. of vinyl fluoride micro mist.
As the preferred technical solution of the present invention, the CABLE MATERIALS further include 3-10 parts (such as 3 parts, 3.5 parts, 4 parts, 4.5
Part, 5 parts, 5.5 parts, 6 parts, 6.5 parts, 7 parts, 7.5 parts, 8 parts, 8.5 parts, 9 parts, 9.5 parts or 10 parts etc.) synergistic flame retardant.
Preferably, the synergistic flame retardant is selected from the combination of one of zinc borate, zinc oxide or red phosphorus or at least two；
The combination is typical but non-limiting example has：The combination of zinc borate and zinc oxide, the combination of zinc borate and red phosphorus, zinc oxide with
The combination etc. of red phosphorus.
Preferably, the CABLE MATERIALS further include 1-5 parts (such as 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts,
4.5 parts or 5 parts etc.) lubricant.
Preferably, the lubricant is selected from ethylene bis stearamide (EBS), zinc stearate, calcium stearate or polyethylene wax
One of or at least two combination；The combination is typical but non-limiting example has：Ethylene bis stearamide and stearic acid
The combination of zinc, the combination of ethylene bis stearamide and polyethylene wax, calcium stearate and combination of polyethylene wax etc..
As the preferred technical solution of the present invention, the CABLE MATERIALS further include 0.4-1.2 parts (such as 0.4 part, 0.5 part,
0.6 part, 0.7 part, 0.8 part, 0.9 part, 1 part, 1.1 parts or 1.2 parts etc.) coupling agent.
Preferably, the coupling agent is selected from silane coupling agent KH172 (vinyl three ('beta '-methoxy ethyoxyl) silane), silicon
In alkane coupling agent KH550 (3- aminopropyl triethoxysilane) or silane coupling agent KH171 (vinyltrimethoxysilane)
It is a kind of or at least two combination；The combination is typical but non-limiting example has：The combination of KH172 and KH550, KH172 with
Combination, combination of KH550 and KH171 of KH171 etc..
Preferably, the CABLE MATERIALS further includes 0.1-0.5 parts (such as 0.1 part, 0.2 part, 0.3 part, 0.4 part or 0.5 part
Deng) antioxidant.
Preferably, the antioxidant is selected from antioxidant 1010 (four [β-(3,5- di-tert-butyl-hydroxy phenyl) propionic acid] seasons
Doutrate), antioxidant 1076 (β-(3,5- di-tert-butyl-hydroxy phenyl) propionic acid octadecanol ester) or irgasfos 168 (three
(2,4- di-tert-butyl-phenyl) phosphite ester) one of or at least two combination；The combination typical case but non-limiting reality
Example has：The combination of antioxidant 1010 and antioxidant 1076, the combination of antioxidant 1010 and antioxidant 1076, antioxidant 1076 and anti-
The combination etc. of oxygen agent 168.
In CABLE MATERIALS provided by the invention, 0.1-1 parts of toners, such as carbon black can also be added according to actual needs.
On the other hand, the present invention provides a kind of preparation method of above-mentioned CABLE MATERIALS, the preparation method is that：It will be each by formula
Component mixing first passes through mixer mixing, then is squeezed out by extruder, obtains the smooth type CABLE MATERIALS.
As the preferred technical solution of the present invention, the temperature of the mixing is 140-150 DEG C, for example, can be 140 DEG C,
141 DEG C, 142 DEG C, 143 DEG C, 144 DEG C, 145 DEG C, 146 DEG C, 147 DEG C, 148 DEG C, 149 DEG C or 150 DEG C etc.；Time is 15-20 points
Clock, for example, can be 15 minutes, 15.5 minutes, 16 minutes, 16.5 minutes, 17 minutes, 17.5 minutes, 18 minutes, 18.5 minutes,
19 minutes, 19.5 minutes or 20 minutes etc..
Preferably, the temperature of the extrusion be 135-155 DEG C, such as can be 135 DEG C, 136 DEG C, 137 DEG C, 138 DEG C,
139℃、140℃、141℃、142℃、143℃、144℃、145℃、146℃、147℃、148℃、149℃、150℃、151
DEG C, 152 DEG C, 153 DEG C, 154 DEG C or 155 DEG C etc.；Residence time is 3-5 minutes, such as be can be 3 minutes, 3.2 minutes, 3.5 points
Clock, 3.8 minutes, 4 minutes, 4.2 minutes, 4.5 minutes, 4.8 minutes or 5 minutes etc..
