CN108907213A - A kind of atomization prepares the device and technique of zinc powder or alloy zinc powder - Google Patents

A kind of atomization prepares the device and technique of zinc powder or alloy zinc powder Download PDF

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Publication number
CN108907213A
CN108907213A CN201810898822.4A CN201810898822A CN108907213A CN 108907213 A CN108907213 A CN 108907213A CN 201810898822 A CN201810898822 A CN 201810898822A CN 108907213 A CN108907213 A CN 108907213A
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CN
China
Prior art keywords
zinc powder
zinc
powder
graphite crucible
atomizer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810898822.4A
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Chinese (zh)
Inventor
唐亦秋
林文军
苗华磊
戴慧敏
张伟
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Zhuzhou Smelter Group Co Ltd
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Zhuzhou Smelter Group Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Zhuzhou Smelter Group Co Ltd filed Critical Zhuzhou Smelter Group Co Ltd
Priority to CN201810898822.4A priority Critical patent/CN108907213A/en
Publication of CN108907213A publication Critical patent/CN108907213A/en
Pending legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F9/00Making metallic powder or suspensions thereof
    • B22F9/02Making metallic powder or suspensions thereof using physical processes
    • B22F9/06Making metallic powder or suspensions thereof using physical processes starting from liquid material
    • B22F9/08Making metallic powder or suspensions thereof using physical processes starting from liquid material by casting, e.g. through sieves or in water, by atomising or spraying
    • B22F9/082Making metallic powder or suspensions thereof using physical processes starting from liquid material by casting, e.g. through sieves or in water, by atomising or spraying atomising using a fluid
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C1/00Making non-ferrous alloys
    • C22C1/04Making non-ferrous alloys by powder metallurgy
    • C22C1/0483Alloys based on the low melting point metals Zn, Pb, Sn, Cd, In or Ga
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C18/00Alloys based on zinc
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F9/00Making metallic powder or suspensions thereof
    • B22F9/02Making metallic powder or suspensions thereof using physical processes
    • B22F9/06Making metallic powder or suspensions thereof using physical processes starting from liquid material
    • B22F9/08Making metallic powder or suspensions thereof using physical processes starting from liquid material by casting, e.g. through sieves or in water, by atomising or spraying
    • B22F9/082Making metallic powder or suspensions thereof using physical processes starting from liquid material by casting, e.g. through sieves or in water, by atomising or spraying atomising using a fluid
    • B22F2009/0892Making metallic powder or suspensions thereof using physical processes starting from liquid material by casting, e.g. through sieves or in water, by atomising or spraying atomising using a fluid casting nozzle; controlling metal stream in or after the casting nozzle

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Manufacture Of Metal Powder And Suspensions Thereof (AREA)

Abstract

The present invention provides the device and technique that a kind of atomization prepares zinc powder or alloy zinc powder, including drainer, the top of the drainer is equipped with cover board, the center of the cover board is equipped with spray holes, atomizer is installed, the atomizer is connected with graphite crucible, and the graphite crucible is mounted on above atomizer on the cover board, the bottom of the graphite crucible is equipped with nozzle, and the nozzle extends down into inside atomizer;The bottom of the drainer is equipped with discharge port, and the lower section of the discharge port is equipped with zinc powder collecting tank.The present apparatus has many advantages, such as that rational technology, powder formation rate are high, granularity is thinner, active more preferable, pollution-free, nonhazardous.

