CN108912414A - A kind of tyre surface scribing line coloring agent slurry and preparation method thereof - Google Patents

A kind of tyre surface scribing line coloring agent slurry and preparation method thereof Download PDF

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Publication number
CN108912414A
CN108912414A CN201810620140.7A CN201810620140A CN108912414A CN 108912414 A CN108912414 A CN 108912414A CN 201810620140 A CN201810620140 A CN 201810620140A CN 108912414 A CN108912414 A CN 108912414A
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CN
China
Prior art keywords
tyre surface
coloring agent
scribing line
surface scribing
line coloring
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Pending
Application number
CN201810620140.7A
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Chinese (zh)
Inventor
邵晓林
周松
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Three Pu Rubber (wuxi) Co Ltd
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Three Pu Rubber (wuxi) Co Ltd
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Publication date
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Priority to CN201810620140.7A priority Critical patent/CN108912414A/en
Publication of CN108912414A publication Critical patent/CN108912414A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L7/00Compositions of natural rubber
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B60VEHICLES IN GENERAL
    • B60CVEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
    • B60C1/00Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
    • B60C1/0016Compositions of the tread
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2296Oxides; Hydroxides of metals of zinc
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • C08K3/26Carbonates; Bicarbonates
    • C08K2003/265Calcium, strontium or barium carbonate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)

Abstract

The invention discloses a kind of tyre surface scribing line coloring agent slurry and preparation method thereof, the component including following portions by weight:40.00-60.00 parts of color masterbatch glue, 100.00 parts of natural rubber, 1.10-1.70 parts of sulphur, 4.00-6.00 parts of zinc oxide, 1.00-1.30 parts of hard acid ester, 1.10-2.20 parts of promotor, 5.00-7.50 parts of titanium dioxide, 10.00-15.00 parts of white carbon black, 120.00-140.00 parts of light calcium, 25.00-35.00 parts of paraffin, 0.90-1.50 parts of antiaging agent, the present invention is using gasoline/toluene mixture liquid as the solvent of tyre surface scribing line coloring agent, it is bright-colored bright, fast drying, different color masterbatch glue is added, the tyre surface scribing line coloring agent slurry of different colours is prepared.

