CN108903066A - A kind of health care underwear - Google Patents
A kind of health care underwear Download PDFInfo
- Publication number
- CN108903066A CN108903066A CN201810746743.1A CN201810746743A CN108903066A CN 108903066 A CN108903066 A CN 108903066A CN 201810746743 A CN201810746743 A CN 201810746743A CN 108903066 A CN108903066 A CN 108903066A
- Authority
- CN
- China
- Prior art keywords
- filler
- layer
- nanoparticle
- polyester
- health care
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 230000036541 health Effects 0.000 title claims abstract description 17
- 239000000945 filler Substances 0.000 claims abstract description 105
- 229920000728 polyester Polymers 0.000 claims abstract description 90
- 239000000835 fiber Substances 0.000 claims abstract description 88
- 239000010410 layer Substances 0.000 claims abstract description 74
- 239000000654 additive Substances 0.000 claims abstract description 30
- 230000000996 additive effect Effects 0.000 claims abstract description 30
- 239000002346 layers by function Substances 0.000 claims abstract description 18
- 239000004744 fabric Substances 0.000 claims abstract description 10
- 230000002209 hydrophobic effect Effects 0.000 claims abstract description 9
- 238000002844 melting Methods 0.000 claims abstract description 7
- 230000008018 melting Effects 0.000 claims abstract description 7
- 239000000758 substrate Substances 0.000 claims abstract description 7
- 239000002105 nanoparticle Substances 0.000 claims description 101
- MCMNRKCIXSYSNV-UHFFFAOYSA-N ZrO2 Inorganic materials O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims description 27
- 229910003264 NiFe2O4 Inorganic materials 0.000 claims description 26
- 239000011858 nanopowder Substances 0.000 claims description 25
- 229940070527 tourmaline Drugs 0.000 claims description 25
- 229910052613 tourmaline Inorganic materials 0.000 claims description 25
- 239000011032 tourmaline Substances 0.000 claims description 25
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 24
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 22
- 239000004743 Polypropylene Substances 0.000 claims description 16
- 238000001354 calcination Methods 0.000 claims description 16
- -1 polypropylene Polymers 0.000 claims description 16
- 229920001155 polypropylene Polymers 0.000 claims description 16
- 239000000126 substance Substances 0.000 claims description 15
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 claims description 13
- 238000005406 washing Methods 0.000 claims description 13
- 229910001928 zirconium oxide Inorganic materials 0.000 claims description 13
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 12
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 12
- 239000007822 coupling agent Substances 0.000 claims description 12
- 239000008367 deionised water Substances 0.000 claims description 12
- 229910021641 deionized water Inorganic materials 0.000 claims description 12
- 229910052757 nitrogen Inorganic materials 0.000 claims description 12
- 239000002002 slurry Substances 0.000 claims description 12
- 238000009987 spinning Methods 0.000 claims description 12
- 238000003756 stirring Methods 0.000 claims description 12
- 125000000129 anionic group Chemical group 0.000 claims description 11
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(I) nitrate Inorganic materials [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 claims description 11
- 239000007788 liquid Substances 0.000 claims description 10
- 238000000034 method Methods 0.000 claims description 10
- 238000001816 cooling Methods 0.000 claims description 9
- 239000004530 micro-emulsion Substances 0.000 claims description 9
- 239000002245 particle Substances 0.000 claims description 9
- 238000006068 polycondensation reaction Methods 0.000 claims description 9
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 8
- 239000012153 distilled water Substances 0.000 claims description 8
- 230000032050 esterification Effects 0.000 claims description 8
- 238000005886 esterification reaction Methods 0.000 claims description 8
- 238000002604 ultrasonography Methods 0.000 claims description 8
- 238000001035 drying Methods 0.000 claims description 7
- 239000002994 raw material Substances 0.000 claims description 7
- 238000002156 mixing Methods 0.000 claims description 6
- 238000002360 preparation method Methods 0.000 claims description 6
- 239000007787 solid Substances 0.000 claims description 6
- 239000002202 Polyethylene glycol Substances 0.000 claims description 5
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 5
- ZLWPAELISNYYGM-UHFFFAOYSA-N azanium;2-dodecylbenzenesulfonate Chemical compound [NH4+].CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O ZLWPAELISNYYGM-UHFFFAOYSA-N 0.000 claims description 5
- 239000004202 carbamide Substances 0.000 claims description 5
- 238000007599 discharging Methods 0.000 claims description 5
- 229920001223 polyethylene glycol Polymers 0.000 claims description 5
- 239000000843 powder Substances 0.000 claims description 5
- 238000010792 warming Methods 0.000 claims description 5
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 claims description 4
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 claims description 4
- 229910001030 Iron–nickel alloy Inorganic materials 0.000 claims description 4
- NGWKGSCSHDHHAJ-YPFQVHCOSA-N Liquoric acid Chemical compound C1C[C@H](O)C(C)(C)C2CC[C@@]3(C)[C@]4(C)C[C@H]5O[C@@H]([C@](C6)(C)C(O)=O)C[C@@]5(C)[C@@H]6C4=CC(=O)C3[C@]21C NGWKGSCSHDHHAJ-YPFQVHCOSA-N 0.000 claims description 4
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 claims description 4
- 239000000908 ammonium hydroxide Substances 0.000 claims description 4
- 239000003054 catalyst Substances 0.000 claims description 4
- 229960001484 edetic acid Drugs 0.000 claims description 4
- 238000007689 inspection Methods 0.000 claims description 4
- 239000000463 material Substances 0.000 claims description 4
- 239000003921 oil Substances 0.000 claims description 4
- 238000000926 separation method Methods 0.000 claims description 4
- 238000004804 winding Methods 0.000 claims description 4
- 239000006249 magnetic particle Substances 0.000 claims description 2
- 239000004594 Masterbatch (MB) Substances 0.000 claims 1
- 240000007594 Oryza sativa Species 0.000 claims 1
- 235000007164 Oryza sativa Nutrition 0.000 claims 1
- 238000004821 distillation Methods 0.000 claims 1
- 238000011049 filling Methods 0.000 claims 1
- 238000000227 grinding Methods 0.000 claims 1
- 235000009566 rice Nutrition 0.000 claims 1
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 90
- 239000011787 zinc oxide Substances 0.000 description 45
- 150000001450 anions Chemical class 0.000 description 17
- 230000000694 effects Effects 0.000 description 14
- 150000002500 ions Chemical class 0.000 description 11
- 239000002270 dispersing agent Substances 0.000 description 4
- 239000004753 textile Substances 0.000 description 4
- 238000010521 absorption reaction Methods 0.000 description 3
- 239000002131 composite material Substances 0.000 description 3
- 238000009833 condensation Methods 0.000 description 3
- 230000005494 condensation Effects 0.000 description 3
- 238000001514 detection method Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 229920002334 Spandex Polymers 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 230000005540 biological transmission Effects 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 239000004065 semiconductor Substances 0.000 description 2
