CN108893181A - A kind of preparation method of the antirust oil of high-strength corrosion-resisting - Google Patents
A kind of preparation method of the antirust oil of high-strength corrosion-resisting Download PDFInfo
- Publication number
- CN108893181A CN108893181A CN201810924132.1A CN201810924132A CN108893181A CN 108893181 A CN108893181 A CN 108893181A CN 201810924132 A CN201810924132 A CN 201810924132A CN 108893181 A CN108893181 A CN 108893181A
- Authority
- CN
- China
- Prior art keywords
- parts
- ester
- oil
- resisting
- antirust
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
- C10M169/04—Mixtures of base-materials and additives
- C10M169/044—Mixtures of base-materials and additives the additives being a mixture of non-macromolecular and macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
- C10M2205/0206—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers used as base material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/02—Hydroxy compounds
- C10M2207/023—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
- C10M2207/026—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings with tertiary alkyl groups
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
- C10M2207/127—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids polycarboxylic
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/282—Esters of (cyclo)aliphatic oolycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/283—Esters of polyhydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/285—Esters of aromatic polycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/40—Fatty vegetable or animal oils
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
- C10M2209/104—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing two carbon atoms only
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2211/00—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions
- C10M2211/04—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions containing carbon, hydrogen, halogen, and oxygen
- C10M2211/042—Alcohols; Ethers; Aldehydes; Ketones
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
- C10M2219/044—Sulfonic acids, Derivatives thereof, e.g. neutral salts
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
- C10M2223/04—Phosphate esters
- C10M2223/045—Metal containing thio derivatives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2010/00—Metal present as such or in compounds
- C10N2010/04—Groups 2 or 12
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/12—Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Preventing Corrosion Or Incrustation Of Metals (AREA)
Abstract
The present invention relates to antirust oil technical fields, and disclose a kind of preparation method of the antirust oil of high-strength corrosion-resisting, the raw material including following parts by weight proportion：The poly alpha olefin that 50-75 parts of base oil, 10-15 parts of lanolin, 3-4 parts of dodecenylsuccinic acid ester, 1-3 parts of 2,6-di-tert-butyl p-cresol, 3-5 parts of 3- fluoro- 4- methoxyl group benzyl chloride, polyethylene glycol 400 is 1-3 parts, 1-3 parts of fatty acid pentaerythritol ester, 2-3 parts of alkenyl azelaic acid, molecular weight is 1-3 parts of chitosan of 15-25 ten thousand, 1-2 parts of barium mahogany sulfonate, 2-3 parts of triethanolamine oleate, 4-5 parts of o-phthalic acid dibutyl ester and 1-3 parts of zinc dialkyl dithiophosphate.By adding a variety of rust-inhibiting additives and its auxiliary additive composition, it is low in cost, effect is good, it is easy to operate, Investment in fastener industry can be used largely, and the antirust oil organic stability as made from this method is good, and corrosion test and salt water immersion test are all qualified, damp heat test can reach 50 days or more, and the antirust period can reach 30 days or more.
Description
Technical field
The present invention relates to antirust oil technical field, specially a kind of preparation method of the antirust oil of high-strength corrosion-resisting.
Background technique
Antirust oil, which is a appearance, has the oil solvent of antirust function in bronzing, by oil-soluble inhibitor, base oil and
The composition such as auxiliary additive, according to performance and purposes, the oil that derusts can be divided into fingerprint removing type antirust oil, water dilution type antirust oil,
The dual-purpose oil of solvent cutback rust preventing oil, anti-rust and lubrication, sealed anti-rust oil, displacing type rust preventive oil, thin layer oil, antirust grease and gas phase are anti-
Become rusty oil etc., and common corrosion inhibiter has alkali salt, lead naphthenate, zinc naphthenate, the stone of fatty acid or aphthenic acids in antirust oil
Oily sodium sulfonate, barium mahogany sulfonate, calcium mahogany sulfonate, three oleic acid tallow diamines and rosin amine etc..