Description

A kind of tyre surface scribing line coloring agent slurry and preparation method thereof
Technical field
The present invention relates to tire manufacturing techniques fields, and in particular to a kind of tyre surface scribing line coloring agent slurry and preparation method thereof.
Background technique
Present automobile is in the universal of China, and the usage amount of tire also accordingly increases, at tyre surface position in Tire production journey Colo(u)r streak mark or numeral identification are carried out, to reach the wheel for clearly distinguishing different cultivars and specification in production management and sale Tire prevents from going wrong in molding, vulcanization, inventory, sales process.There are tyre surface colors for existing tyre surface scribing line coloring agent slurry The shortcomings that not working, tyre surface scribing line are not easily distinguishable, and very big inconvenience are brought to staff, while scribing line coloring agent slurry is not Yi Gan increases the manufacture duration of tire, increases production cost.
Summary of the invention
In order to overcome existing tyre surface scribing line coloring agent pulp color not work and be not easy dry disadvantage, the present invention provides a kind of tires Face scribing line coloring agent slurry and preparation method thereof, which improves the colour brightness of tyre surface scribing line coloring agent slurry, while the tyre surface is drawn Line coloring agent slurry is easy coloring on tyre surface.
To achieve the above object, the present invention provides the following technical solutions:
A kind of tyre surface scribing line coloring agent slurry, the component including following portions by weight:
Preferably, the promotor is captax, accelerant NOBS, and the mixed proportion of the two is 3: 8.
Preferably, the antiaging agent is antiaging agent 4010NA, antiaging agent TMQ (RD), the mixed proportion of the two It is 2:1.
Preferably, the color masterbatch glue is the bluish-green purple five kinds of colors of reddish yellow, and the color masterbatch glue is a kind of monochromatic color masterbatch glue or more The mixture of the monochromatic color masterbatch glue of kind.
Preferably, the tread rubber each group is divided into following portions by weight:
A kind of preparation method of tyre surface scribing line coloring agent slurry, includes the following steps:
S1, natural rubber, color masterbatch glue are subjected to baking tire in 50 DEG C of -70 DEG C of baking tire rooms, spring, summer dry the tire time and be in three season of autumn - 36h for 24 hours, winter dry the tire time for 36-72h, carry out cutting glue again after drying tire, weigh;
S2, natural rubber, the color masterbatch glue after baking tire are added in mixer and are plasticated, controlled at 40-50 DEG C, Plasticate the time be 30-40 second, it is thin lead to plasticate 8-9 times after mention floating weight;
S3, titanium dioxide, white carbon black, light calcium, paraffin are sequentially added into the mixer of S2, controlled at 45-75 DEG C, Floating weight is mentioned after being kneaded 50-80s;
S4, stearic acid, zinc oxide, antiaging agent, promotor, sulphur are sequentially added into the mixer of S3, mixing is extremely Floating weight is mentioned after 110-120 DEG C, obtains tyre surface scribing line coloring agent;
S5, it uniform tyre surface scribing line coloring agent will be kneaded is cut into Minifilm, put into beater, gasoline/first is then added Benzene mixed liquor covers beater mouth, starts to stir, and under being stirred continuously of beater paddle, dissolves sizing material gradually, preparation Uniform tyre surface scribing line coloring agent slurry;
After S6, tyre surface scribing line coloring agent slurry prepare, it is stored in closed deposit and starches in container, temperature is deposited in 20 DEG C of shady place Put time 24-48h.
Preferably, the gasoline/toluene mixture liquid and the mass parts ratio of tyre surface scribing line coloring agent are 1.5:1.
Preferably, the mass parts ratio of gasoline and toluene is 3 in gasoline/toluene mixture liquid in the step S5: 1.
Compared with prior art, beneficial effects of the present invention are as follows:
The present invention is using gasoline/toluene mixture liquid as the solvent of tyre surface scribing line coloring agent, bright-colored bright, fast drying, Different color masterbatch glue is added, the tyre surface scribing line coloring agent slurry of different colours is prepared, can be used to clearly distinguish in production management and sale The tire of different cultivars and specification prevents from going wrong in molding, vulcanization, inventory, sales process.
Specific embodiment
