CN108905903A - A kind of device preparing highly oriented pyrolytic graphite based on graphene oxide - Google Patents
A kind of device preparing highly oriented pyrolytic graphite based on graphene oxide Download PDFInfo
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- CN108905903A CN108905903A CN201810969746.1A CN201810969746A CN108905903A CN 108905903 A CN108905903 A CN 108905903A CN 201810969746 A CN201810969746 A CN 201810969746A CN 108905903 A CN108905903 A CN 108905903A
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- fixedly connected
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- graphene oxide
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- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 108
- 229910021389 graphene Inorganic materials 0.000 title claims abstract description 77
- 229910002804 graphite Inorganic materials 0.000 title claims abstract description 31
- 239000010439 graphite Substances 0.000 title claims abstract description 31
- NJPPVKZQTLUDBO-UHFFFAOYSA-N novaluron Chemical compound C1=C(Cl)C(OC(F)(F)C(OC(F)(F)F)F)=CC=C1NC(=O)NC(=O)C1=C(F)C=CC=C1F NJPPVKZQTLUDBO-UHFFFAOYSA-N 0.000 claims abstract description 10
- 238000005192 partition Methods 0.000 claims description 13
- 230000005611 electricity Effects 0.000 claims description 3
- 238000012545 processing Methods 0.000 abstract description 6
- 238000000197 pyrolysis Methods 0.000 abstract description 6
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- 238000013461 design Methods 0.000 abstract description 2
- 239000007789 gas Substances 0.000 description 17
- 238000002360 preparation method Methods 0.000 description 7
- 238000006243 chemical reaction Methods 0.000 description 4
- 239000002131 composite material Substances 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 150000001336 alkenes Chemical class 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 125000000524 functional group Chemical group 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 241000894007 species Species 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- 241000237858 Gastropoda Species 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000001727 in vivo Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- -1 pedestal and cabinet Chemical compound 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J6/00—Heat treatments such as Calcining; Fusing ; Pyrolysis
- B01J6/008—Pyrolysis reactions
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
- C01B32/20—Graphite
- C01B32/205—Preparation
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Inorganic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Carbon And Carbon Compounds (AREA)
Abstract
The invention discloses a kind of devices that highly oriented pyrolytic graphite is prepared based on graphene oxide, including pedestal and cabinet, cabinet is fixed on the top of pedestal, bracket is fixedly connected on the side wall of the cabinet, the upper end of the bracket is fixedly connected with transverse slat, and one end of transverse slat extends to the inside of cabinet and is fixedly connected with the inner sidewall of cabinet, cavity is offered in the transverse slat, threaded rod is rotatably connected in the cavity, movable block is threaded on the threaded rod, and the upper end of movable block extends to the top of transverse slat, the upper end of the movable block is fixedly connected with placement plate.Structure of the invention is stablized; it is easy to operate; design is scientific and reasonable; it is with short production cycle; need pyrolysis processing graphene can be stable be moved in cabinet and processed; graphene can preferably be protected in pyrolysis processing, so that graphene will not generate damage, more accurately positioning pyrolysis can be carried out according to the demand of people to graphene.
Description
Technical field
The present invention relates to the equipment technical fields that highly oriented pyrolytic graphite is prepared based on graphene oxide, more particularly to one kind
The device of highly oriented pyrolytic graphite is prepared based on graphene oxide.
Background technique
Graphene oxide is the oxide of graphene, and color is brown color, and common product has powdered, piece on the market
Shape and solution shape.It, can be via each because after aoxidizing, oxygen-containing functional group increases and keeps property more active compared with graphene thereon
Kind with reacting for oxygen-containing functional group and improve nature;The product of graphene oxide having arrived widely in our life
With graphene oxide is a kind of new carbon haveing excellent performance, specific surface area with higher and surface function abundant
Group.Graphene oxide composite material is even more to have widely to answer including polymerization species composite material and inorganic species composite material
Become another research emphasis with the surface modification in field, therefore graphene oxide.