- 239000004759 spandex Substances 0.000 description 2
- 210000004243 sweat Anatomy 0.000 description 2
- 229920002955 Art silk Polymers 0.000 description 1
- 235000017166 Bambusa arundinacea Nutrition 0.000 description 1
- 235000017491 Bambusa tulda Nutrition 0.000 description 1
- 241001330002 Bambuseae Species 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 235000015334 Phyllostachys viridis Nutrition 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 239000011425 bamboo Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000017531 blood circulation Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 238000001027 hydrothermal synthesis Methods 0.000 description 1
- 238000005213 imbibition Methods 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 238000009940 knitting Methods 0.000 description 1
- 239000004973 liquid crystal related substance Substances 0.000 description 1
- 238000009766 low-temperature sintering Methods 0.000 description 1
- 239000010687 lubricating oil Substances 0.000 description 1
- 238000002653 magnetic therapy Methods 0.000 description 1
- 230000005389 magnetism Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000002074 melt spinning Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000002086 nanomaterial Substances 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 239000002674 ointment Substances 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 230000002285 radioactive effect Effects 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 229920003051 synthetic elastomer Polymers 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000005061 synthetic rubber Substances 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41B—SHIRTS; UNDERWEAR; BABY LINEN; HANDKERCHIEFS
- A41B9/00—Undergarments
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41B—SHIRTS; UNDERWEAR; BABY LINEN; HANDKERCHIEFS
- A41B17/00—Selection of special materials for underwear
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B3/00—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form
- B32B3/02—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by features of form at particular places, e.g. in edge regions
- B32B3/08—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by features of form at particular places, e.g. in edge regions characterised by added members at particular parts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B3/00—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form
- B32B3/26—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer
- B32B3/266—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer characterised by an apertured layer, the apertures going through the whole thickness of the layer, e.g. expanded metal, perforated layer, slit layer regular cells B32B3/12
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
- B32B5/024—Woven fabric
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/22—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
- B32B5/24—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
- B32B5/26—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer another layer next to it also being fibrous or filamentary
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/24—Formation of filaments, threads, or the like with a hollow structure; Spinnerette packs therefor
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/253—Formation of filaments, threads, or the like with a non-circular cross section; Spinnerette packs therefor
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/88—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds
- D01F6/92—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds of polyesters
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2250/00—Layers arrangement
- B32B2250/20—All layers being fibrous or filamentary
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/02—Synthetic macromolecular fibres
- B32B2262/0253—Polyolefin fibres
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/02—Synthetic macromolecular fibres
- B32B2262/0276—Polyester fibres
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/06—Vegetal fibres
- B32B2262/062—Cellulose fibres, e.g. cotton
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/06—Vegetal fibres
- B32B2262/062—Cellulose fibres, e.g. cotton
- B32B2262/065—Lignocellulosic fibres, e.g. jute, sisal, hemp, flax, bamboo
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/10—Inorganic fibres
- B32B2262/106—Carbon fibres, e.g. graphite fibres
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/20—Properties of the layers or laminate having particular electrical or magnetic properties, e.g. piezoelectric
- B32B2307/212—Electromagnetic interference shielding
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/714—Inert, i.e. inert to chemical degradation, corrosion
- B32B2307/7145—Rot proof, resistant to bacteria, mildew, mould, fungi
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/724—Permeability to gases, adsorption
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/726—Permeability to liquids, absorption
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/728—Hydrophilic
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/73—Hydrophobic
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2437/00—Clothing
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Mechanical Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
This application involves a kind of health care underwears, including underwear ontology, the underwear ontology is made of underwear fabric, the underwear fabric includes the outer layer set gradually from outside to inside, functional layer, secondary internal layer and internal layer, the outer layer is hydrophilic layer, the internal layer is hydrophobic layer, the secondary internal layer is wetness-guiding layer, the functional layer is layer of polyester fiber, it is evenly equipped with the venthole that through-thickness runs through the functional layer thereon, the aperture of venthole is not more than 0.1mm, the quantity of the venthole is not less than 2,000,000 in every square metre of range, the polyester fiber is using polyester as substrate, with filler A, filler B, filler C is additive, by melting blended be prepared.
Description
Technical field
This application involves underwear technical field more particularly to a kind of health care underwears.
Background technique
Underwear refers to the clothing worn next to the skin.It is disclosed in patent document CN201106086Y in a kind of knitting of thermal-protection elastic
Clothing fabric, including internal layer, middle layer, superficial layer, the superficial layer are high branch non-shrinkable wool yarn, and the internal layer is washed for high porosity
Synthetic fibre yarn, the middle layer are spandex thread, and the spandex thread connects between superficial layer and internal layer and connection breaking, makes internal layer and table
Micro- air bag that keeps warm is formed between surface layer.The heat insulation effect of underwear fabric in above patent document, wetness guiding perspiration discharging effect still compared with
Difference, and do not have healthcare function, therefore there is also can improvements for the structure of existing underwear fabric.
Summary of the invention
The present invention is intended to provide a kind of health care underwear, set forth above to solve the problems, such as.
