CN108905617A - A kind of catalysis oxidation heat recovery apparatus of temperature self-regulating nodal pattern - Google Patents

A kind of catalysis oxidation heat recovery apparatus of temperature self-regulating nodal pattern Download PDF

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Publication number
CN108905617A
CN108905617A CN201811042403.7A CN201811042403A CN108905617A CN 108905617 A CN108905617 A CN 108905617A CN 201811042403 A CN201811042403 A CN 201811042403A CN 108905617 A CN108905617 A CN 108905617A
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CN
China
Prior art keywords
pipeline
heat exchanger
catalytic oxidation
oxidation furnace
exhaust gas
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201811042403.7A
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Chinese (zh)
Inventor
刘敬印
周芸
梁春霞
徐世辰
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Cloud Link Environmental Protection Technology Nantong Co Ltd
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Cloud Link Environmental Protection Technology Nantong Co Ltd
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Publication date
Application filed by Cloud Link Environmental Protection Technology Nantong Co Ltd filed Critical Cloud Link Environmental Protection Technology Nantong Co Ltd
Priority to CN201811042403.7A priority Critical patent/CN108905617A/en
Publication of CN108905617A publication Critical patent/CN108905617A/en
Pending legal-status Critical Current

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86Catalytic processes
    • B01D53/8678Removing components of undefined structure
    • B01D53/8687Organic components
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86Catalytic processes
    • B01D53/8696Controlling the catalytic process
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/70Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
    • B01D2257/708Volatile organic compounds V.O.C.'s

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  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Incineration Of Waste (AREA)
  • Exhaust Gas Treatment By Means Of Catalyst (AREA)

Abstract

The invention discloses a kind of catalysis oxidation heat recovery apparatuses of temperature self adjusting, including main air blower, heat recovering heat exchanger, heater, Catalytic oxidation furnace and air quantity adjusting air valve, main air blower one end is exhaust gas inlet, the other end is connected to heat recovering heat exchanger by first pipe, heat recovering heat exchanger is connected to heater by second pipe, heater is connected to Catalytic oxidation furnace by third pipeline, Catalytic oxidation furnace is connected to heat recovering heat exchanger by the 4th pipeline, heat recovering heat exchanger is connected to chimney by the 5th pipeline, first pipe is connected to third pipeline by the 6th pipeline, air quantity adjusting air valve is installed on the 6th pipeline.Structure of the invention principle is simple, high degree of automation, under the operating condition of fluctuation of concentration, the heat recovery efficiency of heat recovering heat exchanger can be adjusted by air quantity adjusting air valve, make the exhaust gas temperature of Catalytic oxidation furnace entrance in the thermotonus window of catalyst, to guarantee exhaust gas constituents fully degraded, exhaust gas qualified discharge is discharged, to reduce pollution of the exhaust gas dump to environment.

