CN210153831U - Organic waste gas catalytic combustion integrated device - Google Patents

Organic waste gas catalytic combustion integrated device Download PDF

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Publication number
CN210153831U
CN210153831U CN201920476394.6U CN201920476394U CN210153831U CN 210153831 U CN210153831 U CN 210153831U CN 201920476394 U CN201920476394 U CN 201920476394U CN 210153831 U CN210153831 U CN 210153831U
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waste gas
organic waste
catalytic combustion
catalytic
gas
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李伯东
王涛
薛岩
郭强
郝刘仓
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PURIFICATION EQUIPMENT RESEARCH INSTITUTE OF CSIC
718th Research Institute of CSIC
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PURIFICATION EQUIPMENT RESEARCH INSTITUTE OF CSIC
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Abstract

The utility model belongs to the environmental protection field, and relates to an organic waste gas catalytic combustion integrated device, which comprises an organic waste gas pretreatment system, a heat exchanger, a heating chamber, a catalytic combustor, an air volume adjusting device and a control system arranged on a main body, wherein the organic waste gas pretreatment system, the heat exchanger, the heating chamber, the catalytic combustor and the air volume adjusting device are sequentially arranged in the main body; after being filtered by a waste gas pretreatment system, the organic waste gas enters a heat exchanger and is subjected to indirect energy exchange with high-temperature gas after catalytic reaction, and the temperature of the waste gas is increased for the first time; organic waste gas with certain temperature enters a heating chamber, and the temperature of the organic waste gas is increased to the optimal temperature of catalytic reaction; the temperature meets the temperature requirement of catalytic reaction, and the organic waste gas is completely decomposed and releases a large amount of heat when entering a catalytic combustor; the purified gas converts heat energy to the pretreated organic waste gas through a heat exchanger, and the organic waste gas is emptied after being cooled. The device has the characteristics of strong universality and low energy consumption.

Description

Organic waste gas catalytic combustion integrated device
Technical Field
The utility model relates to a waste gas catalytic combustion administers technique belongs to the environmental protection field. In particular to an organic waste gas catalytic combustion integrated device.
Background
With the increasing development of modern industry, the pollution of organic waste gas to the environment becomes more serious, especially in the industries of coating, dyeing, painting, printing, automobiles, household appliances, chemical engineering and the like, a large amount of organic waste gas is generated in the production process, and nitrogen-containing organic matters (containing ammonia gas) are one of main components. However, the existing catalytic combustion device usually adopts a noble metal catalyst, the catalyst can well decompose organic matters into water and carbon dioxide, but when organic waste gas contains nitrogen-containing organic matters, a large amount of nitrogen oxides can be generated, the emission of the nitrogen oxides exceeds the standard, and a denitration device is required to be additionally arranged to remove the nitrogen oxides, so that the emission reaching the standard can be realized. Therefore, the conventional catalytic combustion device is only suitable for treating organic matters only containing carbon and hydrogen elements, and can not treat nitrogen-containing organic matters, so that the application of the conventional catalytic combustion device is limited. At present, nitrogen-containing waste gas is treated by adopting an adsorption or incineration mode, for example, Chinese patent application CN2017201283647 discloses a nitrogen-containing waste gas treatment device, which is provided with an oxidizer, a first absorption tower and a second absorption tower in sequence. The oxidizer oxidizes NO in the exhaust gas to NO2And the absorption liquid in the absorption tower is NaOH solution. In this way, the emission of nitrogen oxides at the outlet is reduced. Chinese patent application CN2018101019342 discloses an N, N-Dimethylformamide (DMF) exhaust gas treatment system, which is implemented by washing twice to reduce the concentration of DMF in the exhaust gas to a trace amount, and then passing through a regenerative oxidation furnace. It can be seen that the nitrogen-containing organic waste gas is currently treatedThe treatment is mostly an absorption method. Chinese patent application CN2018103133836 reports a novel heat accumulating type incineration treatment device for nitrogen-containing organic waste gas. The waste gas is decomposed by the incinerator, and the oxygen content of the flue gas in the combustion chamber is controlled by controlling the fan so as to meet the requirement of low nitrogen oxide conversion rate. The device has high energy consumption and no effect. The processing apparatus of above patent implements comparatively complicatedly, and the energy consumption is high, and can not guarantee the discharge to reach standard of export pollutant. The catalytic combustion catalyst for the nitrogen-containing organic matters is a catalyst for treating the nitrogen-containing organic matters in the organic waste gas by adopting a catalytic combustion principle, and a device for treating the organic waste gas by using the catalytic combustion catalyst for the nitrogen-containing organic matters is not reported in the prior art.