A kind of health care underwear, including underwear ontology are provided in the embodiment of the present invention, the underwear ontology is by underwear fabric
It constitutes, which includes the outer layer set gradually from outside to inside, functional layer, secondary internal layer and internal layer, and the outer layer is hydrophilic
Layer, the internal layer are hydrophobic layer, and the secondary internal layer is wetness-guiding layer, and the functional layer is layer of polyester fiber, are evenly equipped with thereon along thickness
The venthole that the functional layer is run through in direction is spent, the aperture of venthole is not more than 0.1mm, the venthole in every square metre of range
Quantity be not less than 2,000,000, the polyester fiber, using filler A, filler B, filler C as additive, passes through using polyester as substrate
Melt blended be prepared；In terms of content, raw material includes according to weight percent：3~9% filler A, 8~12%
Filler B, 4~10% filler C, surplus are polyester；The secondary internal layer be polypropylene fiber weave, polypropylene fiber be it is hollow and
It is equipped with capillary through holes on the surface；The hydrophobic layer is that polypropylene fiber weaves, and used polypropylene fiber has cross
Cross section, T-shaped cross section or Y-shaped cross section.
The technical solution that the embodiment of the present invention provides can include the following benefits：
Heretofore described functional layer is layer of polyester fiber, and the polyester fiber is to be addition with filler A, filler B, filler C
Agent has anion, far infrared, electro-magnetic screen function, and unexpected technical results have been achieved.
The additional aspect of the application and advantage will be set forth in part in the description, and will partially become from the following description
It obtains obviously, or recognized by the practice of the application.It should be understood that above general description and following detailed description are only
Be it is exemplary and explanatory, the application can not be limited.
Detailed description of the invention
The present invention will be further described with reference to the accompanying drawings, but the embodiment in attached drawing is not constituted to any limit of the invention
System, for those of ordinary skill in the art, without creative efforts, can also obtain according to the following drawings
Other attached drawings.
Fig. 1 is the cross-sectional view of underwear fabric of the present invention.
Appended drawing reference is as shown in the figure：1- outer layer；2- functional layer；3- secondary internal layer；4- internal layer.
Specific embodiment
Example embodiments are described in detail here, and the example is illustrated in the accompanying drawings.Following description is related to
When attached drawing, unless otherwise indicated, the same numbers in different drawings indicate the same or similar elements.Following exemplary embodiment
Described in embodiment do not represent all embodiments consistented with the present invention.On the contrary, they be only with it is such as appended
The example of device and method being described in detail in claims, some aspects of the invention are consistent.
Embodiments herein is related to a kind of health care underwear, including underwear ontology, which is made of underwear fabric,
As shown in Figure 1, the underwear fabric includes the outer layer 1 set gradually from outside to inside, functional layer 2, secondary internal layer 3 and internal layer 4, it is described outer
Layer 1 is hydrophilic layer, and the internal layer 4 is hydrophobic layer, and the secondary internal layer 3 is wetness-guiding layer, and the functional layer 2 is layer of polyester fiber,
On be evenly equipped with the venthole that through-thickness runs through the functional layer 2, the aperture of venthole is not more than 0.1mm, every square metre of model
The quantity of the interior venthole is enclosed not less than 2,000,000, and the secondary internal layer 3 is that polypropylene fiber weaves, during polypropylene fiber is
It is empty and be equipped with capillary through holes on the surface；The hydrophobic layer is that polypropylene fiber weaves, and used polypropylene fiber has ten
Font cross section, T-shaped cross section or Y-shaped cross section.
In the present invention, the hydrophobic layer is that polypropylene fiber weaves, and used polypropylene fiber has cross transversal
Face, T-shaped cross section or Y-shaped cross section, so as to form a large amount of sweat guiding troughs, further wetness-guiding layer in hydrophobic layer surface
It is woven for polypropylene fiber, polypropylene fiber is hollow and is equipped with capillary through holes on the surface, so as to reinforce time secondary internal layer
Moisture absorbing and sweat releasing and permeability.
In the present embodiment, the outer layer 1 is with a thickness of 0.8-1.5mm, preferably 1.2mm；
The functional layer 2 with a thickness of 0.5-0.8mm, preferably 0.7mm；
The secondary internal layer 3 with a thickness of 0.3-0.5mm, preferably 0.4mm；
The internal layer 4 with a thickness of 0.2-0.4mm, preferably 0.3mm；
The outer layer 1 is formed by warp thread and weft yarns, and the weft yarn is bamboo fiber yarn and carbon fibre thread is alternate sets
It sets, the warp thread is cotton thread, can guarantee the antibacterial and water imbibition of hydrophilic layer in this way.
Further, it is provided with magnetic-particle (not shown) between the functional layer 2 and secondary internal layer 3, passes through magnetism
The magnetic field that particle generates can effectively play the effect of magnetic therapy.
Functional layer is layer of polyester fiber, which has anion, far infrared, electro-magnetic screen function, specifically, should
Polyester fiber is using polyester as substrate, using filler A, filler B, filler C as additive, by melting blended be prepared；Wherein, should
Filler A includes：ZrO2Nano-powder and ZnO nanoparticle；Filler B includes：Tourmaline nano particle and ZnO nanoparticle；
Filler C includes：NiFe2O4Nanoparticle and ZnO nanoparticle.
In routine techniques, melt spinning is carried out by the way that nano-functional powder will be added in polyester fondant, tool is made
There is the polyester fiber of healthcare function；However, those skilled in the art understand that, the partial size of usual nano material is smaller, table
Face activity and free energy are higher, and the nano particle of addition is caused to have agglomeration tendency, this will largely effect on functional particle performance
Effect；Meanwhile causing polyester fiber modified effect unobvious.In technical solution of the present invention, it is with filler A, filler B and filler C
Polyester fiber is prepared by the way that melting is blended in additive, by controlling mass ratio, above-mentioned filler A, filler B and filler C association
Same-action has expanded polyester so that the polyester functional fibre is provided with anion, far infrared transmission, electro-magnetic screen function significantly
The application range of fiber；In addition, including dispersing agent ZnO nanoparticle, the dispersion in the filler A, filler B and filler C
Agent can effectively prevent the reunion of additive in polyester fiber preparation process, be conducive to anion, far infrared, electromagnetic wave shielding
The performance of energy, achieves unexpected beneficial effect.