Our common graphene oxide Preparation equipments are all by the way that graphene is placed on a closed environment at present
It is interior, oxidation processes then are being carried out to graphene, and such Preparation equipment cannot be preferably according to the requirement of people to stone
Prepared by black alkene, lead to the waste during the preparation process of graphene.
For this purpose, we have proposed a kind of devices for preparing highly oriented pyrolytic graphite based on graphene oxide.
Summary of the invention
The purpose of the present invention is to solve in the prior art cannot preferably according to the requirement of people to graphene into
The problem of prepared by row, lead to the waste during the preparation process of graphene, and the one kind proposed is high based on graphene oxide preparation
The device of directional thermal decomposition graphite.
To achieve the goals above, present invention employs following technical solutions:One kind preparing Gao Ding based on graphene oxide
To the device of pyrolytic graphite, including pedestal and cabinet, cabinet is fixed on the top of pedestal, is fixedly connected on the side wall of the cabinet
Have a bracket, the upper end of the bracket is fixedly connected with transverse slat, and one end of transverse slat extend to cabinet inside and in cabinet
Side wall is fixedly connected, and cavity is offered in the transverse slat, and threaded rod, screw thread on the threaded rod are rotatably connected in the cavity
It being connected with movable block, and the upper end of movable block extends to the top of transverse slat, the upper end of the movable block is fixedly connected with placement plate,
Side of the placement plate far from movable block is symmetrically fixedly connected there are two fixed mechanism, and one end that the transverse slat is located at cabinet is set
There is driving mechanism, and driving mechanism is connect with threaded rod, be fixedly connected with cover on the inner roof wall of the cabinet, in the cover
Symmetrical rotation connection is there are two shaft, and fixing sleeve is equipped with first gear and second gear, the cover respectively in two shafts
It is equipped with motor mechanism in vivo, and motor mechanism is connect with second gear, vertical sliding is connected with siphunculus, and siphunculus in the cover
Two sides connect respectively at first gear with second gear, the lower end of the siphunculus extends to the lower section of cover, the siphunculus
Lower end is fixedly connected with support plate, and the lower end of the support plate is symmetrically fixedly connected there are two spring, under two springs
End is fixedly connected with fixed plate jointly, and the lower end of the fixed plate is equipped with gas hood, and the gas hood passes through the first telescoping tube and siphunculus
Connection.
In the above-mentioned device for preparing highly oriented pyrolytic graphite based on graphene oxide, the driving mechanism includes fixing
Motor housing in transverse slat lower end is fixedly connected with first motor, the driving of the first motor in the inner bottom wall of the motor housing
End is fixedly connected with drive rod, and drive rod extends in cavity far from one end of first motor, and the drive rod is located at cavity
One end be fixedly connected with first bevel gear, fixing sleeve is equipped with second bevel gear, and second bevel gear and the on the threaded rod
The engagement of one bevel gear.
In the above-mentioned device for preparing highly oriented pyrolytic graphite based on graphene oxide, the fixed mechanism includes placing
Two baffles that the upper end of plate is symmetrically fixedly connected vertically, two opposite sides of the baffle are fixedly connected to cylinder, and two
The driving end of a cylinder is fixedly connected to fixture block.
In the above-mentioned device for preparing highly oriented pyrolytic graphite based on graphene oxide, the motor mechanism includes fixing
The second motor on cover inner roof wall, the driving end of second motor is fixedly connected with worm screw, and worm screw is far from the second electricity
One end of machine is rotatably connected in cover inner bottom wall, and fixing sleeve is equipped with worm gear in the first gear, and worm and wheel engages.
In the above-mentioned device for preparing highly oriented pyrolytic graphite based on graphene oxide, the upper end of the siphunculus is communicated with
Second telescoping tube, and the upper end of the second telescoping tube extends to the top of cover.
