CN108867112A - Textile printing adhesive - Google Patents
Textile printing adhesive Download PDFInfo
- Publication number
- CN108867112A CN108867112A CN201710327440.1A CN201710327440A CN108867112A CN 108867112 A CN108867112 A CN 108867112A CN 201710327440 A CN201710327440 A CN 201710327440A CN 108867112 A CN108867112 A CN 108867112A
- Authority
- CN
- China
- Prior art keywords
- textile printing
- adhesive
- added
- acrylonitrile
- color ink
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
- D06P1/5207—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- D06P1/525—Polymers of unsaturated carboxylic acids or functional derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/22—Emulsion polymerisation
- C08F2/24—Emulsion polymerisation with the aid of emulsifying agents
- C08F2/26—Emulsion polymerisation with the aid of emulsifying agents anionic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/22—Emulsion polymerisation
- C08F2/24—Emulsion polymerisation with the aid of emulsifying agents
- C08F2/30—Emulsion polymerisation with the aid of emulsifying agents non-ionic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J133/04—Homopolymers or copolymers of esters
- C09J133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09J133/08—Homopolymers or copolymers of acrylic acid esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The present invention relates to a kind of textile printing adhesives, have good storage stability, and electrolyte-resistant is strong with pigment intermiscibility.It is used as the adhesive of textile printing color ink, it is possible to provide the good dispersibility of textile printing color ink.It is characterized in that：Butyl acrylate, acrylonitrile, 50% hydroxymethyl acrylamide and acrylic acid are added in a kettle, after being uniformly mixed, water is added, in 82-94 DEG C of progress emulsion polymerization in the presence of suitable cetyl polyethylene oxide ether, dodecyl benzene sulfonic acid and potassium peroxydisulfate, being neutralized to ph with suitable sodium hydroxide solution again is 4.5-6, finally obtains polymer dispersion liquid.
Description
Technical field
The present invention relates to a kind of textile printing adhesives and preparation method thereof, belong to technical field of fine.
Background technique
Textile printing adhesive system butyl acrylate, cetyl polyethylene oxide ether, acrylonitrile, detergent alkylate sulphur
Sour sodium, 50% hydroxymethyl acrylamide, potassium peroxydisulfate, acrylic acid, sodium hydroxide, water etc. are that raw material is rationally formulated.
Textile printing is a kind of new product of adhesive with adhesive, is mainly characterized in that：Raw material is easy to get, simple process,
Long shelf-life, it is easy to use, it is firmly bonded, storage stability, electrolyte-resistant, it is strong with pigment intermiscibility.
Textile printing is had the characteristics that with adhesive：With excellent storage stability, electrolyte-resistant mixes with pigment
Property is strong.
The proportion of this textile printing adhesive is seen in the report of scientific and technical literature not yet.
Summary of the invention
The technical problem to be solved in the invention, which is that, to be overcome the deficiencies of existing technologies, and a kind of textile printing glue is provided
Glutinous agent and preparation method thereof, its raw material is easy to get, simple process, and long shelf-life is easy to use, is firmly bonded, and storage stability is resistance to
Electrolyte is strong with pigment intermiscibility.It is used as the adhesive of textile printing color ink, it is possible to provide the good dispersion of textile printing color ink
Property.
To solve the above problems, the present invention adopts the following technical scheme that：
The invention discloses a kind of textile printing adhesive preparation methods, and the textile printing is with adhesive by following weight
The raw material of part proportion is prepared：Butyl acrylate 19.47%~21%, cetyl polyethylene oxide ether is appropriate, acrylonitrile 4%
~4.1%, appropriate dodecyl benzene sulfonic acid, 50% hydroxymethyl acrylamide 1.8%~2.0%, appropriate potassium peroxydisulfate, acrylic acid
0.88%~0.91%, Sodium hydroxide q.s., water 73%~75%.
The present invention provides a kind of preparation method of textile printing adhesive, it is characterised in that：Third is added in a kettle
After being uniformly mixed, water is added, suitable 16 in olefin(e) acid butyl ester, acrylonitrile, 50% hydroxymethyl acrylamide and acrylic acid
In 82-94 DEG C of progress emulsion polymerization in the presence of alkyl polyoxyethylene ether, dodecyl benzene sulfonic acid and potassium peroxydisulfate, then in right amount
Sodium hydroxide solution be neutralized to ph be 4.5-6, finally obtain polymer dispersion liquid.
