CN108878777A - A kind of single-ion conductor polymer lithium-sulfur cell - Google Patents
A kind of single-ion conductor polymer lithium-sulfur cell Download PDFInfo
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- CN108878777A CN108878777A CN201710329705.1A CN201710329705A CN108878777A CN 108878777 A CN108878777 A CN 108878777A CN 201710329705 A CN201710329705 A CN 201710329705A CN 108878777 A CN108878777 A CN 108878777A
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
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- H—ELECTRICITY
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- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
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- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
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- H—ELECTRICITY
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- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/60—Selection of substances as active materials, active masses, active liquids of organic compounds
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- H01M4/604—Polymers containing aliphatic main chain polymers
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- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Abstract
The present invention provides a kind of single-ion conductor polymer lithium-sulfur cells, including：Sulphur anode, cathode and single-ion conductor polymer dielectric blend film, the cathode are metal lithium sheet, and the single-ion conductor polymer dielectric blend film is between the sulphur anode and cathode.Compared with prior art, small molecule lithium salts is free of in single-ion conductor polymer lithium-sulfur cell of the invention, is avoided concentration polarization caused by anions and canons electromigration rate difference, is helped to improve the safety of battery；Also, the dosage of organic solvent is less in polymer lithium-sulfur cell, alleviates the dissolution and loss of active material, helps to improve cyclical stability, avoids using " shuttle " effect caused by ethers electrolyte, avoids using LiPF6Concentration polarization caused by esters electrolyte, safety with higher.
Description
Technical field
The present invention relates to lithium-sulfur cell technical field more particularly to a kind of single-ion conductor polymer lithium-sulfur cells.
Background technique
Elemental sulfur is up to 1675mAh g as the theoretical specific capacity of electrode material-1, the lithium sulphur electricity that is matched with lithium metal
The energy density in pond reaches 2600Wh kg-1, the energy density of the sodium-sulphur battery matched with metallic sodium is up to 1262Wh kg-1,
Metal sulphur battery is a kind of potential high specific energy secondary power supply.But the electronic conductivity of elemental sulfur is very low, about 10-30S
m-1, become and restrict its matter of utmost importance as positive electrode.For the low problem of the electronic conductivity of elemental sulfur, solution point
It is two kinds, the first is the size for reducing sulfur granules, promotes the generation of electron tunneling effect；Second is to become active material
Liquid greatly reduces the interface resistance between collector and solution.Former strategy derives two kinds of specific ways, first is that
Sulfur granules are embedded in micropore carbon carrier, carbon-supported nano sulphur is obtained；Second is that polyacrylonitrile is calcined after being blended with elemental sulfur, by sulphur content
Son is dispersed in the form of chemical bond and is fixed in the composite.The advantage of this strategy is that the electrolysis of esters system still can be used
The battery assembly technology of matter and maturation, the disadvantage is that the carrying capacity of active material is lower, about 35wt%, synthesis technology is cumbersome, and
And still there is a degree of decaying.Latter strategy be replace currently used esters electrolyte with ethers electrolyte, the result is that
The polysulfide dissolution that preliminary electrochemical reduction generates in the electrolytic solution, and is conducive to further electrochemical oxidation.It is this
The advantage of strategy is that the preparation process of anode is simple, the disadvantage is that penetrate porous polymer electrolyte diaphragm right for soluble polysulfide
Redox reaction, i.e. shuttle effect occurs with lithium metal afterwards.
In the solution of above-mentioned sulphur anode, the composite sulfur anode that polyacrylonitrile and elemental sulfur are calcined has been obtained extensively
Application.Certainly, problem is to be dispersed in the form of chemical bond even if sulphur in the carrier, and there are still capacity in esters electrolyte
The problem of decaying.2002, Jiulin Wang etc. was calcined 6 hours after polyacrylonitrile is blended with elemental sulfur at 280-300 DEG C,
The mass fraction of sulphur is 53.41% in obtained composite material, in 1M LiPF6EC/DEC (1:1, v/v) it is provided in electrolyte
700mAh g-1Specific capacity.C.Lai etc. first calcines 6 hours then 300 at 150 DEG C after polyacrylonitrile is blended with elemental sulfur
DEG C continue calcining 3 hours, the mass fraction for obtaining sulphur in S-containing composite is 57%, in 1M LiPF6PC/EC/DEC (1:
4:5, v/v/v) very stable cycle performance is provided in electrolyte, is stablized in 745mAh g-1.Shuya Wei etc. is by polypropylene
Nitrile and elemental sulfur are blended in 400 DEG C of calcinings, and the mass fraction of sulphur is 45.6% in obtained S-containing composite, in 1M LiPF6
EC/DEC (1:1, v/v) stable cycle performance is obtained in electrolyte, capacity remains at after 0.4C runs 1000 circulations
1000mAh g-1More than.
