CN108892999A - UV ink-jet ink of low viscosity quick solidifying and preparation method thereof - Google Patents
UV ink-jet ink of low viscosity quick solidifying and preparation method thereof Download PDFInfo
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- CN108892999A CN108892999A CN201810942895.9A CN201810942895A CN108892999A CN 108892999 A CN108892999 A CN 108892999A CN 201810942895 A CN201810942895 A CN 201810942895A CN 108892999 A CN108892999 A CN 108892999A
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- quick solidifying
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/101—Inks specially adapted for printing processes involving curing by wave energy or particle radiation, e.g. with UV-curing following the printing
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
- C09D11/38—Inkjet printing inks characterised by non-macromolecular additives other than solvents, pigments or dyes
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
- Ink Jet Recording Methods And Recording Media Thereof (AREA)
Abstract
The invention discloses UV ink-jet inks of a kind of low viscosity quick solidifying and preparation method thereof, the UV ink-jet ink, according to parts by weight, including 1~10 part of coloring pigment, 5~25 parts of modified epoxy acrylic ester, 3~10 parts of pure acrylic resin, DPHA5~15 part, TMPTA5~15 part, THFA20~40 part, 5~20 parts of isobornyl acrylate, 5~20 parts of triethyleneglycol divinylether, 1~13 part of photoinitiator, 0.5~5 part of auxiliary agent.Compared to similar product, have that viscosity is small, curing rate is fast, performance can easily be accommodated, adhesive force is strong, wear-resisting, hardness is high, not by oxygen inhibition the characteristics of.
Description
Technical field
The present invention relates to chemical products technical fields, and in particular to a kind of ink-jet ink and preparation method thereof, especially one
The UV ink-jet ink and preparation method thereof of kind low viscosity quick solidifying.
Background technique
Ultraviolet light (UV) cured printing ink is a kind of technology that printer can be made to play optimum efficiency.This technology has oneself
Unique advantage, such as adhesive capacity of the drying, solventless ink, ink immediately in most substrates, tinting strength, tinting power and excellent
Film properties, these advantages are all that UV curable ink obtains the factor that is widely recognized as.UV solidifies in inkjet formulation using collection
In there is respective mixture of different nature, by the characteristic of its own, which kind can the appropriate time with it is light-initiated
The requirement that agent is combined to meet ink.
Ultraviolet light solidification generally refers under ultraviolet light, and photoinitiator generates reactive species, such as free radical or sun
Ion makes the prepolymer with active function groups or functionalization monomer a cured emerging technology at normal temperature, it is as biography
Unite heat curing techniques substitution technique and grow up.UV-curing technology is as environmental-friendly " green technology ", tool
Have that curing rate is fast, solvent resistance is good, pollution less, toxicity it is low, the advantages that low energy consumption and process units is compact, wide adaptability.
Photocuring system mainly has two parts, first is that cause system, mainly photoinitiator, it is anti-for generating initiation polymerization
The reactive species (free radical or cation) answered；First is that photopolymerizable compound, including reactive diluent and oligomer.
UV-curing technology is divided into radical UV curing and cation photocuring by photo-curing mechanism.Free radical polymerization
System is the system applied earliest.Radical UV curing is under light-initiated, and photoinitiator generates free radicals, and causes prepolymer
Polymerization reaction is generated with the unsaturated double-bond on monomer, present photocuring system is based on radically curing, wherein with third
Olefin(e) acid ester type compound is most widely used.Although radical UV curing system has curing rate fast, performance be can easily be accommodated
The advantages of, but also have the problems such as serious contraction, poor adhesive force, be easily oxidized polymerization inhibitor.Cationic curing systems, with free radical propylene
The ink that acid esters mechanism generates is compared, and the advantages of cationic system is：It is not influenced by oxygen killer, excellent adhesiveness, film
Physical property due to the film properties in acrylatcs systems, the viscosity of vinyl ether diluent is very low.
UV curing technology is varied, in addition to coating and typographic application, is also used for binder, composite material and one
A little electronic products.All these technologies all benefit from the key advantages of UV curing technology inherently：Wink-dry, it is solvent-free
System, firm Impedance Membrane, low energy consumption application can stick, external persistent, high gloss in many different substrates.But
There is viscosity height in UV ink-jet ink currently on the market, the technical problem of slow curing, this becomes those skilled in the art always
Thirst for the difficult point solved.