Description

A kind of catalysis oxidation heat recovery apparatus of temperature self-regulating nodal pattern
Technical field
The present invention relates to waste gas purification processing technology field, specially a kind of catalysis oxidation recuperation of heat of temperature self-regulating nodal pattern Device.
Background technique
With the variation of production technology, industrial gas emission the case where there are exhaust gas concentration fluctuations.Since catalyst has one Fixed thermotonus window, in waste gas pollution control and treatment catalytic oxidation technique, often there is temperature alarming in the operating condition of fluctuation of concentration.
It is investigated according to existing domestic market, is directed to the operating condition of fluctuation of concentration at present, catalytic oxidizing equipment one when thermo-field thoery As be to go out a part of high heat gas from the outlet direct emission of Catalytic oxidation furnace, reduce system capacity, but this method can cause Voltage loss reduce, catalyst space velocities increase, catalytic oxidizing equipment governance efficiency decline the problem of, cause exhaust gas concentration of emission and Total emission volumn is exceeded.
Summary of the invention
The purpose of the present invention is to provide a kind of catalysis oxidation heat recovery apparatuses of temperature self-regulating nodal pattern, to solve above-mentioned back The problem of being proposed in scape technology.
To achieve the above object, the present invention provides the following technical solutions:A kind of catalysis oxidation recuperation of heat of temperature self adjusting Device, including main air blower, heat recovering heat exchanger, heater, Catalytic oxidation furnace and air quantity adjusting air valve, described main air blower one end For exhaust gas inlet, the other end is connected to heat recovering heat exchanger by first pipe, and the heat recovering heat exchanger is connected by second pipe Logical heater, the heater are connected to Catalytic oxidation furnace by third pipeline, and the Catalytic oxidation furnace is connected to by the 4th pipeline Heat recovering heat exchanger, the heat recovering heat exchanger are connected to chimney by the 5th pipeline, and the first pipe and third pipeline pass through The connection of 6th pipeline.
Preferably, catalyst is filled in the Catalytic oxidation furnace.
Preferably, air quantity adjusting air valve is installed on the 6th pipeline.
Preferably, the third pipeline is equipped with the first temperature sensor, the catalysis close to Catalytic oxidation furnace inlet Second temperature sensor is installed in oxidation furnace.
Preferably, the heater uses one of electric heater, neat gas burner, near gas burner.
Compared with prior art, the beneficial effects of the invention are as follows:Structure of the invention principle is simple, high degree of automation, Under the operating condition of fluctuation of concentration, the heat recovery efficiency of heat recovering heat exchanger can be adjusted by air quantity adjusting air valve, makes Catalytic oxidation furnace The exhaust gas temperature of entrance is in the thermotonus window of catalyst, to guarantee that VOCs ingredient fully degraded, discharge exhaust gas stabilization reach Mark discharge, to reduce pollution of the exhaust gas dump to environment.
Detailed description of the invention
Fig. 1 is overall structure of the present invention.
Specific embodiment
Following will be combined with the drawings in the embodiments of the present invention, and technical solution in the embodiment of the present invention carries out clear, complete Site preparation description, it is clear that described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.It is based on Embodiment in the present invention, it is obtained by those of ordinary skill in the art without making creative efforts every other Embodiment shall fall within the protection scope of the present invention.
Referring to Fig. 1, the present invention provides a kind of technical solution:A kind of catalysis oxidation heat recovery apparatus of temperature self adjusting, Including main air blower 2, heat recovering heat exchanger 4, heater 6, Catalytic oxidation furnace 8 and air quantity adjusting air valve 13, described 2 one end of main air blower For exhaust gas inlet 1, the other end is connected to heat recovering heat exchanger 4 by first pipe 3, and the heat recovering heat exchanger 4 passes through the second pipe Road 5 is connected to heater 6, and the heater 6 is connected to Catalytic oxidation furnace 8 by third pipeline 7, and the Catalytic oxidation furnace 8 passes through the Four pipelines 9 are connected to heat recovering heat exchanger 4, and the heat recovering heat exchanger 4 is connected to chimney 11, first pipe by the 5th pipeline 10 Road 3 is connected to third pipeline 7 by the 6th pipeline 12, and air quantity adjusting air valve 13 is installed on the 6th pipeline 12.
In the present invention, catalyst is filled in Catalytic oxidation furnace 8, the noble metal that metallic carrier is filled in catalytic bed is urged Agent, noble metal use Pt, Pd etc., and the mesh number of catalyst carrier is -300 mesh of 200 mesh.
In the present invention, second temperature sensor 15 is installed in Catalytic oxidation furnace 8;The third pipeline 7 is close to catalysis oxygen Change 8 inlet of furnace and the first temperature sensor 14 is installed;Heater 6 uses electric heater, neat gas burner, liquefied petroleum gas One of burner.
Working principle:There are two types of operating status, warming-up starting state and normal operating conditions by the present invention.Start shape in warming-up Under state, air enters heat recovering heat exchanger after blower pressurizes and heats up, after heat up through electric heater, then be discharged into Catalytic oxidation furnace Interior heatable catalyst, hot-air carries out heat recovery through heat recovering heat exchanger again later, is finally discharged into smoke stack emission.It is opened in warming-up During dynamic, the temperature sensor of electric heater capacity and Catalytic oxidation furnace entrance is chain, when the air for entering Catalytic oxidation furnace Temperature reach 250 DEG C -650 DEG C of Catalytic oxidation furnace thermotonus window after, warming-up start-up course terminates.
Under normal operating conditions, exhaust gas enters heat recovering heat exchanger after blower pressurizes and heats up, after through electric heater, It is discharged into Catalytic oxidation furnace again, when Catalytic oxidation furnace inlet flue gas temperature is not up to 250 DEG C -650 DEG C of catalyst reaction window, electricity Heater starting heats exhaust gas, and the temperature for making exhaust gas enter Catalytic oxidation furnace reaches 250 DEG C -650 of catalyst temperature Process window ℃.Organic exhaust gas catalyst surface occur redox reaction, VOCs degradation release heat, after through heat recovering heat exchanger return Heat is received, last exhaust gas is through chimney qualified discharge.
When exhaust gas concentration is too high, since to aoxidize release heat too many by VOCs, the temperature of exhaust gas in Catalytic oxidation furnace will lead to More than 250 DEG C -650 DEG C of catalyst reaction window, the reactivity worth of catalyst is influenced.Originally it is applicable in novel by adjusting air quantity adjusting Valve 13 reduces the heat recycled in catalytic oxidizing equipment, controls the temperature of exhaust gas in Catalytic oxidation furnace near 250 DEG C, It prevents catalytic oxidizing equipment heat recovery superfluous, exhaust gas is caused to flow through Catalytic oxidation furnace thermo-field thoery.
Structure of the invention principle is simple, high degree of automation, under the operating condition of fluctuation of concentration, can pass through air quantity adjusting air valve The heat recovery efficiency for adjusting heat recovering heat exchanger, makes the exhaust gas temperature of Catalytic oxidation furnace entrance in the thermotonus window of catalyst It is interior, to guarantee VOCs ingredient fully degraded, discharge exhaust gas stably reaching standard discharge, to reduce dirt of the exhaust gas dump to environment Dye.
It although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with A variety of variations, modification, replacement can be carried out to these embodiments without departing from the principles and spirit of the present invention by understanding And modification, the scope of the present invention is defined by the appended.

