CN108893983A - A kind of dedicated finishing agent of wool fabric and preparation method thereof - Google Patents
A kind of dedicated finishing agent of wool fabric and preparation method thereof Download PDFInfo
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- CN108893983A CN108893983A CN201810583558.5A CN201810583558A CN108893983A CN 108893983 A CN108893983 A CN 108893983A CN 201810583558 A CN201810583558 A CN 201810583558A CN 108893983 A CN108893983 A CN 108893983A
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/58—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with nitrogen or compounds thereof, e.g. with nitrides
- D06M11/67—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with nitrogen or compounds thereof, e.g. with nitrides with cyanogen or compounds thereof, e.g. with cyanhydric acid, cyanic acid, isocyanic acid, thiocyanic acid, isothiocyanic acid or their salts, or with cyanamides; with carbamic acid or its salts
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/144—Alcohols; Metal alcoholates
- D06M13/148—Polyalcohols, e.g. glycerol or glucose
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
- D06M13/188—Monocarboxylic acids; Anhydrides, halides or salts thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
- D06M13/2243—Mono-, di-, or triglycerides
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/46—Compounds containing quaternary nitrogen atoms
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/03—Polysaccharides or derivatives thereof
- D06M15/05—Cellulose or derivatives thereof
- D06M15/09—Cellulose ethers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/53—Polyethers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
- D06M15/6436—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain containing amino groups
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/10—Animal fibres
- D06M2101/12—Keratin fibres or silk
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/50—Modified hand or grip properties; Softening compositions
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention discloses a kind of dedicated finishing agents of wool fabric, are made of the raw material of following parts by weight：10-25 parts of polymethylacrylic acid, 5-10 parts of stearic acid, 5-20 parts of glycerol, 10-20 parts of polyethylene glycol, 2-8 parts of oleic acid monoglyceride, 2-10 parts of Zassol, 5-8 parts of amido silicon oil, 3-8 parts of Thioglycolic acid ammonium, 2-5 parts of hydroxypropyl methyl cellulose, 2-4 parts of hydrophilic surfactant active, 50-100 parts of water.The invention also discloses a kind of preparation methods of the dedicated finishing agent of wool fabric.Transglutaminase, amino silicone cooperation is added in the present invention in wool fabric antipilling finishing agent, significantly reduce the washing shrinkage of wool fiber, and prevent wool fabric yellowing, make gained soft while keeping wool strength simultaneously, it is smooth, soft glossy makes soft fabric, plentiful, well-pressed and flexible.
Description
Technical field
The present invention relates to technical field of textile auxiliary agent, the dedicated finishing agent of specifically a kind of wool fabric and its system
Preparation Method.
Background technique
Wool is a kind of widely used natural protein fibre, has soft touch, the spies such as elasticity is good, warmth retention property is good
Point.Wool cap is made by raw material of wool, is the daily necessity of people's Daily Level Readiness, can decorate, can sunshade, can
It is warming, it is loved by consumers.Pursuit with people to fashion, functional wool product increasingly liked by people and
Pro-gaze.Society gradually expands the demand of wool product in recent years, and the wool product occurred on domestic and international market is many kinds of,
Including knitting product, woolen fabrics and spun yarn product etc..Wherein pure wool shade fabric is naturally soft, good warmth retention effect, is production
The preferred fabric of high-grade suit and overcoat.But usually wool fabric is in the technical process such as weaving, preceding processing, several factors
Wool fabric may be made to become, and feel is coarse, and the soft feel of comfortable is decision of the customer when buying a textile
Property foundation, therefore, soft feel be considered as influence textile sales most important factor.But there are costs for current softener
High, the problems such as performance is single, submissive less effective.Therefore how overcome the deficiencies in the prior art is asking for this field urgent need to resolve
Topic.
Summary of the invention
In view of the defects and deficiencies of the prior art, the present invention intends to provide one kind to make soft fabric, plentiful, well-pressed
And flexible wool fabric soft finishing agent.