Corrosion is one of the principal mode for destroying fastener, can be made to automobile, motorcycle and various vehicles and machinery
At very big loss, according to statistics, the direct economic loss due to caused by metal erosion accounts for about total value of production in national economy every year
2%~4%, to avoid corroding and reduce loss, people use various methods, protect metal with anti-corrosive grease
Fastener is one of current most common means of defence, however the most Acceptable life of antirust oil currently on the market is not
Long and intensity is lower, and user needs to be replaced frequently antirust oil, not only to the certain injury of metal fastenings band, also causes to need
The economy and leeway that often replace and generate.
To a kind of preparation method of 106520286 A of this Chinese patent CN quick-dry type antirust oil proposed, the preparation method
By will dry the lemon grass (Cymbopogon citratus) cauline leaf particle after milling and deionized water heating stirring, refine lemon grass (Cymbopogon citratus) essential oil, then take alkylol,
After the water-baths such as ketene dimer, with being mixed after lye tune its pH, filtering, concentration with lemon grass (Cymbopogon citratus) essential oil and ultrasonic wave dispersion, old
Change, be added after the auxiliary materials oil bath such as vaseline up to a kind of quick-dry type antirust oil, antirust oil intensity obtained by the method it is low and because
It being easy to fall off for drying, the effect of corrosion resistant is not fine, so propose a kind of preparation of the antirust oil of high-strength corrosion-resisting
Method is to solve the above problems.
Summary of the invention
(1) the technical issues of solving
In view of the deficiencies of the prior art, the present invention provides a kind of preparation method of the antirust oil of high-strength corrosion-resisting, tools
Standby intensity is higher and more corrosion resistant advantage, the most Acceptable life of antirust oil solved currently on the market be not long and strong
Spend lower, user needs to be replaced frequently antirust oil, not only to the certain injury of metal fastenings band, also results in the need for often
Replacement and the economy that generates and the problem of the problem of leeway.
(2) technical solution
To realize that above-mentioned intensity is higher and more corrosion resistant purpose, the present invention provide the following technical solutions：It is a kind of high-strength
Corrosion resistant antirust oil is spent, the raw material including following parts by weight proportion：The poly alpha olefin that 50-75 parts of base oil, lanolin
10-15 parts, 3-4 parts of dodecenylsuccinic acid ester, 1-3 parts of 2,6-di-tert-butyl p-cresol, 3-5 parts of 3- fluoro- 4- methoxyl group benzyl chloride,
Polyethylene glycol 400 is 1-3 parts, and 1-3 parts of fatty acid pentaerythritol ester, 2-3 parts of alkenyl azelaic acid, molecular weight is the shell of 15-25 ten thousand
1-3 parts of glycan, 1-2 parts of barium mahogany sulfonate, 2-3 parts of triethanolamine oleate, 4-5 parts of o-phthalic acid dibutyl ester and dialkyl disulfides
For 1-3 parts of trbasic zinc phosphate.
Preferably, the poly alpha olefin of 50 parts of the base oil, 10-15 parts of lanolin, 3-4 parts of dodecenylsuccinic acid ester,
1-3 parts of 2,6-di-tert-butyl p-cresol, 3-5 parts of 3- fluoro- 4- methoxyl group benzyl chloride, polyethylene glycol 400 is 1-3 parts, fatty acid season penta
Four 1-3 parts of alcohol esters, 2-3 parts of alkenyl azelaic acid, molecular weight is 1-3 parts of chitosan of 15-25 ten thousand, 1-2 parts of barium mahogany sulfonate, oleic acid
2-3 parts of triethanolamine, 4-5 parts of o-phthalic acid dibutyl ester and 1-3 parts of zinc dialkyl dithiophosphate.
Preferably, the poly alpha olefin of 65 parts of the base oil, 10-15 parts of lanolin, 3-4 parts of dodecenylsuccinic acid ester,
1-3 parts of 2,6-di-tert-butyl p-cresol, 3-5 parts of 3- fluoro- 4- methoxyl group benzyl chloride, polyethylene glycol 400 is 1-3 parts, fatty acid season penta
Four 1-3 parts of alcohol esters, 2-3 parts of alkenyl azelaic acid, molecular weight is 1-3 parts of chitosan of 15-25 ten thousand, 1-2 parts of barium mahogany sulfonate, oleic acid
2-3 parts of triethanolamine, 4-5 parts of o-phthalic acid dibutyl ester and 1-3 parts of zinc dialkyl dithiophosphate.
