CN108891327B - Rolling curtain cup stand - Google Patents

Rolling curtain cup stand Download PDF

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Publication number
CN108891327B
CN108891327B CN201810653715.5A CN201810653715A CN108891327B CN 108891327 B CN108891327 B CN 108891327B CN 201810653715 A CN201810653715 A CN 201810653715A CN 108891327 B CN108891327 B CN 108891327B
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parts
roller shutter
cup stand
fiber
caragana microphylla
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CN108891327A (en
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吴志光
蒋城娟
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Ningbo Shuaitelong Group Co Ltd
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Ningbo Shuaitelong Group Co Ltd
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B60VEHICLES IN GENERAL
    • B60NSEATS SPECIALLY ADAPTED FOR VEHICLES; VEHICLE PASSENGER ACCOMMODATION NOT OTHERWISE PROVIDED FOR
    • B60N3/00Arrangements or adaptations of other passenger fittings, not otherwise provided for
    • B60N3/10Arrangements or adaptations of other passenger fittings, not otherwise provided for of receptacles for food or beverages, e.g. refrigerated
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L69/00Compositions of polycarbonates; Compositions of derivatives of polycarbonates
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/14Polymer mixtures characterised by other features containing polymeric additives characterised by shape
    • C08L2205/16Fibres; Fibrils

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Transportation (AREA)
  • Physics & Mathematics (AREA)
  • Mechanical Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Thermal Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Physical Vapour Deposition (AREA)
  • Injection Moulding Of Plastics Or The Like (AREA)

Abstract

The invention relates to a cup stand, in particular to a roller shutter cup stand, and belongs to the field of injection molding materials. The rolling curtain cup stand comprises a main body made of PC/ABS alloy material and a PtCu alloy film coated on the surface of the main body. The PC/ABS alloy material comprises the following components in parts by weight: PC: 60-70 parts of ABS resin: 20-30 parts of a reinforcing framework: 20-30 parts, 10-20 parts of PA66, glass fiber: 10-20 parts of caragana microphylla fiber: 10-20 parts of other auxiliary agents: 5-10 parts. The roller shutter cup stand is made of the PC/ABS alloy material, the reinforced framework is adopted in the alloy material as the framework supporting material, a three-dimensional communicated network structure formed by mutually crossing PC, ABS resin and reinforced framework reinforcement can be formed, and the caragana microphylla fiber is added to further enhance the strength of the roller shutter cup stand, so that the strength of the roller shutter cup stand is high, and the requirements of the roller shutter cup stand are met.