Preferably, ZnO nanoparticle partial size is 20-50nm, more preferably 30nm in filler.Zinc oxide is a kind of important
Semiconductor material, be widely used in plastics, silicate product, synthetic rubber, lubricating oil, paint, ointment, adhesive,
In the production of the products such as food, battery, fire retardant.The band gap and exciton bind energy of zinc oxide are larger, and transparency is high, have excellent
Room temperature luminescent properties, answered in the products such as the liquid crystal display, thin film transistor (TFT), light emitting diode of semiconductor field
With.It is creative using zinc oxide nano-particle as the dispersing agent of filler in technical scheme, it achieves unexpected
Technical effect；Also, in filler C, ZnO nanoparticle and NiFe2O4Nanoparticle synergistic effect, for electro-magnetic screen function
Performance play good effect.
In terms of content, in the polyester fiber, raw material includes according to weight percent：3~9% filler A, 8~
12% filler B, 4~10% filler C, surplus are polyester.
Wherein, in filler A, the ZrO2Nano-powder is to be prepared by ultrasonic microemulsion liquid method.
ZrO2Powder is the basis for making zirconium oxide special cermacis, high grade refractory, optical communication device, new energy materials
Raw material, ZrO2With low-temperature sintering, ZrO2Nano-powder is as a kind of non-toxic and non-radioactive and has Low Temperature Far Infrared transmitting
The material of performance is a kind of important far infrared additive；However, if by above-mentioned ZrO2Nano-powder is directly appended to polyester
In fiber, due to nanometer reuniting effect, ZrO2Nano-powder disperses unevenly, to will be greatly reduced far infrared in polyester fiber
The performance of energy；In technical scheme, by by ZrO2Nano-powder and ZnO nanoparticle dispersant, calcining, obtain
Filler A, is then added into polyester fiber again.In above-mentioned mixing, calcination process, so that ZrO2Nano-powder can have
Effect is adsorbed and is incorporated in ZnO nanoparticle surface, substantially increases the uniformity of far infrared transmission, produces unexpected
Technical effect.
Preferably, in filler A, the mass fraction of each substance is：ZrO215 parts of nano-powder, 4 parts of ZnO nanoparticle；It should
ZrO2The partial size of nano-powder is 20nm.
Wherein, during filler B is, the tourmaline nano particle diameter is 100nm.
Tourmaline is a kind of natural electrode with similar to magnet poles, and tourmaline is widely used in environmental protection, day
The often numerous areas such as life, for example, tourmaline powder is added in artificial silk, since tourmaline powder has positive and negative electrode,
After human contact, countless weak currents can be generated in skin surface, stimulate blood circulation, form negative ion effect；However,
In this field, tourmaline is directly used in textile, electronegative ion can not be played well.Technical solution of the present invention
In, by having obtained tourmaline nano particle and ZnO nanoparticle dispersant, calcining filler B, then having been added again
Enter in polyester fiber.By above-mentioned mixing, calcination process, the uniformity of anion emission is substantially increased, produces expectation not
The technical effect arrived.
Preferably, in filler B, the mass fraction of each substance is：17 parts of tourmaline nano particle, 11 parts of ZnO nanoparticle.
Wherein, in filler C, the NiFe2O4The partial size of nanoparticle is 30~50nm；
Preferably, in filler C, the mass fraction of each substance is：NiFe2O45 parts of nanoparticle, 2 parts of ZnO nanoparticle；It should
NiFe2O4Nanoparticle is synthesized by hydro-thermal method, specially：It weighs 10g polyethylene glycol and 7g dodecyl benzene sulfonic acid ammonium is molten
In 20ml distilled water, the Fe (NO of 2mol is then added3)3·9H2O, the Ni (NO of 1mol3)2·6H2O adjusts pH value with urea
It is 11.5, stirs evenly, mixed liquor is transferred in autoclave, 20h is reacted at 270 DEG C, then natural cooling, through solid-liquid point
From, washing, it is dry after, solid matter is calcined into 10h in the case where 400min is warming up to 870 DEG C, obtains NiFe2O4Nanoparticle.
Further explanation is made to the present invention below with reference to embodiment.
Embodiment 1
A kind of polyester fiber with anion, far infrared, electromagnetic shielding performance, the polyester fiber using polyester as substrate,
Using filler A, filler B, filler C as additive, by melting blended be prepared；In terms of content, raw material is according to weight hundred
Point ratio includes：5% filler A, 11% filler B, 6% filler C, surplus are polyester.
Filler A includes：ZrO2Nano-powder and ZnO nanoparticle；Filler B includes：Tourmaline nano particle and ZnO
Nanoparticle；Filler C includes：NiFe2O4Nanoparticle and ZnO nanoparticle；Above-mentioned ZnO nanoparticle partial size is 30nm.
Filler A is far infrared additive, wherein the ZrO2Nano-powder is to be prepared by ultrasonic microemulsion liquid method；It should
ZrO2The partial size of nano-powder is 20nm；In filler A, the mass fraction of each substance is：ZrO215 parts of nano-powder, ZnO nano grain
4 parts of son.Filler B is anionic additive, wherein the tourmaline nano particle diameter is 100nm；In filler B, each substance
Mass fraction be：17 parts of tourmaline nano particle, 11 parts of ZnO nanoparticle.Filler C is electromagnetic shielding filler, wherein described
NiFe2O4The partial size of nanoparticle is 30~50nm；In filler C, the mass fraction of each substance is：NiFe2O4Nanoparticle 5
Part, 2 parts of ZnO nanoparticle.
