CN108892198A - A kind of polyaluminium chloride water purification agent - Google Patents
A kind of polyaluminium chloride water purification agent Download PDFInfo
- Publication number
- CN108892198A CN108892198A CN201810828656.0A CN201810828656A CN108892198A CN 108892198 A CN108892198 A CN 108892198A CN 201810828656 A CN201810828656 A CN 201810828656A CN 108892198 A CN108892198 A CN 108892198A
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- CN
- China
- Prior art keywords
- water purification
- parts
- aluminium polychloride
- block
- component
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 98
- 238000000746 purification Methods 0.000 title claims abstract description 76
- 239000003795 chemical substances by application Substances 0.000 title claims abstract description 39
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 title claims abstract description 21
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 54
- 239000004411 aluminium Substances 0.000 claims abstract description 54
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 54
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 25
- 239000000741 silica gel Substances 0.000 claims abstract description 21
- 229910002027 silica gel Inorganic materials 0.000 claims abstract description 21
- 239000006229 carbon black Substances 0.000 claims abstract description 20
- 239000004615 ingredient Substances 0.000 claims abstract description 19
- 229920002401 polyacrylamide Polymers 0.000 claims abstract description 7
- HJYUZIDYQOZTBZ-UHFFFAOYSA-J [K+].S(=O)(=O)([O-])[O-].[Al+3].NN.S(=O)(=O)([O-])[O-] Chemical compound [K+].S(=O)(=O)([O-])[O-].[Al+3].NN.S(=O)(=O)([O-])[O-] HJYUZIDYQOZTBZ-UHFFFAOYSA-J 0.000 claims abstract description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 15
- 238000007789 sealing Methods 0.000 claims description 7
- 239000003292 glue Substances 0.000 claims description 5
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 claims description 4
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 3
- 229910052796 boron Inorganic materials 0.000 claims description 3
- 239000000843 powder Substances 0.000 claims description 2
- 238000001179 sorption measurement Methods 0.000 abstract description 5
- 239000003643 water by type Substances 0.000 abstract description 5
- 230000006978 adaptation Effects 0.000 abstract description 4
- 238000003894 drinking water pollution Methods 0.000 abstract description 4
- 238000000034 method Methods 0.000 description 12
- 230000008569 process Effects 0.000 description 11
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 7
- 238000010586 diagram Methods 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 6
- 210000003781 tooth socket Anatomy 0.000 description 6
- 239000003651 drinking water Substances 0.000 description 5
- 235000020188 drinking water Nutrition 0.000 description 5
- 239000000203 mixture Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 3
- 230000036541 health Effects 0.000 description 3
- 238000001556 precipitation Methods 0.000 description 3
- 239000011800 void material Substances 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 238000011109 contamination Methods 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000005416 organic matter Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 1
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 1
- 229920001661 Chitosan Polymers 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 description 1
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- ZXRRHFSTAFVGOC-UHFFFAOYSA-N [AlH3].[K] Chemical compound [AlH3].[K] ZXRRHFSTAFVGOC-UHFFFAOYSA-N 0.000 description 1
- 159000000013 aluminium salts Chemical class 0.000 description 1
- 229910000329 aluminium sulfate Inorganic materials 0.000 description 1
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 229910001424 calcium ion Inorganic materials 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 238000005352 clarification Methods 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000011900 installation process Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 description 1
- RUTXIHLAWFEWGM-UHFFFAOYSA-H iron(3+) sulfate Chemical compound [Fe+3].[Fe+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O RUTXIHLAWFEWGM-UHFFFAOYSA-H 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 229910000360 iron(III) sulfate Inorganic materials 0.000 description 1
- 229910001425 magnesium ion Inorganic materials 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 239000008213 purified water Substances 0.000 description 1
- 239000012629 purifying agent Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 239000010865 sewage Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- -1 sulfonic acid magnesium salts Chemical class 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid group Chemical class S(O)(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- 239000002352 surface water Substances 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
- 238000004065 wastewater treatment Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/52—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
- C02F1/5236—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using inorganic agents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/0203—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04
- B01J20/0248—Compounds of B, Al, Ga, In, Tl
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/0203—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04