It is fixed vertically in the cavity to connect in the above-mentioned device for preparing highly oriented pyrolytic graphite based on graphene oxide
It is connected to partition, and partition is set on threaded rod and is rotatablely connected with threaded rod, the side of the partition is fixedly connected with limit
Bar, and gag lever post is fixed on the inner sidewall of cavity far from one end of partition, the movable block is slidably connected on gag lever post.
It is solid on the inner sidewall of the cover in the above-mentioned device for preparing highly oriented pyrolytic graphite based on graphene oxide
Surely it is connected with stable block, and stablizes block and is set on worm screw and is rotatablely connected with worm screw.
In the above-mentioned device for preparing highly oriented pyrolytic graphite based on graphene oxide, opened up on the side wall of the cabinet
There is shifting chute, and transverse slat is located in shifting chute.
Compared with prior art, this gas is prepared the advantages of device of highly oriented pyrolytic graphite based on graphene oxide and existed
In:
1, of the invention, when being moved to the top of graphene by the way that gas hood is arranged and contacted with graphene, it can make solid
Fixed board pushes two and is shunk, so that gas hood will not damage graphene when contact with graphene, first is flexible
Pipe can make gas hood be preferably located at;Shifting chute is offered on the side wall of the cabinet, and transverse slat is located in shifting chute.
2, by two cylinders of setting push fixture blocks to graphene can be more stable in placement plate be fixed, make
Graphene can be stablized to be moved in cabinet and carry out reacting processing.
3, first gear is driven to be rotated in shaft by worm screw by the way that the second motor is arranged, so that first gear
It can more preferably drive siphunculus that gas hood is pushed to be fitted on graphene under the auxiliary of second gear, graphene be pyrolyzed anti-
It answers.
In conclusion structure of the invention is stablized, easy to operate, design is scientific and reasonable, with short production cycle, needs pyrolysis processing
Graphene can be stable be moved in cabinet and processed, graphene can preferably be protected in pyrolysis processing
Shield can carry out more accurately positioning pyrolysis to graphene so that graphene will not generate damage according to the demand of people.
Detailed description of the invention
Fig. 1 is a kind of structural representation for the device that highly oriented pyrolytic graphite is prepared based on graphene oxide proposed by the present invention
Figure;
Fig. 2 is a kind of cover internal structure for the device that highly oriented pyrolytic graphite is prepared based on graphene oxide proposed by the present invention
Schematic diagram;
Fig. 3 is that a kind of mobile block structure for the device that highly oriented pyrolytic graphite is prepared based on graphene oxide proposed by the present invention is shown
It is intended to;
Fig. 4 is a kind of fixed mechanism structure for the device that highly oriented pyrolytic graphite is prepared based on graphene oxide proposed by the present invention
Schematic diagram;
Fig. 5 is a kind of side view for the first gear that highly oriented pyrolytic graphite is prepared based on graphene oxide proposed by the present invention.
In figure:1 pedestal, 2 cabinets, 3 covers, 4 threaded rods, 5 gag lever posts, 6 transverse slats, 7 brackets, 8 second telescoping tubes, 9 second
Block, 11 worm screws, 12 first gears, 13 second gears, 14 siphunculus, 15 support plates, 16 springs, 17 fixed plates, 18 are stablized in motor, 10
First telescoping tube, 19 gas hoods, 20 first motors, 21 motor housings, 22 drive rods, 23 first bevel gears, 24 second bevel gears, 25 are moved
Motion block, 26 placement plates, 27 baffles, 28 cylinders, 29 fixture blocks, 30 worm gears.
Specific embodiment
Following embodiment only exists in illustrative purpose, limits the scope of the invention without being intended to.
