CN108904381A - A kind of paper handkerchief and its manufacturing method with moisture-keeping functions - Google Patents
A kind of paper handkerchief and its manufacturing method with moisture-keeping functions Download PDFInfo
- Publication number
- CN108904381A CN108904381A CN201810897387.3A CN201810897387A CN108904381A CN 108904381 A CN108904381 A CN 108904381A CN 201810897387 A CN201810897387 A CN 201810897387A CN 108904381 A CN108904381 A CN 108904381A
- Authority
- CN
- China
- Prior art keywords
- mass parts
- deionized water
- nano
- paper handkerchief
- component
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
- A61K8/97—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
- A61K8/9783—Angiosperms [Magnoliophyta]
- A61K8/9789—Magnoliopsida [dicotyledons]
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/0208—Tissues; Wipes; Patches
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/25—Silicon; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/27—Zinc; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/29—Titanium; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/345—Alcohols containing more than one hydroxy group
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/731—Cellulose; Quaternized cellulose derivatives
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/41—Particular ingredients further characterized by their size
- A61K2800/413—Nanosized, i.e. having sizes below 100 nm
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/59—Mixtures
- A61K2800/592—Mixtures of compounds complementing their respective functions
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/59—Mixtures
- A61K2800/592—Mixtures of compounds complementing their respective functions
- A61K2800/5922—At least two compounds being classified in the same subclass of A61K8/18
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/80—Process related aspects concerning the preparation of the cosmetic composition or the storage or application thereof
- A61K2800/82—Preparation or application process involves sonication or ultrasonication
Abstract
The present invention relates to paper handkerchief manufacturing fields, provide a kind of paper handkerchief and its manufacturing method with moisture-keeping functions, and red swelling of the skin caused by paper handkerchief is used for multiple times in the short time for solving the problems, such as.A kind of paper handkerchief and its manufacturing method with moisture-keeping functions provided by the invention, including paper pulp and medical fluid, the medical fluid include 10 ~ 15 mass parts of glycerol, 2 ~ 6 mass parts of propylene glycol, 15 ~ 20 mass parts of grape extract, 20 ~ 30 mass parts of polyethylene glycol, 40 ~ 60 mass parts of deionized water.The compounding such as the same glycerol of grape extract, propylene glycol, can produce good moistening effect, further compound with paper pulp, and the skin-moisturizing, skin effect that paper handkerchief is improved after paper handkerchief is made.
Description
Technical field
The present invention relates to paper handkerchief manufacturing fields, and in particular to a kind of paper handkerchief and its manufacturing method with moisture-keeping functions.
Background technique
With the improvement of people's life quality, paper for daily use not only relatively broad by people application, but also its function
Also it is extended.The existing tissue paper of the so-called high type of skin soft-touch containing medical fluids such as softening agents, due to i.e.
Make frequently to wipe nose also not tending to have skin irritation sense or be not easy to keep nose red and swollen, receives pursuing for user.
But prevent the effect of skin irritation sense or red swelling of the skin insufficient containing the sanitary paper of medical fluid in the past, it is short
Being used for multiple times in time causes skin excessively dry, it is possible to further stimulate skin, cause skin redness, itch etc. occur and ask
Topic.
Summary of the invention
Present invention solves the technical problem that the problem of for red swelling of the skin caused by paper handkerchief is used for multiple times in the short time, provide one
Kind has the paper handkerchief and its manufacturing method of moisture-keeping functions.
In order to solve the above technical problem, the present invention provides technical solution be：
A kind of paper handkerchief and its manufacturing method with moisture-keeping functions, including paper pulp and medical fluid, the medical fluid include 1 ~ 5 matter of glycerol
Measure part, 2 ~ 6 mass parts of propylene glycol, 15 ~ 20 mass parts of grape extract, 2 ~ 3 mass parts of polyethylene glycol, 40 ~ 60 matter of deionized water
Measure part.
The compounding such as the same glycerol of grape extract, propylene glycol, can produce good moistening effect, further multiple with paper pulp
Match, the effect for improving the skin-moisturizing, skin of paper handkerchief after paper handkerchief is made.
Paper handkerchief containing grape extract can effectively keep the wet of skin, avoid repeatedly being wiped because of skin by paper handkerchief
The skin problems such as caused redness.
Preferably, the medical fluid includes 2 ~ 5 mass parts of glycerol, 4 ~ 6 mass parts of propylene glycol, 16 ~ 20 matter of grape extract
Measure part, 2.5 ~ 3 mass parts of polyethylene glycol, 50 ~ 60 mass parts of deionized water.