- B01J20/0274—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04 characterised by the type of anion
- B01J20/0288—Halides of compounds other than those provided for in B01J20/046
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/04—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of alkali metals, alkaline earth metals or magnesium
- B01J20/045—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of alkali metals, alkaline earth metals or magnesium containing sulfur, e.g. sulfates, thiosulfates, gypsum
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
- B01J20/103—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate comprising silica
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/20—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising free carbon; comprising carbon obtained by carbonising processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
- B01J20/26—Synthetic macromolecular compounds
- B01J20/261—Synthetic macromolecular compounds obtained by reactions only involving carbon to carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/28—Treatment of water, waste water, or sewage by sorption
- C02F1/281—Treatment of water, waste water, or sewage by sorption using inorganic sorbents
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/28—Treatment of water, waste water, or sewage by sorption
- C02F1/283—Treatment of water, waste water, or sewage by sorption using coal, charred products, or inorganic mixtures containing them
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/28—Treatment of water, waste water, or sewage by sorption
- C02F1/285—Treatment of water, waste water, or sewage by sorption using synthetic organic sorbents
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/52—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
- C02F1/54—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using organic material
- C02F1/56—Macromolecular compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2220/00—Aspects relating to sorbent materials
- B01J2220/40—Aspects relating to the composition of sorbent or filter aid materials
- B01J2220/46—Materials comprising a mixture of inorganic and organic materials
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Analytical Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Water Treatment By Sorption (AREA)
Abstract
The invention discloses a kind of polyaluminium chloride water purification agents comprising ingredient and mass content be：78-89 parts of component first, component second is 15-28 parts；Wherein, the component first be water purification host agent comprising ingredient and mass content be：White aluminium polychloride 56-78 parts, 32-45 parts of polyacrylamide, 15-27 parts of 12 hydrazine aluminum sulfate potassium；Wherein, the component second be water purifying assistant, including ingredient and mass content be：8-12 parts of carbon black, 3-11 parts of silica gel.Water purification agent adaptation waters is wider, and adsorption capacity is strong, and purification thoroughly, can avoid drinking water pollution threat caused by human body completely.
Description
Technical field
The invention belongs to water-purifying material technical field more particularly to a kind of polyaluminium chloride water purification agents.
Background technique
With the continuous propulsion of process of industrialization, various pollutions are got worse.Especially in terms of the underground drinking-water water in rural area,
These underground water typical contamination, especially underground water and surface water calcium ions and magnesium ions, carbanion, ferrimanganic, suspended matter, colloid
Object, toxic byproduct, bacterium, silt, iron rust, solid impurity contamination hazard, natural stream networks pollutant are severely exceeded, can not be drunk,
Threaten the health of the mankind.The status of above-mentioned pollution is constituted to the unit in charge of construction and outgoing trip in life in the countryside, operation
Swim the great threat of personnel health.
In order to eliminate the pollution to water quality, the health for influencing people is prevented, in the prior art common water purification agent
Have following several：
Chinese patent application 201510782534.9 discloses a kind of water purification agent composition, mainly includes with water purification agent composition
Weight be 100% meter following component：5-10 weight % chitosan, 20-30 weight % bodied ferric sulfate, 50-60 weight %
Active carbon and 10-20 weight % aluminum sulfate.Water purification agent composition of the invention be applied to wastewater treatment when, be in dosage
When 200mg/L, to turbidity of wastewater removal rate up to 99.1%, total tp removal rate is reachable up to the removal rate of 90% or more, COD
35% or more, BOD removal rate are 80% or more, and the raw material sources of the water purification agent composition are abundant, at low cost.
Chinese patent application 201410341470.4 discloses a kind of composite water purifying agent, by the organic of 50-1000 parts by weight
The organic matter ingredient of salt water purification agent and 0.1-1000 parts by weight, is prepared with simple and easy bulking process, is used for sewage
Purified treatment, organic salt water purification agent used are one or both of aluminium salt, molysite etc., a variety of arbitrary proportion combinations, institute
It is one or both of sulfonic acid magnesium salts, magnesium sulfate salt etc., a variety of arbitrary proportion combinations with organic matter.