Preferably, the poly alpha olefin of 75 parts of the base oil, 10-15 parts of lanolin, 3-4 parts of dodecenylsuccinic acid ester,
1-3 parts of 2,6-di-tert-butyl p-cresol, 3-5 parts of 3- fluoro- 4- methoxyl group benzyl chloride, polyethylene glycol 400 is 1-3 parts, fatty acid season penta
Four 1-3 parts of alcohol esters, 2-3 parts of alkenyl azelaic acid, molecular weight is 1-3 parts of chitosan of 15-25 ten thousand, 1-2 parts of barium mahogany sulfonate, oleic acid
2-3 parts of triethanolamine, 4-5 parts of o-phthalic acid dibutyl ester and 1-3 parts of zinc dialkyl dithiophosphate.
Another technical problem to be solved by the present invention is that providing a kind of preparation method of the antirust oil of high-strength corrosion-resisting, wrap
Include following steps：
1) weighing base oil is 50-75 parts of poly alpha olefins, and the base oil of this number is put into conical flask, then logical
Enter nitrogen air is discharged, conical flask be subjected to heating water bath in the environment of nitrogen is full of in flask, and be heated to 90 DEG C,
Heat 65~75min.
2) lanolin 10-15 parts is then added into conical flask to continue to be warming up to 90 DEG C with heating water bath, heat 60~
70min, after 3-4 parts of dodecenylsuccinic acid ester and polyethylene glycol 400 is added into conical flask at this temperature, heat preservation
Then 20min places room temperature and cools to 40 DEG C.
3) in parts by weight, weigh 2,6-di-tert-butyl p-cresol 1-3 parts, the fluoro- 4- methoxyl group benzyl chloride 3-5 of 3- respectively
Part, polyethylene glycol 400 are 1-3 parts, 1-3 parts of fatty acid pentaerythritol ester, 2-3 parts of alkenyl azelaic acid, barium mahogany sulfonate 1-2, oil
Triethylenetetraminehexaacetic acid hydramine 2-3, o-phthalic acid dibutyl ester 4-5 and zinc dialkyl dithiophosphate 1-3, and by above-mentioned with being added to triangle
It is cooling to place at room temperature and after uniform stirring in beaker, 10~15min of ultrasonic wave decentralized processing at 200~300W.
4) in parts by weight, weighing molecular weight is 1-3 parts of ten thousand chitosan of 15-25, and adds it to conical beaker
In, 10~15min of oil bath heating at 120~125 DEG C then stops heating and is cooled to 70~75 DEG C straight, insulated and stirred
It stands and is cooled to room temperature after 30min, it is then degassed and finished product is obtained by filtration.
5) first metal works are integrally put into deionized water completely, and washing 100 under the ultrasonic wave of 200~300W
~13min is immersed in 1~3min in the antirust oil of high-strength corrosion-resisting produced by the present invention, and leads to after drying metal works
It crosses and allows metal bow and arrow uniformly to impregnate with handshaking, then place with centrifuge, dried at room temperature, it is organic through detecting
It has good stability, corrosion test and salt water immersion test are all qualified, and damp heat test can reach 50 days or more, and the antirust period can reach
By 30 days or more.
(3) beneficial effect
Compared with prior art, the present invention provides a kind of preparation method of the antirust oil of high-strength corrosion-resisting, have with
Lower beneficial effect：
1, the preparation method of the antirust oil of the high-strength corrosion-resisting is added by adding a variety of rust-inhibiting additives and its auxiliary
Agent composition, easy to use, low in cost, effect is good, and easy to operate, Investment in fastener industry can be used largely.
2, the preparation method of the antirust oil of the high-strength corrosion-resisting, the antirust oil organic stability as made from this method are good
Good, corrosion test and salt water immersion test are all qualified, and damp heat test can reach 50 days or more, the antirust period can reach 30 days with
On.