Summary of the invention
In view of the deficiencies of the prior art, the present invention provides UV ink-jet ink and its preparation side of a kind of low viscosity quick solidifying
Method overcomes the shortcomings of existing ink-jet ink, has good storage stability, excellent water resistance, resistant of high or low temperature, mechanicalness good, especially
The advantages of it is low viscosity quick solidifying.
In order to solve the above technical problems, the present invention provides the following technical solutions：
On the one hand, the present invention provides a kind of UV ink-jet ink of low viscosity quick solidifying, according to parts by weight, including coloring face
Expect 1~10 part, 15~25 parts of modified epoxy acrylic ester, 3~10 parts of pure acrylic resin, DPHA5~15 part, TMPTA5~15
Part, THFA20~40 part, 5~20 parts of isobornyl acrylate, 5~20 parts of triethyleneglycol divinylether, photoinitiator 1~13
Part, 0.5~5 part of auxiliary agent.
Pigment range used in the present invention is azo, phthalein blueness is pigment.
Modified epoxy acrylic ester used in the present invention, pure acrylic resin；24 hours water absorption rate≤10% after film forming；Cream
Liquid clear appearance is transparent-blue light or yellowish translucent liquid, -50-120 DEG C of glass transition temperature, and viscosity<800 centipoises are even low
To 50 centipoises, hardness is adjustable, and long shelf-life was up to 2 years, all-transparent after film forming.
DPHA (dipentaerythritol hexaacrylate)；TMPTA (trimethylolpropane trimethacrylate)；THFA (tetrahydro
Furfuryl acrylic acid ester).
Further, the photoinitiator includes 1~8 part of 1- hydroxy-cyclohexyl-phenyl ketone, 2,4,6- trimethylbenzenes
1~5 part of formoxyl-diphenyl phosphine oxide or both of combination.Preferably, the photoinitiator includes 1- hydroxy-cyciohexyl-benzene
The combination of 5 parts of base ketone, 2.5 parts of 2,4,6- trimethylbenzoy-dipheny phosphine oxide or both.
Further, the auxiliary agent include 0.5~2 part of polymethyl siloxane, 0.1~1 part of silane coupling agent, levelling agent or
The combination of 0.5~2 part of surfactant or various auxiliary agents.Preferably, the auxiliary agent includes 1 part of polymethyl siloxane, silane idol
Join 0.5 part of agent, the combination of levelling agent or 1 part of surfactant or various auxiliary agents.
The surfactant selects safe and non-toxic raw material.Such as：Nonionic surfactant, anionic surface are living
Property agent, amphoteric surfactant.Nonionic surfactant, preferably polyoxyethylene aliphatic alcohol ether (AEO), Polyoxyethylene fatty
Acid esters (AE), polyol ester, Sucrose Fatty Acid Ester, alcohol ether carboxylate (AEC-H), alkyl polyglycoside (APG)；Anionic surfactant, preferably
For alcohol ether carboxylate surfactant (AEC), sulphosuccinates, secondary alkyl sulfonate (MES), fatty alcohol polyoxyethylene ether
Sulfuric acid ester salt (AES), a- alkenyl sulfonate.Amphoteric surfactant, preferably betaine type amphoteric surfac-tant, imidazoline
Type amphoteric surfactant.
Further, the UV ink-jet ink of the low viscosity quick solidifying according to parts by weight, including 5 parts of coloring pigment, changes
Property 15 parts of epoxy acrylate, 5 parts of pure acrylic resin, 10 parts of DPHA, TMPTA10 parts, THFA25 parts, isobomyl acrylate
10 parts of ester, 10 parts of triethyleneglycol divinylether, 7.5 parts of photoinitiator, 2.5 parts of auxiliary agent.