But above-mentioned water purification agent in the prior art adapts to that waters is narrow, and adsorption capacity is not strong, and purification is not thorough, cannot
Drinking water pollution threat caused by human body is avoided completely.
But existing aluminium polychloride is mostly used by spraying mode, after use, it is also necessary to purified
Water is further precipitated or is filtered, and just can be carried out effective use, this results in cleaning procedure too long, and the clarification time is too long,
Purification efficiency is lower, is unfavorable for the realization of purification process.
Since the stability of aluminium polychloride is poor, there is corrosivity, in process of production, such as splash on skin and want accidentally
It is rinsed with water immediately completely, producers will wear work clothes, wear masks, gloves, wear gum boots, significantly limit polymerization chlorine
The production for changing aluminium water purification rod, is unfavorable for promoting the use of on a large scale.
Summary of the invention
The purpose of the present invention is to solve disadvantages existing in the prior art, disclose a kind of aluminium polychloride water purification
Agent, adaptation waters is wider, and adsorption capacity is strong, and purification thoroughly, can avoid drinking water pollution threat caused by human body completely, with
It solves the problems, such as to propose in above-mentioned background.
To achieve the above object, the present invention provides the following technical solutions：
A kind of polyaluminium chloride water purification agent comprising ingredient and mass content be：78-89 parts of component first, component second is 15-28
Part；
Wherein, the component first be water purification host agent comprising ingredient and mass content be：White aluminium polychloride 56-78
Part, 32-45 parts of polyacrylamide, 15-27 parts of 12 hydrazine aluminum sulfate potassium；
Wherein, the component second be water purifying assistant, including ingredient and mass content be：8-12 parts of carbon black, 3-11 parts of silica gel.
Preferably, the component second further includes 0.7-4.2 parts of boron glue.
Preferably, the carbon black is in powdered, and specific surface area A is 1200-2300 meters squared per gram.
Preferably, the silica gel is activated silica gel.Its hole holds V（The total volume of every gram of silica gel internal void）For 1.7-
2.5mL/g。
Preferably, the hole of the specific surface area A of the carbon black and silica gel holds V and meets：AV be more than or equal to 2100 be less than etc.
In 5500.
Preferably, the content K of the aluminum oxide in the white aluminium polychloride is more than or equal to 31% and is less than or equal to 52%；
Further, the specific surface area A of the content K of the aluminum oxide and carbon black, silica gel hole hold V meet following relationship：
；
Wherein, ω is the aluminum oxide in white aluminium polychloride containing coefficient of discharge, value range 0.26-0.59.
For better purifying drinking water, the present invention also provides a kind of aluminium polychloride water purification rod, including stick pipe and poly-
Aluminium chloride filter layer is closed, the aluminium polychloride filter layer is made of polyaluminium chloride water purification agent, and the top of the stick pipe is provided with
Water inlet is provided with thread segment on the upside of the stick pipe, cover board is bolted on the outside of the thread segment, the inner wall of the stick pipe is set
It is equipped with guide groove, the guide groove is internally provided with sliding block, and the upside between the sliding block is provided with baffle, between the sliding block
Downside is provided with supporting block, and the top of the supporting block is equipped with limited block, and the aluminium polychloride filter layer is set to limit
Between block, the lower part of the supporting block is equipped with activated carbon filter layer, and the side of the stick pipe is provided with water outlet.
Preferably, carbon black part is used in the activated carbon filter layer, the specific surface area B of carbon black powder is flat for 1400-2300
Square rice/gram.
Preferably, the internal screw thread to match with thread segment is provided on the inside of the cover board, and the side of the cover board is equal
It is even to be disposed with convex block.
Preferably, the sliding block is symmetrically arranged with two groups relative to stick pipe, and the top of the sliding block is provided with sealing ring.
Preferably, in order to which sealing is better achieved, the material of the sealing ring is silica gel or rubber, and elongation P is 450-
680%。
Preferably, the middle part of the baffle and the middle part of supporting block are uniformly covered with respectively through-hole, the limited block it is upper
Portion is installed on the lower part of baffle, and the limited block is provided with through hole close to the side of baffle.