The preparation process of the polyester fiber is：
Step 1, NiFe is prepared2O4Nanoparticle：It weighs 10g polyethylene glycol and 7g dodecyl benzene sulfonic acid ammonium is dissolved in 20ml
In distilled water, the Fe (NO of 2mol is then added3)3·9H2O, the Ni (NO of 1mol3)2·6H2O, adjusting pH value with urea is
11.5, it stirs evenly, mixed liquor is transferred in autoclave, 20h is reacted at 270 DEG C, then natural cooling, be separated by solid-liquid separation,
After washing, drying, solid matter is calcined into 10h in the case where 400min is warming up to 870 DEG C, obtains NiFe2O4Nanoparticle；
Step 2 prepares zirconium oxide presoma：By the ZrOCl of 720g/L2·8H2The ethylenediamine tetra-acetic acid of O and 94g/L according to
Volume ratio 2:1 mixing, being vigorously stirred 30min is uniformly mixed it, obtains transparent micro emulsion, then adjusts pH value with ammonium hydroxide and is
11.4, ultrasound 14min, ultrasonic power 20KHz obtain clear gel at 84 DEG C, are then washed with distilled water to AgNO3
Solution inspection does not measure Cl-, then use ethanol washing 3 times, the zirconium oxide presoma after washing be put into thermostatic drying chamber, 60
DEG C dry 15h；
Step 3 prepares filler：Zirconium oxide presoma, ZnO nanoparticle and titanate coupling agent are added to deionized water
In, it stirs, obtains far infrared additive slurry, be then baked to, under nitrogen protection in 360 DEG C of calcining 5h,
It pulverizes to get filler A；
Tourmaline nano particle, ZnO nanoparticle and titanate coupling agent are add to deionized water, are sufficiently stirred
It is even, obtain anionic additive slurry, be then baked to, under nitrogen protection in 480 DEG C of calcining 6h, pulverize to get
Filler B；
By NiFe2O4Nanoparticle, ZnO nanoparticle and titanate coupling agent are add to deionized water, and are sufficiently stirred
It is even, electromagnetic shielding additive slurry is obtained, is then baked to, under nitrogen protection in 450 DEG C of calcining 5h, pulverizes, i.e.,
Obtain filler C；
Step 4 prepares the polyester fiber：Firstly, by filler A, filler B, filler C and ethylene glycol mix, after stirring
Ultrasound 5h at room temperature, obtains mixed liquor；Then mixed liquor and p-phthalic acid, catalyst aid are esterified, polymerize, obtains
Polyester master particle；Wherein, esterification temperature is 280 DEG C, and pressure 270kPa carries out polycondensation reaction when esterification yield reaches greater than 95.5%,
Condensation temperature is 2850 DEG C, is evacuated to 22MPa, when polycondensation to inherent viscosity is 0.74 deciliter/gram, discharging, and blank；
Polyester master particle is melted, filter is then fed into and is filtered, after metering, into spinning pack, then will be sprayed
Tow carry out it is cooling, oil, preoriented yarn is wound into after deflector roll, wherein spinning temperature is 290 DEG C, and spinning speed is
3200m/min；
Polyester preoriented yarn can be prepared into the polyester fiber after a roller, hot tank, two rollers, scroll tube, winding, wherein
Draft speed is 480m/min, and draw ratio 3.1, a roll temperature is 90 DEG C, and two roll temperatures are 140 DEG C.
The far-infrared radiated property of fiber is characterized by measuring the normal emittance of polyester fiber in the present embodiment, is examined
The result shows that its normal emittance is 0.94, quasi- about the assessment of bids of far infrared performance according to this field, normal emittance is more than or equal to
0.8 can be assessed as far-infrared textiles, and the composite fibre in the present embodiment is met the requirements of the standard；
Measure the anionic property of polyester fiber in the present embodiment：
It is detected using air ion concentration relative standard's measuring device, the polyester fiber that the application is obtained and common
Polyester fiber is cut into 10 × 10cm respectively2Size, apart from above-mentioned detection device 6.5cm2Air inlet 2mm or so, measure air
Middle negative ion concentration, the polyester fiber anion emission number for obtaining the application is 4683 anion/cm3, and conventional polyester
The negative ion concentration of fiber is substantially zeroed, illustrates that the polyester fiber of the application has good anion emission performance.
The absorbing property of polyester fiber in the present embodiment is measured, maximum absorption peak is -24.6dB, and the bandwidth of -5dB is
2500MHz has good electromagnetic shielding performance.
Embodiment 2
A kind of polyester fiber with anion, far infrared, electromagnetic shielding performance, the polyester fiber using polyester as substrate,
Using filler A, filler B, filler C as additive, by melting blended be prepared；In terms of content, raw material is according to weight hundred
Point ratio includes：9% filler A, 12% filler B, 10% filler C, surplus are polyester.
Filler A includes：ZrO2Nano-powder and ZnO nanoparticle；Filler B includes：Tourmaline nano particle and ZnO
Nanoparticle；Filler C includes：NiFe2O4Nanoparticle and ZnO nanoparticle；Above-mentioned ZnO nanoparticle partial size is 30nm.
Filler A is far infrared additive, wherein the ZrO2Nano-powder is to be prepared by ultrasonic microemulsion liquid method；It should
ZrO2The partial size of nano-powder is 20nm；In filler A, the mass fraction of each substance is：ZrO215 parts of nano-powder, ZnO nano grain
4 parts of son.Filler B is anionic additive, wherein the tourmaline nano particle diameter is 100nm；In filler B, each substance
Mass fraction be：17 parts of tourmaline nano particle, 11 parts of ZnO nanoparticle.Filler C is electromagnetic shielding filler, wherein described
NiFe2O4The partial size of nanoparticle is 30~50nm；In filler C, the mass fraction of each substance is：NiFe2O4Nanoparticle 5
Part, 2 parts of ZnO nanoparticle.