As the preferred technical solution of the present invention, the preparation method is that：Each component is mixed by formula, mixer is added
In, then the mixing at 140 DEG C obtained mixed material is added in extruder, the control residence time is 3-5 minutes,
It is squeezed out at 135-155 DEG C, obtains the smooth type CABLE MATERIALS.
Compared with prior art, the invention has the advantages that：
The present invention utilizes the synergistic effect of low friction resin and slipping agent, then matches with the component of other special ratios,
To make CABLE MATERIALS while keeping good mechanical performance, coefficient of friction is reduced.Its tensile strength is 10.8-
12.5MPa, elongation at break 240-275%, coefficient of friction 0.18-0.23, surface is smooth, is made into electric wire adhesion, energy
Enough light sliding extensions.
Specific embodiment
Below by specific embodiment to further illustrate the technical scheme of the present invention.Those skilled in the art should be bright
, the described embodiments are merely helpful in understanding the present invention, should not be regarded as a specific limitation of the invention.
Embodiment 1
The present embodiment provides a kind of smooth type CABLE MATERIALS, the component including following parts by weight：
The preparation method of above-mentioned smooth type CABLE MATERIALS is as follows：
Each component is mixed by formula, is added in mixer, mixing 20 minutes at 140 DEG C, the mixing that then will be obtained
Material is added in extruder, and the control residence time is 3 minutes, squeezes out at 155 DEG C, obtains above-mentioned smooth type CABLE MATERIALS.
Embodiment 2
The present embodiment provides a kind of smooth type CABLE MATERIALS, the component including following parts by weight：
The preparation method of above-mentioned smooth type CABLE MATERIALS is as follows：
Each component is mixed by formula, is added in mixer, mixing 15 minutes at 150 DEG C, the mixing that then will be obtained
Material is added in extruder, and the control residence time is 5 minutes, squeezes out at 135 DEG C, obtains above-mentioned smooth type CABLE MATERIALS.
Embodiment 3
The present embodiment provides a kind of smooth type CABLE MATERIALS, the component including following parts by weight：
The preparation method of above-mentioned smooth type CABLE MATERIALS is as follows：
Each component is mixed by formula, is added in mixer, mixing 18 minutes at 145 DEG C, the mixing that then will be obtained
Material is added in extruder, and the control residence time is 4 minutes, squeezes out at 140 DEG C, obtains above-mentioned smooth type CABLE MATERIALS.
Embodiment 4
The present embodiment provides a kind of smooth type CABLE MATERIALS, the component including following parts by weight：
The preparation method of above-mentioned smooth type CABLE MATERIALS is as follows：
Each component is mixed by formula, is added in mixer, mixing 16 minutes at 142 DEG C, the mixing that then will be obtained
Material is added in extruder, and the control residence time is 3.5 minutes, squeezes out at 150 DEG C, obtains above-mentioned smooth type CABLE MATERIALS.
Embodiment 5
The present embodiment provides a kind of smooth type CABLE MATERIALS, the component including following parts by weight：
The preparation method of above-mentioned smooth type CABLE MATERIALS is as follows：
Each component is mixed by formula, is added in mixer, mixing 20 minutes at 148 DEG C, the mixing that then will be obtained
Material is added in extruder, and the control residence time is 4.5 minutes, squeezes out at 140 DEG C, obtains above-mentioned smooth type CABLE MATERIALS.
Embodiment 6
The present embodiment provides a kind of smooth type CABLE MATERIALS, the component including following parts by weight：
The preparation method of above-mentioned smooth type CABLE MATERIALS is as follows：
Each component is mixed by formula, is added in mixer, then the mixing at 145 DEG C adds obtained mixed material
Enter in extruder, the control residence time is 3 minutes, squeezes out at 150 DEG C, obtains above-mentioned smooth type CABLE MATERIALS.
Comparative example 1
Difference with embodiment 6 is that polyacrylic parts by weight are 21 parts, and the dosage of ptfe micropowder is 0,
His component, dosage and preparation method are same as Example 6.
Comparative example 2
Difference with embodiment 6 is that polyacrylic dosage is 0, and the parts by weight of ptfe micropowder are 21 parts,
His component, dosage and preparation method are same as Example 6.
Comparative example 3
Difference with embodiment 6 is that the parts by weight of ethylene-octene copolymer are 15 parts, other components, dosage and system
Preparation Method is same as Example 6.
Comparative example 4
Difference with embodiment 6 is that the parts by weight of ethylene-octene copolymer are 55 parts, other components, dosage and system
Preparation Method is same as Example 6.