Specific embodiment
Below in conjunction with the embodiment of the present invention, technical solution in the embodiment of the present invention is clearly and completely retouched
It states, it is clear that described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.Based on the present invention
In embodiment, every other implementation obtained by those of ordinary skill in the art without making creative efforts
Example, shall fall within the protection scope of the present invention.
Embodiment one：
A kind of antirust oil of high-strength corrosion-resisting, the raw material including following parts by weight proportion：50 parts of base oil of poly- α-
Alkene, 10-15 parts of lanolin, 3-4 parts of dodecenylsuccinic acid ester, 1-3 parts of 2,6-di-tert-butyl p-cresol, the fluoro- 4- methoxy of 3-
3-5 parts of base benzyl chloride, polyethylene glycol 400 is 1-3 parts, and 1-3 parts of fatty acid pentaerythritol ester, 2-3 parts of alkenyl azelaic acid, molecular weight is
1-3 parts of the chitosan of 15-25 ten thousand, 1-2 parts of barium mahogany sulfonate, 2-3 parts of triethanolamine oleate, 4-5 parts of o-phthalic acid dibutyl ester
With 1-3 parts of zinc dialkyl dithiophosphate.
A kind of preparation method of the antirust oil of high-strength corrosion-resisting, includes the following steps：
1) a kind of preparation method of the antirust oil of high-strength corrosion-resisting, the weighing base oil are 50 parts of poly alpha olefins, will
The base oil of this number is put into conical flask, is subsequently passed nitrogen and air is discharged, in the environment of nitrogen is full of in flask
Conical flask is subjected to heating water bath, and is heated to 90 DEG C, heats 65~75min.
2) lanolin 10-15 parts is then added into conical flask to continue to be warming up to 90 DEG C with heating water bath, heat 60~
70min, after 3-4 parts of dodecenylsuccinic acid ester and polyethylene glycol 400 is added into conical flask at this temperature, heat preservation
Then 20min places room temperature and cools to 40 DEG C.
3) in parts by weight, weigh 2,6-di-tert-butyl p-cresol 1-3 parts, the fluoro- 4- methoxyl group benzyl chloride 3-5 of 3- respectively
Part, polyethylene glycol 400 are 1-3 parts, 1-3 parts of fatty acid pentaerythritol ester, 2-3 parts of alkenyl azelaic acid, barium mahogany sulfonate 1-2, oil
Triethylenetetraminehexaacetic acid hydramine 2-3, o-phthalic acid dibutyl ester 4-5 and zinc dialkyl dithiophosphate 1-3, and by above-mentioned with being added to triangle
It is cooling to place at room temperature and after uniform stirring in beaker, 10~15min of ultrasonic wave decentralized processing at 200~300W.
4) in parts by weight, weighing molecular weight is 1-3 parts of ten thousand chitosan of 15-25, and adds it to conical beaker
In, 10~15min of oil bath heating at 120~125 DEG C then stops heating and is cooled to 70~75 DEG C straight, insulated and stirred
It stands and is cooled to room temperature after 30min, it is then degassed and finished product is obtained by filtration.
5) first metal works are integrally put into deionized water completely, and washing 100 under the ultrasonic wave of 200~300W
~13min is immersed in 1~3min in the antirust oil of high-strength corrosion-resisting produced by the present invention, and leads to after drying metal works
It crosses and allows metal bow and arrow uniformly to impregnate with handshaking, then place with centrifuge, dried at room temperature, it is organic through detecting
It has good stability, corrosion test and salt water immersion test are all qualified, and damp heat test can reach 50 days, and the antirust period can reach 30
It.
Embodiment two：
A kind of antirust oil of high-strength corrosion-resisting, the raw material including following parts by weight proportion：65 parts of base oil of poly- α-
Alkene, 10-15 parts of lanolin, 3-4 parts of dodecenylsuccinic acid ester, 1-3 parts of 2,6-di-tert-butyl p-cresol, the fluoro- 4- methoxy of 3-
3-5 parts of base benzyl chloride, polyethylene glycol 400 is 1-3 parts, and 1-3 parts of fatty acid pentaerythritol ester, 2-3 parts of alkenyl azelaic acid, molecular weight is
1-3 parts of the chitosan of 15-25 ten thousand, 1-2 parts of barium mahogany sulfonate, 2-3 parts of triethanolamine oleate, 4-5 parts of o-phthalic acid dibutyl ester
With 1-3 parts of zinc dialkyl dithiophosphate.