The preparation process of the polyester fiber is：
Step 1, NiFe is prepared2O4Nanoparticle：It weighs 10g polyethylene glycol and 7g dodecyl benzene sulfonic acid ammonium is dissolved in 20ml
In distilled water, the Fe (NO of 2mol is then added3)3·9H2O, the Ni (NO of 1mol3)2·6H2O, adjusting pH value with urea is
11.5, it stirs evenly, mixed liquor is transferred in autoclave, 20h is reacted at 270 DEG C, then natural cooling, be separated by solid-liquid separation,
After washing, drying, solid matter is calcined into 10h in the case where 400min is warming up to 870 DEG C, obtains NiFe2O4Nanoparticle；
Step 2 prepares zirconium oxide presoma：By the ZrOCl of 720g/L2·8H2The ethylenediamine tetra-acetic acid of O and 94g/L according to
Volume ratio 2:1 mixing, being vigorously stirred 30min is uniformly mixed it, obtains transparent micro emulsion, then adjusts pH value with ammonium hydroxide and is
11.4, ultrasound 14min, ultrasonic power 20KHz obtain clear gel at 84 DEG C, are then washed with distilled water to AgNO3
Solution inspection does not measure Cl-, then use ethanol washing 3 times, the zirconium oxide presoma after washing be put into thermostatic drying chamber, 60
DEG C dry 15h；
Step 3 prepares filler：Zirconium oxide presoma, ZnO nanoparticle and titanate coupling agent are added to deionized water
In, it stirs, obtains far infrared additive slurry, be then baked to, under nitrogen protection in 360 DEG C of calcining 5h,
It pulverizes to get filler A；
Tourmaline nano particle, ZnO nanoparticle and titanate coupling agent are add to deionized water, are sufficiently stirred
It is even, obtain anionic additive slurry, be then baked to, under nitrogen protection in 480 DEG C of calcining 6h, pulverize to get
Filler B；
By NiFe2O4Nanoparticle, ZnO nanoparticle and titanate coupling agent are add to deionized water, and are sufficiently stirred
It is even, electromagnetic shielding additive slurry is obtained, is then baked to, under nitrogen protection in 450 DEG C of calcining 5h, pulverizes, i.e.,
Obtain filler C；
Step 4 prepares the polyester fiber：Firstly, by filler A, filler B, filler C and ethylene glycol mix, after stirring
Ultrasound 5h at room temperature, obtains mixed liquor；Then mixed liquor and p-phthalic acid, catalyst aid are esterified, polymerize, obtains
Polyester master particle；Wherein, esterification temperature is 280 DEG C, and pressure 270kPa carries out polycondensation reaction when esterification yield reaches greater than 95.5%,
Condensation temperature is 2850 DEG C, is evacuated to 22MPa, when polycondensation to inherent viscosity is 0.74 deciliter/gram, discharging, and blank；
Polyester master particle is melted, filter is then fed into and is filtered, after metering, into spinning pack, then will be sprayed
Tow carry out it is cooling, oil, preoriented yarn is wound into after deflector roll, wherein spinning temperature is 290 DEG C, and spinning speed is
3200m/min；
Polyester preoriented yarn can be prepared into the polyester fiber after a roller, hot tank, two rollers, scroll tube, winding, wherein
Draft speed is 480m/min, and draw ratio 3.1, a roll temperature is 90 DEG C, and two roll temperatures are 140 DEG C.
The far-infrared radiated property of fiber is characterized by measuring the normal emittance of polyester fiber in the present embodiment, is examined
The result shows that its normal emittance is 0.92, quasi- about the assessment of bids of far infrared performance according to this field, normal emittance is more than or equal to
0.8 can be assessed as far-infrared textiles, and the composite fibre in the present embodiment is met the requirements of the standard；
Measure the anionic property of polyester fiber in the present embodiment：
It is detected using air ion concentration relative standard's measuring device, the polyester fiber that the application is obtained and common
Polyester fiber is cut into 10 × 10cm respectively2Size, apart from above-mentioned detection device 6.5cm2Air inlet 2mm or so, measure air
Middle negative ion concentration, the polyester fiber anion emission number for obtaining the application is 4218 anion/cm3, and conventional polyester
The negative ion concentration of fiber is substantially zeroed, illustrates that the polyester fiber of the application has good anion emission performance.
The absorbing property of polyester fiber in the present embodiment is measured, maximum absorption peak is -21.6dB, and the bandwidth of -5dB is
2300MHz has good electromagnetic shielding performance.
Embodiment 3
A kind of polyester fiber with anion, far infrared, electromagnetic shielding performance, the polyester fiber using polyester as substrate,
Using filler A, filler B, filler C as additive, by melting blended be prepared；In terms of content, raw material is according to weight hundred
Point ratio includes：3% filler A, 8% filler B, 4% filler C, surplus are polyester.
Filler A includes：ZrO2Nano-powder and ZnO nanoparticle；Filler B includes：Tourmaline nano particle and ZnO
Nanoparticle；Filler C includes：NiFe2O4Nanoparticle and ZnO nanoparticle；Above-mentioned ZnO nano particle diameter is 30nm。
Filler A is far infrared additive, wherein the ZrO2Nano-powder is to be prepared by ultrasonic microemulsion liquid method；It should
ZrO2The partial size of nano-powder is 20nm；In filler A, the mass fraction of each substance is：ZrO215 parts of nano-powder, ZnO nanoparticle
4 parts of son.Filler B is anionic additive, wherein the tourmaline nano particle diameter is 100nm；In filler B, each substance
Mass fraction be：17 parts of tourmaline nano particle, 11 parts of ZnO nanoparticle.Filler C is electromagnetic shielding filler, wherein described
NiFe2O4The partial size of nanoparticle is 30~50nm；In filler C, the mass fraction of each substance is：NiFe2O4Nanoparticle 5
Part, 2 parts of ZnO nanoparticle.