Preferably, the medical fluid includes 2 mass parts of glycerol, 4 mass parts of propylene glycol, 16 mass parts of grape extract, is gathered
2.5 mass parts of ethylene glycol, 50 mass parts of deionized water.
Preferably, the grape extract includes grape pip component and modified component.Grape comprising modified component mentions
Take object that can significantly improve the moistening effect of medical fluid.
Preferably, the grape extract is made by the following method：The grape pip component includes Semen Vitis Amurensis
10 ~ 15 mass parts, 30 ~ 45 mass parts of ethyl alcohol, 20 ~ 40 mass parts of deionized water crush after drying Semen Vitis Amurensis at 50 DEG C
To 30 mesh, ethyl alcohol and deionized water premixing is added, carries out ultrasound on extracting after mixing evenly, supersonic frequency 25,50,
Tri- frequency composite ultraphonic of 90kHz, 30 ~ 50min of ultrasonic extraction are extracted with ethyl acetate after obtained leaching liquor filtering, concentration to having
Machine layer is colourless, concentrated extract, and freeze-drying obtains grape pip component；The modification component includes 1 ~ 2 matter of nano zine oxide
Measure part, 1 ~ 3 mass parts of nano silica, 0.2 ~ 0.5 mass parts of nano-titanium dioxide, by above-mentioned nano-oxide be dissolved in from
In sub- water, 40 DEG C of ultrasonic water bath 3h obtain modified component after drying；By 1 ~ 5 mass parts of grape pip component with modified component 0.5 ~ 1
It is dissolved in the deionized water of 10 ~ 20 mass parts after mass parts mixing and both obtains grape extract.
The grape pip component that three frequency composite ultraphonics extract has aobvious with the grape extract obtained after modified component compounding
The moisture-keeping function of work, while modified component can promote grape pip component to be evenly dispersed on paper handkerchief.
Preferably, the grape extract is made by the following method：The grape pip component includes Semen Vitis Amurensis
12 ~ 15 mass parts, 30 ~ 45 mass parts of ethyl alcohol, 30 ~ 40 mass parts of deionized water crush after drying Semen Vitis Amurensis at 50 DEG C
To 30 mesh, ethyl alcohol and deionized water premixing is added, carries out ultrasound on extracting after mixing evenly, supersonic frequency 25,50,
Tri- frequency composite ultraphonic of 90kHz, 40 ~ 50min of ultrasonic extraction are extracted with ethyl acetate after obtained leaching liquor filtering, concentration to having
Machine layer is colourless, concentrated extract, and freeze-drying obtains grape pip component；The modification component includes nano zine oxide 1.5 ~ 2
Above-mentioned nano-oxide is dissolved in by mass parts, 2 ~ 3 mass parts of nano silica, 0.3 ~ 0.5 mass parts of nano-titanium dioxide
In ionized water, 40 DEG C of ultrasonic water bath 3h obtain modified component after drying；By 2 ~ 5 mass parts of grape pip component with modified component 0.6
It is dissolved in the deionized water of 18 ~ 20 mass parts after the mixing of ~ 1 mass parts and both obtains grape extract.
Preferably, the grape extract is made by the following method：The grape pip component includes Semen Vitis Amurensis
12 mass parts, 30 mass parts of ethyl alcohol, 30 mass parts of deionized water are crushed to 30 mesh after drying Semen Vitis Amurensis at 50 DEG C, add
Enter ethyl alcohol and deionized water premixing, carry out ultrasound on extracting after mixing evenly, supersonic frequency 25,50,90kHz tri- are answered frequently
Ultrasound is closed, concentration extraction colourless to organic layer is extracted with ethyl acetate in ultrasonic extraction 40min after obtained leaching liquor filtering, concentration
Liquid is taken, freeze-drying obtains grape pip component；The modification component includes 1.5 mass parts of nano zine oxide, nanometer titanium dioxide
2 mass parts of silicon, 0.3 mass parts of nano-titanium dioxide, above-mentioned nano-oxide is dissolved in deionized water, 40 DEG C of ultrasonic water baths
3h obtains modified component after drying；18 mass are dissolved in after 2 mass parts of grape pip component are mixed with modified 0.6 mass parts of component
Both grape extract is obtained in the deionized water of part.
Preferably, the nano-titanium dioxide is modified nano-titanium dioxide；The modified nano-titanium dioxide
Method of modifying is：Take the TiCl of 15 ~ 20 mass parts4It is dissolved in 80 ~ 120 mass parts deionized waters, is stirred under ice-water bath, is added
25% ammonium hydroxide of 12 ~ 16 mass parts, adds the hydroxymethyl cellulose of 12 ~ 20 mass parts, at 100 ~ 120 DEG C after being sufficiently stirred
Under the conditions of carry out hydro-thermal reaction, for product after deionized water is cleaned, 80 DEG C of drying obtain modified nano-silica after reaction
Titanium.