In order to preferably provide water purification rod, the present invention also provides a kind of aluminium polychloride water purification rod process units, including dress
Ontology and electric telescopic rod are set, described device ontology is internally provided with station, is provided with bearing in the middle part of the station,
The bearing top is equipped with fixture block, and the inner wall of the fixture block is provided with rubber pad, and the bearing passes through far from one end of fixture block
Drive shaft turns are connected with motor, and the electric telescopic rod is installed on the upper wall of device noumenon, and the electric telescopic rod is stretched
End is equipped with link block, and the lower part of the link block is equipped with sucker, is equipped with fixture on the outside of the link block.
Preferably, the fixture block is arranged in semicircular arc, and the fixture block is symmetrically arranged with two groups relative to bearing.
Preferably, the motor is installed on the lower wall of device noumenon by fixing seat, and the motor uses variable-frequency motor
Setting.
Preferably, the sucker is arranged symmetrically relative to link block, and connection is provided between the sucker and link block
Bar.
Preferably, the fixture is in and is oppositely arranged, and the inside equidistant placement of the fixture has tooth socket with station.
Compared with prior art, technical effect and advantage of the invention：
1, polyaluminium chloride water purification agent of the invention, host agent is using white aluminium polychloride, polyacrylamide, 12 hydrated sulfuric acids
Aluminium potassium, stability is good, and adaptation waters is wide, and hydrolysis rate is fast, and adsorption capacity is strong, and formation alumen ustum is big, and the close precipitating of matter is fast, delivery turbidity
Low, dewatering is good excellent, can be fully cleaned up drinking water, prevents from doing harm to huamn body.
2, polyaluminium chloride water purification agent of the invention, by the way that the Kong Rong of the specific surface area and silica gel of carbon black in auxiliary agent is arranged
Range and relationship, with preferably water purification.
3, polyaluminium chloride water purification agent of the invention realizes the purified treatment to water in a manner of water purification rod, avoids purifying
Precipitation process needed for afterwards improves the purification efficiency of aluminium polychloride water purification rod.
4, polyaluminium chloride water purification agent of the invention, manufactured water purification rod in process of production, effectively reduce manually with
The contact of aluminium polychloride, convenient for artificial operation, convenient for the production of aluminium polychloride water purification rod.
5, polyaluminium chloride water purification agent of the invention, by the content for the aluminum oxide being arranged in white aluminium polychloride
Range, and with the specific surface area of carbon black, silica gel Kong Rong between relationship, to improve the adaptation waters width of water purification agent, inhale
Attached ability makes purification thoroughly can avoid drinking water pollution threat caused by human body completely.
Detailed description of the invention
Fig. 1 is aluminium polychloride water purification stick pipe structural schematic diagram of the invention；
Fig. 2 is aluminium polychloride water purification rod covering plate structure schematic diagram of the invention；
Fig. 3 is aluminium polychloride water purification rod aluminium polychloride filtering layer structure schematic diagram of the invention；
Fig. 4 is aluminium polychloride water purification rod device noumenon structural schematic diagram of the invention；
Fig. 5 is aluminium polychloride water purification rod clamp structure schematic diagram of the invention；
Fig. 6 is aluminium polychloride water purification rod station structural schematic diagram of the invention.
In figure：1, stick pipe；2, aluminium polychloride filter layer；3, water inlet；4, thread segment；5, cover board；6, guide groove；7, sliding
Block；8, baffle；9, supporting block；10, limited block；11, activated carbon filter layer；12, water outlet；13, internal screw thread；14, convex block；15,
Sealing ring；16, through-hole；17, through hole；18, device noumenon；19, electric telescopic rod；20, station；21, bearing；22, fixture block；
23, rubber pad；24, drive shaft；25, motor；26, link block；27, sucker；28, fixture；29, fixing seat；30, connecting rod；31,
Tooth socket.
Specific embodiment
Following will be combined with the drawings in the embodiments of the present invention, and technical solution in the embodiment of the present invention carries out clear, complete
Site preparation description, it is clear that described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.It is based on
Embodiment in the present invention, it is obtained by those of ordinary skill in the art without making creative efforts every other
Embodiment shall fall within the protection scope of the present invention.