On the other hand, the present invention provides a kind of preparation method of the UV ink-jet ink of low viscosity quick solidifying, including walks as follows
Suddenly：
1) by coloring pigment, modified epoxy acrylic ester, pure acrylic resin, DPHA, TMPTA, THFA, the different ice of acrylic acid
Piece ester, triethyleneglycol divinylether and auxiliary agent mixing, are heated to the first temperature and stir evenly；
2) second temperature is cooled the temperature to, photoinitiator is added, stirs and evenly mixs, is ground after cooling and obtains low viscosity quick solidifying
UV ink-jet ink.
Further, first temperature is 70~90 DEG C.
Further, in the step 1), the time of stirring is 30~60 minutes.
Further, the second temperature is 60~70 DEG C.
Further, in the step 2), the time of stirring is 1~2 hour.
The application of UV ink-jet ink of the present invention, is printed upon uncoated medium and non-print coating media, hydrophobicity
On oil medium.
In the UV ink-jet ink of low viscosity quick solidifying of the invention, modified epoxy acrylic ester and pure acrylic resin are resistant to
The ageing-resistant barrier ultraviolet light of illumination；Photoinitiator can absorb ultraviolet light, prevents illumination to the fast decoupled of coloring pigment, can also
Cause free radical and causes cation, the adhesive force and hardness with ink；Coloring pigment is coated on modified epoxy third
Olefin(e) acid ester and pure acrylic resin are formed by film, can completely cut off the oxygen and hydrone for so that it is generated chemical reaction and fading
Reaction environment；And in ink preparation process of the invention, the not participation of water passes through DPHA, TMPTA, THFA, the different ice of acrylic acid
The environment of piece ester and triethyleneglycol divinylether dilution and maintenance system, can more prevent the environment of hydrone, keep ink more steady
It is fixed；DPHA, TMPTA, THFA, isobornyl acrylate and triethyleneglycol divinylether can improve system as monomer simultaneously
Thermal stability, the free radical in molecule can inhibit polymerization caused by oxygen to harden, can also accelerate the curing rate of system, can subtract
Volume contraction when solidifying less can increase adhesive force, stability of ink can also be made good, use is more permanent, is not easy by external environment
Destroy the film of ink system；Auxiliary agent can effectively disperse and maintain the stability of ink.
Beneficial effects of the present invention
The present invention relates to a kind of UV ink-jet inks of low viscosity quick solidifying, compare similar product, solidification speed small with viscosity
Degree is fast, performance can easily be accommodated, and adhesive force is strong, wear-resisting, hardness is high, not by oxygen inhibition the characteristics of.
UV ink-jet ink of the invention overcomes the insufficient determination of existing stability of ink, by by each component in heating
Under the conditions of directly mix, do not add water, be not in layering, precipitating the phenomenon that.There is organic phase between each component, is in after mixing
It now carries out, auxiliary agent is added as dispersing agent, levelling agent or amphiphilic surfactant, each component can be uniformly dispersed, in turn
Realize stable effect.
UV ink-jet ink each component of the invention is all coated on modified epoxy acrylic ester and pure acrylic resin is formed
Film in, be not easy by the external world destroy, it is more permanent using the time.
Preparation method provided by the invention is simple, and the process of mixing is simple, is not required to operation of precision tool, strong operability,
Favorable reproducibility, it is at low cost, it is suitble to industrial application.Safe and non-toxic in the production process, the product of manufacture also has the feature of environmental protection.
Specific embodiment
Technical solution in order to enable those skilled in the art to better understand the present invention, With reference to embodiment to this
Invention is further described.
Specific embodiment
Embodiment 1
A kind of UV ink-jet ink of low viscosity quick solidifying, according to parts by weight, including 1 part of coloring pigment, modified epoxy third
25 parts of olefin(e) acid ester, 3 parts of pure acrylic resin, DPHA10 parts, TMPTA15 parts, THFA20 parts, 15 parts of isobornyl acrylate, three
10 parts of ethylene glycol divinyl ether, 13 parts of photoinitiator, 0.5 part of auxiliary agent.
Pigment used is azo pigment；The photoinitiator includes 1 part of 1- hydroxy-cyclohexyl-phenyl ketone and 2,4,
5 parts of 6- trimethylbenzoy-dipheny phosphine oxide.The auxiliary agent includes 0.5 part of polymethyl siloxane, 1 part of silane coupling agent.