SUMMERY OF THE UTILITY MODEL
In view of this, the utility model aims at providing an organic waste gas catalytic combustion integrated device, the device adopts the catalytic combustion principle, can be used to handle conventional organic matter and/or nitrogenous organic pollutant, improves catalytic combustion device's commonality.
In order to achieve the above purpose, the technical scheme of the utility model is as follows:
an organic waste gas catalytic combustion integrated device comprises a filtering device, a heat exchanger, a heating chamber and a catalytic combustor which are sequentially arranged in a main body;
wherein, both sides of the main body are provided with an organic waste gas inlet and a purified gas outlet; the organic waste gas inlet is positioned at the side of the filtering device, and the purified gas outlet is positioned at the side of the catalytic combustor;
the filtering device is used for filtering dust and particulate matters in the organic waste gas entering from the organic waste gas inlet;
the heat exchanger is used for transferring the heat of the purified organic waste gas to the organic waste gas pretreated by the filtering device;
the heating chamber is used for heating the organic waste gas preheated by the heat exchanger to a set catalytic activation temperature;
the catalytic burner is used for catalytically burning the organic waste gas heated by the heating chamber to complete the purification of the organic waste gas, and the purified organic waste gas is discharged from the outlet of the catalytic burner; the catalytic combustor comprises an integral catalytic combustion catalyst and a catalyst support layer for supporting the integral catalytic combustion catalyst; the integral catalytic combustion catalyst comprises a nitrogen-containing organic matter catalytic combustion catalyst and/or a VOCs catalytic combustion catalyst;
the purified organic waste gas is divided into two branches, one branch enters a heat exchanger through a gas channel A arranged on the upper side in the main body for heat exchange and then is discharged from a purified gas outlet through a gas channel B arranged on the lower side in the main body; the other path is directly discharged through a purified gas outlet.
Furthermore, the integral catalytic combustion catalyst comprises a nitrogen-containing organic matter catalytic combustion catalyst and a VOCs catalytic combustion catalyst which are sequentially arranged from the inlet to the outlet of the catalytic combustor.
The flow regulating device is arranged at the outlet of the catalytic combustor and used for regulating the trend of the purified organic waste gas flow and the distribution of the gas flow in the two branches; when the temperature rise of the gas at the outlet of the catalytic burner relative to the gas in the heating chamber is greater than a set value, the flow rate on the branch directly discharged from the purified gas outlet is increased.
Further, the filter device comprises a frame and a filter sheet supported on the frame.
Furthermore, the heat exchanger comprises a heat exchanger organic waste gas inlet and a heat exchange channel, the heat exchanger organic waste gas inlet is arranged at one end of the heat exchanger opposite to the waste gas pretreatment system, the purified organic waste gas enters from the upper part of the heat exchange channel, the pretreated organic waste gas enters from the heat exchanger organic waste gas inlet, and the purified organic waste gas transfers heat to the pretreated organic waste gas and then is discharged from the lower part of the heat exchange channel.
Furthermore, the active component in the nitrogen-containing organic catalytic combustion catalyst takes a molecular sieve as a framework, and comprises metal ion active species embedded in the molecular sieve framework and metal oxide active species on the surface of the molecular sieve.
Furthermore, the active component in the VOCs catalytic combustion catalyst is noble metal Pt and/or Pd.