Hereinafter, preferred embodiments of the present invention will be described, it should be understood that preferred embodiment described herein is only used In the description and interpretation present invention, it is not intended to limit the present invention.
Embodiment 1
A kind of tyre surface scribing line coloring agent slurry, the component including following portions by weight:
The preparation method of above-mentioned tyre surface scribing line coloring agent slurry, includes the following steps:
S1, natural rubber, color masterbatch glue are subjected to baking tire in 50 DEG C of -70 DEG C of baking tire rooms, spring, summer dry the tire time and be in three season of autumn - 36h for 24 hours, winter dry the tire time for 36-72h, carry out cutting glue again after drying tire, weigh;
S2, natural rubber, the color masterbatch glue after baking tire are added in mixer and are plasticated, controlled at 40-50 DEG C, Plasticate the time be 30-40 second, it is thin lead to plasticate 8-9 times after mention floating weight;
S3, titanium dioxide, white carbon black, light calcium, paraffin are sequentially added into the mixer of S2, controlled at 45-75 DEG C, Floating weight is mentioned after being kneaded 50-80s;
S4, stearic acid, zinc oxide, antiaging agent, promotor, sulphur are sequentially added into the mixer of S3, mixing is extremely Floating weight is mentioned after 110-120 DEG C, obtains tyre surface scribing line coloring agent;
S5, it uniform tyre surface scribing line coloring agent will be kneaded is cut into Minifilm, put into beater, gasoline/first is then added Benzene mixed liquor covers beater mouth, starts to stir, and under being stirred continuously of beater paddle, dissolves sizing material gradually, preparation Uniform tyre surface scribing line coloring agent slurry;
After S6, tyre surface scribing line coloring agent slurry prepare, it is stored in closed deposit and starches in container, temperature is deposited in 20 DEG C of shady place Put time 24-48h.
Embodiment 2
A kind of tyre surface scribing line coloring agent slurry, the tread rubber each group are divided into following portions by weight:
The preparation method of above-mentioned tyre surface scribing line coloring agent slurry, includes the following steps:
S1, natural rubber, color masterbatch glue are subjected to baking tire in 50 DEG C of -70 DEG C of baking tire rooms, spring, summer dry the tire time and be in three season of autumn - 36h for 24 hours, winter dry the tire time for 36-72h, carry out cutting glue again after drying tire, weigh;
S2, natural rubber, the color masterbatch glue after baking tire are added in mixer and are plasticated, controlled at 40-50 DEG C, Plasticate the time be 30-40 second, it is thin lead to plasticate 8-9 times after mention floating weight;
S3, titanium dioxide, white carbon black, light calcium, paraffin are sequentially added into the mixer of S2, controlled at 45-75 DEG C, Floating weight is mentioned after being kneaded 50-80s;
S4, stearic acid, zinc oxide, antiaging agent, promotor, sulphur are sequentially added into the mixer of S3, mixing is extremely Floating weight is mentioned after 110-120 DEG C, obtains tyre surface scribing line coloring agent;
S5, it uniform tyre surface scribing line coloring agent will be kneaded is cut into Minifilm, put into beater, gasoline/first is then added Benzene mixed liquor, the mass parts ratio of gasoline and toluene is 3 in gasoline/toluene mixture liquid in the step S5:1, the gasoline/ Toluene mixture liquid and the mass parts ratio of tyre surface scribing line coloring agent are 1.5:1, beater mouth is covered, starts to stir, is starched in beater It under being stirred continuously of leaf, dissolves sizing material gradually, prepares uniform tyre surface scribing line coloring agent slurry;
After S6, tyre surface scribing line coloring agent slurry prepare, it is stored in closed deposit and starches in container, temperature is deposited in 20 DEG C of shady place Put time 24-48h.
Embodiment 3
A kind of tyre surface scribing line coloring agent slurry, the tread rubber each group are divided into following portions by weight:
The preparation method of above-mentioned tyre surface scribing line coloring agent slurry, includes the following steps:
S1, natural rubber, color masterbatch glue are subjected to baking tire in 50 DEG C of -70 DEG C of baking tire rooms, spring, summer dry the tire time and be in three season of autumn - 36h for 24 hours, winter dry the tire time for 36-72h, carry out cutting glue again after drying tire, weigh;
S2, natural rubber, the color masterbatch glue after baking tire are added in mixer and are plasticated, controlled at 40-50 DEG C, Plasticate the time be 30-40 second, it is thin lead to plasticate 8-9 times after mention floating weight;