A kind of preparation method of the antirust oil of high-strength corrosion-resisting, includes the following steps：
1) a kind of preparation method of the antirust oil of high-strength corrosion-resisting, the weighing base oil are 65 parts of poly alpha olefins, will
The base oil of this number is put into conical flask, is subsequently passed nitrogen and air is discharged, in the environment of nitrogen is full of in flask
Conical flask is subjected to heating water bath, and is heated to 90 DEG C, heats 65~75min.
2) lanolin 10-15 parts is then added into conical flask to continue to be warming up to 90 DEG C with heating water bath, heat 60~
70min, after 3-4 parts of dodecenylsuccinic acid ester and polyethylene glycol 400 is added into conical flask at this temperature, heat preservation
Then 20min places room temperature and cools to 40 DEG C.
3) in parts by weight, weigh 2,6-di-tert-butyl p-cresol 1-3 parts, the fluoro- 4- methoxyl group benzyl chloride 3-5 of 3- respectively
Part, polyethylene glycol 400 are 1-3 parts, 1-3 parts of fatty acid pentaerythritol ester, 2-3 parts of alkenyl azelaic acid, barium mahogany sulfonate 1-2, oil
Triethylenetetraminehexaacetic acid hydramine 2-3, o-phthalic acid dibutyl ester 4-5 and zinc dialkyl dithiophosphate 1-3, and by above-mentioned with being added to triangle
It is cooling to place at room temperature and after uniform stirring in beaker, 10~15min of ultrasonic wave decentralized processing at 200~300W.
4) in parts by weight, weighing molecular weight is 1-3 parts of ten thousand chitosan of 15-25, and adds it to conical beaker
In, 10~15min of oil bath heating at 120~125 DEG C then stops heating and is cooled to 70~75 DEG C straight, insulated and stirred
It stands and is cooled to room temperature after 30min, it is then degassed and finished product is obtained by filtration.
5) first metal works are integrally put into deionized water completely, and washing 100 under the ultrasonic wave of 200~300W
~13min is immersed in 1~3min in the antirust oil of high-strength corrosion-resisting produced by the present invention, and leads to after drying metal works
It crosses and allows metal bow and arrow uniformly to impregnate with handshaking, then place with centrifuge, dried at room temperature, it is organic through detecting
It has good stability, corrosion test and salt water immersion test are all qualified, and damp heat test can reach 55 days, and the antirust period can reach 35
It.
Embodiment three：
A kind of antirust oil of high-strength corrosion-resisting, the raw material including following parts by weight proportion：75 parts of base oil of poly- α-
Alkene, 10-15 parts of lanolin, 3-4 parts of dodecenylsuccinic acid ester, 1-3 parts of 2,6-di-tert-butyl p-cresol, the fluoro- 4- methoxy of 3-
3-5 parts of base benzyl chloride, polyethylene glycol 400 is 1-3 parts, and 1-3 parts of fatty acid pentaerythritol ester, 2-3 parts of alkenyl azelaic acid, molecular weight is
1-3 parts of the chitosan of 15-25 ten thousand, 1-2 parts of barium mahogany sulfonate, 2-3 parts of triethanolamine oleate, 4-5 parts of o-phthalic acid dibutyl ester
With 1-3 parts of zinc dialkyl dithiophosphate.
A kind of preparation method of the antirust oil of high-strength corrosion-resisting, includes the following steps：
1) a kind of preparation method of the antirust oil of high-strength corrosion-resisting, the weighing base oil are 75 parts of poly alpha olefins, will
The base oil of this number is put into conical flask, is subsequently passed nitrogen and air is discharged, in the environment of nitrogen is full of in flask
Conical flask is subjected to heating water bath, and is heated to 90 DEG C, heats 65~75min.