Description

Rolling curtain cup stand
Technical Field
The invention relates to a cup stand, in particular to a roller shutter cup stand, and belongs to the field of injection molding materials.
Background
The cup stand is the common accessory among the automotive interior spare, and its effect is used for placing articles such as drinking cup, mineral water bottle, for the convenience that increases roll up curtain cup stand and use, travelling process plays the fixed action to its built-in thing to the travelling of car.
The rolling curtain cup stand realizes the closing and opening of the opening on the cup bracket by sliding the cup cover. However, the roller shutter type cup cover has a large freedom of movement, so that a sufficient gap is left between the sliding groove of the cup support and the cup cover in sliding fit, otherwise, the sliding friction between the local position of the cup cover and the sliding groove is too large or is blocked, otherwise, the cup cover slides under the action of self inertia due to the too large sliding gap, so that an opening in the cup support cannot be effectively closed, and particularly, the cup cover slides under the conditions of vehicle running, vehicle acceleration or braking along with the fluctuation of a road surface, and the like, so that the service life of the roller shutter cup support is short, and the conditions occur in use.
Disclosure of Invention
Aiming at the problems in the prior art, the invention provides the roller shutter cup stand which is high in strength, not easy to break and long in service life.
The purpose of the invention is realized by the following technical scheme: a rolling shutter cup stand comprises a main body made of a PC/ABS alloy material and a PtCu alloy film coated on the surface of the main body.
In the roller shutter cup stand, the PC/ABS alloy material comprises the following components in parts by weight: PC: 60-70 parts of ABS resin: 20-30 parts of a reinforcing framework: 20-30 parts, 10-20 parts of PA66, glass fiber: 10-20 parts of caragana microphylla fiber: 10-20 parts of other auxiliary agents: 5-10 parts.
The roller shutter cup stand is made of the PC/ABS alloy material, the reinforced framework is adopted in the alloy material as the framework supporting material, a three-dimensional communicated network structure formed by mutually crossing PC, ABS resin and reinforced framework reinforcement can be formed, and the caragana microphylla fiber is added to further enhance the strength of the roller shutter cup stand, so that the strength of the roller shutter cup stand is high, and the requirements of the roller shutter cup stand are met.
In the rolling shutter cup stand, the part ratio of the PC to the ABS resin is (2.5-3): 1. in the invention, the tensile strength, the bending modulus and the heat distortion temperature of the PC/ABS alloy material are all reduced along with the increase of the content of the ABS resin and show a linear relation, and the impact strength and the processing fluidity and the component ratio of the PC and the ABS resin show an obvious curve relation.
In the above rolling shutter saucer, the reinforcing frame is made of metal organic frame and VH2And (4) forming. The metal organic framework composing the framework has a microporous three-dimensional network structure, and the synthesized polymer is a network structure formed by stacking nano particles, the particles are very small, about 10-15nm, and the metal organic framework and VH are very suitable to be used as filling materials2The surface structure of the PC/ABS alloy material is changed in the preparation process to generate more defects on the surface of the PC/ABS alloy material, but the existence of the defects can enhance H2And PC will be towards H2The number of transferred charges increases and the stability of the formed inorganic-organic structure is enhanced. At the same time, the presence of defects contributes to H2Is adsorbed to AThe BS resin surface forms a bonding effect with hydrogen bonds in PC, so that the difficulty of forming vacant positions in PC/ABS materials is reduced, the structure is more stable, the stability of the cup stand can be enhanced when the BS resin surface is applied to the roller shutter cup stand, and meanwhile, the strength of the roller shutter cup stand can be enhanced due to the excellent physical performance of the framework.
Preferably, the metal-organic framework and VH2With a mass ratio of (3-5: 1. with an excessive content of metal-organic framework, VH is formed as a concerted action in the reinforcing framework2The content is correspondingly reduced, and the stabilizing effect in the roller shutter cup stand is reduced; VH when the content of the metal-organic skeleton is too small2Easily form broken hydrogen bonds with PC materials, lead to the decline of overall stability and intensity also can't obtain promoting.
In the roller shutter cup stand, the diameter of the caragana microphylla fiber is 20-25 nm. According to the invention, the caragana microphylla fiber is added into the PC/ABS alloy material, wherein the caragana microphylla fiber is high in content, and is long in fiber cell, high in crystallinity and high in fiber orientation degree, so that the fiber is tough, strong and small in elongation.