Description

A kind of atomization prepares the device and technique of zinc powder or alloy zinc powder
Technical field
The present invention relates to smelting field of nonferrous metal, and in particular to a kind of atomization prepare zinc powder or alloy zinc powder device and Technique.
Background technique
In wet process zinc metallurgical process, the general copper using in zinc replacement removing solution of zinc sulfate, cadmium, arsenic, antimony, The impurity such as cobalt, nickel achieve the purpose that solution purification cleans.The production main technique of zinc powder has two major classes at present, and first major class is Metal zinc fume condensation process, the second major class are metallic zinc air atomizing technique.First major class production zinc powder raw material be usually Zinc oxide carries out zinc oxide to be reduced to metallic zinc by the way that the reducing agents such as coke are added, and metallic zinc is under the reducing conditions with steam Form volatilization, and solid is cooled in condensation chamber;Since the technique capital equipment is electric furnace, the zinc powder of production accounts for zinc powder toatl proportion 80% or more.The raw material that second major class produces zinc powder is usually metallic zinc, and metallic zinc is molten into solution, allows swiftly flowing gas Body carries out being cut into particulate liquid and be quickly cooled down simultaneously, obtains zinc powder to liquid Zn metal.
Gas atomization has effective Zn content height, direct yield height, low energy consumption, technique peace compared to steam condensation method Entirely, the advantages that small pollution of the environment.But existing technique that there is zinc powder particle sizes is larger, powder formation rate is low, zinc powder activity is low, The disadvantages such as device efficiency is low.
Summary of the invention
In order to overcome the appeal disadvantage of existing gas atomization, the present invention provides a kind of new atomization prepare zinc powder or The device and technique of alloy zinc powder.
It is as follows that the present invention solves technical solution used by above-mentioned technical problem:
A kind of atomization prepares the device of zinc powder or alloy zinc powder, including graphite crucible, nozzle, atomizer, drainer, cover board, goes out Material mouth, collecting tank, the top of the drainer are equipped with cover board, and the center of the cover board is equipped with spray holes, installs on the cover board There is atomizer, the atomizer is connected with graphite crucible, and the graphite crucible is mounted on above atomizer, the graphite crucible Bottom is equipped with nozzle, and the nozzle extends down into inside atomizer;The bottom of the drainer be equipped with discharge port, it is described go out The lower section of material mouth is equipped with zinc powder collecting tank.
Further, the atomizer is connected with gas input device, and the gas input device includes air inlet pipe, air Compressor, air inlet pipe valve, cool air hose air intake valve, hot air pipe air intake valve, heating mantle, hot air pipe outlet valve, the sky Air compressor is connected by air inlet pipe with atomizer, and the air inlet pipe is divided into cool air hose, hot air pipe, is equipped on the cool air hose Cool air hose air intake valve is equipped with heating mantle in the middle part of the hot air pipe, and the both ends of the hot air pipe are separately installed with hot air pipe Air intake valve, hot air pipe outlet valve.
Further, the graphite crucible bottom is inverted conical shape, to guarantee that zinc liquid flows completely out.
Further, the nozzle is made of graphite material.
Further, fire clay is filled between the graphite crucible and graphite nozzle.
Further, the condensation pot bottom is inverted conical shape, to facilitate zinc powder to collect.
A kind of atomization prepares the technique of zinc powder or alloy zinc powder, includes the following steps:
S1:Nozzle is placed in graphite crucible bottom and is sealed with fire clay, graphite crucible is then put into electric furnace and is heated, Zinc ingot metal or kirsite are put into heating in common crucible simultaneously and dissolve into zinc liquid or zinc liquid.
S2:It opens air compressor and is passed through air, open simultaneously cool air hose air intake valve or hot air pipe air intake valve, heat Air hose outlet valve, heating mantle is powered on.
S3:Graphite crucible is placed on atomizer from taking-up in electric furnace, and the nozzle of graphite crucible is made to extend into atomization Then the zinc liquid or zinc liquid that dissolve in common crucible are poured into graphite crucible, are atomized by the center inside device Blow powder operation.
S4:Open the collection that collecting tank carries out zinc powder or Zinc alloy powder, it is to be atomized blow powder after the completion of, close air pressure The gentle tube valve of contracting machine, covers collecting tank.
A kind of atomization of the invention prepares the device and technique of zinc powder or alloy zinc powder, with the existing zinc powder that is used to prepare Device is compared, and is had the advantages that:
(1)Graphite nozzle can be processed by technique requirement, change nozzle length, the diameter of nozzle bore, to blow out The zinc powder of different quality.
(2)Using graphite crucible and graphite nozzle, it can put it into electric furnace and be heated to guarantee crucible and nozzle Temperature, reduce its negative effect caused by zinc powder mobility when blowing powder.
(3)Air inlet pipe is divided into cool air hose and hot air pipe, and the zinc powder of blowout different quality can be required according to different technique.
The present invention has many advantages, such as that rational technology, powder formation rate are high, granularity is thinner, active more preferable, pollution-free, nonhazardous.
Detailed description of the invention
Fig. 1 is structural schematic diagram of the invention.
Fig. 2 is the structural schematic diagram of the graphite crucible in the present invention.
Fig. 3 is the structural schematic diagram of the gas input device in the present invention.
In attached drawing:1-drainer;2-graphite crucibles;3-nozzles;4-atomizers;5-discharge ports;6-collecting tanks; 7-cover boards;8-fire clays;9-air compressors;10-air inlet pipe;11-hot air pipe outlet valves;12-cool air hoses;13— Hot air pipe;14-air inlet pipe valves;15-cool air hose air intake valves;16-hot air pipe air intake valves;17-heating mantles.
Specific embodiment
In order to which the technical problems, technical solutions and beneficial effects solved by the present invention is more clearly understood, below in conjunction with Accompanying drawings and embodiments, the present invention is further described in detail.It should be appreciated that specific embodiment described herein is only To explain the present invention, it is not intended to limit the present invention.
Fig. 1,2,3 are please referred to, a kind of atomization prepares the device of zinc powder or alloy zinc powder, including graphite crucible 2, nozzle 3, mist Change device 4, drainer 1, cover board 7, discharge port 5, collecting tank 6.The top of drainer 1 is equipped with lid by way of welding or being glued Plate 7, the center of the cover board 7 are provided with spray holes, and atomizer 4 is equipped on the cover board 7, and the atomizer 4 is solid by bolt It is scheduled on cover board 7, the outlet face spray holes of atomizer 4.Atomizer 4 is connected with graphite crucible 2, and the graphite crucible 2 is installed Above atomizer 4, the bottom of the graphite crucible 2 is equipped with nozzle 3, and the nozzle 3 extends down into inside atomizer 4. Using the filling sealing of fire clay 8 between the graphite crucible 2 and nozzle 3, the nozzle 3 is made of graphite material, can be by Technique requires to be processed, and changes 3 length of nozzle, the diameter of 3 inner hole of nozzle, to blow out the zinc powder of different quality.It is preferred that Ground, 2 bottom of graphite crucible is inverted conical shape, to guarantee that zinc liquid flows completely out.The bottom of the drainer 1 is equipped with discharge port 5, the lower section of the discharge port 5 is equipped with zinc powder collecting tank 6.1 bottom of drainer is inverted conical shape, to facilitate zinc powder to collect.