Meanwhile restrict the practical application of lithium-sulfur cell there are one factor, i.e. lithium anode bring safety is hidden
Suffer from.Traditional commerce electrolyte is to conduct ion by small molecule lithium salts, can be rich in fact, anion and be not involved in electrode reaction
Collection causes concentration polarization, and then lead to the formation of dendrite in electrode surface.
Summary of the invention
Present invention solves the technical problem that being to provide a kind of single-ion conductor polymer lithium-sulfur cell, concentration polarization is avoided
Change, safety with higher.
In view of this, the present invention provides a kind of single-ion conductor polymer lithium-sulfur cells, including：Sulphur anode, cathode and
Single-ion conductor polymer dielectric blend film, the cathode are metal lithium sheet, and the single-ion conductor polymer dielectric is total
Mixed film is between the sulphur anode and cathode.
Preferably, the sulphur anode is prepared as follows：Polyacrylonitrile and elemental sulfur are calcined in nitrogen atmosphere, obtained
To polyacrylonitrile-sulphur；Polyacrylonitrile-the sulphur, carbon dust and bonding agent are mixed, obtain sulphur anode after rolling film.
Preferably, the mass ratio of the polyacrylonitrile and elemental sulfur is 1：4.
Preferably, calcination temperature is 340-360 DEG C, and calcination time is 6 hours.
Preferably, the single-ion conductor polymer dielectric blend film is as electrolyte and diaphragm.
Preferably, the single-ion conductor polymer dielectric blend film is that poly- (ethylene-alt- maleic anhydride) side chain connects
The polymer dielectric blend film of the double sulfimides of branch.
Preferably, the single-ion conductor polymer dielectric blend film is prepared as follows：By single-ion conductor
The ionomer of polymer and (Kynoar-hexafluoropropene) copolymer mix, and N-Methyl pyrrolidone is added, and heating stirring obtains
To homogeneous phase solution；The homogeneous phase solution is placed in culture dish, heats, takes film off after solvent is evaporated, is sliced, vacuum is dry
It is dry, obtain single-ion conductor polymer dielectric blend film.
Preferably, the matter of the ionomer of the single-ion conductor polymer and (Kynoar-hexafluoropropene) copolymer
Amount is than being 2：3.
Preferably, the ionomer of the single-ion conductor polymer is prepared as follows：By poly- (ethylene-alt- horse
Carry out acid anhydrides) it is mixed with the double sulfimides of 4- aminobenzene-trifluoromethyl, using metacresol as solvent, isoquinolin is catalyst, and heating is anti-
It answers, it is dry by lithium ion exchanged, obtain the ionomer of single-ion conductor polymer.
Preferably, the single-ion conductor polymer dielectric blend film is carried out using one or more of following solvent
The solvation of lithium ion：Ethylene carbonate, propene carbonate, dimethyl carbonate, diethyl carbonate, methyl ethyl carbonate.
The present invention provides a kind of single-ion conductor polymer lithium-sulfur cells, including：Sulphur anode, cathode and single-ion conductor
Polymer dielectric blend film, the cathode are metal lithium sheet, and the single-ion conductor polymer dielectric blend film is described
Between sulphur anode and cathode.Compared with prior art, small molecule is free of in single-ion conductor polymer lithium-sulfur cell of the invention
Lithium salts avoids concentration polarization caused by zwitterion electromigration rate difference, helps to improve the safety of battery；Also,
The dosage of organic solvent is less in polymer lithium-sulfur cell, reduces the dissolution and loss of active material, and it is steady to help to improve circulation
It is qualitative, it avoids using " shuttle " effect caused by ethers electrolyte, avoids using LiPF6Concentration difference caused by esters electrolyte
Polarization, safety with higher.