The preparation process of the polyester fiber is：
Step 1, NiFe is prepared2O4Nanoparticle：It weighs 10g polyethylene glycol and 7g dodecyl benzene sulfonic acid ammonium is dissolved in 20ml
In distilled water, the Fe (NO of 2mol is then added3)3·9H2O, the Ni (NO of 1mol3)2·6H2O, adjusting pH value with urea is
11.5, it stirs evenly, mixed liquor is transferred in autoclave, 20h is reacted at 270 DEG C, then natural cooling, be separated by solid-liquid separation,
After washing, drying, solid matter is calcined into 10h in the case where 400min is warming up to 870 DEG C, obtains NiFe2O4Nanoparticle；
Step 2 prepares zirconium oxide presoma：By the ZrOCl of 720g/L2·8H2The ethylenediamine tetra-acetic acid of O and 94g/L according to
Volume ratio 2:1 mixing, being vigorously stirred 30min is uniformly mixed it, obtains transparent micro emulsion, then adjusts pH value with ammonium hydroxide and is
11.4, ultrasound 14min, ultrasonic power 20KHz obtain clear gel at 84 DEG C, are then washed with distilled water to AgNO3
Solution inspection does not measure Cl-, then use ethanol washing 3 times, the zirconium oxide presoma after washing be put into thermostatic drying chamber, 60
DEG C dry 15h；
Step 3 prepares filler：Zirconium oxide presoma, ZnO nanoparticle and titanate coupling agent are added to deionized water
In, it stirs, obtains far infrared additive slurry, be then baked to, under nitrogen protection in 360 DEG C of calcining 5h,
It pulverizes to get filler A；
Tourmaline nano particle, ZnO nanoparticle and titanate coupling agent are add to deionized water, are sufficiently stirred
It is even, obtain anionic additive slurry, be then baked to, under nitrogen protection in 480 DEG C of calcining 6h, pulverize to get
Filler B；
By NiFe2O4Nanoparticle, ZnO nanoparticle and titanate coupling agent are add to deionized water, and are sufficiently stirred
It is even, electromagnetic shielding additive slurry is obtained, is then baked to, under nitrogen protection in 450 DEG C of calcining 5h, pulverizes, i.e.,
Obtain filler C；
Step 4 prepares the polyester fiber：Firstly, by filler A, filler B, filler C and ethylene glycol mix, after stirring
Ultrasound 5h at room temperature, obtains mixed liquor；Then mixed liquor and p-phthalic acid, catalyst aid are esterified, polymerize, obtains
Polyester master particle；Wherein, esterification temperature is 280 DEG C, and pressure 270kPa carries out polycondensation reaction when esterification yield reaches greater than 95.5%,
Condensation temperature is 2850 DEG C, is evacuated to 22MPa, when polycondensation to inherent viscosity is 0.74 deciliter/gram, discharging, and blank；
Polyester master particle is melted, filter is then fed into and is filtered, after metering, into spinning pack, then will be sprayed
Tow carry out it is cooling, oil, preoriented yarn is wound into after deflector roll, wherein spinning temperature is 290 DEG C, and spinning speed is
3200m/min；
Polyester preoriented yarn can be prepared into the polyester fiber after a roller, hot tank, two rollers, scroll tube, winding, wherein
Draft speed is 480m/min, and draw ratio 3.1, a roll temperature is 90 DEG C, and two roll temperatures are 140 DEG C.
The far-infrared radiated property of fiber is characterized by measuring the normal emittance of polyester fiber in the present embodiment, is examined
The result shows that its normal emittance is 0.88, quasi- about the assessment of bids of far infrared performance according to this field, normal emittance is more than or equal to
0.8 can be assessed as far-infrared textiles, and the composite fibre in the present embodiment is met the requirements of the standard；
Measure the anionic property of polyester fiber in the present embodiment：
It is detected using air ion concentration relative standard's measuring device, the polyester fiber that the application is obtained and common
Polyester fiber is cut into 10 × 10cm respectively2Size, apart from above-mentioned detection device 6.5cm2Air inlet 2mm or so, measure air
Middle negative ion concentration, the polyester fiber anion emission number for obtaining the application is 3672 anion/cm3, and conventional polyester
The negative ion concentration of fiber is substantially zeroed, illustrates that the polyester fiber of the application has good anion emission performance.
The absorbing property of polyester fiber in the present embodiment is measured, maximum absorption peak is -23.8dB, and the bandwidth of -5dB is
2100MHz has good electromagnetic shielding performance.
The foregoing is merely preferred modes of the invention, are not intended to limit the invention, all in spirit and original of the invention
Within then, any modification, equivalent replacement, improvement and so on be should all be included in the protection scope of the present invention.
Claims (10)
1. a kind of health care underwear, including underwear ontology, which is made of underwear fabric, which is characterized in that the underwear face
Material includes outer layer, functional layer, secondary internal layer and the internal layer set gradually from outside to inside, and the outer layer is hydrophilic layer, and the internal layer is
Hydrophobic layer, the secondary internal layer are wetness-guiding layer, and the functional layer is layer of polyester fiber, are evenly equipped with through-thickness thereon through described
The venthole of functional layer, the aperture of venthole are not more than 0.1mm, and the quantity of the venthole is not less than in every square metre of range
2000000, the polyester fiber is using polyester as substrate, using filler A, filler B, filler C as additive, by melting blended preparation
It obtains；In terms of content, raw material includes according to weight percent：3~9% filler A, 8~12% filler B, 4~10%
Filler C, surplus be polyester；The secondary internal layer is that polypropylene fiber weaves, and polypropylene fiber is hollow and is equipped on the surface
Capillary through holes；The hydrophobic layer is that polypropylene fiber weaves, and used polypropylene fiber has cross-like cross-section, T-shaped
Cross section or Y-shaped cross section.
2. a kind of health care underwear according to claim 1, which is characterized in that the outer layer thickness is 0.8-1.5mm.
3. a kind of health care underwear according to claim 1, which is characterized in that the secondary internal layer 3 with a thickness of 0.3-
0.5mm。
4. a kind of health care underwear according to claim 1, which is characterized in that the internal layer with a thickness of 0.2-0.4mm.
5. a kind of health care underwear according to claim 1, which is characterized in that be provided between the functional layer and secondary internal layer
Magnetic-particle.
6. a kind of health care underwear according to claim 1, which is characterized in that the filler A includes：ZrO2Nano-powder and
ZnO nanoparticle；The filler B includes：Tourmaline nano particle and ZnO nanoparticle；The filler C includes：NiFe2O4It receives
Rice corpuscles and ZnO nanoparticle；Wherein, the ZnO nanoparticle partial size is 30nm.
