CN108905617A - A kind of catalysis oxidation heat recovery apparatus of temperature self-regulating nodal pattern - Google Patents
A kind of catalysis oxidation heat recovery apparatus of temperature self-regulating nodal pattern Download PDFInfo
- Publication number
- CN108905617A CN108905617A CN201811042403.7A CN201811042403A CN108905617A CN 108905617 A CN108905617 A CN 108905617A CN 201811042403 A CN201811042403 A CN 201811042403A CN 108905617 A CN108905617 A CN 108905617A
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- China
- Prior art keywords
- pipeline
- heat exchanger
- catalytic oxidation
- oxidation furnace
- exhaust gas
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- 230000003647 oxidation Effects 0.000 title claims abstract description 47
- 238000007254 oxidation reaction Methods 0.000 title claims abstract description 47
- 238000011084 recovery Methods 0.000 title claims abstract description 15
- 238000006555 catalytic reaction Methods 0.000 title claims abstract description 14
- 230000003197 catalytic effect Effects 0.000 claims abstract description 39
- 239000003054 catalyst Substances 0.000 claims abstract description 15
- 238000010438 heat treatment Methods 0.000 claims 1
- 238000009434 installation Methods 0.000 claims 1
- 239000000470 constituent Substances 0.000 abstract 1
- 239000007789 gas Substances 0.000 description 24
- 238000000034 method Methods 0.000 description 4
- 230000001590 oxidative effect Effects 0.000 description 4
- 239000012855 volatile organic compound Substances 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 229910000510 noble metal Inorganic materials 0.000 description 2
- 239000002912 waste gas Substances 0.000 description 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 239000003546 flue gas Substances 0.000 description 1
- 239000003915 liquefied petroleum gas Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 238000006479 redox reaction Methods 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
- B01D53/8678—Removing components of undefined structure
- B01D53/8687—Organic components
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
- B01D53/8696—Controlling the catalytic process
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/70—Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
- B01D2257/708—Volatile organic compounds V.O.C.'s
Landscapes
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Biomedical Technology (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Incineration Of Waste (AREA)
- Exhaust Gas Treatment By Means Of Catalyst (AREA)
Abstract
The invention discloses a kind of catalysis oxidation heat recovery apparatuses of temperature self adjusting, including main air blower, heat recovering heat exchanger, heater, Catalytic oxidation furnace and air quantity adjusting air valve, main air blower one end is exhaust gas inlet, the other end is connected to heat recovering heat exchanger by first pipe, heat recovering heat exchanger is connected to heater by second pipe, heater is connected to Catalytic oxidation furnace by third pipeline, Catalytic oxidation furnace is connected to heat recovering heat exchanger by the 4th pipeline, heat recovering heat exchanger is connected to chimney by the 5th pipeline, first pipe is connected to third pipeline by the 6th pipeline, air quantity adjusting air valve is installed on the 6th pipeline.Structure of the invention principle is simple, high degree of automation, under the operating condition of fluctuation of concentration, the heat recovery efficiency of heat recovering heat exchanger can be adjusted by air quantity adjusting air valve, make the exhaust gas temperature of Catalytic oxidation furnace entrance in the thermotonus window of catalyst, to guarantee exhaust gas constituents fully degraded, exhaust gas qualified discharge is discharged, to reduce pollution of the exhaust gas dump to environment.
Description
Technical field
The present invention relates to waste gas purification processing technology field, specially a kind of catalysis oxidation recuperation of heat of temperature self-regulating nodal pattern
Device.
Background technique
With the variation of production technology, industrial gas emission the case where there are exhaust gas concentration fluctuations.Since catalyst has one
Fixed thermotonus window, in waste gas pollution control and treatment catalytic oxidation technique, often there is temperature alarming in the operating condition of fluctuation of concentration.