Detailed description of the invention
Fig. 1 is the structural schematic diagram of polymer lithium-sulfur cell；
Fig. 2 is the cyclic voltammetry curve of the polymer lithium-sulfur cell of preparation of the embodiment of the present invention；
Fig. 3 is the charge/discharge platform curve (0.2C) of the polymer lithium-sulfur cell of preparation of the embodiment of the present invention；
Fig. 4 is the high rate performance of the polymer lithium-sulfur cell of preparation of the embodiment of the present invention；
Fig. 5 is charge and discharge platform curve of the polymer lithium-sulfur cell of preparation of the embodiment of the present invention under different multiplying；
Fig. 6 is cycle performance of the polymer lithium-sulfur cell of preparation of the embodiment of the present invention under 1C multiplying power.
Specific embodiment
For a further understanding of the present invention, the preferred embodiment of the invention is described below with reference to embodiment, still
It should be appreciated that these descriptions are only further explanation the features and advantages of the present invention, rather than to the claims in the present invention
Limitation.
The embodiment of the invention discloses a kind of single-ion conductor polymer lithium-sulfur cells, as shown in Figure 1, including：Sulphur anode
101, cathode 102 and single-ion conductor polymer dielectric blend film 103, cathode 102 are metal lithium sheet, single-ion conductor polymerization
Object electrolyte blend film 103 is between sulphur anode 101 and cathode 102.
Specifically, the present invention mixes polyacrylonitrile with the calcined product of elemental sulfur with a certain proportion of carbon dust and bonding agent
Film preparation sulphur anode is rolled after conjunction, using metal lithium sheet as cathode, with the double sulfimides of poly- (ethylene-alt- maleic anhydride) side chain graft
Polymer dielectric blend film as diaphragm and electrolyte, the mixed solvent of ethylene carbonate and dimethyl carbonate is as molten
The solvation of agent help lithium ion.
Preferably, the sulphur anode is prepared as follows：By polyacrylonitrile and elemental sulfur in nitrogen atmosphere
Calcining, obtains polyacrylonitrile-sulphur；Polyacrylonitrile-the sulphur, carbon dust and bonding agent are mixed, obtain sulphur anode after rolling film.Its
In, the mass ratio of the polyacrylonitrile and elemental sulfur is preferably 1：4；Calcination temperature is preferably 340-360 DEG C, more preferably 350-
360 DEG C, calcination time is preferably 6 hours, and heating rate is preferably 4-6 DEG C/min, and more preferably 5 DEG C/min.System of the present invention
Standby polyacrylonitrile-sulphur, the mass fraction of sulphur are about 45wt%.The mass ratio of the polyacrylonitrile-sulphur, carbon dust and bonding agent is excellent
It is selected as 2-4：1：1, more preferably 3：1：1.The step for obtaining sulphur anode is specially：It weighs polyacrylonitrile-sulphur, acetylene black and gathers inclined
Vinyl fluoride sulphur is added suitable N-Methyl pyrrolidone (NMP) in small beaker, and heating stirring obtains sticky equal afterwards for a period of time
Even slurry；Slurry is coated uniformly on aluminium foil surface with scraper, 60 DEG C of drying remove NMP, then are cut into directly with slicer
Diameter is the round positive plate of 16mm, continues 60 DEG C and is dried in vacuo 24 hours.
Preferably, the single-ion conductor polymer dielectric blend film is used as electrolyte and diaphragm, lithium simultaneously
Transference number of ions is 1 or close to 1.Preferably poly- (the Malaysia ethylene-alt- of single-ion conductor polymer dielectric blend film
Acid anhydrides) the double sulfimides of side chain graft polymer dielectric blend film.The single-ion conductor polymer dielectric blend film
It is prepared as follows：The ionomer of single-ion conductor polymer and (Kynoar-hexafluoropropene) copolymer are mixed,
N-Methyl pyrrolidone is added, heating stirring obtains homogeneous phase solution；The homogeneous phase solution is inclined in culture dish, is heated, to
Solvent takes film off after being evaporated, be sliced, and vacuum drying obtains single-ion conductor polymer dielectric blend film.Wherein, the list
The mass ratio of the ionomer of ionic conduction polymer and (Kynoar-hexafluoropropene) copolymer is preferably 2：3.