2) lanolin 10-15 parts is then added into conical flask to continue to be warming up to 90 DEG C with heating water bath, heat 60~
70min, after 3-4 parts of dodecenylsuccinic acid ester and polyethylene glycol 400 is added into conical flask at this temperature, heat preservation
Then 20min places room temperature and cools to 40 DEG C.
3) in parts by weight, weigh 2,6-di-tert-butyl p-cresol 1-3 parts, the fluoro- 4- methoxyl group benzyl chloride 3-5 of 3- respectively
Part, polyethylene glycol 400 are 1-3 parts, 1-3 parts of fatty acid pentaerythritol ester, 2-3 parts of alkenyl azelaic acid, barium mahogany sulfonate 1-2, oil
Triethylenetetraminehexaacetic acid hydramine 2-3, o-phthalic acid dibutyl ester 4-5 and zinc dialkyl dithiophosphate 1-3, and by above-mentioned with being added to triangle
It is cooling to place at room temperature and after uniform stirring in beaker, 10~15min of ultrasonic wave decentralized processing at 200~300W.
4) in parts by weight, weighing molecular weight is 1-3 parts of ten thousand chitosan of 15-25, and adds it to conical beaker
In, 10~15min of oil bath heating at 120~125 DEG C then stops heating and is cooled to 70~75 DEG C straight, insulated and stirred
It stands and is cooled to room temperature after 30min, it is then degassed and finished product is obtained by filtration.
5) first metal works are integrally put into deionized water completely, and washing 100 under the ultrasonic wave of 200~300W
~13min is immersed in 1~3min in the antirust oil of high-strength corrosion-resisting produced by the present invention, and leads to after drying metal works
It crosses and allows metal bow and arrow uniformly to impregnate with handshaking, then place with centrifuge, dried at room temperature, it is organic through detecting
It has good stability, corrosion test and salt water immersion test are all qualified, and damp heat test can reach 58 days, and the antirust period can reach 39
It.
The beneficial effects of the invention are as follows：By adding a variety of rust-inhibiting additives and its auxiliary additive composition, its user
Just, low in cost, effect is good, easy to operate, and Investment in fastener industry can be used largely, and the antirust oil as made from this method is organic steady
Qualitative good, corrosion test and salt water immersion test are all qualified, and damp heat test can reach 50 days or more, and the antirust period can reach
30 days or more.
It although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with
A variety of variations, modification, replacement can be carried out to these embodiments without departing from the principles and spirit of the present invention by understanding
And modification, the scope of the present invention is defined by the appended.
Claims (5)
1. a kind of antirust oil of high-strength corrosion-resisting, which is characterized in that the raw material including following parts by weight proportion：Base oil
50-75 parts of poly alpha olefin, 10-15 parts of lanolin, 3-4 parts of dodecenylsuccinic acid ester, 2,6-di-tert-butyl p-cresol 1-3
Part, 3-5 part of 3- fluoro- 4- methoxyl group benzyl chloride, polyethylene glycol 400 be 1-3 parts, 1-3 parts of fatty acid pentaerythritol ester, alkenyl azelaic acid
2-3 parts, molecular weight is 1-3 parts of chitosan of 15-25 ten thousand, 1-2 parts of barium mahogany sulfonate, 2-3 parts of triethanolamine oleate, O-phthalic
Sour dibutyl ester 4-5 parts and zinc dialkyl dithiophosphate 1-3 parts.
2. a kind of antirust oil of high-strength corrosion-resisting, which is characterized in that the poly alpha olefin of 50 parts of the base oil, lanolin 10-
15 parts, 3-4 parts of dodecenylsuccinic acid ester, 1-3 parts of 2,6-di-tert-butyl p-cresol, 3-5 parts of 3- fluoro- 4- methoxyl group benzyl chloride is gathered
Ethylene glycol 400 is 1-3 parts, and 1-3 parts of fatty acid pentaerythritol ester, 2-3 parts of alkenyl azelaic acid, the shell that molecular weight is 15-25 ten thousand is poly-
It is 1-3 parts sugared, 1-2 parts of barium mahogany sulfonate, 2-3 parts of triethanolamine oleate, 4-5 parts of o-phthalic acid dibutyl ester and dialkyl dithio
1-3 parts of trbasic zinc phosphate.