To achieve the above object, the technical solution adopted by the present invention is that：
A kind of dedicated finishing agent of wool fabric, is made of the raw material of following parts by weight：
10-25 parts of polymethylacrylic acid, 5-10 parts of stearic acid, 5-20 parts of glycerol, 10-20 parts of polyethylene glycol, oleic acid monoglyceride 2-8
Part, 2-10 parts of Zassol, 5-8 parts of amido silicon oil, 3-8 parts of Thioglycolic acid ammonium, 2-5 parts of hydroxypropyl methyl cellulose, hydrophily table
Activating agent 2-4 parts of face, 50-100 parts of water.
In preferably one embodiment of the invention, it is made of following component according to parts by weight：18 parts of polymethylacrylic acid,
8 parts of stearic acid, 15 parts of glycerol, 15 parts of polyethylene glycol, 5 parts of oleic acid monoglyceride, 6 parts of Zassol, 6 parts of amido silicon oil, Thioglycolic acid
5 parts of ammonium, 4 parts of hydroxypropyl methyl cellulose, 3 parts of hydrophilic surfactant active, 70 parts of water.
Preferably, the hydrophilic surfactant active is sodium alkyl benzene sulfonate, cetyl trimethylammonium bromide, poly- second two
The mixture of one or more of alcohol, carboxymethyl cellulose, polyvinylpyrrolidone.
Based on same purpose, the present invention also provides a kind of method for preparing the dedicated finishing agent of above-mentioned wool fabric, including：
Raw material is mixed and is poured into water, is heated to 50-55 DEG C, after being kept for 22-28 minutes, is continuously heating to 60-70 DEG C, stirring
30-40 minutes, cooled to room temperature obtained finished product.
Beneficial effects of the present invention are：
1, transglutaminase, amino silicone cooperation is added in the present invention in wool fabric antipilling finishing agent, is greatly reduced
The washing shrinkage of wool fiber, and wool fabric yellowing is prevented, while keeping gained feel soft keep wool strength while
Soft, smooth, soft glossy makes soft fabric, plentiful, well-pressed and flexible.
2, oleic acid monoglyceride, Zassol and amido silicon oil be joined in raw material of the invention, to play activation to wool
Effect improves the feel of wool fabric, ensure that the physical mechanical of wool fabric itself while improving the flexibility that wool is knitted
Performance improves the whiteness and wetability of wool fiber not by too much influence, assigns wool clothing excellent shrink resistance.
Specific embodiment
In order to make the objectives, technical solutions, and advantages of the present invention clearer, right below in conjunction with specific embodiment
The present invention is further elaborated.It should be appreciated that the specific embodiments described herein are only to explain the present invention, and
It is not used in the restriction present invention.
Embodiment 1
Raw material：10 parts of polymethylacrylic acid, 5 parts of stearic acid, 6 parts of glycerol, 12 parts of polyethylene glycol, 2 parts of oleic acid monoglyceride, Zassol
2 parts, 5 parts of amido silicon oil, 3 parts of Thioglycolic acid ammonium, 2 parts of hydroxypropyl methyl cellulose, 2 parts of hydrophilic surfactant active, 60 parts of water.
Raw material is mixed and is poured into water, is heated to 50 DEG C, after being kept for 22 minutes, 60 DEG C is continuously heating to, stirs 30 minutes,
Cooled to room temperature obtains finished product.
Embodiment 2
Raw material：18 parts of polymethylacrylic acid, 8 parts of stearic acid, 15 parts of glycerol, 15 parts of polyethylene glycol, 5 parts of oleic acid monoglyceride, cyanic acid
6 parts of sodium, 6 parts of amido silicon oil, 5 parts of Thioglycolic acid ammonium, 4 parts of hydroxypropyl methyl cellulose, 3 parts of hydrophilic surfactant active, water 70
Part.