Embodiment 1
A kind of polyaluminium chloride water purification agent comprising ingredient and mass content be：78-89 parts of component first, component second is 15-28
Part；
Wherein, the component first be water purification host agent comprising ingredient and mass content be：White aluminium polychloride 56-78
Part, 32-45 parts of polyacrylamide, 15-27 parts of 12 hydrazine aluminum sulfate potassium；
Wherein, the component second be water purifying assistant, including ingredient and mass content be：8-12 parts of carbon black, 3-11 parts of silica gel.
For the carbon black in powdered, specific surface area A is 1200-2300 meters squared per gram.
According to Fig. 1-3, for preferably purifying drinking water, the present invention also provides a kind of aluminium polychloride water purification rod,
Including stick pipe 1 and aluminium polychloride filter layer 2, the aluminium polychloride filter layer 2 is made of polyaluminium chloride water purification agent, described
The top of stick pipe 1 is provided with water inlet 3, and the upside of the stick pipe 1 is provided with thread segment 4, and the outside of the thread segment 4 is bolted with lid
Plate 5, the inner wall of the stick pipe 1 are provided with guide groove 6, and the guide groove 6 is internally provided with sliding block 7, the upside between the sliding block 7
It is provided with baffle 8, the downside between the sliding block 7 is provided with supporting block 9, and the top of the supporting block 9 is equipped with limited block 10,
The aluminium polychloride filter layer 2 is set between limited block 10, and the lower part of the supporting block 9 is equipped with activated carbon filter layer
11, the side of the stick pipe 1 is provided with water outlet 12.
The inside of the cover board 5 is provided with the internal screw thread 13 to match with thread segment 4, and the side of the cover board 5 is uniform
It is disposed with convex block 14.Internal screw thread 13 can preferably realize being spirally connected between cover board 5 and stick pipe 1, and convex block 14 effectively increases frictional force,
Facilitate the unlatching and use of personnel.
The sliding block 7 is symmetrically arranged with two groups relative to stick pipe 1, and the top of the sliding block 7 is provided with sealing ring 15.Side
Just sliding block 7 is moved, reaches and the aluminium polychloride filter layer 2 inside limited block 10 is installed, realizes whole peace
Dress process.
The middle part of the baffle 8 and the middle part of supporting block 9 are uniformly covered with respectively through-hole 16, the top of the limited block 10
It is installed on the lower part of baffle 8, and the limited block 10 is provided with through hole 17 close to the side of baffle 8.Through-hole 16 and through hole
17 can more conveniently realize the entrance and flowing of water flow, improve purification efficiency.
According to Fig. 4-6, a kind of aluminium polychloride water purification rod process units, including device noumenon 18 and electric telescopic rod
19, described device ontology 18 is internally provided with station 20, and the middle part of the station 20 is provided with bearing 21, the bearing
21 tops are equipped with fixture block 22, and the inner wall of the fixture block 22 is provided with rubber pad 23, the described one end of bearing 21 far from fixture block 22
It is rotatably connected to motor 25 by drive shaft 24, the electric telescopic rod 19 is installed on the upper wall of device noumenon 18, described electronic
The telescopic end of telescopic rod 19 is equipped with link block 26, and the lower part of the link block 26 is equipped with sucker 27, the link block 26
Outside is equipped with fixture 28.
The fixture block 22 is arranged in semicircular arc, and the fixture block 22 is symmetrically arranged with two groups relative to bearing 21.It is convenient
Stick pipe 1 is fixed in fixture block 22, reaches preferable fixed effect, convenient for being spirally connected for subsequent cover board 5.
The motor 25 is installed on the lower wall of device noumenon 18 by fixing seat 29, and the motor 25 uses variable-frequency motor
Setting.Convenient for the fixation of motor 25 and the control of 25 speed of motor.
The sucker 27 is arranged symmetrically relative to link block 26, is provided with connection between the sucker 27 and link block 26
Bar 30.Sucker 27 preferably adsorbs sliding block 7, and sliding block 7 is promoted to the inside of guide groove 6 convenient for electric telescopic rod 19.