It is firstly added coloring pigment, modified epoxy acrylic ester, the pure acrylic resin of low viscosity, THFA (tetrahydro chaff
Base acrylate), isobornyl acrylate, TMPTA (trimethylolpropane trimethacrylate), triethyleneglycol divinylether,
Polymethyl siloxane, silane coupling agent are heated to 70 DEG C, stir 60 minutes, stir evenly；Then 60 DEG C are cooled to, 1- is added
Hydroxy-cyclohexyl-phenyl ketone, 2,4,6- trimethylbenzoy-dipheny phosphine oxides stir 2 hours；After cooling, grinding
Obtain UV ink-jet ink.
Embodiment 2
A kind of UV ink-jet ink of low viscosity quick solidifying, according to parts by weight, including 10 parts of coloring pigment, modified epoxy third
15 parts of olefin(e) acid ester, 10 parts of pure acrylic resin, DPHA15 parts, TMPTA5 parts, THFA40 parts, 15 parts of isobornyl acrylate, three
5 parts of ethylene glycol divinyl ether, 2 parts of photoinitiator, 5 parts of auxiliary agent.
Pigment range used is that phthalein blueness is pigment.The photoinitiator includes 8 parts of 1- hydroxy-cyclohexyl-phenyl ketone, 2,
1 part of 4,6- trimethylbenzoy-dipheny phosphine oxide.The auxiliary agent includes 0.5 part of polymethyl siloxane, silane coupling agent
0.1 part, 0.5 part of surfactant.
It is firstly added coloring pigment, modified epoxy acrylic ester, the pure acrylic resin of low viscosity, THFA (tetrahydro chaff
Base acrylate), isobornyl acrylate, TMPTA (trimethylolpropane trimethacrylate), triethyleneglycol divinylether,
Polymethyl siloxane, silane coupling agent, surfactant are heated to 90 DEG C, stir 30 minutes, stir evenly；Then it is cooled to
70 DEG C, 1- hydroxy-cyclohexyl-phenyl ketone, 2,4,6- trimethylbenzoy-dipheny phosphine oxides is added, stirs 1 hour；
After cooling, UV ink-jet ink is ground to obtain.
Embodiment 3
A kind of UV ink-jet ink of low viscosity quick solidifying, according to parts by weight, including 5 parts of coloring pigment, modified epoxy third
15 parts of olefin(e) acid ester, 10 parts of pure acrylic resin, DPHA5 parts, TMPTA10 parts, THFA25 parts, 10 parts of isobornyl acrylate, three
10 parts of ethylene glycol divinyl ether, 10 parts of photoinitiator, 2 parts of auxiliary agent.
Pigment range used is azo pigment.
The photoinitiator includes 5 parts of 1- hydroxy-cyclohexyl-phenyl ketone, 2,4,6- trimethylbenzoy-dipheny
4 parts of phosphine oxide.
The auxiliary agent includes 1 part of polymethyl siloxane, 0.5 part of silane coupling agent, 1 part of surfactant.
It is firstly added coloring pigment, modified epoxy acrylic ester, the pure acrylic resin of low viscosity, THFA (tetrahydro chaff
Base acrylate), isobornyl acrylate, TMPTA (trimethylolpropane trimethacrylate), triethyleneglycol divinylether,
Polymethyl siloxane, silane coupling agent, surfactant are heated to 80 DEG C, stir 40 minutes, stir evenly；Then it is cooled to
60 DEG C, 1- hydroxy-cyclohexyl-phenyl ketone, 2,4,6- trimethylbenzoy-dipheny phosphine oxides is added, stirring 1.5 is small
When；After cooling, UV ink-jet ink is ground to obtain.
Embodiment 4
A kind of UV ink-jet ink of low viscosity quick solidifying, according to parts by weight, including 2 parts of coloring pigment, modified epoxy third
25 parts of olefin(e) acid ester, 10 parts of pure acrylic resin, DPHA5 parts, TMPTA15 parts, THFA25 parts, 20 parts of isobornyl acrylate, three
15 parts of ethylene glycol divinyl ether, 13 parts of photoinitiator, 4 parts of auxiliary agent.