As shown in figure 3, atomizer 4 is connected with gas input device, the gas input device includes air inlet pipe 10, air Compressor 9, air inlet pipe valve 14, cool air hose air intake valve 15, hot air pipe air intake valve 16, heating mantle 17, hot air pipe air outlet valve Door 11.The air compressor 9 is connected by air inlet pipe 10 with atomizer 4, and the air inlet pipe 10 is divided for cool air hose 12, hot air pipe 13, the cool air hose 12,13 associated connection of hot air pipe.Cool air hose air intake valve 15, the heat are installed on the cool air hose 12 The middle part of air hose 13 is equipped with heating mantle 17, and the both ends of the hot air pipe 13 are separately installed with hot air pipe air intake valve 16, hot wind Pipe outlet valve 11.The heating mantle 17 is sleeved on the outside of hot air pipe 13, and resistive heater is equipped in heating mantle 17, described Resistive heater is connected by switch with external power supply.
The device that zinc powder or alloy zinc powder are prepared using above-mentioned atomization, the technique for preparing zinc powder or alloy zinc powder, including with Lower step:
S1:Nozzle 3 is placed in 2 bottom of graphite crucible and is sealed with fire clay 8, is then put into the graphite crucible 2 with nozzle 3 Electric furnace is heated, and to guarantee the temperature of crucible and nozzle 3, reduces its negative shadow caused by zinc powder mobility when blowing powder It rings.Zinc ingot metal or kirsite are put into heating in common crucible simultaneously and dissolve into zinc liquid or zinc liquid.
S2:It opens air compressor 9 and is passed through air, open simultaneously cool air hose air intake valve 15 or hot air pipe air intake valve 16, hot air pipe outlet valve 11 powers on heating mantle 17.
S3:Graphite crucible 2 is placed on atomizer 4 from taking-up in electric furnace, and extend into the nozzle 3 of graphite crucible 2 Then center inside atomizer 4 is poured into the zinc liquid or zinc liquid that dissolve in common crucible in graphite crucible 2, into Powder operation is blown in row atomization.
S4:Open the collection that collecting tank 6 carries out zinc powder or Zinc alloy powder, it is to be atomized blow powder after the completion of, close air The gentle tube valve of compressor 9, covers collecting tank 6.
Embodiment 1
Pure zinc powder is manufactured using above equipment and technique, wherein atomizing medium is air, pressure 0.4MPa, and zinc liquid temperature is 600 DEG C, the powder size distribution manufactured is as follows:
- 200 mesh + 200~-50 mesh + 150~-120 mesh + 120~-100 mesh + 100~-80 mesh + 80~-40 mesh + 40 mesh
9.35% 6.01% 9.15% 48.11% 15.24% 5.32% 5.21%
The rate of recovery of zinc is 98.39%.
Embodiment 2
Zinc alloy powder is manufactured using above equipment and technique, wherein kirsite ingredient is:1.5%Pb, 1%Sn, surplus are Zinc, atomizing medium are air, and pressure 0.4MPa, alloy zinc liquid temperature is 750 DEG C, and the powder size distribution manufactured is as follows :
- 200 mesh + 200~-50 mesh + 150~-120 mesh + 120~-100 mesh + 100~-80 mesh + 80~-40 mesh + 40 mesh
4.29 5.11% 7.21% 54.98% 16.55% 7.45% 2.88%
The rate of recovery of zinc is 98.47%.
Embodiment 3
Zinc alloy powder is manufactured using above equipment and technique, wherein kirsite ingredient is:0.05%Bi, 0.05%In, 0.01%Al, surplus are zinc, and atomizing medium is air, and pressure 0.4MPa, alloy zinc liquid temperature is 550 DEG C, the powder manufactured Last size distribution is as follows:
- 200 mesh + 200~-50 mesh + 150~-120 mesh + 120~-100 mesh + 100~-80 mesh + 80~-40 mesh + 40 mesh
5.65% 7.01% 16.12% 48.35% 11.98% 7.55% 2.78%
The rate of recovery of zinc is 99.44%.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all in essence of the invention Made any modifications, equivalent replacements, and improvements etc., should all be included in the protection scope of the present invention within mind and principle.