It is investigated according to existing domestic market, is directed to the operating condition of fluctuation of concentration at present, catalytic oxidizing equipment one when thermo-field thoery
As be to go out a part of high heat gas from the outlet direct emission of Catalytic oxidation furnace, reduce system capacity, but this method can cause
Voltage loss reduce, catalyst space velocities increase, catalytic oxidizing equipment governance efficiency decline the problem of, cause exhaust gas concentration of emission and
Total emission volumn is exceeded.
Summary of the invention
The purpose of the present invention is to provide a kind of catalysis oxidation heat recovery apparatuses of temperature self-regulating nodal pattern, to solve above-mentioned back
The problem of being proposed in scape technology.
To achieve the above object, the present invention provides the following technical solutions:A kind of catalysis oxidation recuperation of heat of temperature self adjusting
Device, including main air blower, heat recovering heat exchanger, heater, Catalytic oxidation furnace and air quantity adjusting air valve, described main air blower one end
For exhaust gas inlet, the other end is connected to heat recovering heat exchanger by first pipe, and the heat recovering heat exchanger is connected by second pipe
Logical heater, the heater are connected to Catalytic oxidation furnace by third pipeline, and the Catalytic oxidation furnace is connected to by the 4th pipeline
Heat recovering heat exchanger, the heat recovering heat exchanger are connected to chimney by the 5th pipeline, and the first pipe and third pipeline pass through
The connection of 6th pipeline.
Preferably, catalyst is filled in the Catalytic oxidation furnace.
Preferably, air quantity adjusting air valve is installed on the 6th pipeline.
Preferably, the third pipeline is equipped with the first temperature sensor, the catalysis close to Catalytic oxidation furnace inlet
Second temperature sensor is installed in oxidation furnace.
Preferably, the heater uses one of electric heater, neat gas burner, near gas burner.
Compared with prior art, the beneficial effects of the invention are as follows:Structure of the invention principle is simple, high degree of automation,
Under the operating condition of fluctuation of concentration, the heat recovery efficiency of heat recovering heat exchanger can be adjusted by air quantity adjusting air valve, makes Catalytic oxidation furnace
The exhaust gas temperature of entrance is in the thermotonus window of catalyst, to guarantee that VOCs ingredient fully degraded, discharge exhaust gas stabilization reach
Mark discharge, to reduce pollution of the exhaust gas dump to environment.
Detailed description of the invention
Fig. 1 is overall structure of the present invention.
Specific embodiment
Following will be combined with the drawings in the embodiments of the present invention, and technical solution in the embodiment of the present invention carries out clear, complete
Site preparation description, it is clear that described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.It is based on
Embodiment in the present invention, it is obtained by those of ordinary skill in the art without making creative efforts every other
Embodiment shall fall within the protection scope of the present invention.
Referring to Fig. 1, the present invention provides a kind of technical solution:A kind of catalysis oxidation heat recovery apparatus of temperature self adjusting,
Including main air blower 2, heat recovering heat exchanger 4, heater 6, Catalytic oxidation furnace 8 and air quantity adjusting air valve 13, described 2 one end of main air blower
For exhaust gas inlet 1, the other end is connected to heat recovering heat exchanger 4 by first pipe 3, and the heat recovering heat exchanger 4 passes through the second pipe
Road 5 is connected to heater 6, and the heater 6 is connected to Catalytic oxidation furnace 8 by third pipeline 7, and the Catalytic oxidation furnace 8 passes through the
Four pipelines 9 are connected to heat recovering heat exchanger 4, and the heat recovering heat exchanger 4 is connected to chimney 11, first pipe by the 5th pipeline 10
Road 3 is connected to third pipeline 7 by the 6th pipeline 12, and air quantity adjusting air valve 13 is installed on the 6th pipeline 12.
In the present invention, catalyst is filled in Catalytic oxidation furnace 8, the noble metal that metallic carrier is filled in catalytic bed is urged
Agent, noble metal use Pt, Pd etc., and the mesh number of catalyst carrier is -300 mesh of 200 mesh.
In the present invention, second temperature sensor 15 is installed in Catalytic oxidation furnace 8;The third pipeline 7 is close to catalysis oxygen
Change 8 inlet of furnace and the first temperature sensor 14 is installed;Heater 6 uses electric heater, neat gas burner, liquefied petroleum gas
One of burner.