After the same nano zine oxide of modified nano-titanium dioxide, nano silica compounding, it can significantly improve grape
The moistening effect of extract, while modifying titanium dioxide can adsorb certain pollutant, remove the grease on skin, and then promote
Enter skin into grape extract, improves moistening effect.
Preferably, the method for modifying of the modified nano-titanium dioxide is：Take the TiCl of 18 mass parts4It is dissolved in 100 matter
It measures in part deionized water, is stirred under ice-water bath, 25% ammonium hydroxide of 14 mass parts is added, adds the methylol of 15 mass parts
Cellulose carries out hydro-thermal reaction under the conditions of 105 DEG C after being sufficiently stirred, and product is after deionized water is cleaned after reaction, and 80
DEG C drying obtains modified nano-titanium dioxide.
A kind of paper handkerchief manufacturing method with moisture-keeping functions, includes the following steps：（1）, glycerol, propylene glycol, grape mentioned
It takes object, polyethylene glycol to be added in deionized water, stirs evenly and medical fluid is made；（2）, slurrying, by 80 ~ 90 mass parts of paper pulp, medical fluid
After the mixing of 10 ~ 12 mass parts, free beating is carried out using fluffer and fiberizer series connection, desanding screening the pulp after slurry is made, removes
Biggish undissolved solid or fiber in slurry；（3）, whitewashing, paper web will be formed on slurry spray mo(u)lding screen cloth；（4）,
After being dehydrated, being dried to paper web, removing, cutting obtain the paper handkerchief with moisture-keeping functions.
Medical fluid is mixed into paper pulp, the component with moisture-keeping functions can be made to be evenly dispersed in paper pulp, by paper pulp
Spray mo(u)lding, obtained web properties variation less, remain the effect of medical fluid to greatest extent.
Compared with prior art, the device have the advantages that being：The compounding such as the same glycerol of grape extract, propylene glycol,
It can produce good moistening effect, further compounded with paper pulp, the skin-moisturizing, skin effect for improving paper handkerchief after paper handkerchief is made；
The grape pip component that three frequency composite ultraphonics extract has significant moisturizing with the grape extract obtained after modified component compounding
Effect, while modified component can promote grape pip component to be evenly dispersed on paper handkerchief.
Specific embodiment
Following implementation column is to further explanation of the invention, is not limitation of the present invention.
Embodiment 1
A kind of paper handkerchief and its manufacturing method with moisture-keeping functions, including paper pulp and medical fluid, the medical fluid include 12 matter of glycerol
Measure part, 4 mass parts of propylene glycol, 16 mass parts of grape extract, 25 mass parts of polyethylene glycol, 50 mass parts of deionized water.It is described
Grape extract include grape pip component and modified component.The grape extract is made by the following method：Described
Grape pip component includes 12 mass parts of Semen Vitis Amurensis, 30 mass parts of ethyl alcohol, 30 mass parts of deionized water, by Semen Vitis Amurensis at 50 DEG C
It is crushed to 30 mesh after lower drying, ethyl alcohol and deionized water premixing is added, carries out ultrasound on extracting, supersonic frequency after mixing evenly
Rate is 25,50, tri- frequency composite ultraphonic of 90kHz, and ultrasonic extraction 40min is extracted after obtained leaching liquor filtering, concentration with ethyl acetate
, concentrated extract colourless to organic layer is taken, freeze-drying obtains grape pip component；The modification component includes nano zine oxide
1.5 mass parts, 2 mass parts of nano silica, 0.3 mass parts of nano-titanium dioxide, by above-mentioned nano-oxide be dissolved in from
In sub- water, 40 DEG C of ultrasonic water bath 3h obtain modified component after drying；By 2 mass parts of grape pip component with modified 0.6 mass of component
It is dissolved in the deionized water of 18 mass parts after part mixing and both obtains grape extract.The modification side of the modified nano-titanium dioxide
Method is：Take the TiCl of 18 mass parts4It is dissolved in 100 mass parts deionized waters, is stirred under ice-water bath, 14 mass parts are added
25% ammonium hydroxide adds the hydroxymethyl cellulose of 15 mass parts, carries out hydro-thermal reaction under the conditions of 105 DEG C after being sufficiently stirred, instead
For product after deionized water is cleaned, 80 DEG C of drying obtain modified nano-titanium dioxide after answering.