3. a kind of antirust oil of high-strength corrosion-resisting, which is characterized in that the poly alpha olefin of 65 parts of the base oil, lanolin 10-
15 parts, 3-4 parts of dodecenylsuccinic acid ester, 1-3 parts of 2,6-di-tert-butyl p-cresol, 3-5 parts of 3- fluoro- 4- methoxyl group benzyl chloride is gathered
Ethylene glycol 400 is 1-3 parts, and 1-3 parts of fatty acid pentaerythritol ester, 2-3 parts of alkenyl azelaic acid, the shell that molecular weight is 15-25 ten thousand is poly-
It is 1-3 parts sugared, 1-2 parts of barium mahogany sulfonate, 2-3 parts of triethanolamine oleate, 4-5 parts of o-phthalic acid dibutyl ester and dialkyl dithio
1-3 parts of trbasic zinc phosphate.
4. a kind of antirust oil of high-strength corrosion-resisting, which is characterized in that the poly alpha olefin of 75 parts of the base oil, lanolin 10-
15 parts, 3-4 parts of dodecenylsuccinic acid ester, 1-3 parts of 2,6-di-tert-butyl p-cresol, 3-5 parts of 3- fluoro- 4- methoxyl group benzyl chloride is gathered
Ethylene glycol 400 is 1-3 parts, and 1-3 parts of fatty acid pentaerythritol ester, 2-3 parts of alkenyl azelaic acid, the shell that molecular weight is 15-25 ten thousand is poly-
It is 1-3 parts sugared, 1-2 parts of barium mahogany sulfonate, 2-3 parts of triethanolamine oleate, 4-5 parts of o-phthalic acid dibutyl ester and dialkyl dithio
1-3 parts of trbasic zinc phosphate.
5. a kind of preparation method of the antirust oil of high-strength corrosion-resisting, which is characterized in that include the following steps：
1) a kind of preparation method of the antirust oil of high-strength corrosion-resisting, which is characterized in that the weighing base oil is 50-75 parts poly-
The base oil of this number is put into conical flask by alpha-olefin, is subsequently passed nitrogen and air is discharged, and nitrogen is full of in flask
Conical flask is subjected to heating water bath in the environment of gas, and is heated to 90 DEG C, heats 65~75min.
2) lanolin 10-15 parts is then added into conical flask to continue to be warming up to 90 DEG C with heating water bath, heat 60~
70min, after 3-4 parts of dodecenylsuccinic acid ester and polyethylene glycol 400 is added into conical flask at this temperature, heat preservation
Then 20min places room temperature and cools to 40 DEG C.
3) in parts by weight, respectively weigh 2,6-di-tert-butyl p-cresol 1-3 parts, 3-5 parts of 3- fluoro- 4- methoxyl group benzyl chloride,
Polyethylene glycol 400 is 1-3 parts, 1-3 parts of fatty acid pentaerythritol ester, 2-3 parts of alkenyl azelaic acid, barium mahogany sulfonate 1-2, oleic acid three
Ethanol amine 2-3, o-phthalic acid dibutyl ester 4-5 and zinc dialkyl dithiophosphate 1-3, and by above-mentioned with being added to conical beaker
In, cooling to place at room temperature and after uniform stirring, 10~15min of ultrasonic wave decentralized processing at 200~300W.
4) in parts by weight, weighing molecular weight is 1-3 parts of ten thousand chitosan of 15-25, and is added it in conical beaker,
10~15min of oil bath heating at 120~125 DEG C then stops heating and is cooled to 70~75 DEG C straight, insulated and stirred 30min
It stands and is cooled to room temperature afterwards, it is then degassed and finished product is obtained by filtration.