A kind of textile printing adhesive system butyl acrylate of the present invention, cetyl polyethylene oxide ether, acrylonitrile, ten
Dialkyl benzene sulfonic acids sodium, 50% hydroxymethyl acrylamide, potassium peroxydisulfate, acrylic acid, sodium hydroxide, water bonding as main component
Agent.Storage stability, electrolyte-resistant are strong with pigment intermiscibility.It is used as the adhesive of textile printing color ink, it is possible to provide textile printing
The good dispersibility of color ink.
Specific embodiment
Example 1
Textile printing is prepared with adhesive by the raw material of following weight：Butyl acrylate 19.6%, cetyl are poly-
Ethylene oxide ether is appropriate, acrylonitrile 4.05%, appropriate dodecyl benzene sulfonic acid, 50% hydroxymethyl acrylamide 1.86%, potassium peroxydisulfate
In right amount, acrylic acid 0.88%, Sodium hydroxide q.s., water 73.9%.
Butyl acrylate, acrylonitrile, 50% hydroxymethyl acrylamide and acrylic acid are added in a kettle, is stirred
After even, water is added, in 82- in the presence of suitable cetyl polyethylene oxide ether, dodecyl benzene sulfonic acid and potassium peroxydisulfate
94 DEG C of progress emulsion polymerizations, then being neutralized to ph with suitable sodium hydroxide solution is 4.5-6, finally obtains polymer dispersion liquid.
Example 2
Textile printing is prepared with adhesive by the raw material of following weight：Butyl acrylate 20%, cetyl polycyclic
Oxidative ethane ether is appropriate, acrylonitrile 4.09%, appropriate dodecyl benzene sulfonic acid, 50% hydroxymethyl acrylamide 1.9%, potassium peroxydisulfate are fitted
Amount, acrylic acid 0.89%, Sodium hydroxide q.s., water 74.6%.
Butyl acrylate, acrylonitrile, 50% hydroxymethyl acrylamide and acrylic acid are added in a kettle, is stirred
After even, water is added, in 82- in the presence of suitable cetyl polyethylene oxide ether, dodecyl benzene sulfonic acid and potassium peroxydisulfate
94 DEG C of progress emulsion polymerizations, then being neutralized to ph with suitable sodium hydroxide solution is 4.5-6, finally obtains polymer dispersion liquid.
Example 3
Textile printing is prepared with adhesive by the raw material of following weight：Butyl acrylate 21%, cetyl polycyclic
Oxidative ethane ether is appropriate, acrylonitrile 4.1%, appropriate dodecyl benzene sulfonic acid, 50% hydroxymethyl acrylamide 2.0%, potassium peroxydisulfate are fitted
Amount, acrylic acid 0.91%, Sodium hydroxide q.s., water 75%.
Butyl acrylate, acrylonitrile, 50% hydroxymethyl acrylamide and acrylic acid are added in a kettle, is stirred
After even, water is added, in 82- in the presence of suitable cetyl polyethylene oxide ether, dodecyl benzene sulfonic acid and potassium peroxydisulfate
94 DEG C of progress emulsion polymerizations, then being neutralized to ph with suitable sodium hydroxide solution is 4.5-6, finally obtains polymer dispersion liquid.
Finally it should be noted that：Obviously, the above embodiment is merely an example for clearly illustrating the present invention, and simultaneously
Restriction to embodiment.For those of ordinary skill in the art, it can also make on the basis of the above description
Other various forms of variations or variation.There is no necessity and possibility to exhaust all the enbodiments.And it is thus amplified
Obvious changes or variations out are still in the protection scope of this invention.
Claims (3)
1. a kind of textile printing adhesive, the present invention has good storage stability, electrolyte-resistant, with pigment intermiscibility
By force, it is used as the adhesive of textile printing color ink, it is possible to provide the good dispersibility of textile printing color ink.