Furthermore, heat insulation cotton is arranged in the gas channel A and the gas channel B.
Furthermore, flow regulator is including setting up the valve on by the direct discharge branch road of purified gas outlet, and the catalytic combustor exit is equipped with temperature-sensing probe, and temperature-sensing probe transmits the temperature signal of catalytic combustor exit for the control system who sets up in the main part, and control system controls the switching and the aperture size of valve according to the temperature rise condition control valve of catalytic combustor exit gas for the heating chamber.
Furthermore, a temperature control induction probe is arranged in the heating chamber, the control system controls the heating power of the heater according to a set temperature value, and the temperature in the heating chamber is ensured to be consistent with a set value according to a temperature signal fed back by the temperature control induction probe.
The organic waste gas purification process of the nitrogen-containing organic waste gas catalytic combustion integrated device comprises the following steps that organic waste gas is filtered by a waste gas pretreatment system, enters a heat exchanger, and indirectly exchanges energy with high-temperature gas after catalytic reaction, and the temperature of the waste gas is increased for the first time; organic waste gas with certain temperature enters a heating chamber, and the temperature of the organic waste gas is increased to the optimal temperature of catalytic reaction; the temperature meets the temperature requirement of catalytic reaction, and the organic waste gas is completely decomposed and releases a large amount of heat when entering a catalytic combustor; the purified gas converts heat energy to the pretreated organic waste gas through a heat exchanger, and the organic waste gas is emptied after being cooled.
Advantageous effects
The device not only can independently treat the nitrogenous organic matter or the conventional organic waste gas, but also can simultaneously treat the alkaline nitrogenous organic matter and the conventional organic matter, and when the pollutant reaches a certain concentration, the heater does not need to work, thereby realizing self-sustaining, and having the characteristics of strong universality, low energy consumption and the like.
Drawings
Fig. 1 is a schematic structural diagram of the device of the present invention.
The system comprises a main body 1, a filtering device 2, a heat exchanger 3, a heat exchanger 4, a heat exchanger organic waste gas inlet, a heat exchange channel 5, a heating chamber 6, a heater 7, a temperature control induction probe 8, a catalytic combustor 9, a nitrogen-containing organic matter catalytic combustion catalyst 10, a catalyst supporting layer 11, a conventional VOCs catalytic combustion catalyst 12, a catalytic combustor outlet 13, a purified gas outlet 14, heat insulation cotton 15, a flow regulating device 16 and a control system 17.
Detailed Description
The present invention will be described in further detail with reference to specific examples.
As shown in fig. 1, the device for the catalytic combustion of organic waste gas comprises an organic waste gas pretreatment filtering device 2, a heat exchanger 3, a heating chamber 6, a catalytic combustor 9, a flow regulating device 16 and a control system 17 arranged on a main body 1, which are arranged in sequence in the main body 1.
Wherein, the two sides of the main body 1 are provided with an organic waste gas inlet and a purified gas outlet 14; the organic waste gas inlet is positioned at the side of the organic waste gas pretreatment system 2, and the purified gas outlet 14 is positioned at the side of the catalytic combustor 9.
The filtering device 2 is positioned at the foremost end inside the main body 1 and used for filtering and treating dust and particles in waste gas, so that the organic waste gas is pretreated, and the catalytic combustor 9 is prevented from being blocked. The exhaust gas pretreatment filtering device 2 is composed of a frame and a filter disc supported on the frame, and parameters such as the number of filtering stages and the filtering precision of the filter disc are set according to the required treatment effect.
The heat exchanger 3 is used for recovering heat of the catalytic combustor and reducing energy consumption of the device. Can be a shell and tube, a fin or a ceramic heat exchanger. And a heat exchanger organic waste gas inlet 4 is arranged at one end of the heat exchanger 3 opposite to the waste gas pretreatment filtering device 2.