Embodiment
Referring to Fig.1-5, a kind of device preparing highly oriented pyrolytic graphite based on graphene oxide, including pedestal 1 and cabinet
2, cabinet 2 is fixed on the top of pedestal 1, and bracket 7 is fixedly connected on the side wall of cabinet 2, and the upper end of bracket 7 is fixedly connected with cross
Plate 6, and one end of transverse slat 6 extends to the inside of cabinet 2 and is fixedly connected with the inner sidewall of cabinet 2, opens up in transverse slat 6 free
Chamber is rotatably connected to threaded rod 4 in cavity, movable block 25 is threaded on threaded rod 4, and the upper end of movable block 25 extends to
The top of transverse slat 6, the upper end of movable block 25 are fixedly connected with placement plate 26, and side of the placement plate 26 far from movable block 25 is symmetrically solid
Fixed connection is there are two fixed mechanism, and one end that transverse slat 6 is located at cabinet 2 is equipped with driving mechanism, and driving mechanism and threaded rod 4 connect
It connects, the graphene that needs can be processed is placed into placement plate 26, and the graphene in placement plate 26 is being moved by threaded rod 4
It moves to production preparation is carried out in cabinet 2, can more preferably save manpower and graphene is delivered in cabinet 2 and be reacted;
It is fixedly connected with cover 3 on the inner roof wall of cabinet 2, symmetrically rotation connection is there are two shaft in cover 3, in two shafts point
Other fixing sleeve is equipped with first gear 12 and second gear 13, and motor mechanism, and motor mechanism and second gear 13 are equipped in cover 3
It connects, vertical sliding is connected with siphunculus 14 in cover 3, and the two sides of siphunculus 14 connect respectively at first gear 12 and second gear 13
It connects, siphunculus 14 can make the gas to graphene pyrolytic reaction be delivered on graphene, prepare to graphene, siphunculus 14
Lower end extend to the lower section of cover 3, the lower end of siphunculus 14 is fixedly connected with support plate 15, and the lower end of support plate 15 is symmetrically fixed
There are two spring 16, the lower end of two springs 16 is fixedly connected with fixed plate 17 jointly for connection, and the lower end of fixed plate 17 is equipped with gas
Cover 19, gas hood 19 are connected to by the first telescoping tube 18 with siphunculus 14, when gas hood 19 is moved to the top of graphene and and graphene
When contact, it can make fixed plate 17 that two springs 16 be pushed to be shunk, so that gas hood 19 was contacted with graphene
When graphene will not be damaged, the first telescoping tube 18 can make gas hood 19 be preferably located at;The side wall of cabinet 2
On offer shifting chute, and transverse slat 6 is located in shifting chute;
Driving mechanism includes the motor housing 21 for being fixed on 6 lower end of transverse slat, and the first electricity is fixedly connected in the inner bottom wall of motor housing 21
Machine 20, the driving end of first motor 20 is fixedly connected with drive rod 22, and drive rod 22 extends far from one end of first motor 20
To cavity, one end that drive rod 22 is located at cavity is fixedly connected with first bevel gear 23, and fixing sleeve is equipped with second on threaded rod 4
Bevel gear 24, and second bevel gear 24 is engaged with first bevel gear 23, can preferably drive threaded rod 4 by first motor 20
It carries out stablizing movement in cavity, be pyrolyzed to drive the placement plate 26 on mobile 25 that graphene is delivered in cabinet 2
Reaction;
Partition is fixedly connected in cavity vertically, and partition is set on threaded rod 4 and is rotatablely connected with threaded rod 4, partition
Side is fixedly connected with gag lever post 5, and gag lever post 5 is fixed on the inner sidewall of cavity far from one end of partition, and movable block 25 is sliding
Dynamic to be connected on gag lever post 5, gag lever post 5 is used to that movable block 25 is assisted to be moved on threaded rod 4, allow graphene more
Add stable be moved in cabinet 2;
Fixed mechanism includes two baffles 27 that the upper end of placement plate 26 is symmetrically fixedly connected vertically, two baffles 27 it is opposite one
Side is fixedly connected to cylinder 28, and the driving end of two cylinders 28 is fixedly connected to fixture block 29, and two cylinders 28 push fixture block
29 pairs of graphenes can be more stable in placement plate 26 be fixed;
Motor mechanism includes the second motor 9 being fixed on 3 inner roof wall of cover, and the driving end of the second motor 9 is fixedly connected with snail
Bar 11, and worm screw 11 is rotatably connected in 3 inner bottom wall of cover far from one end of the second motor 9, fixation is arranged in first gear 12
There is worm gear 30, and worm screw 11 engages with worm gear 30, the second motor 9 drives first gear 12 to carry out in shaft by worm screw 11
Rotation, so that first gear 12 can more preferably drive siphunculus 14 that gas hood 19 is pushed to be fitted in graphite under the auxiliary of second gear 13
On alkene, pyrolytic reaction is carried out to graphene;
It is fixedly connected with stable block 10 on the inner sidewall of cover 3, and stablizes block 10 and is set on worm screw 11 and is rotated with worm screw 11
Connection stablizes block 10 for supporting worm 11 and carries out stable rotation in cover 3.