The compounding such as the same glycerol of grape extract, propylene glycol, can produce good moistening effect, further multiple with paper pulp
Match, after paper handkerchief is made, paper handkerchief is also provided with the effect of skin-moisturizing, skin.
Paper handkerchief containing grape extract can effectively keep the wet of skin, avoid repeatedly being wiped because of skin by paper handkerchief
The skin problems such as caused redness.Grape extract comprising modified component can significantly improve the moistening effect of medical fluid.Packet
Grape extract containing modified component can significantly improve the moistening effect of medical fluid.The grape pip that three frequency composite ultraphonics extract
Component has significant moisture-keeping function with the grape extract obtained after modified component compounding, while modified component can promote Portugal
Grape seed component is evenly dispersed on paper handkerchief.The same nano zine oxide of modified nano-titanium dioxide, nano silica compounding
Afterwards, the moistening effect of grape extract can significantly be improved, while modifying titanium dioxide can adsorb certain pollutant, clearly
Except the grease on skin, and then grape extract is promoted to enter skin, improves moistening effect.
A kind of paper handkerchief manufacturing method with moisture-keeping functions, includes the following steps：（1）, glycerol, propylene glycol, grape mentioned
It takes object, polyethylene glycol to be added in deionized water, stirs evenly and medical fluid is made；（2）, slurrying, by 90 mass parts of paper pulp, 12 matter of medical fluid
After measuring part mixing, free beating is carried out using fluffer and fiberizer series connection, desanding screening the pulp after slurry is made, removes in slurry
Biggish undissolved solid or fiber；（3）, whitewashing, paper web will be formed on slurry spray mo(u)lding screen cloth；（4）, to paper web into
Row dehydration after being dried, removes winding and obtains wettable water paper handkerchief.
Medical fluid is mixed into paper pulp, the component with moisture-keeping functions can be made to be evenly dispersed in paper pulp, by paper pulp
Spray mo(u)lding, obtained web properties variation less, remain the effect of medical fluid to greatest extent.
Embodiment 2
Embodiment 2 with embodiment 1 the difference is that, including paper pulp and medical fluid, the medical fluid includes 1 mass parts of glycerol, third
2 mass parts of glycol, 15 mass parts of grape extract, 2 mass parts of polyethylene glycol, 40 ~ 60 mass parts of deionized water.
Embodiment 3
Embodiment 3 with embodiment 1 the difference is that, including paper pulp and medical fluid, the medical fluid includes 5 mass parts of glycerol, third
6 mass parts of glycol, 20 mass parts of grape extract, 3 mass parts of polyethylene glycol, 40 ~ 60 mass parts of deionized water.
Embodiment 4
Embodiment 4 with embodiment 1 the difference is that, the grape extract is made by the following method：The grape
Seed component includes 10 mass parts of Semen Vitis Amurensis, 30 mass parts of ethyl alcohol, and 20 mass parts of deionized water dry Semen Vitis Amurensis at 50 DEG C
It is crushed to 30 mesh after dry, ethyl alcohol and deionized water premixing is added, carries out ultrasound on extracting after mixing evenly, supersonic frequency is
25,50, tri- frequency composite ultraphonic of 90kHz, ultrasonic extraction 30min, obtain leaching liquor filtering, concentration after be extracted with ethyl acetate to
Organic layer is colourless, concentrated extract, and freeze-drying obtains grape pip component；The modification component includes 1 matter of nano zine oxide
Part, 1 mass parts of nano silica are measured, above-mentioned nano-oxide is dissolved in deionized water by 0.2 mass parts of nano-titanium dioxide
In, 40 DEG C of ultrasonic water bath 3h obtain modified component after drying；1 mass parts of grape pip component are mixed with modified 0.5 mass parts of component
It is dissolved in after conjunction in the deionized water of 10 mass parts and both obtains grape extract.
Embodiment 5
Embodiment 5 with embodiment 1 the difference is that, the grape extract is made by the following method：The grape
Seed component includes 15 mass parts of Semen Vitis Amurensis, 45 mass parts of ethyl alcohol, and 40 mass parts of deionized water dry Semen Vitis Amurensis at 50 DEG C
It is crushed to 30 mesh after dry, ethyl alcohol and deionized water premixing is added, carries out ultrasound on extracting after mixing evenly, supersonic frequency is
25,50, tri- frequency composite ultraphonic of 90kHz, ultrasonic extraction 50min, obtain leaching liquor filtering, concentration after be extracted with ethyl acetate to
Organic layer is colourless, concentrated extract, and freeze-drying obtains grape pip component；The modification component includes 2 matter of nano zine oxide
Part, 3 mass parts of nano silica are measured, above-mentioned nano-oxide is dissolved in deionized water by 0.5 mass parts of nano-titanium dioxide
In, 40 DEG C of ultrasonic water bath 3h obtain modified component after drying；5 mass parts of grape pip component are mixed with modified 1 mass parts of component
It is dissolved in the deionized water of 20 mass parts afterwards and both obtains grape extract..