The heating chamber 6 is composed of a heater 7 and a temperature sensing probe 8 and is used for heating the organic waste gas to reach the use temperature required by the catalytic combustor 9. Can be an electric heater, an electric heating rod or a gas heater. The control system controls the heating power of the heater 7 according to the set temperature and ensures that the temperature in the heating chamber 6 is consistent with the set value according to the temperature signal fed back by the temperature sensing probe 8.
The flow regulating device 16 comprises a valve for regulating the gas flow direction of the purified organic waste gas and the distribution of the gas flow of each component. The control system 17 controls the opening and closing of the valve and the opening degree of the valve through an actuator according to the temperature rise of the gas at the outlet 13 of the catalytic burner and the gas in the heating chamber 6. When the temperature rise of the gas at the outlet 13 of the catalytic burner and the gas in the heating chamber 6 is larger than a set value, the valve is opened and the opening degree is adjusted to directly discharge a part of purified gas through the purified gas outlet 14; when the temperature rise is less than or equal to the set value, the valve is closed, so that the purified gas passes through the gas channel A, the heat exchange channel 5 and the gas channel B in sequence and is discharged from the purified gas outlet 14.
The catalytic burner 9 is used for catalytically burning the organic waste gas heated by the heating chamber 6, the purified organic waste gas is discharged from an outlet 13 of the catalytic burner, and the outlet 13 of the catalytic burner is arranged on one side, close to a purified gas outlet 14, of the catalytic burner 9; a temperature sensing probe is arranged at the outlet 13 of the catalytic combustor. The catalytic combustor 9 includes an integrated catalytic combustion catalyst and a catalyst support layer 11 for supporting the integrated catalytic combustion catalyst; the integral catalytic combustion catalyst comprises a nitrogen-containing organic matter catalytic combustion catalyst 10 and/or a conventional VOCs catalytic combustion catalyst 12, nitrogen-containing organic matter in organic waste gas is treated by a nitrogen-containing organic matter selective catalytic combustion catalyst 16 and can be converted into nitrogen, water and carbon dioxide, secondary pollution is avoided, conventional organic matter in organic waste gas is treated by the conventional VOCs catalytic combustion catalyst 12 and can be converted into water and carbon dioxide, and the waste gas is discharged up to the standard.
When one of the two catalysts is filled, the nitrogen-containing organic pollutants or the conventional organic pollutants can be treated independently, if the nitrogen-containing organic pollutants and the conventional organic pollutants need to be treated simultaneously, the two catalysts are filled simultaneously, the filling sequence firstly passes through the nitrogen-containing organic catalytic combustion catalyst and then passes through the organic catalytic combustion catalyst according to the air flow, and the filling amount of the two catalysts is determined by the actual working conditions (parameters such as pollutant concentration, waste gas amount and the like).
The catalytic combustion catalyst 10 containing nitrogen-containing organic matter contains two active species, namely metal ion active species embedded in a molecular sieve framework respectively, so as toAnd metal oxide active species on the surface of the catalyst. The active metal oxide species can reduce the active temperature of the nitrogen-containing organic waste gas decomposed by the metal oxide species, and meanwhile, the active metal ion species can ensure that the trace of nitrogen oxide in the outlet gas reaches the standard and is discharged. Can convert the nitrogenous organic matters into nitrogen, water and carbon dioxide with high selectivity without causing secondary pollution. The using conditions of the catalyst are as follows: space velocity less than 50000h-1The using temperature is 150-500 ℃, the concentration of the pollutants is less than one fourth of the explosion limit, and under the conditions, the conversion efficiency of the pollutants is more than 98 percent.
The conventional VOCs catalytic combustion catalyst 12 adopts noble metals Pt and Pd as active centers, and performs chemical activation, so that the conversion temperature of organic pollutants is greatly reduced, and the conventional organic pollutants can be converted into carbon dioxide and water at a lower temperature. The using conditions of the catalyst are as follows: space velocity less than 50000h-1The using temperature is 150-700 ℃, the concentration of the pollutants is less than one fourth of the explosion limit, and under the conditions, the conversion efficiency of the pollutants is more than 98 percent.