The fixture 28 is in be oppositely arranged, and the inside equidistant placement of the fixture 28 has tooth socket 31 with station 20.Folder
Tool 28 can preferably clamp cover board 5, and tooth socket 31 can be realized preferably to rub with the increase of convex block 14, be convenient for cover board 5 and stick
Being spirally connected between pipe 1.
Working principle：Water purification rod when in use, is increased the frictional force of palm and 5 side wall of cover board by convex block 14, unscrews lid
Plate 5 separates cover board 5 and stick pipe 1, and water flow enters the inside of stick pipe 1, and uniform flow under the action of baffle 8 by water inlet 3
Enter between limited block 10, under the action of aluminium polychloride filter layer 2, adsorption precipitation is carried out to the impurity in water, water is by passing through
Perforation 17 is discharged between limited block 10, is then further filtered by supporting block 9 with activated carbon filter layer 11, and absorption is more
The small particle of refinement, obtains clean water, and clean water is discharged stick pipe 1 by water outlet 12, is convenient for the user to use, in water purification process
In, effectively avoid the aluminium polychloride of Sprayable from spraying absorption, the precipitation process needed for avoiding after purifying improves polyaluminium
The purification efficiency of aluminium water purification rod.
Stick pipe 1 is placed between fixture block 22 and is fixed in production by water purification rod, and sucker 27 adsorbs sliding block 7, fixture 28
Cover board 5 is clamped, the elongation of electric telescopic rod 19 pushes link block 26 to move downward, so that the sliding block 7 that sucker 27 adsorbs is along guide groove 6
It is mounted on the inside of stick pipe 1, then the rotation of motor 25 band dynamic bearing 21 rotates, and bearing 21 drives fixture block 22 to rotate, so that fixture
28 clamping cover boards 5 and stick pipe 1 realization is spirally connected, realization integral installation process, effectively effectively reduce manually with aluminium polychloride
Contact, convenient for artificial operation, convenient for the production of aluminium polychloride water purification rod.
Embodiment 2
A kind of polyaluminium chloride water purification agent comprising ingredient and mass content be：78 parts of component first, component second is 15 parts；
Wherein, the component first be water purification host agent comprising ingredient and mass content be：56 parts of white aluminium polychloride,
32 parts of polyacrylamide, 15 parts of 12 hydrazine aluminum sulfate potassium；
Wherein, the component second be water purifying assistant, including ingredient and mass content be：8 parts of carbon black, 3 parts of silica gel, boron glue
0.7 part.
For the carbon black in powdered, specific surface area A is 1200-2300 meters squared per gram.
The silica gel is activated silica gel.Its hole holds V（The total volume of every gram of silica gel internal void）For 1.7-2.5mL/g.
The specific surface area A of the carbon black and the hole of silica gel hold V and meet：AV is more than or equal to 2100 and is less than or equal to 5500.
According to Fig. 1-3, for preferably purifying drinking water, the present invention also provides a kind of aluminium polychloride water purification rod,
Including stick pipe 1 and aluminium polychloride filter layer 2, the aluminium polychloride filter layer 2 is made of polyaluminium chloride water purification agent, described
The top of stick pipe 1 is provided with water inlet 3, and the upside of the stick pipe 1 is provided with thread segment 4, and the outside of the thread segment 4 is bolted with lid
Plate 5, the inner wall of the stick pipe 1 are provided with guide groove 6, and the guide groove 6 is internally provided with sliding block 7, the upside between the sliding block 7
It is provided with baffle 8, the downside between the sliding block 7 is provided with supporting block 9, and the top of the supporting block 9 is equipped with limited block 10,
The aluminium polychloride filter layer 2 is set between limited block 10, and the lower part of the supporting block 9 is equipped with activated carbon filter layer
11, the side of the stick pipe 1 is provided with water outlet 12.
The inside of the cover board 5 is provided with the internal screw thread 13 to match with thread segment 4, and the side of the cover board 5 is uniform
It is disposed with convex block 14.Internal screw thread 13 can preferably realize being spirally connected between cover board 5 and stick pipe 1, and convex block 14 effectively increases frictional force,
Facilitate the unlatching and use of personnel.