Embodiment 6
Embodiment 6 with embodiment 1 the difference is that, the nano-titanium dioxide be modified nano-titanium dioxide；Described
The method of modifying of modified nano-titanium dioxide is：Take the TiCl of 15 mass parts4It is dissolved in 80 mass parts deionized waters, in ice-water bath
Lower stirring is added 25% ammonium hydroxide of 12 mass parts, the hydroxymethyl cellulose of 12 mass parts is added, at 100 DEG C after being sufficiently stirred
Under the conditions of carry out hydro-thermal reaction, for product after deionized water is cleaned, 80 DEG C of drying obtain modified nano-silica after reaction
Titanium.
Embodiment 7
Embodiment 7 with embodiment 1 the difference is that, the nano-titanium dioxide be modified nano-titanium dioxide；Described
The method of modifying of modified nano-titanium dioxide is：Take the TiCl of 20 mass parts4It is dissolved in 120 mass parts deionized waters, in ice water
The lower stirring of bath, is added 25% ammonium hydroxide of 16 mass parts, the hydroxymethyl cellulose of 20 mass parts is added, 120 after being sufficiently stirred
Hydro-thermal reaction is carried out under the conditions of DEG C, for product after deionized water is cleaned, 80 DEG C of drying obtain modified nano-silica after reaction
Change titanium.
Embodiment 8
Embodiment 8 with embodiment 1 the difference is that, slurrying, by 80 mass parts of paper pulp, 10 mass parts of medical fluid mix after, use
Fluffer and fiberizer series connection carry out free beating, and desanding screening the pulp after slurry is made, and remove biggish undissolved in slurry
Solid or fiber
Comparative example 1
Comparative example 1 with embodiment 1 the difference is that, without modified component in the grape extract.
Comparative example 2
Comparative example 2 with embodiment 1 the difference is that, the main component of the paper handkerchief herb liquid is propylene glycol.
Experimental example
30 18 ~ 50 years old Healthy Peoples are randomly selected as volunteer, the paper handkerchief of embodiment 1 ~ 7 and comparative example 1 ~ 2 is provided, is pressed
Stipulated number wipes nose, and whether point 5 grades of evaluation noses are not easy to feel pain, and then record each volunteer of statistics uses body
It tests, is averaged, following table is experimental result.
As it can be seen from table 1 embodiment 1 ~ 7 all has the effect of certain skin-moisturizing, skin, compared with comparative example, to skin
Irritation is small, shows that the grape extract used in the examples containing modified component has better moisture-keeping functions, has aobvious
The skin-moisturizing, skin effect of work.
Embodiment 1 is that preferably embodiment, overall merit are higher with embodiment 3（The average of two evaluation indexes）,
But the dosage of various raw materials is larger in embodiment 3, higher cost, therefore embodiment 1 is more preferably embodiment, embodiment 2
Dosage it is less, moistening effect still has significant effect compared with comparative example, shows the grape extract comprising modified component
Effect in terms of protecting skin is more important；The grape extract that comparative example 1 uses is free of modified component, and user is anti-
Reflect poor, but user's evaluation is still greater than 3, and the grape pip component of the application also has comparable moisture-keeping functions；Medicine in comparative example 2
Liquid is propylene glycol, is more traditional moisturizing medicament, effective to be lower than embodiment 1 ~ 7 and comparative example 1.
The various dosages of grape extract are different in embodiment 4 and 5, and effect has apparent difference；Wherein embodiment 4
Moistening effect be weaker than embodiment 2, show that the content of various components in grape extract changes the moistening effect for paper handkerchief
It influences to be greater than influence of the grape extract dosage change to the moistening effect of paper handkerchief.
In embodiment 6 and 7, each content of material is different in modified component, and wherein the moistening effect of embodiment 6 is weaker than embodiment
4, the influence for showing that the content of various components in modified component changes for the moistening effect of paper handkerchief is greater than modified component dosage
Change the influence to the moistening effect of paper handkerchief.