When the device works, organic waste gas is pretreated by the organic waste gas pretreatment system 2 and then enters the heat exchanger 3 through the heat exchanger organic waste gas inlet 4, the organic waste gas exchanges heat with purified gas in the heat exchange channel 5 to primarily raise the temperature of the waste gas, then the waste gas enters the heating chamber 6, the waste gas is heated to a required temperature through the heater 7, the temperature is fed back to the control system 17 through the temperature sensing probe 8, and the control system 17 adjusts the heating power of the heater 7 to ensure that the energy utilization rate of the whole system is optimal; heating the waste gas to a required temperature, then feeding the waste gas into a catalytic combustor 9, firstly enabling the waste gas to pass through a nitrogen-containing organic matter catalytic combustion catalyst 10 to convert the nitrogen-containing organic matter into nitrogen and water, and then enabling the nitrogen-containing organic matter to pass through a conventional VOCs catalytic combustion catalyst 12 to completely remove the residual organic matter; the waste gas that has been handled through catalytic combustor 9, according to the temperature rise (the temperature difference of catalytic combustor export 13 and temperature sensing probe 8) condition of waste gas at catalytic combustor export 13, the flow of the waste gas after the distribution purification at heat transfer passageway 5 and purge gas export 14 by flow control device 16 (if the temperature rise is greater than certain limit value can make the organic waste gas temperature that gets into catalytic combustor 9 too high, consequently need to change the aperture of flow control device 16, make some hot gas discharge from purge gas export 14), make catalytic combustor import temperature maintain at normal level, prevent that catalytic combustor import temperature is too high. The control system 17 judges the temperature difference through temperature signals transmitted by the temperature sensing probe 8 in the heating chamber and the temperature sensing probe at the outlet 13 of the catalytic combustor, and controls the valve opening of the flow regulating device 16 through an actuator, so as to achieve the purpose of controlling the temperature. Be equipped with heat preservation cotton 15 in main part inside gas passage A and the gas passage B, keep warm to the organic waste gas after the purification, reduce calorific loss, play energy saving and consumption reduction's effect.
In summary, the present invention includes but is not limited to the above embodiments, and any equivalent substitutions or partial modifications made under the spirit and principle of the present invention are considered to be within the protection scope of the present invention.

Claims (10)

1. The utility model provides an organic waste gas catalytic combustion integrated device which characterized in that: the device comprises a filtering device (2), a heat exchanger (3), a heating chamber (6) and a catalytic combustor (9) which are arranged in a main body (1) in sequence;
wherein, both sides of the main body (1) are provided with an organic waste gas inlet and a purified gas outlet (14); the organic waste gas inlet is positioned at the side of the filtering device (2), and the purified gas outlet (14) is positioned at the side of the catalytic combustor (9);
the filtering device (2) is used for filtering dust and particulate matters in the organic waste gas entering from the organic waste gas inlet;
the heat exchanger (3) is used for transferring the heat of the purified organic waste gas to the organic waste gas pretreated by the filtering device (2);
the heating chamber (6) is used for heating the organic waste gas preheated by the heat exchanger (3) to a set catalytic activation temperature;
the catalytic combustor (9) is used for catalytically combusting the organic waste gas heated by the heating chamber (6) to complete the purification of the organic waste gas, and the purified organic waste gas is discharged from an outlet (13) of the catalytic combustor; the catalytic burner (9) comprises a monolithic catalytic combustion catalyst and a catalyst support layer (11) for supporting the monolithic catalytic combustion catalyst; the integral catalytic combustion catalyst comprises a nitrogen-containing organic matter catalytic combustion catalyst (10) and/or a VOCs catalytic combustion catalyst (12);
the purified organic waste gas is divided into two branches, one branch enters the heat exchanger (3) through a gas channel A arranged on the upper side in the main body (1) for heat exchange and then is discharged from a purified gas outlet (14) through a gas channel B arranged on the lower side in the main body (1); the other path is directly discharged through a purified gas outlet (14).