S3, titanium dioxide, white carbon black, light calcium, paraffin are sequentially added into the mixer of S2, controlled at 45-75 DEG C, Floating weight is mentioned after being kneaded 50-80s;
S4, stearic acid, zinc oxide, antiaging agent, promotor, sulphur are sequentially added into the mixer of S3, mixing is extremely Floating weight is mentioned after 110-120 DEG C, obtains tyre surface scribing line coloring agent;
S5, it uniform tyre surface scribing line coloring agent will be kneaded is cut into Minifilm, put into beater, gasoline/first is then added Benzene mixed liquor, the mass parts ratio of gasoline and toluene is 3 in gasoline/toluene mixture liquid in the step S5:1, the gasoline/ Toluene mixture liquid and the mass parts ratio of tyre surface scribing line coloring agent are 1.5:1, beater mouth is covered, starts to stir, is starched in beater It under being stirred continuously of leaf, dissolves sizing material gradually, prepares uniform tyre surface scribing line coloring agent slurry;
After S6, tyre surface scribing line coloring agent slurry prepare, it is stored in closed deposit and starches in container, temperature is deposited in 20 DEG C of shady place Put time 24-48h.
Embodiment 4
A kind of tyre surface scribing line coloring agent slurry, the tread rubber each group are divided into following portions by weight:
The preparation method of above-mentioned tyre surface scribing line coloring agent slurry, includes the following steps:
S1, natural rubber, color masterbatch glue are subjected to baking tire in 50 DEG C of -70 DEG C of baking tire rooms, spring, summer dry the tire time and be in three season of autumn - 36h for 24 hours, winter dry the tire time for 36-72h, carry out cutting glue again after drying tire, weigh;
S2, natural rubber, the color masterbatch glue after baking tire are added in mixer and are plasticated, controlled at 40-50 DEG C, Plasticate the time be 30-40 second, it is thin lead to plasticate 8-9 times after mention floating weight;
S3, titanium dioxide, white carbon black, light calcium, paraffin are sequentially added into the mixer of S2, controlled at 45-75 DEG C, Floating weight is mentioned after being kneaded 50-80s;
S4, stearic acid, zinc oxide, antiaging agent, promotor, sulphur are sequentially added into the mixer of S3, mixing is extremely Floating weight is mentioned after 110-120 DEG C, obtains tyre surface scribing line coloring agent;
S5, it uniform tyre surface scribing line coloring agent will be kneaded is cut into Minifilm, put into beater, gasoline/first is then added Benzene mixed liquor, the mass parts ratio of gasoline and toluene is 3 in gasoline/toluene mixture liquid in the step S5:1, the gasoline/ Toluene mixture liquid and the mass parts ratio of tyre surface scribing line coloring agent are 1.5:1, beater mouth is covered, starts to stir, is starched in beater It under being stirred continuously of leaf, dissolves sizing material gradually, prepares uniform tyre surface scribing line coloring agent slurry;
After S6, tyre surface scribing line coloring agent slurry prepare, it is stored in closed deposit and starches in container, temperature is deposited in 20 DEG C of shady place Put time 24-48h.
Preferably, the color masterbatch glue is the bluish-green purple five kinds of colors of reddish yellow, and the color masterbatch glue is a kind of monochromatic color masterbatch glue or more The mixture of the monochromatic color masterbatch glue of kind.
Embodiment 1-4 provided by the invention, adds different color masterbatch glue types, and the color masterbatch glue is reddish yellow bluish-green purple five Kind color, the color masterbatch glue are a kind of monochromatic color masterbatch glue, are prepared for the tyre surface scribing line coloring agent slurry of the bluish-green purple five kinds of colors of reddish yellow, The color masterbatch glue is the mixture of a variety of monochromatic color masterbatch glue, adds suitable parts by weight, prepares as dark red, bright red, brown Red, orange, deep yellow, yellowish, blackish green, dark green, olive green, yellowish green, emerald green, ultramarine, it is sky blue, it is cobalt blue, violet, orange ash, purple The multiple colors such as ash, ashy green, tooth Huang ash.
Finally it should be noted that:The foregoing is merely preferred embodiments of the invention, are not intended to restrict the invention, Although the present invention is described in detail referring to the foregoing embodiments, for those skilled in the art, still may be used To modify the technical solutions described in the foregoing embodiments or equivalent replacement of some of the technical features. All within the spirits and principles of the present invention, any modification, equivalent replacement, improvement and so on should be included in of the invention In protection scope.