It can be seen that from the rising scale of skin moisture content and further demonstrate that the content of various components in grape extract changes
Influence for the moistening effect of paper handkerchief is greater than influence of the grape extract dosage change to the moistening effect of paper handkerchief.
Above-listed detailed description is illustrating for possible embodiments of the present invention, and above embodiments are not to limit this
The scope of the patents of invention, all equivalence enforcements or change without departing from carried out by the present invention, is intended to be limited solely by the scope of the patents of this case.
Claims (10)
1. a kind of paper handkerchief with moisture-keeping functions, which is characterized in that including paper pulp and medical fluid, the medical fluid includes glycerol 1 ~ 5
Mass parts, 2 ~ 6 mass parts of propylene glycol, 15 ~ 20 mass parts of grape extract, 2 ~ 3 mass parts of polyethylene glycol, deionized water 40 ~ 60
Mass parts.
2. a kind of paper handkerchief with moisture-keeping functions according to claim 1, which is characterized in that the medical fluid includes glycerol
2 ~ 5 mass parts, 4 ~ 6 mass parts of propylene glycol, 16 ~ 20 mass parts of grape extract, 2.5 ~ 3 mass parts of polyethylene glycol, deionized water
50 ~ 60 mass parts.
3. a kind of paper handkerchief with moisture-keeping functions according to claim 2, which is characterized in that the medical fluid includes glycerol
2 mass parts, 4 mass parts of propylene glycol, 16 mass parts of grape extract, 2.5 mass parts of polyethylene glycol, 50 mass parts of deionized water.
4. a kind of paper handkerchief with moisture-keeping functions according to claim 1, which is characterized in that the grape extract packet
Include grape pip component and modified component.
5. a kind of paper handkerchief with moisture-keeping functions according to claim 4, which is characterized in that the grape extract is logical
Following methods are crossed to be made：
The grape pip component includes 10 ~ 15 mass parts of Semen Vitis Amurensis, 30 ~ 45 mass parts of ethyl alcohol, 20 ~ 40 mass of deionized water
Part, it is crushed to 30 mesh after Semen Vitis Amurensis is dried at 50 DEG C, ethyl alcohol and deionized water premixing is added, carries out after mixing evenly
Ultrasound on extracting, supersonic frequency 25,50, tri- frequency composite ultraphonic of 90kHz, 30 ~ 50min of ultrasonic extraction, obtained leaching liquor
, concentrated extract colourless to organic layer is extracted with ethyl acetate after filtering, concentration, freeze-drying obtains grape pip component；
The modification component includes 1 ~ 2 mass parts of nano zine oxide, 1 ~ 3 mass parts of nano silica, nano-titanium dioxide
Above-mentioned nano-oxide is dissolved in deionized water by 0.2 ~ 0.5 mass parts, 40 DEG C of ultrasonic water bath 3h, and modified group is obtained after drying
Part；
The deionized water of 10 ~ 20 mass parts is dissolved in after 1 ~ 5 mass parts of grape pip component are mixed with modified 0.5 ~ 1 mass parts of component
In both grape extract.
6. a kind of paper handkerchief with moisture-keeping functions according to claim 1, which is characterized in that the grape extract is logical
Following methods are crossed to be made：
The grape pip component includes 12 ~ 15 mass parts of Semen Vitis Amurensis, 30 ~ 45 mass parts of ethyl alcohol, 30 ~ 40 mass of deionized water
Part, it is crushed to 30 mesh after Semen Vitis Amurensis is dried at 50 DEG C, ethyl alcohol and deionized water premixing is added, carries out after mixing evenly
Ultrasound on extracting, supersonic frequency 25,50, tri- frequency composite ultraphonic of 90kHz, 40 ~ 50min of ultrasonic extraction, obtained leaching liquor
, concentrated extract colourless to organic layer is extracted with ethyl acetate after filtering, concentration, freeze-drying obtains grape pip component；
The modification component includes 1.5 ~ 2 mass parts of nano zine oxide, 2 ~ 3 mass parts of nano silica, nanometer titanium dioxide
0.3 ~ 0.5 mass parts of titanium, above-mentioned nano-oxide is dissolved in deionized water, and 40 DEG C of ultrasonic water bath 3h are modified after drying
Component；
The deionized water of 18 ~ 20 mass parts is dissolved in after 2 ~ 5 mass parts of grape pip component are mixed with modified 0.6 ~ 1 mass parts of component
In both grape extract.