2. An integrated catalytic combustion device for organic exhaust gases, as claimed in claim 1, wherein: the integral catalytic combustion catalyst comprises a nitrogen-containing organic matter catalytic combustion catalyst (10) and a VOCs catalytic combustion catalyst (12) which are sequentially arranged from the inlet to the outlet of the catalytic combustor (9).
3. An integrated catalytic combustion device for organic exhaust gases as claimed in claim 1 or 2, wherein: the device also comprises a flow regulating device (16) arranged at the outlet (13) of the catalytic combustor, wherein the flow regulating device (16) regulates the trend of the purified organic waste gas flow and the distribution of the gas flow in the two branches; when the temperature rise of the gas at the outlet (13) of the catalytic burner relative to the gas in the heating chamber (6) is greater than a set value, the flow rate on the branch directly discharged from the purified gas outlet (14) is increased.
4. An integrated catalytic combustion device for organic exhaust gases as claimed in claim 1 or 2, wherein: the filter device (2) comprises a frame and a filter sheet supported on the frame.
5. An integrated catalytic combustion device for organic exhaust gases as claimed in claim 1 or 2, wherein: the heat exchanger (3) comprises a heat exchanger organic waste gas inlet (4) and a heat exchange channel (5), the heat exchanger organic waste gas inlet (4) is formed in one end, opposite to the filtering device (2), of the heat exchanger (3), purified organic waste gas enters from the top of the heat exchange channel (5), pretreated organic waste gas enters from the heat exchanger organic waste gas inlet (4), and the purified organic waste gas transfers heat to the pretreated organic waste gas and then is discharged from the lower portion of the heat exchange channel (5).
6. An integrated catalytic combustion device for organic exhaust gases as claimed in claim 1 or 2, wherein: the active component in the nitrogen-containing organic matter catalytic combustion catalyst (10) takes a molecular sieve as a framework, and comprises metal ion active species embedded into the molecular sieve framework and metal oxide active species on the surface of the molecular sieve.
7. An integrated catalytic combustion device for organic exhaust gases as claimed in claim 1 or 2, wherein: the active component in the VOCs catalytic combustion catalyst (12) is noble metal Pt and/or Pd.
8. An integrated catalytic combustion device for organic exhaust gases as claimed in claim 1 or 2, wherein: and heat insulation cotton (15) is arranged in the gas channel A and the gas channel B.
9. An integrated catalytic combustion device for organic exhaust gases, as claimed in claim 3, wherein: the flow regulating device (16) comprises a valve arranged on a branch which is directly discharged from a purified gas outlet (14), a temperature sensing probe is arranged at the outlet (13) of the catalytic combustor, the temperature sensing probe transmits a temperature signal of the outlet (13) of the catalytic combustor to a control system (17) arranged on the main body (1), and the control system (17) controls the opening and closing of the valve and the opening degree of the valve according to the temperature rise condition of gas at the outlet (13) of the catalytic combustor relative to gas in the heating chamber (6).
10. An integrated catalytic combustion device for organic exhaust gases, as claimed in claim 3, wherein: a temperature control induction probe (8) is arranged in the heating chamber (6), the control system (17) controls the heating power of the heater (7) according to a set temperature value, and the temperature in the heating chamber (6) is ensured to be consistent with a set value according to a temperature signal fed back by the temperature control induction probe (8).
CN201920476394.6U 2019-04-10 2019-04-10 Organic waste gas catalytic combustion integrated device Active CN210153831U (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110030567A (en) * 2019-04-10 2019-07-19 中国船舶重工集团公司第七一八研究所 A kind of organic waste gas catalytic combustion integrated apparatus

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110030567A (en) * 2019-04-10 2019-07-19 中国船舶重工集团公司第七一八研究所 A kind of organic waste gas catalytic combustion integrated apparatus
CN110030567B (en) * 2019-04-10 2023-11-07 中国船舶重工集团公司第七一八研究所 Organic waste gas catalytic combustion integrated device

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