The sliding block 7 is symmetrically arranged with two groups relative to stick pipe 1, and the top of the sliding block 7 is provided with sealing ring 15.Side
Just sliding block 7 is moved, reaches and the aluminium polychloride filter layer 2 inside limited block 10 is installed, realizes whole peace
Dress process.
The middle part of the baffle 8 and the middle part of supporting block 9 are uniformly covered with respectively through-hole 16, the top of the limited block 10
It is installed on the lower part of baffle 8, and the limited block 10 is provided with through hole 17 close to the side of baffle 8.Through-hole 16 and through hole
17 can more conveniently realize the entrance and flowing of water flow, improve purification efficiency.
According to Fig. 4-6, a kind of aluminium polychloride water purification rod process units, including device noumenon 18 and electric telescopic rod
19, described device ontology 18 is internally provided with station 20, and the middle part of the station 20 is provided with bearing 21, the bearing
21 tops are equipped with fixture block 22, and the inner wall of the fixture block 22 is provided with rubber pad 23, the described one end of bearing 21 far from fixture block 22
It is rotatably connected to motor 25 by drive shaft 24, the electric telescopic rod 19 is installed on the upper wall of device noumenon 18, described electronic
The telescopic end of telescopic rod 19 is equipped with link block 26, and the lower part of the link block 26 is equipped with sucker 27, the link block 26
Outside is equipped with fixture 28.
The fixture block 22 is arranged in semicircular arc, and the fixture block 22 is symmetrically arranged with two groups relative to bearing 21.It is convenient
Stick pipe 1 is fixed in fixture block 22, reaches preferable fixed effect, convenient for being spirally connected for subsequent cover board 5.
The motor 25 is installed on the lower wall of device noumenon 18 by fixing seat 29, and the motor 25 uses variable-frequency motor
Setting.Convenient for the fixation of motor 25 and the control of 25 speed of motor.
The sucker 27 is arranged symmetrically relative to link block 26, is provided with connection between the sucker 27 and link block 26
Bar 30.Sucker 27 preferably adsorbs sliding block 7, and sliding block 7 is promoted to the inside of guide groove 6 convenient for electric telescopic rod 19.
The fixture 28 is in be oppositely arranged, and the inside equidistant placement of the fixture 28 has tooth socket 31 with station 20.Folder
Tool 28 can preferably clamp cover board 5, and tooth socket 31 can be realized preferably to rub with the increase of convex block 14, be convenient for cover board 5 and stick
Being spirally connected between pipe 1.
Embodiment 3
A kind of polyaluminium chloride water purification agent comprising ingredient and mass content be：89 parts of component first, component second is 28 parts；
Wherein, the component first be water purification host agent comprising ingredient and mass content be：78 parts of white aluminium polychloride,
45 parts of polyacrylamide, 27 parts of 12 hydrazine aluminum sulfate potassium；
Wherein, the component second be water purifying assistant, including ingredient and mass content be：12 parts of carbon black, 11 parts of silica gel.
For the carbon black in powdered, specific surface area A is 1200-2300 meters squared per gram.The silica gel is activated silica
Glue.Its hole holds V（The total volume of every gram of silica gel internal void）For 1.7-2.5mL/g.
The specific surface area A of the carbon black and the hole of silica gel hold V and meet：AV is more than or equal to 2100 and is less than or equal to 5500.
The content K of aluminum oxide in the white aluminium polychloride is more than or equal to 31% and is less than or equal to 52%；Further, described
The specific surface area A of the content K of aluminum oxide and carbon black, silica gel hole hold V and meet following relationship：
；
Wherein, ω is the aluminum oxide in white aluminium polychloride containing coefficient of discharge, value range 0.26-0.59.
Finally it should be noted that：The foregoing is merely preferred embodiments, are not intended to restrict the invention, although reference
Invention is explained in detail for previous embodiment, for those skilled in the art, still can be to aforementioned each
Technical solution documented by embodiment is modified or equivalent replacement of some of the technical features, of the invention
Within spirit and principle, any modification, equivalent replacement, improvement and so on are all included in the scope of protection of the present invention.