Working principle:There are two types of operating status, warming-up starting state and normal operating conditions by the present invention.Start shape in warming-up
Under state, air enters heat recovering heat exchanger after blower pressurizes and heats up, after heat up through electric heater, then be discharged into Catalytic oxidation furnace
Interior heatable catalyst, hot-air carries out heat recovery through heat recovering heat exchanger again later, is finally discharged into smoke stack emission.It is opened in warming-up
During dynamic, the temperature sensor of electric heater capacity and Catalytic oxidation furnace entrance is chain, when the air for entering Catalytic oxidation furnace
Temperature reach 250 DEG C -650 DEG C of Catalytic oxidation furnace thermotonus window after, warming-up start-up course terminates.
Under normal operating conditions, exhaust gas enters heat recovering heat exchanger after blower pressurizes and heats up, after through electric heater,
It is discharged into Catalytic oxidation furnace again, when Catalytic oxidation furnace inlet flue gas temperature is not up to 250 DEG C -650 DEG C of catalyst reaction window, electricity
Heater starting heats exhaust gas, and the temperature for making exhaust gas enter Catalytic oxidation furnace reaches 250 DEG C -650 of catalyst temperature Process window
℃.Organic exhaust gas catalyst surface occur redox reaction, VOCs degradation release heat, after through heat recovering heat exchanger return
Heat is received, last exhaust gas is through chimney qualified discharge.
When exhaust gas concentration is too high, since to aoxidize release heat too many by VOCs, the temperature of exhaust gas in Catalytic oxidation furnace will lead to
More than 250 DEG C -650 DEG C of catalyst reaction window, the reactivity worth of catalyst is influenced.Originally it is applicable in novel by adjusting air quantity adjusting
Valve 13 reduces the heat recycled in catalytic oxidizing equipment, controls the temperature of exhaust gas in Catalytic oxidation furnace near 250 DEG C,
It prevents catalytic oxidizing equipment heat recovery superfluous, exhaust gas is caused to flow through Catalytic oxidation furnace thermo-field thoery.
Structure of the invention principle is simple, high degree of automation, under the operating condition of fluctuation of concentration, can pass through air quantity adjusting air valve
The heat recovery efficiency for adjusting heat recovering heat exchanger, makes the exhaust gas temperature of Catalytic oxidation furnace entrance in the thermotonus window of catalyst
It is interior, to guarantee VOCs ingredient fully degraded, discharge exhaust gas stably reaching standard discharge, to reduce dirt of the exhaust gas dump to environment
Dye.
It although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with
A variety of variations, modification, replacement can be carried out to these embodiments without departing from the principles and spirit of the present invention by understanding
And modification, the scope of the present invention is defined by the appended.
Claims (5)
1. a kind of catalysis oxidation heat recovery apparatus of temperature self adjusting, including main air blower(2), heat recovering heat exchanger(4), heating
Device (6), Catalytic oxidation furnace(8)With air quantity adjusting air valve(13), it is characterised in that:The main air blower(2)One end is gas feed
(1), the other end passes through first pipe(3)It is connected to heat recovering heat exchanger(4), the heat recovering heat exchanger(4)Pass through second pipe
(5)It is connected to heater(6), the heater(6)Pass through third pipeline(7)It is connected to Catalytic oxidation furnace(8), the Catalytic oxidation furnace
(8)Pass through the 4th pipeline(9)It is connected to heat recovering heat exchanger(4), the heat recovering heat exchanger(4)Pass through the 5th pipeline(10)Connection
Chimney(11), the first pipe(3)With third pipeline(7)Pass through the 6th pipeline(12)Connection.
2. a kind of catalysis oxidation heat recovery apparatus of temperature self-regulating nodal pattern according to claim 1, it is characterised in that:It is described
Catalytic oxidation furnace(8)In be filled with catalyst.