Preferably, the caragana microphylla fibers are pre-treated by low-temperature plasma and a silane coupling agent. The caragana microphylla fiber treated by low-temperature plasma has new impurities such as-OH, pectin and the like which are thoroughly removed, and the etching effect on the surface of the fiber is moderate; treating the surface of the fiber by a silane coupling agent to form a layer of coupling agent film, wherein C-Si and C-O-Si bonds appear on the surface of the fiber, and the film formed by polycondensation is smooth and complete; the fiber surface treated by the combination has the effect of independent treatment of the fiber surface and the fiber surface, and the formed coupling agent film is compact and uniform.
In the above rolling shutter saucer, the thickness of the PtCu alloy film is 2 to 3 nm. The PtCu alloy film is coated on the surface of the roller shutter cup stand, elements at all positions of the film layer are distributed uniformly, and the average alloy composition is Pt59Cu41. The invention coats a PtCu alloy film on the surface of a main material, and the disordered arrangement of Cu in Pt gaps causes the local distortion of a crystal surface field of Pt, so that the prepared PtCu alloy filmThe PtCu alloy film forms an interface different from the PC material on the surface of the host material, and can enhance the strength of the host material.
In the above-mentioned one of the roller shutter cup holders, the other auxiliary agents include a compatibilizer, an antioxidant, and a lubricant. Preferably, the compatibilizer is a styrene-maleic anhydride copolymer; the antioxidant is one or two of antioxidant 1010 and antioxidant 1076; the lubricant is one or two of stearic acid amide and EBS.
The invention also aims to provide a preparation method of the roller shutter cup stand, which specifically comprises the following steps:
mechanical mixing: adding PC, ABS resin, a reinforced framework, PA66, glass fiber, caragana microphylla fiber and other auxiliary agents into a high-speed mixer, mixing at high speed, and discharging after mixing uniformly;
and (3) extruding and granulating: adding the uniformly mixed materials into a double-screw extruder, and extruding and granulating;
injection molding: adding the particles obtained by extrusion granulation into an injection molding machine, and performing injection molding to obtain a semi-finished product of the roller shutter cup stand;
coating of a coating: and coating the PtCu alloy film on the surface of the semi-finished product of the roller shutter saucer to obtain the finished product of the roller shutter saucer.
In the preparation method of the roller shutter cup stand, the temperature of the double-screw extruder from the feeding head to the machine port is 132-.
In the preparation method of the roller shutter cup stand, the injection molding temperature is 180-190 ℃, and the injection molding pressure is 67-72 MPa.
Compared with the prior art, the invention has the following advantages:
1. the roller shutter cup stand is made of the PC/ABS alloy material, the reinforced framework is adopted in the alloy material as the framework supporting material, a three-dimensional communicated network structure formed by mutually crossing PC, ABS resin and reinforced framework reinforcement can be formed, and the caragana microphylla fiber is added to further enhance the strength of the roller shutter cup stand, so that the strength of the roller shutter cup stand is high, and the requirements of the roller shutter cup stand are met;
2. the invention relates to a metal organic framework and VH2The formed inorganic-organic structure has enhanced stability by combining to form an enhanced framework, so that the finally prepared roller shutter cup stand has high strength;
3. the caragana microphylla fiber is pretreated by low-temperature plasma and a silane coupling agent, the surface of the fiber is jointly treated, the fiber and the fiber have the independent treatment effect, and the formed coupling agent film is compact and uniform.
Detailed Description
The following are specific examples of the present invention and further describe the technical solutions of the present invention, but the present invention is not limited to these examples.
Table 1: EXAMPLES 1-5 Components and parts of materials for rolling shutter cup holder
Figure BDA0001704851510000051
Figure BDA0001704851510000061
Example 1
Mechanical mixing: adding PC, ABS resin, a reinforced framework, PA66, glass fiber, caragana microphylla fiber and other auxiliary agents into a high-speed mixer according to the embodiment 1 in Table 1, mixing at high speed, and discharging after mixing uniformly; wherein the reinforcing skeleton is composed of a metal-organic skeleton and VH2Composition of the metal-organic framework and VH2The mass ratio of (A) to (B) is 3: 1, the diameter of the caragana microphylla fiber is 20nm, and the caragana microphylla fiber is pretreated by low-temperature plasma and a silane coupling agent;
and (3) extruding and granulating: adding the uniformly mixed materials into a double-screw extruder, and extruding and granulating; the temperature of the double-screw extruder from the feeding head to the machine port is 132 ℃, 162 ℃, 167 ℃, 172 ℃, 177 ℃, 182 ℃, 182 ℃, 172 ℃, and the rotating speed of the double-screw extruder is 77 r/min;
injection molding: adding the particles obtained by extrusion granulation into an injection molding machine, and performing injection molding to obtain a semi-finished product of the roller shutter cup stand; the injection molding temperature is 180 ℃, and the injection molding pressure is 67 MPa;
coating of a coating: and coating a PtCu alloy film on the surface of the semi-finished product of the roller shutter saucer to obtain a roller shutter saucer finished product, wherein the thickness of the PtCu alloy film is 2 nm.
Example 2