The electric elements occurred in this article are electrically connected with extraneous main controller and 220V alternating current, and main controller can be meter
Calculation machine etc. plays the conventionally known equipment of control.
The present invention is placed into the graphene for needing to be oxidized processing in placement plate 26, is then pushed away by the cylinder 28 of two sides
Dynamic fixture block 29 grips graphene, then drives the drive rod 22 on driving end to be rotated by first motor 20, makes
The first bevel gear 23 that must be fixed on drive rod 22 drives threaded rod 4 to be rotated on partition by second bevel gear 24,
So that movable block 25 pushes placement plate 26 to be moved in cabinet 2 under the limit of gag lever post 5, then driven by the second motor 9
Worm screw 11 is rotated on stablizing block 10, and worm screw 11 with engaging for worm gear 30 by driving the first gear 12 enterprising in shaft
Row rotation, and then the siphunculus 14 between second gear 13 and a gear 12 can be driven to be displaced, so that being fixed on siphunculus 14
The gas hood 19 of lower end is moved on graphene, then to carry out reaction preparation in placement plate 26 to graphene.
Although pedestal 1, cabinet 2, cover 3, threaded rod 4, gag lever post 5, transverse slat 6, bracket 7, is used more herein
Two telescoping tubes 8, stablize block 10, worm screw 11, first gear 12, second gear 13, siphunculus 14, support plate 15, bullet at second motor 9
Spring 16, fixed plate 17, the first telescoping tube 18, gas hood 19, first motor 20, motor housing 21, drive rod 22, first bevel gear 23,
The terms such as second bevel gear 24, movable block 25, placement plate 26, baffle 27, cylinder 28, fixture block 29, worm gear 30, but be not precluded and make
A possibility that with other terms.The use of these items is only for be more convenient to describe and explain essence of the invention;It
To be construed to any additional limitation disagreed with spirit of that invention.
Claims (8)
1. a kind of device for preparing highly oriented pyrolytic graphite based on graphene oxide, including pedestal(1)With cabinet(2), feature
It is, cabinet(2)It is fixed on pedestal(1)Top, the cabinet(2)Side wall on be fixedly connected with bracket(7), the bracket
(7)Upper end be fixedly connected with transverse slat(6), and transverse slat(6)One end extend to cabinet(2)Inside and and cabinet(2)It is interior
Side wall is fixedly connected, the transverse slat(6)Cavity is inside offered, is rotatably connected to threaded rod in the cavity(4), the threaded rod
(4)On be threaded with movable block(25), and movable block(25)Upper end extend to transverse slat(6)Top, the movable block
(25)Upper end be fixedly connected with placement plate(26), the placement plate(26)Far from movable block(25)Side be symmetrically fixedly connected
There are two fixed mechanism, the transverse slats(6)Positioned at cabinet(2)One end be equipped with driving mechanism, and driving mechanism and threaded rod(4)
Connection, the cabinet(2)Inner roof wall on be fixedly connected with cover(3), the cover(3)There are two turn for interior symmetrical rotation connection
Axis, fixing sleeve is equipped with first gear respectively in two shafts(12)With second gear(13), the cover(3)It is interior to be equipped with electricity
Machine mechanism, and motor mechanism and second gear(13)Connection, the cover(3)Interior vertical sliding is connected with siphunculus(14), and it is logical
Pipe(14)Two sides respectively at first gear(12)With second gear(13)Connection, the siphunculus(14)Lower end extend to cover
(3)Lower section, the siphunculus(14)Lower end be fixedly connected with support plate(15), the support plate(15)Lower end symmetrically fix
There are two springs for connection(16), two springs(16)Lower end be fixedly connected with fixed plate jointly(17), the fixed plate
(17)Lower end be equipped with gas hood(19), the gas hood(19)Pass through the first telescoping tube(18)With siphunculus(14)Connection.