3. a kind of catalysis oxidation heat recovery apparatus of temperature self-regulating nodal pattern according to claim 1, it is characterised in that:It is described
6th pipeline(12)Upper installation air quantity adjusting air valve(13).
4. a kind of catalysis oxidation heat recovery apparatus of temperature self-regulating nodal pattern according to claim 1, it is characterised in that:It is described
Third pipeline(7)Close to Catalytic oxidation furnace(8)Inlet is equipped with the first temperature sensor(14), the Catalytic oxidation furnace(8)
Second temperature sensor is inside installed(15).
5. a kind of catalysis oxidation heat recovery apparatus of temperature self-regulating nodal pattern according to claim 1, it is characterised in that:It is described
Heater(6)Using one of electric heater, neat gas burner, near gas burner.
Priority Applications (1)
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CN201811042403.7A CN108905617A (en) | 2018-09-07 | 2018-09-07 | A kind of catalysis oxidation heat recovery apparatus of temperature self-regulating nodal pattern |
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CN201811042403.7A CN108905617A (en) | 2018-09-07 | 2018-09-07 | A kind of catalysis oxidation heat recovery apparatus of temperature self-regulating nodal pattern |
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CN108905617A true CN108905617A (en) | 2018-11-30 |
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CN201811042403.7A Pending CN108905617A (en) | 2018-09-07 | 2018-09-07 | A kind of catalysis oxidation heat recovery apparatus of temperature self-regulating nodal pattern |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109668157A (en) * | 2018-12-27 | 2019-04-23 | 北京中电联环保股份有限公司 | Waste gas catalytic incineration processing system and its adjustment control method |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101716462A (en) * | 2010-01-26 | 2010-06-02 | 浙江卫星丙烯酸制造有限公司 | Catalysis and oxidation method of high-concentration waste gas |
CN105854588A (en) * | 2016-03-31 | 2016-08-17 | 湖南安淳高新技术有限公司 | A sulfur recovering isothermal reactor and a process thereof |
CN106765217A (en) * | 2015-11-19 | 2017-05-31 | 中国石油化工股份有限公司 | A kind of organic waste gas furnace and incinerating method |
CN207025073U (en) * | 2016-12-08 | 2018-02-23 | 中国石油化工股份有限公司 | One kind saves strong ecad catalysis oxidation emission-control equipment |
KR101837060B1 (en) * | 2017-09-15 | 2018-03-12 | (주)대양이엔아이 | Indoor concentration and combustion device |
CN208893973U (en) * | 2018-09-07 | 2019-05-24 | 云汇环保科技南通有限公司 | A kind of catalysis oxidation heat recovery apparatus of temperature self-regulating nodal pattern |
-
2018
- 2018-09-07 CN CN201811042403.7A patent/CN108905617A/en active Pending
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101716462A (en) * | 2010-01-26 | 2010-06-02 | 浙江卫星丙烯酸制造有限公司 | Catalysis and oxidation method of high-concentration waste gas |
CN106765217A (en) * | 2015-11-19 | 2017-05-31 | 中国石油化工股份有限公司 | A kind of organic waste gas furnace and incinerating method |
CN105854588A (en) * | 2016-03-31 | 2016-08-17 | 湖南安淳高新技术有限公司 | A sulfur recovering isothermal reactor and a process thereof |
CN207025073U (en) * | 2016-12-08 | 2018-02-23 | 中国石油化工股份有限公司 | One kind saves strong ecad catalysis oxidation emission-control equipment |
KR101837060B1 (en) * | 2017-09-15 | 2018-03-12 | (주)대양이엔아이 | Indoor concentration and combustion device |
CN208893973U (en) * | 2018-09-07 | 2019-05-24 | 云汇环保科技南通有限公司 | A kind of catalysis oxidation heat recovery apparatus of temperature self-regulating nodal pattern |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109668157A (en) * | 2018-12-27 | 2019-04-23 | 北京中电联环保股份有限公司 | Waste gas catalytic incineration processing system and its adjustment control method |
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