The ionomer of the single-ion conductor polymer is preferably prepared as follows：By poly- (ethylene-alt- maleic acid
Acid anhydride) it is mixed with the double sulfimides of 4- aminobenzene-trifluoromethyl, using metacresol as solvent, isoquinolin is catalyst, heating reaction,
It is dry by lithium ion exchanged, obtain the ionomer of single-ion conductor polymer.Synthesis path is as follows：
Preferably, the single-ion conductor polymer dielectric blend film uses one of following solvent or several
Kind carries out the solvation of lithium ion：Ethylene carbonate, propene carbonate, dimethyl carbonate, diethyl carbonate, methyl ethyl carbonate.
From above scheme as can be seen that being free of small molecule lithium in single-ion conductor polymer lithium-sulfur cell provided by the invention
Salt avoids concentration polarization caused by zwitterion electromigration rate difference, helps to improve the safety of battery；Also, it is poly-
The dosage for closing organic solvent in object lithium-sulfur cell is less, reduces the dissolution and loss of active material, helps to improve stable circulation
Property, it avoids using " shuttle " effect caused by ethers electrolyte, avoids using LiPF6Concentration polarization caused by esters electrolyte
Change, safety with higher.
For a further understanding of the present invention, technical solution provided by the invention is carried out specifically below with reference to embodiment
Bright, protection scope of the present invention is not limited by the following examples.
Raw material and chemical reagent used in the embodiment of the present invention are commercially available.
Embodiment 1
(1) polyacrylonitrile-magister of sulfur：It is in mass ratio 1 by polyacrylonitrile and elemental sulfur:It is ground in mortar after 4 weighings
Mill makes to be uniformly mixed for 1.5 hours.Then by it, 350 DEG C are calcined 6 hours in a nitrogen atmosphere, and heating rate is 5 DEG C/min.It is cold
But product " polyacrylonitrile-sulphur " is obtained afterwards.Elemental analysis shows that the mass fraction of wherein sulphur is about 45wt%.
(2) preparation of sulfur electrode piece：According to 6:2:2 mass ratio weighs polyacrylonitrile-sulphur, acetylene black respectively and gathers inclined fluorine
Ethylene sulphur is added suitable N-Methyl pyrrolidone (NMP) in small beaker, and heating stirring obtains sticky uniform afterwards for a period of time
Slurry.Slurry is coated uniformly on aluminium foil surface with scraper, 60 DEG C of drying remove NMP, then are cut into diameter with slicer
For the round positive plate of 16mm, continues 60 DEG C and be dried in vacuo 24 hours.
(3) preparation of the polymer dielectric of the double sulfimides of poly- (ethylene-alt- maleic anhydride) side chain graft：Poly- (second
Alkene-alt- maleic anhydride) it is mixed with the double sulfimides of 4- aminobenzene-trifluoromethyl according to stoichiometric ratio, it is molten with metacresol
Agent, isoquinolin are catalyst, heating reaction.It is dry using lithium ion exchanged, obtain single-ion conductor polymer from poly-
Object.
(5) preparation of single-ion conductor polymer dielectric blend film：It is 2 according to mass ratio：3 weigh respectively ionomer and
In small beaker suitable N-Methyl pyrrolidone is added as solvent, heating is stirred in (Kynoar-hexafluoropropene) copolymer
It mixes to obtain transparent homogeneous phase solution.Solution is inclined in culture dish, being placed in horizontal heating plate and is heated, is taken off after solvent is evaporated
Lower film.The blend film tentatively prepared is cut into the disk that diameter is 18mm.Disk diaphragm is continued to be dried in vacuo thorough removing
Organic solvent.
(6) button cell assembles：In the glove box of argon gas protection, elastic slice, gasket, lithium are sequentially placed into negative electrode casing
Piece, ethylene carbonate and dimethyl carbonate (v/v, 1:1) polymer dielectric blend film, ethylene carbonate and the carbonic acid impregnated
Dimethyl ester (v/v, 1:1) the sulphur anode infiltrated, is packaged after covering anode cover with sealing machine.