Mechanical mixing: adding PC, ABS resin, a reinforced framework, PA66, glass fiber, caragana microphylla fiber and other auxiliary agents into a high-speed mixer according to the embodiment 2 in Table 1, mixing at high speed, and discharging after mixing uniformly; wherein the reinforcing skeleton is composed of a metal-organic skeleton and VH2Composition of the metal-organic framework and VH2The mass ratio of (A) to (B) is 3.5: 1, the diameter of the caragana microphylla fiber is 21nm, and the caragana microphylla fiber is pretreated by low-temperature plasma and a silane coupling agent;
and (3) extruding and granulating: adding the uniformly mixed materials into a double-screw extruder, and extruding and granulating; the temperature of the double-screw extruder from the feeding head to the machine port is 133 ℃, 162 ℃, 167 ℃, 172 ℃, 177 ℃, 182 ℃, 182 ℃, 172 ℃, and the rotating speed of the double-screw extruder is 79 r/min;
injection molding: adding the particles obtained by extrusion granulation into an injection molding machine, and performing injection molding to obtain a semi-finished product of the roller shutter cup stand; the injection molding temperature is 182 ℃, and the injection molding pressure is 69 MPa;
coating of a coating: and coating a PtCu alloy film on the surface of the semi-finished product of the roller shutter saucer to obtain a finished product of the roller shutter saucer, wherein the thickness of the PtCu alloy film is 2.2 nm.
Example 3
Mechanical mixing: adding PC, ABS resin, a reinforced framework, PA66, glass fiber, caragana microphylla fiber and other auxiliary agents into a high-speed mixer according to the embodiment 3 in Table 1, mixing at high speed, and discharging after mixing uniformly; wherein the reinforcing skeleton is composed of a metal-organic skeleton and VH2Composition of the metal-organic framework and VH2The mass ratio of (A) to (B) is 4: 1, the diameter of the caragana microphylla fiber is 22.5nm, and the caragana microphylla fiber is subjected to low-temperature plasma and silane coupling agentPretreated caragana microphylla fibers;
and (3) extruding and granulating: adding the uniformly mixed materials into a double-screw extruder, and extruding and granulating; the temperature of the double-screw extruder from the feeding head to the machine port is 134 ℃, 163 ℃, 168 ℃, 173 ℃, 178 ℃, 183 ℃, 183 ℃, 173 ℃, and the rotating speed of the double-screw extruder is 80 r/min;
injection molding: adding the particles obtained by extrusion granulation into an injection molding machine, and performing injection molding to obtain a semi-finished product of the roller shutter cup stand; the injection molding temperature is 185 ℃, and the injection molding pressure is 70 MPa;
coating of a coating: and coating a PtCu alloy film on the surface of the semi-finished product of the roller shutter saucer to obtain a finished product of the roller shutter saucer, wherein the thickness of the PtCu alloy film is 2.5 nm.
Example 4
Mechanical mixing: adding PC, ABS resin, a reinforced framework, PA66, glass fiber, caragana microphylla fiber and other auxiliary agents into a high-speed mixer according to the embodiment 4 in the table 1, mixing at high speed, and discharging after mixing uniformly; wherein the reinforcing skeleton is composed of a metal-organic skeleton and VH2Composition of the metal-organic framework and VH2The mass ratio of (A) to (B) is 4.8: 1, the diameter of the caragana microphylla fiber is 4.5nm, and the caragana microphylla fiber is pretreated by low-temperature plasma and a silane coupling agent;
and (3) extruding and granulating: adding the uniformly mixed materials into a double-screw extruder, and extruding and granulating; the temperature of the double-screw extruder from the feeding head to the machine port is 136 ℃, 163 ℃, 169 ℃, 174 ℃, 178 ℃, 184 ℃, 184 ℃, 173 ℃, and the rotating speed of the double-screw extruder is 81 r/min;
injection molding: adding the particles obtained by extrusion granulation into an injection molding machine, and performing injection molding to obtain a semi-finished product of the roller shutter cup stand; the injection molding temperature is 188 ℃, and the injection molding pressure is 70 MPa;
coating of a coating: and coating a PtCu alloy film on the surface of the semi-finished product of the roller shutter saucer to obtain a finished product of the roller shutter saucer, wherein the thickness of the PtCu alloy film is 2.8 nm.
Example 5
Mechanical mixing: mixing PC, ABS resin, reinforcing skeleton, PA66, glass fiber, and caragana microphylla fiberAdding other auxiliary agents into a high-speed mixer, mixing at a high speed, and discharging after uniformly mixing; wherein the reinforcing skeleton is composed of a metal-organic skeleton and VH2Composition of the metal-organic framework and VH2The mass ratio of (A) to (B) is 5: 1, the diameter of the caragana microphylla fiber is 25nm, and the caragana microphylla fiber is pretreated by low-temperature plasma and a silane coupling agent;
and (3) extruding and granulating: adding the uniformly mixed materials into a double-screw extruder, and extruding and granulating; the temperature of the double-screw extruder from the feeding head to the machine port is 137 ℃, 164 ℃, 169 ℃, 174 ℃, 179 ℃, 184 ℃, 184 ℃, 174 ℃, and the rotating speed of the double-screw extruder is 82 r/min;
injection molding: adding the particles obtained by extrusion granulation into an injection molding machine, and performing injection molding to obtain a semi-finished product of the roller shutter cup stand; the injection molding temperature is 190 ℃, and the injection molding pressure is 72 MPa;