7. a kind of paper handkerchief with moisture-keeping functions according to claim 1, which is characterized in that the grape extract is logical
Following methods are crossed to be made：
The grape pip component includes 12 mass parts of Semen Vitis Amurensis, 30 mass parts of ethyl alcohol, 30 mass parts of deionized water, by mountain Portugal
Grape seed is crushed to 30 mesh after drying at 50 DEG C, ethyl alcohol and deionized water premixing is added, carries out ultrasonic wave added after mixing evenly
Extraction, supersonic frequency 25,50, tri- frequency composite ultraphonic of 90kHz, ultrasonic extraction 40min, after obtained leaching liquor filtering, concentration
, concentrated extract colourless to organic layer is extracted with ethyl acetate, freeze-drying obtains grape pip component；
The modification component includes 1.5 mass parts of nano zine oxide, 2 mass parts of nano silica, nano-titanium dioxide 0.3
Above-mentioned nano-oxide is dissolved in deionized water by mass parts, 40 DEG C of ultrasonic water bath 3h, and modified component is obtained after drying；
It is dissolved in the deionized water of 18 mass parts after 2 mass parts of grape pip component are mixed with modified 0.6 mass parts of component and both obtaining
Grape extract.
8. a kind of paper handkerchief with moisture-keeping functions according to claim 5, which is characterized in that the nano-titanium dioxide
For modified nano-titanium dioxide；The method of modifying of the modified nano-titanium dioxide is：Take the TiCl of 15 ~ 20 mass parts4It is molten
It in 80 ~ 120 mass parts deionized waters, is stirred under ice-water bath, 25% ammonium hydroxide of 12 ~ 16 mass parts is added, add 12 ~
The hydroxymethyl cellulose of 20 mass parts carries out hydro-thermal reaction under the conditions of 100 ~ 120 DEG C after being sufficiently stirred, after reaction product
After deionized water is cleaned, 80 DEG C of drying obtain modified nano-titanium dioxide.
9. a kind of paper handkerchief with moisture-keeping functions according to claim 8, which is characterized in that the modified nano-silica
Change titanium method of modifying be：Take the TiCl of 18 mass parts4It is dissolved in 100 mass parts deionized waters, is stirred under ice-water bath, is added
25% ammonium hydroxide of 14 mass parts, adds the hydroxymethyl cellulose of 15 mass parts, carries out under the conditions of 105 DEG C after being sufficiently stirred
Hydro-thermal reaction, for product after deionized water is cleaned, 80 DEG C of drying obtain modified nano-titanium dioxide after reaction.
10. a kind of paper handkerchief manufacturing method with moisture-keeping functions, including claim 1 ~ 9 are described in any item with moisture-keeping functions
Paper handkerchief, which is characterized in that include the following steps：
（1）, by glycerol, propylene glycol, grape extract, polyethylene glycol be added deionized water in, stir evenly and medical fluid be made；
（2）, slurrying, by 80 ~ 90 mass parts of paper pulp, 10 ~ 12 mass parts of medical fluid mix after, using fluffer and fiberizer connect into
Desanding screening the pulp after slurry is made in row free beating, removes biggish undissolved solid or fiber in slurry；
（3）, whitewashing, paper web will be formed on slurry spray mo(u)lding screen cloth；
（4）, paper web is dehydrated, is dried after, removing, cutting obtain the paper handkerchief with moisture-keeping functions.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810897387.3A CN108904381B (en) | 2018-08-08 | 2018-08-08 | Tissue with moisturizing function and manufacturing method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810897387.3A CN108904381B (en) | 2018-08-08 | 2018-08-08 | Tissue with moisturizing function and manufacturing method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN108904381A true CN108904381A (en) | 2018-11-30 |
| CN108904381B CN108904381B (en) | 2021-12-07 |
Family
ID=64397234
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810897387.3A Active CN108904381B (en) | 2018-08-08 | 2018-08-08 | Tissue with moisturizing function and manufacturing method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108904381B (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111493722A (en) * | 2020-05-30 | 2020-08-07 | 青岛玉竹叶纸品科技有限责任公司 | Antibacterial wet tissue and preparation method thereof |
| CN114652643A (en) * | 2022-04-06 | 2022-06-24 | 常州米柔科技发展有限公司 | Paper towel with moisturizing function and manufacturing method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2006207046A (en) * | 2005-01-25 | 2006-08-10 | Kujira House Kk | Antibacterial paper, nonwoven fabric or textile product |