Comparative example 5
Difference with embodiment 6 is that polyacrylic parts by weight are 7 parts, other components, dosage and preparation method and reality
It is identical to apply example 6.
Comparative example 6
Difference with embodiment 6 is, polyacrylic parts by weight are 33 parts, other components, dosage and preparation method with
Embodiment 6 is identical.
Comparative example 7
Difference with embodiment 6 is that the parts by weight of polyurethane are 1 part, other components, dosage and preparation method and reality
It is identical to apply example 6.
Comparative example 8
Difference with embodiment 6 is, the parts by weight of polyurethane are 13 parts, other components, dosage and preparation method with
Embodiment 6 is identical.
The mechanical performance and coefficient of friction of above-described embodiment 1-6 and comparative example 1-7 CABLE MATERIALS provided are tested, surveyed
Test-object standard and result are as shown in table 1 below：
Table 1
As shown in Table 1, there is collaboration to reduce CABLE MATERIALS coefficient of friction for low friction resin and slipping agent in the present invention
Effect, when only adding low friction resin or when slipping agent, the coefficient of friction of CABLE MATERIALS can obviously become larger.Existed by each component
It is matched under suitable ratio, CABLE MATERIALS can be made to keep good mechanical performance, when the content of each component is excessive or very few,
The every mechanical performance that will lead to CABLE MATERIALS is difficult to equilibrium, and comprehensive performance is deteriorated.
The Applicant declares that the foregoing is merely a specific embodiment of the invention, but protection scope of the present invention not office
It is limited to this, it should be clear to those skilled in the art, any to belong to those skilled in the art and take off in the present invention
In the technical scope of dew, any changes or substitutions that can be easily thought of, and all of which fall within the scope of protection and disclosure of the present invention.
Claims (10)
1. a kind of smooth type CABLE MATERIALS, which is characterized in that the CABLE MATERIALS includes the component of following parts by weight：
2. CABLE MATERIALS according to claim 1, which is characterized in that the polyolefin resin is total selected from ethene-vinyl acetate
One of polymers, vinyl-acrylate copolymer or ethylene-octene copolymer or at least two combination；
Preferably, the vinyl-acrylate copolymer is ethylene-ethyl acrylate copolymer.
3. CABLE MATERIALS according to claim 1 or 2, which is characterized in that the low friction resin be high density polyethylene (HDPE) and/
Or polypropylene；
The compatilizer is selected from the combination of one of POE-g-MAH, EVA-g-MAH or PE-g-MAH or at least two.
4. CABLE MATERIALS according to claim 1-3, which is characterized in that the fire-retardant filler be magnesium hydroxide and/
Or aluminium hydroxide.
5. CABLE MATERIALS according to claim 1-4, which is characterized in that the slipping agent is selected from methyl ethylene silicon
One of rubber, dimethicone or ptfe micropowder or at least two combination.
6. CABLE MATERIALS according to claim 1-5, which is characterized in that the CABLE MATERIALS further includes 3-10 parts of synergistics
Fire retardant；
Preferably, the synergistic flame retardant is selected from the combination of one of zinc borate, zinc oxide or red phosphorus or at least two；
Preferably, the CABLE MATERIALS further includes 1-5 parts of lubricants；
Preferably, the lubricant be selected from one of ethylene bis stearamide, zinc stearate, calcium stearate or polyethylene wax or
At least two combination.
7. CABLE MATERIALS according to claim 1-6, which is characterized in that the CABLE MATERIALS further includes 0.4-1.2 parts
Coupling agent；
Preferably, the coupling agent is in silane coupling agent KH172, Silane coupling agent KH550 or silane coupling agent KH171
It is a kind of or at least two combination；
Preferably, the CABLE MATERIALS further includes 0.1-0.5 parts of antioxidant；
Preferably, the antioxidant is selected from one of antioxidant 1010, antioxidant 1076 or irgasfos 168 or at least two
Combination.
8. the preparation method of CABLE MATERIALS according to claim 1-7, which is characterized in that the preparation method is that：
Each component is mixed by formula, mixer mixing is first passed through, then squeeze out by extruder, obtains the smooth type CABLE MATERIALS.
9. preparation method according to claim 8, which is characterized in that the temperature of the mixing is 140-150 DEG C, and the time is
15-20 minutes；
Preferably, the temperature of the extrusion is 135-155 DEG C, and the residence time is 3-5 minutes.