coating of a coating: and coating a PtCu alloy film on the surface of the semi-finished product of the roller shutter saucer to obtain a roller shutter saucer finished product, wherein the thickness of the PtCu alloy film is 3 nm.
Example 6
The difference from embodiment 3 is only that the main material of the rolling shutter cup holder of this embodiment does not contain a reinforcing skeleton, and the rest is the same as that of embodiment 3, and the description is omitted here.
Example 7
The difference from embodiment 3 is only that the main material of the rolling shutter cup holder of this embodiment does not contain PA66, and the rest is the same as embodiment 3, and the description is omitted here.
Example 8
The difference from the embodiment 3 is only that the main material of the roller shutter cup holder of the embodiment does not contain caragana microphylla fiber, and the rest is the same as the embodiment 3, and the description is omitted.
Example 9
The difference from the embodiment 3 is only that the part ratio of the PC to the ABS resin in the main material of the rolling curtain cup holder of the embodiment is 2.3: 1, the rest is the same as embodiment 3, and is not described herein again.
Example 10
The difference from the embodiment 3 is only that the part ratio of the PC to the ABS resin in the main material of the rolling curtain cup holder of the embodiment is 3.2: 1, the rest is the same as embodiment 3, and is not described herein again.
Example 11
The difference from the embodiment 3 is only that the reinforced framework in the main material of the rolling shutter cup holder of the embodiment is a reinforced framework which is generally sold in the market, and the rest is the same as the embodiment 3, and the description is omitted here.
Example 12
The difference from embodiment 3 is only that the reinforced framework in the main material of the rolling shutter cup holder of this embodiment is only composed of metal organic framework, and the rest is the same as embodiment 3, and will not be described again here.
Example 13
The difference from the embodiment 3 is only that the reinforcing framework in the main body material of the rolling shutter cup holder of the embodiment is only formed by VH2The composition is otherwise the same as in example 3, and will not be described again here.
Example 14
The difference from the embodiment 3 is only that the caragana microphylla fiber in the main body material of the roller shutter cup holder of the embodiment is caragana microphylla fiber which is not pretreated, and the rest is the same as the embodiment 3, and the description is omitted.
Example 15
The difference from the embodiment 3 is only that the caragana microphylla fiber in the main body material of the roller shutter cup holder of the embodiment is only subjected to the low-temperature plasma treatment, and the rest is the same as the embodiment 3, and the description is omitted.
Example 16
The difference from the embodiment 3 is only that the caragana microphylla fiber in the main body material of the roller shutter cup holder of the embodiment is only pretreated by the silane coupling agent, and the rest is the same as the embodiment 3, and the description is omitted.
Example 17
The difference from embodiment 3 is only that the thickness of the PtCu alloy film of the rolling shutter cup holder in this embodiment is 1.8nm, and the rest is the same as that of embodiment 3, and the description thereof is omitted.
Example 18
The difference from embodiment 3 is only that the thickness of the PtCu alloy film of the rolling shutter cup holder in this embodiment is 3.2nm, and the rest is the same as that of embodiment 3, and the description thereof is omitted.
Comparative example 1
The difference from example 3 is only that the rolling blind cup holder of the comparative example is made of common commercial injection molding material, and the rest is the same as example 3, and the description is omitted.
Comparative example 2
The difference from example 3 is only that the surface of the comparative example body is not coated with the PtCu alloy film, and the rest is the same as example 3, and is not described again here.
The rolling blind cup holders of examples 1 to 18 and comparative examples 1 to 2 were subjected to performance tests, and the test results are shown in table 2.
Table 2: performance test results of the roller blind cup holders of examples 1 to 18 and comparative examples 1 to 2
Figure BDA0001704851510000111
Figure BDA0001704851510000121
The roller shutter cup stand is made of the PC/ABS alloy material, the reinforced framework is adopted in the alloy material as the framework supporting material, a three-dimensional communicated network structure formed by mutually crossing PC, ABS resin and reinforced framework reinforcement can be formed, and the caragana microphylla fiber is added to further enhance the strength of the roller shutter cup stand, so that the strength of the roller shutter cup stand is high, and the requirements of the roller shutter cup stand are met.
The specific embodiments described herein are merely illustrative of the spirit of the invention. Various modifications or additions may be made to the described embodiments or alternatives may be employed by those skilled in the art without departing from the spirit or ambit of the invention as defined in the appended claims.
While the invention has been described in detail and with reference to specific embodiments thereof, it will be apparent to one skilled in the art that various changes and modifications can be made therein without departing from the spirit and scope thereof.