2. a kind of device for being prepared highly oriented pyrolytic graphite based on graphene oxide according to claim 1, feature are existed
In the driving mechanism includes being fixed on transverse slat(6)The motor housing of lower end(21), the motor housing(21)Inner bottom wall on it is fixed
It is connected with first motor(20), the first motor(20)Driving end be fixedly connected with drive rod(22), and drive rod(22)
Far from first motor(20)One end extend in cavity, the drive rod(22)One end positioned at cavity is fixedly connected with first
Bevel gear(23), the threaded rod(4)Upper fixing sleeve is equipped with second bevel gear(24), and second bevel gear(24)With the first cone tooth
Wheel(23)Engagement.
3. a kind of device for being prepared highly oriented pyrolytic graphite based on graphene oxide according to claim 1, feature are existed
In the fixed mechanism includes placement plate(26)Two baffles being symmetrically fixedly connected vertically of upper end(27), two gears
Plate(27)Opposite side is fixedly connected to cylinder(28), two cylinders(28)Driving end be fixedly connected to fixture block
(29).
4. a kind of device for being prepared highly oriented pyrolytic graphite based on graphene oxide according to claim 2, feature are existed
In the motor mechanism includes being fixed on cover(3)The second motor on inner roof wall(9), second motor(9)Driving end
It is fixedly connected with worm screw(11), and worm screw(11)Far from the second motor(9)One end be rotatably connected on cover(3)In inner bottom wall,
The first gear(12)Upper fixing sleeve is equipped with worm gear(30), and worm screw(11)With worm gear(30)Engagement.
5. a kind of device for being prepared highly oriented pyrolytic graphite based on graphene oxide according to claim 1, feature are existed
In the siphunculus(14)Upper end be communicated with the second telescoping tube(8), and the second telescoping tube(8)Upper end extend to cover(3)'s
Top.
6. a kind of device for being prepared highly oriented pyrolytic graphite based on graphene oxide according to claim 1, feature are existed
In partition being fixedly connected in the cavity vertically, and partition is set in threaded rod(4)Upper and and threaded rod(4)Rotation connection,
The side of the partition is fixedly connected with gag lever post(5), and gag lever post(5)One end far from partition is fixed on the inner sidewall of cavity
On, the movable block(25)It is slidably connected at gag lever post(5)On.
7. a kind of device for being prepared highly oriented pyrolytic graphite based on graphene oxide according to claim 1, feature are existed
In the cover(3)Inner sidewall on be fixedly connected with stable block(10), and stablize block(10)It is set in worm screw(11)It is upper and with
Worm screw(11)Rotation connection.
8. a kind of device for being prepared highly oriented pyrolytic graphite based on graphene oxide according to claim 1, feature are existed
In the cabinet(2)Side wall on offer shifting chute, and transverse slat(6)In shifting chute.
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文周等: "《食品包装技术》", 31 August 2017, 中国轻工业出版社 * |
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Application publication date: 20181130 |