Raw material is mixed and is poured into water, is heated to 53 DEG C, after being kept for 25 minutes, 65 DEG C is continuously heating to, stirs 35 minutes,
Cooled to room temperature obtains finished product.
Embodiment 3
Raw material：120 parts of polymethylacrylic acid, 10 parts of stearic acid, 20 parts of glycerol, 20 parts of polyethylene glycol, 7 parts of oleic acid monoglyceride, cyanogen
8 parts of sour sodium, 8 parts of amido silicon oil, 8 parts of Thioglycolic acid ammonium, 5 parts of hydroxypropyl methyl cellulose, 4 parts of hydrophilic surfactant active, water
100 parts.
Raw material is mixed and is poured into water, is heated to 55 DEG C, after being kept for 27 minutes, 70 DEG C is continuously heating to, stirs 40 minutes,
Cooled to room temperature obtains finished product.
The preparation process of the anti pilling sweater inorganic agent of present embodiment is：By the raw material in above-described embodiment according to
Certain proportion mixing, then after mixing evenly.
By the softening agent prepared in the embodiment of the present invention, treated that fabric is tested, and and untreated fabric（Comparison
Example）Wool fabric is compared respectively, by treated, wool fabric carries out performance detection, testing result such as the following table 1 institute
Show, thus to the performance for evaluating the dedicated finishing agent of the wool fabric.
Test method：
(1) wrinkle recovery angle of woven fabrics using viscoelasticity theory
By AATCC 66-2006 test method, using crease recovery angle tester M003A.
(2) boardness
By GB/T7689.4-2001 test method, using Stiffness Tester P50971520.
(3) Research in Fabric Shear
20cm × 20cm sample is taken, at 20 ± 2 DEG C of temperature, relative humidity uses KES-FB1 Fabric Hand Test under conditions of being 65 ± 2%
Cutting performance of the fabric under underload effect.
(4) Fabrics Bending Properties
20cm × 20cm sample is taken, is 20 ± 2 DEG C in temperature, relative humidity uses KES-FB2 style instrument under conditions of being 65 ± 2%
Bending property of the test fabric under underload effect.
Test result is as shown in table 1.
Table 1
In conclusion untreated fabric and the variation of the stiffness of treated fabric are bigger, the fabric softness that illustrates that treated
Better；Creasy recovery angle can characterize fabric elasticity, and creasy recovery angle is bigger, and the elasticity of fabric is better；Shearing rigidity characterization is knitted
The shearing rigidity of object softness, fabric is smaller, and softness is bigger；Bending stiffness characterize fabric softness, bending stiffness is smaller, fabric it is soft
It spends bigger.
From the point of view of table 1, treated that soft fabric performance is good for the dedicated finishing agent of wool fabric prepared by the present invention, elasticity
Greatly.
The dedicated finishing agent of wool fabric produced by the present invention has preferable holding wool strongly and soft in fabric
Effect, the feel using rear fabric is preferable, and prevents wool fabric yellowing, while making institute while keeping wool strength
Soft, smooth, soft glossy, make soft fabric, plentiful, well-pressed and flexible.
In addition, it should be understood that although this specification is described in terms of embodiments, but not each embodiment is only wrapped
Containing an independent technical solution, this description of the specification is merely for the sake of clarity, and those skilled in the art should
It considers the specification as a whole, the technical solutions in the various embodiments may also be suitably combined, forms those skilled in the art
The other embodiments being understood that.
Claims (4)
1. a kind of dedicated finishing agent of wool fabric, which is characterized in that be made of the raw material of following parts by weight：
10-25 parts of polymethylacrylic acid, 5-10 parts of stearic acid, 5-20 parts of glycerol, 10-20 parts of polyethylene glycol, oleic acid monoglyceride 2-8
Part, 2-10 parts of Zassol, 5-8 parts of amido silicon oil, 3-8 parts of Thioglycolic acid ammonium, 2-5 parts of hydroxypropyl methyl cellulose, hydrophily table
Activating agent 2-4 parts of face, 50-100 parts of water.