| CN101137724A (en) * | 2005-03-08 | 2008-03-05 | 西巴特殊化学制品控股公司 | Metal oxide nanoparticles coated with specific n-acylaminomethylene phosphonates |
| CN101822754A (en) * | 2010-05-28 | 2010-09-08 | 江苏大学 | Double-frequency ultrasound-assisted extraction method for grape seed extract and application of grape seed extract as lipase inhibitor |
| CN103405349A (en) * | 2013-08-14 | 2013-11-27 | 金红叶纸业集团有限公司 | Skin care composition and paper towel using same |
-
2018
- 2018-08-08 CN CN201810897387.3A patent/CN108904381B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2006207046A (en) * | 2005-01-25 | 2006-08-10 | Kujira House Kk | Antibacterial paper, nonwoven fabric or textile product |
| CN101137724A (en) * | 2005-03-08 | 2008-03-05 | 西巴特殊化学制品控股公司 | Metal oxide nanoparticles coated with specific n-acylaminomethylene phosphonates |
| CN101822754A (en) * | 2010-05-28 | 2010-09-08 | 江苏大学 | Double-frequency ultrasound-assisted extraction method for grape seed extract and application of grape seed extract as lipase inhibitor |
| CN103405349A (en) * | 2013-08-14 | 2013-11-27 | 金红叶纸业集团有限公司 | Skin care composition and paper towel using same |
Non-Patent Citations (1)
| Title |
|---|
| 王春晓等: "化妆品功效评价(Ⅱ)—保湿功效宣称的科学支持", 《日用化学工业》 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111493722A (en) * | 2020-05-30 | 2020-08-07 | 青岛玉竹叶纸品科技有限责任公司 | Antibacterial wet tissue and preparation method thereof |
| CN114652643A (en) * | 2022-04-06 | 2022-06-24 | 常州米柔科技发展有限公司 | Paper towel with moisturizing function and manufacturing method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN108904381B (en) | 2021-12-07 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105544282B (en) | A kind of paper technology method using tapa as raw material | |
| CN107268096A (en) | A kind of preparation method of wormwood antibacterial viscose fiber | |
| CN108904381A (en) | A kind of paper handkerchief and its manufacturing method with moisture-keeping functions | |
| CN108042388A (en) | A kind of moisturizing and skin rejuvenating facial mask and preparation method thereof | |
| CN108472660A (en) | Cornstalk pre-processing device and the method for manufacturing paper pulp from cornstalk | |
| KR101852779B1 (en) | Method for preparing mask pack sheet comprising algae fiber and mask pack sheet prepared thereby | |
| CN101942112A (en) | Bamboo pulp sponge product and preparation method thereof | |
| CN102215815B (en) | Mask pack comprising cosmetic cotton-like material prepared from paper mulberry | |
| CN108904321A (en) | A kind of hygenic towelette and its manufacturing method with moisture-keeping functions | |
| CN105986497A (en) | Process for extracting cellulose from natural wormwood | |
| CN110179717A (en) | A kind of ginseng vesica cleaning pack and preparation method thereof | |
| CN106676929B (en) | Mineral skin-protecting oil-absorbing paper and preparation method thereof | |
| CN109024080A (en) | A kind of environment friendly bacteriostatic type tissue and preparation method thereof | |
| CN101492892A (en) | Method for producing paper-pulp by using cotton stalk core or kendir stalk core | |
| CN111996830A (en) | Production process of fiber composite material household paper | |
| CN110042691A (en) | A kind of sugarcane paper paper stick cotton swab and preparation method thereof | |
| CN108166294A (en) | A kind of paper products of graphene-containing and preparation method thereof | |
| CN105559670A (en) | Wet paper towel for kitchen and preparation method thereof | |
| CN112754944B (en) | Bio-cellulose-based skin cleaning product and preparation method and application thereof | |
| CN107190349B (en) | Method for preparing nanofiber by using yak hair | |
| CN206589079U (en) | A kind of bamboo wood autoclaving pot for reducing bamboo Kun losses | |
| CN108034526A (en) | A kind of biological green environment protection multifunctional special efficacy liquid detergent and preparation method thereof | |
| CN105732846B (en) | It is a kind of for extracting the straw pretreatment method of hemicellulose | |
| CN107119334A (en) | A kind of apocynum fibre degumming method of comprehensive utilization | |
| CN108852888A (en) | A kind of mild non-stimulated shower cream and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| TA01 | Transfer of patent application right | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20211117 Address after: 225000 west side of Baoyuan Road, Anyi Town, Baoying County, Yangzhou City, Jiangsu Province Applicant after: YANGZHOU SUXIANG MEDICAL DEVICES Co.,Ltd. Address before: 523000 Wanjiang Guyong Industrial Zone, Dongguan City, Guangdong Province Applicant before: DONGGUAN BAITIANE PAPER Co.,Ltd. |
|
| GR01 | Patent grant | ||
| GR01 | Patent grant |