Claims (8)
1. a kind of polyaluminium chloride water purification agent, which is characterized in that including ingredient and mass content be：78-89 parts of component first, group
Dividing second is 15-28 parts；
Wherein, the component first be water purification host agent comprising ingredient and mass content be：White aluminium polychloride 56-78
Part, 32-45 parts of polyacrylamide, 15-27 parts of 12 hydrazine aluminum sulfate potassium；
Wherein, the component second be water purifying assistant, including ingredient and mass content be：8-12 parts of carbon black, 3-11 parts of silica gel.
2. a kind of polyaluminium chloride water purification agent according to claim 1, it is characterised in that：The component second further includes boron
0.7-4.2 parts of glue.
3. a kind of polyaluminium chloride water purification agent according to claim 1 or 2, it is characterised in that：The carbon black is in powder
Shape, specific surface area A are 1200-2300 meters squared per gram.
4. a kind of polyaluminium chloride water purification agent according to claim 1 to 3, it is characterised in that：The silica gel is activated silica
Glue, it is 1.7-2.5mL/g that hole, which holds V,.
5. a kind of aluminium polychloride water purification rod, it is characterised in that：Including stick pipe（1）With aluminium polychloride filter layer（2）, described poly-
Close aluminium chloride filter layer（2）It is made of the polyaluminium chloride water purification agent in claim 1-4；The stick pipe（1）Top be provided with
Water inlet（3）, the stick pipe（1）Upside be provided with thread segment（4）, the thread segment（4）Outside be bolted with cover board（5）,
The stick pipe（1）Inner wall be provided with guide groove（6）, the guide groove（6）Be internally provided with sliding block（7）, the sliding block（7）Between
Upside be provided with baffle（8）, the sliding block（7）Between downside be provided with supporting block（9）, the supporting block（9）Top
Limited block is installed（10）, the aluminium polychloride filter layer（2）It is set to limited block（10）Between, the supporting block（9）'s
Lower part is equipped with activated carbon filter layer（11）, the stick pipe（1）Side be provided with water outlet（12）.
6. a kind of aluminium polychloride water purification rod according to claim 5, it is characterised in that：The cover board（5）Inside set
It is equipped with and thread segment（4）The internal screw thread to match（13）, and the cover board（5）Side be evenly arranged convex block（14）.
7. a kind of aluminium polychloride water purification rod according to claim 5 and 6, it is characterised in that：The sliding block（7）Relative to
Stick pipe（1）It is symmetrically arranged with two groups, and the sliding block（7）Top be provided with sealing ring（15）.
8. a kind of aluminium polychloride water purification rod according to claim 7, it is characterised in that：The baffle（8）Middle part and
Supporting block（9）Middle part be uniformly covered with have through-hole respectively（16）, the limited block（10）Top be installed on baffle（8）Under
Portion.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810828656.0A CN108892198A (en) | 2018-07-25 | 2018-07-25 | A kind of polyaluminium chloride water purification agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810828656.0A CN108892198A (en) | 2018-07-25 | 2018-07-25 | A kind of polyaluminium chloride water purification agent |
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| Publication Number | Publication Date |
|---|---|
| CN108892198A true CN108892198A (en) | 2018-11-27 |
Family
ID=64352487
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103739034A (en) * | 2014-01-27 | 2014-04-23 | 北京戴斯科技有限公司 | Composite water purifying agent and preparation method thereof |
| CN105461032A (en) * | 2015-10-30 | 2016-04-06 | 无锡市嘉邦电力管道厂 | Sewage treatment flocculant and application thereof |
| CN108273319A (en) * | 2018-03-31 | 2018-07-13 | 郑州智谷工业技术有限公司 | A kind of waste cooking oils filter |
-
2018
- 2018-07-25 CN CN201810828656.0A patent/CN108892198A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103739034A (en) * | 2014-01-27 | 2014-04-23 | 北京戴斯科技有限公司 | Composite water purifying agent and preparation method thereof |
| CN105461032A (en) * | 2015-10-30 | 2016-04-06 | 无锡市嘉邦电力管道厂 | Sewage treatment flocculant and application thereof |
| CN108273319A (en) * | 2018-03-31 | 2018-07-13 | 郑州智谷工业技术有限公司 | A kind of waste cooking oils filter |
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