2. the dedicated finishing agent of a kind of wool fabric according to claim 1, it is characterised in that：By following component according to weight
Part composition：18 parts of polymethylacrylic acid, 8 parts of stearic acid, 15 parts of glycerol, 15 parts of polyethylene glycol, 5 parts of oleic acid monoglyceride, Zassol 6
Part, 6 parts of amido silicon oil, 5 parts of Thioglycolic acid ammonium, 4 parts of hydroxypropyl methyl cellulose, 3 parts of hydrophilic surfactant active, 70 parts of water.
3. the dedicated finishing agent of a kind of wool fabric according to claim 1, it is characterised in that：The hydrophilic surfactant
Agent is sodium alkyl benzene sulfonate, in cetyl trimethylammonium bromide, polyethylene glycol, carboxymethyl cellulose, polyvinylpyrrolidone
One or more kinds of mixtures.
4. a kind of preparation method of the dedicated finishing agent of wool fabric, including：
Raw material is mixed and is poured into water, is heated to 50-55 DEG C, after being kept for 22-28 minutes, is continuously heating to 60-70 DEG C, stirring
30-40 minutes, cooled to room temperature obtained finished product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810583558.5A CN108893983A (en) | 2018-06-08 | 2018-06-08 | A kind of dedicated finishing agent of wool fabric and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810583558.5A CN108893983A (en) | 2018-06-08 | 2018-06-08 | A kind of dedicated finishing agent of wool fabric and preparation method thereof |
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| Publication Number | Publication Date |
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| CN108893983A true CN108893983A (en) | 2018-11-27 |
Family
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| CN201810583558.5A Pending CN108893983A (en) | 2018-06-08 | 2018-06-08 | A kind of dedicated finishing agent of wool fabric and preparation method thereof |
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103422344A (en) * | 2013-08-02 | 2013-12-04 | 吴江市七都镇庙港雅迪针织制衣厂 | Pilling-resistant shrinkage-resistant woolen sweater treating agent with microcrystalline wax |
| CN104088141A (en) * | 2014-06-18 | 2014-10-08 | 桐乡市濮院毛针织技术服务中心 | Wool anti-pilling auxiliary agent |
| CN105671969A (en) * | 2016-01-25 | 2016-06-15 | 苏州印丝特纺织数码科技有限公司 | Modified siloxane softening agent for spinning and preparation method of modified siloxane softening agent for spinning |
| CN107227618A (en) * | 2017-06-28 | 2017-10-03 | 常州美帛纺织品有限公司 | A kind of wool fabric antipilling finishing agent |
| CN107829295A (en) * | 2017-11-30 | 2018-03-23 | 安徽中福毛纺制帽有限公司 | A kind of special antibacterial and mouldproof finishing agent of wool cap |
-
2018
- 2018-06-08 CN CN201810583558.5A patent/CN108893983A/en active Pending
Patent Citations (5)
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| CN104088141A (en) * | 2014-06-18 | 2014-10-08 | 桐乡市濮院毛针织技术服务中心 | Wool anti-pilling auxiliary agent |
| CN105671969A (en) * | 2016-01-25 | 2016-06-15 | 苏州印丝特纺织数码科技有限公司 | Modified siloxane softening agent for spinning and preparation method of modified siloxane softening agent for spinning |
| CN107227618A (en) * | 2017-06-28 | 2017-10-03 | 常州美帛纺织品有限公司 | A kind of wool fabric antipilling finishing agent |
| CN107829295A (en) * | 2017-11-30 | 2018-03-23 | 安徽中福毛纺制帽有限公司 | A kind of special antibacterial and mouldproof finishing agent of wool cap |
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Application publication date: 20181127 |