Claims (8)

1. a kind of tyre surface scribing line coloring agent slurry, which is characterized in that the component including following portions by weight:
2. tyre surface scribing line coloring agent slurry according to claim 1, which is characterized in that the promotor is captax, promotes Agent NOBS, the mixed proportion of the two are 3:8.
3. tyre surface scribing line coloring agent slurry according to claim 1, which is characterized in that the antiaging agent is antiaging agent 4010NA, antiaging agent TMQ (RD), the mixed proportion of the two are 2:1.
4. tyre surface scribing line coloring agent slurry according to claim 1, which is characterized in that the color masterbatch glue is bluish-green purple five kinds of reddish yellow Color, the color masterbatch glue are the mixture of a kind of monochromatic color masterbatch glue or a variety of monochromatic color masterbatch glue.
5. tyre surface scribing line coloring agent slurry according to claim 1, which is characterized in that the tread rubber each group is divided into following weight Number:
6. a kind of preparation method of tyre surface scribing line coloring agent slurry, which is characterized in that include the following steps:
S1, natural rubber, color masterbatch glue are subjected to baking tire in 50 DEG C of -70 DEG C of baking tire rooms, spring, summer, dry in three season of autumn the tire time be for 24 hours - 36h, winter dry the tire time for 36-72h, carry out cutting glue again after drying tire, weigh;
S2, natural rubber, the color masterbatch glue after baking tire are added in mixer and are plasticated, controlled at 40-50 DEG C, when plasticating Between be 30-40 second, it is thin lead to plasticate 8-9 times after mention floating weight;
S3, titanium dioxide, white carbon black, light calcium, paraffin are sequentially added into the mixer of S2, controlled at 45-75 DEG C, be kneaded Floating weight is mentioned after 50-80s;
S4, stearic acid, zinc oxide, antiaging agent, promotor, sulphur, mixing to 110-120 are sequentially added into the mixer of S3 Floating weight is mentioned after DEG C, obtains tyre surface scribing line coloring agent;
S5, it uniform tyre surface scribing line coloring agent will be kneaded is cut into Minifilm, put into beater, it is mixed that gasoline/toluene is then added Liquid is closed, beater mouth is covered, starts to stir, under being stirred continuously of beater paddle, dissolve sizing material gradually, preparation is uniform Tyre surface scribing line coloring agent slurry;
After S6, tyre surface scribing line coloring agent slurry prepare, be stored in it is closed deposit in slurry container, shady place of the temperature at 20 DEG C, when storage Between 24-48h.
7. the preparation method of tyre surface scribing line coloring agent slurry according to claim 6, which is characterized in that the gasoline/toluene is mixed The mass parts ratio for closing liquid and tyre surface scribing line coloring agent is 1.5:1.
8. the preparation method of tyre surface scribing line coloring agent slurry according to claim 6, which is characterized in that vapour in the step S5 The mass parts ratio of gasoline and toluene is 3 in oil/toluene mixture liquid:1.
CN201810620140.7A 2018-06-15 2018-06-15 A kind of tyre surface scribing line coloring agent slurry and preparation method thereof Pending CN108912414A (en)

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20010039308A1 (en) * 1999-05-28 2001-11-08 Michelin Recherche Et Technique S.A. Rubber composition for a tire, based on diene elastomer and a reinforcing titanium oxide
CN101492580A (en) * 2008-01-21 2009-07-29 赛轮股份有限公司 Tire casing sign liquid and method of producing the same
CN105261307A (en) * 2015-11-18 2016-01-20 周宏宝 Colored noctilucent rubber tire mark, preparation method thereof, die and tire
CN106566323A (en) * 2016-10-21 2017-04-19 徐州工业职业技术学院 Tire tread line-marking rubber slurry preparation method

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20010039308A1 (en) * 1999-05-28 2001-11-08 Michelin Recherche Et Technique S.A. Rubber composition for a tire, based on diene elastomer and a reinforcing titanium oxide
CN101492580A (en) * 2008-01-21 2009-07-29 赛轮股份有限公司 Tire casing sign liquid and method of producing the same
CN105261307A (en) * 2015-11-18 2016-01-20 周宏宝 Colored noctilucent rubber tire mark, preparation method thereof, die and tire
CN106566323A (en) * 2016-10-21 2017-04-19 徐州工业职业技术学院 Tire tread line-marking rubber slurry preparation method

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