Claims (3)

1. The rolling shutter cup stand is characterized by comprising a main body made of a PC/ABS alloy material and a PtCu alloy film coated on the surface of the main body; the PC/ABS alloy material comprises the following components in parts by weight: PC: 60-70 parts of ABS resin: 20-30 parts of a reinforcing framework: 20-30 parts, 10-20 parts of PA66, glass fiber: 10-20 parts of caragana microphylla fiber: 10-20 parts of other auxiliary agents: 5-10 parts; the parts ratio of the PC to the ABS resin is (2.5-3): 1; the reinforced skeleton consists of a metal-organic skeleton and VH2 Composition is carried out; the metal-organic frameworks and VH2The mass ratio of (3-5): 1; the caragana microphylla fiber is pretreated by low-temperature plasma and a silane coupling agent.
2. The rolling cup holder as claimed in claim 1, wherein the caragana microphylla fiber has a diameter of 20-25 nm.
3. The rolling shutter cup holder of claim 1, wherein the PtCu alloy film has a thickness of 2-3 nm.
CN201810653715.5A 2018-06-22 2018-06-22 Rolling curtain cup stand Active CN108891327B (en)

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Publication number Priority date Publication date Assignee Title
CN101303325B (en) * 2008-06-25 2011-03-30 华东师范大学 Method for preparing platinum nanometer perforated electrodes with electrodeposition
CN102516735B (en) * 2011-12-09 2013-06-12 上海锦湖日丽塑料有限公司 Low-internal-stress electroplating PC/ABS alloy material and preparation method thereof
CN203666456U (en) * 2013-09-25 2014-06-25 芜湖福赛科技有限公司 Automobile auxiliary instrument panel cup holder and sundry box roller shutter structure
CN205615383U (en) * 2016-04-19 2016-10-05 常熟安通林汽车饰件有限公司 Motor vehicle console rolls up curtain saucer

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