5) first metal works are integrally put into deionized water completely, and washing 100 under the ultrasonic wave of 200~300W~
13min is immersed in 1~3min in the antirust oil of high-strength corrosion-resisting produced by the present invention, and passes through after drying metal works
It allows metal bow and arrow uniformly to impregnate with handshaking, then places with centrifuge, dried at room temperature, through detecting, You Jiwen
Qualitative good, corrosion test and salt water immersion test are all qualified, and damp heat test can reach 50 days or more, and the antirust period can reach
30 days or more.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810924132.1A CN108893181A (en) | 2018-08-14 | 2018-08-14 | A kind of preparation method of the antirust oil of high-strength corrosion-resisting |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810924132.1A CN108893181A (en) | 2018-08-14 | 2018-08-14 | A kind of preparation method of the antirust oil of high-strength corrosion-resisting |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108893181A true CN108893181A (en) | 2018-11-27 |
Family
ID=64354448
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810924132.1A Pending CN108893181A (en) | 2018-08-14 | 2018-08-14 | A kind of preparation method of the antirust oil of high-strength corrosion-resisting |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108893181A (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103254978A (en) * | 2013-04-16 | 2013-08-21 | 马鞍山采石矶涂料有限公司 | Anti-rust oil and preparation method thereof |
| CN106520286A (en) * | 2016-10-13 | 2017-03-22 | 常州创索新材料科技有限公司 | Preparation method for quick-drying antirust oil |
| CN106590859A (en) * | 2016-11-02 | 2017-04-26 | 山东滑孚石化有限公司 | Antirust oil and preparation method of same |
| CN107603694A (en) * | 2017-09-04 | 2018-01-19 | 吴江华威特种油有限公司 | A kind of antirust oil and preparation method thereof |
-
2018
- 2018-08-14 CN CN201810924132.1A patent/CN108893181A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103254978A (en) * | 2013-04-16 | 2013-08-21 | 马鞍山采石矶涂料有限公司 | Anti-rust oil and preparation method thereof |
| CN106520286A (en) * | 2016-10-13 | 2017-03-22 | 常州创索新材料科技有限公司 | Preparation method for quick-drying antirust oil |
| CN106590859A (en) * | 2016-11-02 | 2017-04-26 | 山东滑孚石化有限公司 | Antirust oil and preparation method of same |
| CN107603694A (en) * | 2017-09-04 | 2018-01-19 | 吴江华威特种油有限公司 | A kind of antirust oil and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US2224695A (en) | Inhibitor | |
| CN103980994A (en) | Anti-rust oil having high resistance to damp-heat | |
| CN104004573A (en) | Antirust oil for engine seal | |
| CN102585781A (en) | Environment-friendly engine trying liquid | |
| CN108659708B (en) | Metal antirust agent meeting spraying adhesion and preparation method thereof | |
| CN107663471A (en) | A kind of high capability of anti-salt mist solvent cutback rust preventing oil and preparation method thereof | |
| CN103980998A (en) | Gas-phase rust preventive oil | |
| CN103468350B (en) | Phosphated metal rust-proof oil and preparation method thereof | |
| CN108893181A (en) | A kind of preparation method of the antirust oil of high-strength corrosion-resisting | |
| CN102839037B (en) | Water replacement type anti-emulsifying oil soluble corrosion inhibitor | |
| CN103992845A (en) | Corrosion resistant antirust oil | |
| CN109054977B (en) | Graphene cutting fluid and preparation method thereof | |
| CN105349228A (en) | Corrosion-resistant rust-proof oil for metal workpieces | |
| CN103992857B (en) | One is quick-drying stablizes antirust oil | |
| CN103695885A (en) | Preparation method of oil-removing and rust-removing two-in-one treating agent | |
| CN108640301A (en) | A kind of chemical field anti-incrustation corrosion inhibitor and its preparation process | |
| US2191435A (en) | Bearing member | |
| CN103992840A (en) | Corrosion-resistant antirust oil | |
| CN106835145A (en) | A kind of yellow fume-free aluminium alloy chemical polishing solution without nitric acid and preparation method thereof | |
| CN107059017A (en) | A kind of highly effective antirust liquid and its synthesis technique | |
| CN103992859A (en) | Bacteriostatic antirust oil | |
| CN103980996A (en) | Quick-drying hard film rust-preventive oil | |
| CN105297027A (en) | Metal surface corrosion-resistant protective agent and preparation method thereof | |
| CN105297028A (en) | Aluminum alloy surface anticorrosive protective agent and anticorrosive method | |
| CN105239063A (en) | Aluminum alloy corrosion-resistant protective agent and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20181127 |