Pigment range used is azo pigment.
The photoinitiator includes 5 parts of 1- hydroxy-cyclohexyl-phenyl ketone, 2,4,6- trimethylbenzoy-dipheny
2 parts of phosphine oxide or both of combination.
The auxiliary agent includes 1 part of polymethyl siloxane, 0.5 part of silane coupling agent, 1.5 parts of surfactant.
It is firstly added coloring pigment, modified epoxy acrylic ester, the pure acrylic resin of low viscosity, THFA (tetrahydro chaff
Base acrylate), isobornyl acrylate, TMPTA (trimethylolpropane trimethacrylate), triethyleneglycol divinylether,
Polymethyl siloxane, silane coupling agent, surfactant are heated to 80 DEG C, stir 50 minutes, stir evenly；Then it is cooled to
65 DEG C, 1- hydroxy-cyclohexyl-phenyl ketone, 2,4,6- trimethylbenzoy-dipheny phosphine oxides is added, stirring 1.5 is small
When；After cooling, UV ink-jet ink is ground to obtain.
Embodiment 5
A kind of UV ink-jet ink of low viscosity quick solidifying, according to parts by weight, including 3 parts of coloring pigment, modified epoxy third
20 parts of olefin(e) acid ester, 8 parts of pure acrylic resin, DPHA10 parts, TMPTA8 parts, THFA20 parts, 20 parts of isobornyl acrylate, three second
13 parts of divinyl ether, 4.5 parts of photoinitiator, 2.5 parts of auxiliary agent.
The photoinitiator includes 4 parts of 1- hydroxy-cyclohexyl-phenyl ketone, 2,4,6- trimethylbenzoy-dipheny
1.5 parts of phosphine oxide.
The auxiliary agent includes 1 part of polymethyl siloxane, 0.5 part of silane coupling agent, 1 part of surfactant.
It is firstly added coloring pigment, modified epoxy acrylic ester, the pure acrylic resin of low viscosity, THFA (tetrahydro chaff
Base acrylate), isobornyl acrylate, TMPTA (trimethylolpropane trimethacrylate), triethyleneglycol divinylether,
Polymethyl siloxane, silane coupling agent, surfactant are heated to 80 DEG C, stir 50 minutes, stir evenly；Then it is cooled to
65 DEG C, 1- hydroxy-cyclohexyl-phenyl ketone, 2,4,6- trimethylbenzoy-dipheny phosphine oxides is added, stirring 1.5 is small
When；After cooling, UV ink-jet ink is ground to obtain.
Embodiment 6
1) film thickness by the spraying of UV ink-jet ink prepared by the embodiment of the present invention on the substrate：10~15um；
The emission wavelength (200~500nm) of LED ultra-violet light-emitting lamp；Curing time：3~5S compares the similar product ink cured time：4
~6S, time are shorter.
2) mode of tested viscosity：NDJ-1 rotary viscosimeter；UV ink-jet ink prepared by the embodiment of the present invention is viscous
Degree：8~10 (units：Cps, 25 DEG C), similar product viscosity：10~12 (units：Cps, 25 DEG C).
It is understood that the principle that embodiment of above is intended to be merely illustrative of the present and the exemplary implementation that uses
Mode, however the present invention is not limited thereto.For those skilled in the art, essence of the invention is not being departed from
Mind and essence in the case where, various changes and modifications can be made therein, these variations and modifications be also considered as be comprised in it is of the invention
In protection scope.
Claims (10)
1. a kind of UV ink-jet ink of low viscosity quick solidifying, which is characterized in that according to parts by weight, including coloring pigment 1~10
Part, 5~25 parts of modified epoxy acrylic ester, 3~10 parts of pure acrylic resin, DPHA5~15 part, TMPTA5~15 part,
THFA20~40 part, 5~20 parts of isobornyl acrylate, 5~20 parts of triethyleneglycol divinylether, 1~13 part of photoinitiator,
0.5~5 part of auxiliary agent.
2. the UV ink-jet ink of low viscosity quick solidifying according to claim 1, which is characterized in that the photoinitiator includes
1~8 part of 1- hydroxy-cyclohexyl-phenyl ketone, 1~5 part of 2,4,6- trimethylbenzoy-dipheny phosphine oxide or both
Combination.