Claims (7)

1. the device that a kind of atomization prepares zinc powder or alloy zinc powder, it is characterised in that:Including graphite crucible, nozzle, atomizer, cold Solidifying tank, cover board, discharge port, collecting tank, the top of the drainer are equipped with cover board, and the center of the cover board is equipped with spray holes, institute It states and atomizer is installed on cover board, the atomizer is connected with graphite crucible, and the graphite crucible is mounted on above atomizer, institute The bottom for stating graphite crucible is equipped with nozzle, and the nozzle extends down into inside atomizer;The bottom of the drainer is equipped with The lower section of discharge port, the discharge port is equipped with zinc powder collecting tank.
2. the device that a kind of atomization according to claim 1 prepares zinc powder or alloy zinc powder, it is characterised in that:The atomization Device is connected with gas input device, and the gas input device includes air inlet pipe, air compressor, air inlet pipe valve, cool air hose Air intake valve, hot air pipe air intake valve, heating mantle, hot air pipe outlet valve, the air compressor pass through air inlet pipe and atomization Device is connected, and the air inlet pipe is divided into cool air hose, hot air pipe, and cool air hose air intake valve, the hot wind are equipped on the cool air hose Heating mantle is installed, the both ends of the hot air pipe are separately installed with hot air pipe air intake valve, hot air pipe outlet valve in the middle part of pipe.
3. the device that a kind of atomization according to claim 1 prepares zinc powder or alloy zinc powder, it is characterised in that:The graphite Crucible bottom is inverted conical shape, to guarantee that zinc liquid flows completely out.
4. the device that a kind of atomization according to claim 1 prepares zinc powder or alloy zinc powder, it is characterised in that:The nozzle It is made of graphite material.
5. the device that a kind of atomization according to claim 1 prepares zinc powder or alloy zinc powder, it is characterised in that:The graphite Fire clay is filled between crucible and graphite nozzle.
6. the device that a kind of atomization according to claim 1 prepares zinc powder or alloy zinc powder, it is characterised in that:The condensation Pot bottom is inverted conical shape, to facilitate zinc powder to collect.
7. the technique that a kind of atomization prepares zinc powder or alloy zinc powder, which is characterized in that include the following steps:
S1:Nozzle is placed in graphite crucible bottom and is sealed with fire clay, graphite crucible is then put into electric furnace and is heated, Zinc ingot metal or kirsite are put into heating in common crucible simultaneously and dissolve into zinc liquid or zinc liquid;
S2:It opens air compressor and is passed through air, open simultaneously cool air hose air intake valve or hot air pipe air intake valve, hot air pipe Outlet valve powers on heating mantle;
S3:Graphite crucible is placed on atomizer from taking-up in electric furnace, and extend into the nozzle of graphite crucible in atomizer Then the center in portion is poured into the zinc liquid or zinc liquid that dissolve in common crucible in graphite crucible, carry out atomization and blow powder Operation;
S4:Open the collection that collecting tank carries out zinc powder or Zinc alloy powder, it is to be atomized blow powder after the completion of, close air compressor Gentle tube valve, covers collecting tank.
CN201810898822.4A 2018-08-08 2018-08-08 A kind of atomization prepares the device and technique of zinc powder or alloy zinc powder Pending CN108907213A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113618072A (en) * 2021-08-27 2021-11-09 新疆紫金有色金属有限公司 Method for preparing lead-zinc alloy powder by water atomization method

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102009181A (en) * 2010-12-21 2011-04-13 株洲冶炼集团股份有限公司 Atomizer for producing zinc powder or alloy zinc powder
CN102407338A (en) * 2011-12-06 2012-04-11 中南大学 Gas atomization device for preparing superfine spherical metal powder with low oxygen content
CN107262730A (en) * 2017-08-01 2017-10-20 北京有色金属研究总院 The gas atomization preparation method and its equipment of a kind of superfine spherical metal powder
CN209021240U (en) * 2018-08-08 2019-06-25 株洲冶炼集团股份有限公司 Atomization prepares the device of zinc powder or alloy zinc powder

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102009181A (en) * 2010-12-21 2011-04-13 株洲冶炼集团股份有限公司 Atomizer for producing zinc powder or alloy zinc powder
CN102407338A (en) * 2011-12-06 2012-04-11 中南大学 Gas atomization device for preparing superfine spherical metal powder with low oxygen content
CN107262730A (en) * 2017-08-01 2017-10-20 北京有色金属研究总院 The gas atomization preparation method and its equipment of a kind of superfine spherical metal powder
CN209021240U (en) * 2018-08-08 2019-06-25 株洲冶炼集团股份有限公司 Atomization prepares the device of zinc powder or alloy zinc powder

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113618072A (en) * 2021-08-27 2021-11-09 新疆紫金有色金属有限公司 Method for preparing lead-zinc alloy powder by water atomization method

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