Cyclic voltammetry of the present invention is using electrode system：Lithium metal is used as to electrode and reference electrode, sulfur electrode
As anode.Electrical potential scan rate is 0.1mV/s, 1.5~3V of scanning range (vs.Li+/Li)。
Charge-discharge test carries out on blue electric tester, investigates the high rate performance and cyclical stability of battery.
Test result is described as follows：
Test results are shown in figure 2 for the cyclic voltammetric of the polymer lithium-sulfur cell of preparation of the embodiment of the present invention, from figure
As can be seen that it has a pair of of redox peaks, the peak potential of oxidation peak is 2.4V, and the peak potential of reduction peak is 1.5V.Document
Middle polyacrylonitrile-sulphur anode is in LiPF6Esters electrolyte in cyclic voltammetric also only a pair of of redox peaks.It therefore can be with
Find out, although the small molecule lithium salts of any double ion type is not added in the present invention, battery can still run, obtain just
Normal electrochemical redox behavior.
Charge/discharge voltage platform curve corresponding with Fig. 2 is as shown in figure 3, it can be seen from the figure that charge/discharge voltage is flat
The peak potential of the corresponding voltage in the center of platform curve and Fig. 2 cyclic voltammetric corresponds, and the specific capacity of charge/discharge is
1000mAh g-1。
Test results are shown in figure 4 for the multiplying power of the polymer lithium-sulfur cell of preparation of the embodiment of the present invention, 1140mAh g-1@
0.2C, 1020mAh g-1@0.4C, 876mAh g-1@0.6C, 700mAh g-1@0.8C, 568mAh g-1@1.0C.It can be with from figure
Find out, with being stepped up for multiplying power, specific discharge capacity is gradually reduced, then, change multiplying power again, as a result, it has been found that specific capacity with
The multiplying power test result of front is consistent, shows that single-ion conductor polymer dielectric being capable of steadily conducting lithium ions.
For charge/discharge voltage platform curve corresponding with multiplying power shown in Fig. 3 test as shown in figure 5, multiplying power is bigger, polarization is electric
It presses bigger.Finally, the loop test under 1C multiplying power is carried out to battery, as shown in fig. 6, having carried out 300 circulations, battery specific capacity
Stablize in~600mAh g-1。
Above-mentioned test result proves, what gel single-ion conductor polymer dielectric, polyacrylonitrile-sulphur and lithium metal were constituted
Single-ion conductor polymer lithium-sulfur cell be it is feasible, avoid polysulfide caused by using ethers electrolyte shuttle effect
It answers, avoids using LiPF6Esters electrolyte bring concentration polarization.
The above description of the embodiment is only used to help understand the method for the present invention and its core ideas.It should be pointed out that pair
For those skilled in the art, without departing from the principle of the present invention, the present invention can also be carried out
Some improvements and modifications, these improvements and modifications also fall within the scope of protection of the claims of the present invention.
Claims (10)
1. a kind of single-ion conductor polymer lithium-sulfur cell, which is characterized in that including：Sulphur anode, cathode and single-ion conductor are poly-
Polymer electrolyte blend film, the cathode are metal lithium sheet, and the single-ion conductor polymer dielectric blend film is in the sulphur
Between anode and cathode.
2. single-ion conductor polymer lithium-sulfur cell according to claim 1, which is characterized in that the sulphur anode is according to such as
The preparation of lower section method：
Polyacrylonitrile and elemental sulfur are calcined in nitrogen atmosphere, obtain polyacrylonitrile-sulphur；
Polyacrylonitrile-the sulphur, carbon dust and bonding agent are mixed, obtain sulphur anode after rolling film.
3. single-ion conductor polymer lithium-sulfur cell according to claim 2, which is characterized in that the polyacrylonitrile and list
The mass ratio of matter sulphur is 1：4.
4. single-ion conductor polymer lithium-sulfur cell according to claim 2, which is characterized in that calcination temperature 340-
360 DEG C, calcination time is 6 hours.
5. single-ion conductor polymer lithium-sulfur cell according to claim 1, which is characterized in that the single-ion conductor is poly-
Polymer electrolyte blend film is as electrolyte and diaphragm.
6. single-ion conductor polymer lithium-sulfur cell according to claim 1, which is characterized in that the single-ion conductor is poly-
Polymer electrolyte blend film is that the polymer dielectric of the double sulfimides of poly- (ethylene-alt- maleic anhydride) side chain graft is blended
Film.