3. the UV ink-jet ink of low viscosity quick solidifying according to claim 1, which is characterized in that the auxiliary agent includes poly- first
The group of 0.5~2 part of radical siloxane, 0.1~1 part of silane coupling agent, levelling agent or 0.5~2 part of surfactant or various auxiliary agents
It closes.
4. the UV ink-jet ink of low viscosity quick solidifying according to claim 1, which is characterized in that according to parts by weight, packet
Include 5 parts of coloring pigment, 15 parts of modified epoxy acrylic ester, 5 parts of pure acrylic resin, 10 parts of DPHA, TMPTA10 parts, THFA25
Part, 10 parts of isobornyl acrylate, 10 parts of triethyleneglycol divinylether, 7.5 parts of photoinitiator, 2.5 parts of auxiliary agent.
5. a kind of preparation method of the UV ink-jet ink of the described in any item low viscosity quick solidifyings of Claims 1 to 4, feature exist
In including the following steps：
1) by coloring pigment, modified epoxy acrylic ester, pure acrylic resin, TMPTA, THFA, isobornyl acrylate, three second
Divinyl ether and auxiliary agent mixing, are heated to the first temperature and stir evenly；
2) second temperature is cooled the temperature to, photoinitiator is added, stirs and evenly mixs, is ground after cooling and obtains the UV of low viscosity quick solidifying
Ink-jet ink.
6. the preparation method of the UV ink-jet ink of low viscosity quick solidifying according to claim 5, which is characterized in that described
One temperature is 70~90 DEG C.
7. the preparation method of the UV ink-jet ink of low viscosity quick solidifying according to claim 5, which is characterized in that the step
It is rapid 1) in, time of stirring is 30~60 minutes.
8. the preparation method of the UV ink-jet ink of low viscosity quick solidifying according to claim 5, which is characterized in that described
Two temperature are 60~70 DEG C.
9. the preparation method of the UV ink-jet ink of low viscosity quick solidifying according to claim 5, which is characterized in that the step
It is rapid 2) in, time of stirring is 1~2 hour.
10. the application of the described in any item UV ink-jet inks of Claims 1 to 4, which is characterized in that be printed upon uncoated medium and
On non-print coating media, hydrophobicity and oil medium.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201810942895.9A CN108892999A (en) | 2018-08-17 | 2018-08-17 | UV ink-jet ink of low viscosity quick solidifying and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810942895.9A CN108892999A (en) | 2018-08-17 | 2018-08-17 | UV ink-jet ink of low viscosity quick solidifying and preparation method thereof |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101805542A (en) * | 2010-05-13 | 2010-08-18 | 鲁继烈 | Water-based dye ink and application thereof |
| CN101914324A (en) * | 2010-08-26 | 2010-12-15 | 鲁继烈 | Modified polyurethane resin emulsion dye ink and application thereof |
| CN105713452A (en) * | 2014-12-22 | 2016-06-29 | 海德堡印刷机械股份公司 | Fast-curing UV inkjet ink based on hyperbranched polyester acrylate |
| CN107400408A (en) * | 2017-09-22 | 2017-11-28 | 江门市久冠松高分子材料有限公司 | A kind of UV solidification decorative inks of unsuitable xanthochromia and preparation method thereof |
-
2018
- 2018-08-17 CN CN201810942895.9A patent/CN108892999A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101805542A (en) * | 2010-05-13 | 2010-08-18 | 鲁继烈 | Water-based dye ink and application thereof |
| CN101914324A (en) * | 2010-08-26 | 2010-12-15 | 鲁继烈 | Modified polyurethane resin emulsion dye ink and application thereof |
| CN105713452A (en) * | 2014-12-22 | 2016-06-29 | 海德堡印刷机械股份公司 | Fast-curing UV inkjet ink based on hyperbranched polyester acrylate |
| CN107400408A (en) * | 2017-09-22 | 2017-11-28 | 江门市久冠松高分子材料有限公司 | A kind of UV solidification decorative inks of unsuitable xanthochromia and preparation method thereof |
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Application publication date: 20181127 |