7. a kind of health care underwear according to claim 6, which is characterized in that filler A is far infrared additive, wherein described
ZrO2Nano-powder is to be prepared by ultrasonic microemulsion liquid method；The ZrO2The partial size of nano-powder is 20nm；In filler A, each substance
Mass fraction be：ZrO215 parts of nano-powder, 4 parts of ZnO nanoparticle.
8. a kind of health care underwear according to claim 6, which is characterized in that filler B is anionic additive, wherein described
Tourmaline nano particle diameter be 100nm；In filler B, the mass fraction of each substance is：17 parts of tourmaline nano particle, ZnO
11 parts of nanoparticle.
9. a kind of health care underwear according to claim 6, which is characterized in that filler C is electromagnetic shielding filler, wherein described
NiFe2O4The partial size of nanoparticle is 30~50nm；In filler C, the mass fraction of each substance is：NiFe2O4Nanoparticle 5
Part, 2 parts of ZnO nanoparticle.
10. a kind of health care underwear according to claim 6, which is characterized in that the preparation process of the polyester fiber is：
Step 1, NiFe is prepared2O4Nanoparticle：It weighs 10g polyethylene glycol and 7g dodecyl benzene sulfonic acid ammonium is dissolved in 20ml distillation
In water, the Fe (NO of 2mol is then added3)3·9H2O, the Ni (NO of 1mol3)2·6H2O, adjusting pH value with urea is 11.5, is stirred
It mixes uniformly, mixed liquor is transferred in autoclave, 20h is reacted at 270 DEG C, then natural cooling, through separation of solid and liquid, washing, do
After dry, solid matter is calcined into 10h in the case where 400min is warming up to 870 DEG C, obtains NiFe2O4Nanoparticle；
Step 2 prepares zirconium oxide presoma：By the ZrOCl of 720g/L2·8H2The ethylenediamine tetra-acetic acid of O and 94g/L is according to volume
Than 2:1 mixing, being vigorously stirred 30min is uniformly mixed it, obtains transparent micro emulsion, and then adjusting pH value with ammonium hydroxide is 11.4,
Ultrasound 14min, ultrasonic power 20KHz obtain clear gel at 84 DEG C, are then washed with distilled water to AgNO3Solution
Inspection does not measure Cl-, it then uses ethanol washing 3 times, the zirconium oxide presoma after washing is put into thermostatic drying chamber, it is dry at 60 DEG C
Dry 15h；
Step 3 prepares filler：Zirconium oxide presoma, ZnO nanoparticle and titanate coupling agent are add to deionized water,
It stirs, obtains far infrared additive slurry, be then baked to, under nitrogen protection in 360 DEG C of calcining 5h, grinding
At powder to get filler A；
Tourmaline nano particle, ZnO nanoparticle and titanate coupling agent are add to deionized water, stirred,
Anionic additive slurry is obtained, is then baked to, under nitrogen protection in 480 DEG C of calcining 6h, is pulverized to get filler
B；
By NiFe2O4Nanoparticle, ZnO nanoparticle and titanate coupling agent are add to deionized water, and are stirred,
Electromagnetic shielding additive slurry is obtained, is then baked to, under nitrogen protection in 450 DEG C of calcining 5h, pulverizes to get filling out
Expect C；
Step 4 prepares the polyester fiber：Firstly, filler A, filler B, filler C and ethylene glycol are mixed, in room temperature after stirring
Lower ultrasound 5h, obtains mixed liquor；Then mixed liquor and p-phthalic acid, catalyst aid are esterified, polymerize, obtains polyester
Master batch；Wherein, esterification temperature is 280 DEG C, and pressure 270kPa carries out polycondensation reaction, polycondensation when esterification yield reaches greater than 95.5%
Temperature is 2850 DEG C, is evacuated to 22MPa, when polycondensation to inherent viscosity is 0.74 deciliter/gram, discharging, and blank；
Polyester master particle is melted, filter is then fed into and is filtered, after metering, into spinning pack, then by the silk of ejection
Shu Jinhang is cooling, oils, and preoriented yarn is wound into after deflector roll, wherein spinning temperature is 290 DEG C, spinning speed 3200m/
min；
Polyester preoriented yarn can be prepared into the polyester fiber after a roller, hot tank, two rollers, scroll tube, winding, wherein drawing-off
Speed is 480m/min, and draw ratio 3.1, a roll temperature is 90 DEG C, and two roll temperatures are 140 DEG C.
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| CN201810746743.1A CN108903066A (en) | 2018-07-09 | 2018-07-09 | A kind of health care underwear |
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| CN201810746743.1A CN108903066A (en) | 2018-07-09 | 2018-07-09 | A kind of health care underwear |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112252027A (en) * | 2020-10-28 | 2021-01-22 | 浙江金澜服饰有限公司 | Preparation method of anion health-care underwear |
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|---|---|---|---|---|
| CN206287618U (en) * | 2016-11-30 | 2017-06-30 | 海宁顺龙染整有限公司 | Far infrared underwear fabric |
| CN107083579A (en) * | 2017-06-07 | 2017-08-22 | 广州市中诚新型材料科技有限公司 | Anion, far infrared, antibiosis anti-acarien composite polyester fiber and its manufacture method |
| CN107123465A (en) * | 2017-06-07 | 2017-09-01 | 深圳众厉电力科技有限公司 | A kind of cable based on compound polyester functional fibre |
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2018
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Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN206287618U (en) * | 2016-11-30 | 2017-06-30 | 海宁顺龙染整有限公司 | Far infrared underwear fabric |
| CN107083579A (en) * | 2017-06-07 | 2017-08-22 | 广州市中诚新型材料科技有限公司 | Anion, far infrared, antibiosis anti-acarien composite polyester fiber and its manufacture method |
| CN107123465A (en) * | 2017-06-07 | 2017-09-01 | 深圳众厉电力科技有限公司 | A kind of cable based on compound polyester functional fibre |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN112252027A (en) * | 2020-10-28 | 2021-01-22 | 浙江金澜服饰有限公司 | Preparation method of anion health-care underwear |
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