7. single-ion conductor polymer lithium-sulfur cell according to claim 1, which is characterized in that the single-ion conductor is poly-
Polymer electrolyte blend film is prepared as follows：
The ionomer of single-ion conductor polymer and (Kynoar-hexafluoropropene) copolymer are mixed, N- methyl pyrrole is added
Pyrrolidone, heating stirring obtain homogeneous phase solution；
The homogeneous phase solution is placed in culture dish, heats, takes film off after solvent is evaporated, is sliced, vacuum drying obtains list
Ionic conduction polymer electrolyte blend film.
8. single-ion conductor polymer lithium-sulfur cell according to claim 7, which is characterized in that the single-ion conductor is poly-
The mass ratio of the ionomer and (Kynoar-hexafluoropropene) copolymer that close object is 2：3.
9. single-ion conductor polymer lithium-sulfur cell according to claim 7, which is characterized in that the single-ion conductor is poly-
The ionomer for closing object is prepared as follows：
Poly- (ethylene-alt- maleic anhydride) is mixed with the double sulfimides of 4- aminobenzene-trifluoromethyl, using metacresol as solvent,
Isoquinolin is catalyst, heating reaction, dry by lithium ion exchanged, obtains the ionomer of single-ion conductor polymer.
10. single-ion conductor polymer lithium-sulfur cell according to claim 1, which is characterized in that the single-ion conductor
Polymer dielectric blend film carries out the solvation of lithium ion using one or more of following solvent：
Ethylene carbonate, propene carbonate, dimethyl carbonate, diethyl carbonate, methyl ethyl carbonate.
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| KR20220129515A (en) * | 2019-12-03 | 2022-09-23 | 벨레노스 클린 파워 홀딩 아게 | Single-ion conductive polymers for electrochemical devices |
| EP3832757A1 (en) * | 2019-12-03 | 2021-06-09 | Belenos Clean Power Holding AG | Single-ion conductive polymers for electrochemical devices |
| JP2021088695A (en) * | 2019-12-03 | 2021-06-10 | ベレノス・クリーン・パワー・ホールディング・アーゲー | Single-ion conductive polymers for electrochemical devices |
| KR20210070189A (en) * | 2019-12-03 | 2021-06-14 | 벨레노스 클린 파워 홀딩 아게 | Single-ion conductive polymers for electrochemical devices |
| CN112898457B (en) * | 2019-12-03 | 2023-11-17 | 巴莱诺斯清洁能源控股公司 | Single ion conductive polymer for electrochemical device |
| CN112898457A (en) * | 2019-12-03 | 2021-06-04 | 巴莱诺斯清洁能源控股公司 | Single ion conducting polymers for electrochemical devices |
| JP7128877B2 (en) | 2019-12-03 | 2022-08-31 | ベレノス・クリーン・パワー・ホールディング・アーゲー | Single conducting polymer for electrochemical devices |
| JP7297127B2 (en) | 2019-12-03 | 2023-06-23 | ベレノス・クリーン・パワー・ホールディング・アーゲー | Single conducting polymer for electrochemical devices |
| US11479626B2 (en) | 2019-12-03 | 2022-10-25 | Belenos Clean Power Holding Ag | Single-ion conductive polymers for electrochemical devices |
| KR102516919B1 (en) | 2019-12-03 | 2023-03-31 | 벨레노스 클린 파워 홀딩 아게 | Single-ion conductive polymers for electrochemical devices |
| KR102539814B1 (en) * | 2019-12-03 | 2023-06-02 | 벨레노스 클린 파워 홀딩 아게 | Single-ion conductive polymers for electrochemical devices |
| CN112382788A (en) * | 2020-09-08 | 2021-02-19 | 合肥国轩高科动力能源有限公司 | Single-ion conductive polymer electrolyte and preparation method and application thereof |
| CN112382788B (en) * | 2020-09-08 | 2022-04-12 | 合肥国轩高科动力能源有限公司 | Single-ion conductive polymer electrolyte and preparation method and application thereof |
| JP7373008B2 (en) | 2022-03-31 | 2023-11-01 | 住友化学株式会社 | Alkali metal-containing polymer, and electrolyte composition and battery containing the same |
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