2. a kind of textile printing adhesive preparation method, which is characterized in that the textile printing is with adhesive by following weight
The raw material of part proportion is prepared：Butyl acrylate 20%, cetyl polyethylene oxide ether is appropriate, acrylonitrile 4.09%, 12
Appropriate alkyl benzene sulphonate, 50% hydroxymethyl acrylamide 1.9%, appropriate potassium peroxydisulfate, acrylic acid 0.89%, Sodium hydroxide q.s., water
74.6%。
3. the preparation method of textile printing adhesive as claimed in claim 2, it is characterised in that：Third is added in a kettle
After being uniformly mixed, water is added, suitable 16 in olefin(e) acid butyl ester, acrylonitrile, 50% hydroxymethyl acrylamide and acrylic acid
In 82-94 DEG C of progress emulsion polymerization in the presence of alkyl polyoxyethylene ether, dodecyl benzene sulfonic acid and potassium peroxydisulfate, then in right amount
Sodium hydroxide solution be neutralized to ph be 4.5-6, finally obtain polymer dispersion liquid.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710327440.1A CN108867112A (en) | 2017-05-11 | 2017-05-11 | Textile printing adhesive |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710327440.1A CN108867112A (en) | 2017-05-11 | 2017-05-11 | Textile printing adhesive |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108867112A true CN108867112A (en) | 2018-11-23 |
Family
ID=64319309
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710327440.1A Pending CN108867112A (en) | 2017-05-11 | 2017-05-11 | Textile printing adhesive |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108867112A (en) |
-
2017
- 2017-05-11 CN CN201710327440.1A patent/CN108867112A/en active Pending
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102533177B (en) | High water resistance emulsion polyacrylate pressure-sensitive adhesive and preparation method and application thereof | |
| CN104004477B (en) | A kind of room-temperature self crosslinking polyacrylate pressure-sensitive and preparation method thereof and application | |
| CN101302407A (en) | Double-sided adhesive sheet | |
| CN104497201B (en) | Rosin derivative/polyacrylate hybrid miniemulsion pressure sensitive adhesive and preparation method thereof | |
| CN105219316A (en) | A kind of high adhesion energy medical polyacrylate pressure-sensitive adhesive sticks agent | |
| CN107641487B (en) | A kind of lignin/polyacrylate composite adhesive and preparation method thereof | |
| CN104497927B (en) | Butadiene rubber modified vinyl acetate-acrylate latex adhesive and preparation method | |
| CN103030914B (en) | Acrylic ester composition, preparation method of acrylic ester composition, and adhesive tape applying composition | |
| CN102516906B (en) | Method for preparing ethanol-soluble laminating adhesive | |
| CN105713131A (en) | Styrene-acrylic emulsion, preparation method and application thereof | |
| CN101787172A (en) | Preparation method of EVA sole surface treating agent | |
| CN104710562B (en) | Styrene-modified acrylate pressure-sensitive adhesive emulsion and preparation method thereof | |
| CN107419563A (en) | A kind of polymer overmold dispersible pigment color paste and preparation method thereof | |
| CN112391131B (en) | Environment-friendly water-soluble acrylate pressure-sensitive adhesive, adhesive tape and preparation method and application thereof | |
| CN106046243B (en) | A kind of environment-friendly type large arch dam PVC floor latex solution and preparation method thereof | |
| CN108867112A (en) | Textile printing adhesive | |
| CN102796476A (en) | Preparation method for water-soluble acrylic ester printing table glue | |
| CN106753086B (en) | Environment-friendly water-based glue spraying and preparation method thereof | |
| CN104334670B (en) | wet glue | |
| KR20170106295A (en) | Polymer Latex Composition for Fibre Binding | |
| CN108314755A (en) | A kind of environment-protection coating printing adhesive lotion and its preparation method and application | |
| CN103666341A (en) | Electrostatic flocking adhesive and preparation method thereof | |
| JP5727717B2 (en) | Method for producing polymer emulsion | |
| CN102977258B (en) | Styrene acrylic latex for surface coating as well as preparation method and application thereof | |
| CN102549021B (en) | Method for producing polychloroprene latex, polychloroprene latex, and adhesive using same |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20181123 |
|
| WD01 | Invention patent application deemed withdrawn after publication |