Claims (5)

1. a kind of catalysis oxidation heat recovery apparatus of temperature self adjusting, including main air blower(2), heat recovering heat exchanger(4), heating Device (6), Catalytic oxidation furnace(8)With air quantity adjusting air valve(13), it is characterised in that:The main air blower(2)One end is gas feed (1), the other end passes through first pipe(3)It is connected to heat recovering heat exchanger(4), the heat recovering heat exchanger(4)Pass through second pipe (5)It is connected to heater(6), the heater(6)Pass through third pipeline(7)It is connected to Catalytic oxidation furnace(8), the Catalytic oxidation furnace (8)Pass through the 4th pipeline(9)It is connected to heat recovering heat exchanger(4), the heat recovering heat exchanger(4)Pass through the 5th pipeline(10)Connection Chimney(11), the first pipe(3)With third pipeline(7)Pass through the 6th pipeline(12)Connection.
2. a kind of catalysis oxidation heat recovery apparatus of temperature self-regulating nodal pattern according to claim 1, it is characterised in that:It is described Catalytic oxidation furnace(8)In be filled with catalyst.
3. a kind of catalysis oxidation heat recovery apparatus of temperature self-regulating nodal pattern according to claim 1, it is characterised in that:It is described 6th pipeline(12)Upper installation air quantity adjusting air valve(13).
4. a kind of catalysis oxidation heat recovery apparatus of temperature self-regulating nodal pattern according to claim 1, it is characterised in that:It is described Third pipeline(7)Close to Catalytic oxidation furnace(8)Inlet is equipped with the first temperature sensor(14), the Catalytic oxidation furnace(8) Second temperature sensor is inside installed(15).
5. a kind of catalysis oxidation heat recovery apparatus of temperature self-regulating nodal pattern according to claim 1, it is characterised in that:It is described Heater(6)Using one of electric heater, neat gas burner, near gas burner.
CN201811042403.7A 2018-09-07 2018-09-07 A kind of catalysis oxidation heat recovery apparatus of temperature self-regulating nodal pattern Pending CN108905617A (en)

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CN201811042403.7A CN108905617A (en) 2018-09-07 2018-09-07 A kind of catalysis oxidation heat recovery apparatus of temperature self-regulating nodal pattern

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109668157A (en) * 2018-12-27 2019-04-23 北京中电联环保股份有限公司 Waste gas catalytic incineration processing system and its adjustment control method

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101716462A (en) * 2010-01-26 2010-06-02 浙江卫星丙烯酸制造有限公司 Catalysis and oxidation method of high-concentration waste gas
CN105854588A (en) * 2016-03-31 2016-08-17 湖南安淳高新技术有限公司 A sulfur recovering isothermal reactor and a process thereof
CN106765217A (en) * 2015-11-19 2017-05-31 中国石油化工股份有限公司 A kind of organic waste gas furnace and incinerating method
CN207025073U (en) * 2016-12-08 2018-02-23 中国石油化工股份有限公司 One kind saves strong ecad catalysis oxidation emission-control equipment
KR101837060B1 (en) * 2017-09-15 2018-03-12 (주)대양이엔아이 Indoor concentration and combustion device
CN208893973U (en) * 2018-09-07 2019-05-24 云汇环保科技南通有限公司 A kind of catalysis oxidation heat recovery apparatus of temperature self-regulating nodal pattern

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101716462A (en) * 2010-01-26 2010-06-02 浙江卫星丙烯酸制造有限公司 Catalysis and oxidation method of high-concentration waste gas
CN106765217A (en) * 2015-11-19 2017-05-31 中国石油化工股份有限公司 A kind of organic waste gas furnace and incinerating method
CN105854588A (en) * 2016-03-31 2016-08-17 湖南安淳高新技术有限公司 A sulfur recovering isothermal reactor and a process thereof
CN207025073U (en) * 2016-12-08 2018-02-23 中国石油化工股份有限公司 One kind saves strong ecad catalysis oxidation emission-control equipment
KR101837060B1 (en) * 2017-09-15 2018-03-12 (주)대양이엔아이 Indoor concentration and combustion device
CN208893973U (en) * 2018-09-07 2019-05-24 云汇环保科技南通有限公司 A kind of catalysis oxidation heat recovery apparatus of temperature self-regulating nodal pattern

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109668157A (en) * 2018-12-27 2019-04-23 北京中电联环保股份有限公司 Waste gas catalytic incineration processing system and its adjustment control method

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