10. preparation method according to claim 8 or claim 9, which is characterized in that the preparation method is that：By formula by each group
Divide mixing, be added in mixer, the mixing at 140 DEG C, then obtained mixed material is added in extruder, when controlling stop
Between be 3-5 minutes, squeezed out at 135-155 DEG C, obtain the smooth type CABLE MATERIALS.
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109651640A (en) * | 2018-12-21 | 2019-04-19 | 上海申远高温线有限公司 | A kind of production method of anti-sticking silicone rubber wire cable |
| CN110144112A (en) * | 2019-05-13 | 2019-08-20 | 浙江万马聚力新材料科技有限公司 | Halogen-free cable material and preparation method thereof and cable comprising the halogen-free cable material |
| CN111073173A (en) * | 2019-12-23 | 2020-04-28 | 江西洪茂线缆有限公司 | Wire and cable protective material and preparation method thereof |
| CN112646261A (en) * | 2020-12-21 | 2021-04-13 | 河北中联银杉新材料有限公司 | Insulating material for manufacturing photovoltaic cable |
| CN114989525A (en) * | 2022-08-01 | 2022-09-02 | 常丰线缆有限公司 | Flame-retardant cable and preparation method thereof |
| CN115850844A (en) * | 2022-11-18 | 2023-03-28 | 广东聚石化学股份有限公司 | Cable material and preparation method and application thereof |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20030232933A1 (en) * | 2002-06-17 | 2003-12-18 | Didier Lagneaux | Reactive blend ploymer compositions with thermoplastic polyurethane |
| CN101020771A (en) * | 2006-02-13 | 2007-08-22 | 尼克桑斯公司 | Composition of sheath material for a power and/or telecommunications cable |
| CN102585338A (en) * | 2011-01-13 | 2012-07-18 | 苏州汉扬精密电子有限公司 | Anti-wear halogen-free flame-retardant cable material |
| CN105542443A (en) * | 2016-01-28 | 2016-05-04 | 常熟市中联光电新材料有限责任公司 | Halogen-free flame-retardant thermal plastic polyurethane cable sheath material and preparation method thereof |
| CN106009459A (en) * | 2016-06-18 | 2016-10-12 | 合肥浦尔菲电线科技有限公司 | Novel soft cable for data cable |
| CN106496757A (en) * | 2016-11-07 | 2017-03-15 | 中广核三角洲（中山）高聚物有限公司 | A kind of resistance to 150 DEG C are exempted from irradiation oil-resistant low-smoke halogen-free flame-retardant cable material of polyolefin and preparation method thereof |
-
2018
- 2018-06-11 CN CN201810593523.XA patent/CN108912470A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20030232933A1 (en) * | 2002-06-17 | 2003-12-18 | Didier Lagneaux | Reactive blend ploymer compositions with thermoplastic polyurethane |
| CN101020771A (en) * | 2006-02-13 | 2007-08-22 | 尼克桑斯公司 | Composition of sheath material for a power and/or telecommunications cable |
| CN102585338A (en) * | 2011-01-13 | 2012-07-18 | 苏州汉扬精密电子有限公司 | Anti-wear halogen-free flame-retardant cable material |
| CN105542443A (en) * | 2016-01-28 | 2016-05-04 | 常熟市中联光电新材料有限责任公司 | Halogen-free flame-retardant thermal plastic polyurethane cable sheath material and preparation method thereof |
| CN106009459A (en) * | 2016-06-18 | 2016-10-12 | 合肥浦尔菲电线科技有限公司 | Novel soft cable for data cable |
| CN106496757A (en) * | 2016-11-07 | 2017-03-15 | 中广核三角洲（中山）高聚物有限公司 | A kind of resistance to 150 DEG C are exempted from irradiation oil-resistant low-smoke halogen-free flame-retardant cable material of polyolefin and preparation method thereof |
Non-Patent Citations (4)
| Title |
|---|
| 任晓兵: "开口爽滑剂在低密度聚乙烯薄膜中的应用", 《当代化工》 * |
| 吕世光: "《塑料助剂手册》", 31 March 1986, 轻工业出版社 * |
| 徐同考: "《塑料改性实用技术》", 31 October 2012, 中国轻工业出版社 * |
| 林茵 等: "《有机化学辞典》", 30 September 2006, 远方出版社 * |
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| CN110144112A (en) * | 2019-05-13 | 2019-08-20 | 浙江万马聚力新材料科技有限公司 | Halogen-free cable material and preparation method thereof and cable comprising the halogen-free cable material |
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