One kind is reusable to drop the system that blocks water
Technical field
It blocks water system the present invention relates to a kind of reusable drop, is mainly used for fine and close oil gas sandstone reservoir volume fracturing and changes
It makes.
Background technique
The low-pressure construction that the system that blocks water mainly realizes compact reservoir using the low frictional resistance effect of friction reducer, resistance-reducing yield drop
It is the key index of friction reducer.Currently, blocking water system friction reducer predominantly in polyacrylamide macromolecule for drop both at home and abroad
Polymer, wherein such friction reducer and can be subdivided into emulsion-type and two kinds of powder-type according to the difference of production and processing mode.Existing
In the work progress of field, powder-type friction reducer must be configured to aqueous solution using artificial or liquid equipment, this just gives fine and close storage
The massive hydraulic fracturing construction of layer brings inconvenience, as fracturing unit placing space is limited, flow container placing space is limited, Ren Yuanlao
Big, long construction period of intensity etc. before dynamic, and emulsion-type or Instant friction reducer at the scene in work progress discovery exist layering or
Caking phenomenon, properties of product are greatly reduced;Part drop blocks water, and sand carrying effect is poor, and scene need to improve pump note discharge capacity to make up system
Sand carrying effect cause a large amount of fracturing outlet liquid after Large Construction further, since the anti-hardness performance of polymer salt tolerant itself is poor
Cannot effective reuse, or using reuse after high price water treatment technology, the system is caused not to be well positioned to meet low cost development
Site operation demand.
Therefore, it develops that a kind of resistance-reducing yield is high, the row of helping performance is good, salt resistant character is good, construction and reuses simple process
Reusable drop block water system system, to solve prior art problem, and will have good popularization and application foreground.
Summary of the invention
In order to overcome the problems, such as that existing resistance-reducing yield is low, the row's of helping performance is poor, salt resistant character is poor and cannot recycle, the present invention
It proposes a kind of reusable drop to block water system, is liquid it is an object of the present invention to friction reducer and regulator, increases
The thick time is less than 10 seconds, it can be achieved that online mixture.
The second object of the present invention is of the invention under the normal temperature condition of ground, 1.3~30mPas of fracturing fluid viscosity, and
It can be according to construction demand, the instantaneous conversion of canbe used on line fracturing fluid viscosity.
The third object of the present invention is that the present invention can use clear water or salt content and match in the drain of returning of 100000ppm
Liquid, and without removing calcium ions and magnesium ions, resistance to bacterium it is anti-it is rotten, recycling technique is easier.
The fourth object of the present invention is that the system that blocks water provided by the invention that drops is faintly acid to neutrality, avoids pressing effectively
While splitting the corrosion of equipment and down-hole string, can effective acid etching reservoir carbonate mineral, injury rate is lower, and effect of increasing production is more
Obviously.
The technical solution adopted by the present invention is:
One kind is reusable to drop the system that blocks water, it is formulated in following mass component ratio:
Friction reducer:0.2 part~1.5 parts;
Regulator:0~1 part;
Surplus is with liquid water.
It is formulated in following mass component ratio:
Friction reducer:1 part;
Regulator:0.5 part;
Surplus is with liquid water.
The friction reducer is 40~55% surfactants, 4~15%, 10~20% solvent of salicylic acid, and surplus is water.
The solvent is one or more mixtures of methanol, isobutanol, ethylene glycol, glycerol.
The surfactant is dodecyl tertiary amine oxide, oleamide diemethylamine, erucyl amide propyl two
One of methylamine or a variety of mixtures.
The regulator is acidity.
The liquid water of matching is the fracturing outlet liquid of clear water or salt content in 100000ppm.
Fracturing outlet liquid of the salt content in 100000ppm is to drop to block water to return drain, corruption or uncorrupted
Guanidine glue returns drain, putrid and deteriorated or uncorrupted EM series returns drain or stratum pumping water or output water.
A kind of recycling drop prepared blocks water as faintly acid to neutrality.
The drop blocks water online mixture when site operation, prepares drop and blocks water the system thickening time lower than 10s, and online mixture
1.3~the 30mPas of system viscosity that blocks water drops.
Beneficial effects of the present invention are:
In the present invention, a kind of recycling drop blocks water by forming following weight percentage components:Friction reducer:0.2 part~1.5
Part;Regulator:0~1 part;Surplus is with liquid water.Friction reducer and regulator are liquid, thicken the time less than 10 seconds, it can be achieved that
Online mixture.
In the present invention, a kind of recycling drop resistance-reducing yield that blocks water reaches as high as 70% or more.
In the present invention, a kind of recycling drop system that blocks water is faintly acid to neutrality, is effectively avoiding fracturing unit and well
While the corrosion of lower tubular column, can effective acid etching reservoir carbonate mineral, injury rate is lower, and effect of increasing production becomes apparent from.
In the present invention, a kind of recycling drop blocks water under the normal temperature condition of ground, 1.3~30mPas of fracturing fluid viscosity,
And it can be according to construction demand, the instantaneous conversion of canbe used on line fracturing fluid viscosity.
In the present invention, a kind of recycling drop, which blocks water, can use the drain of returning of clear water or salt content in 100000ppm and matches
Liquid, and without removing calcium ions and magnesium ions, resistance to bacterium it is anti-it is rotten, recycling technique is easier.
In the present invention, a kind of recycling drop block water anti-dilative up to 85% or more, and after system pressure the row of helping is functional.
In the present invention, a kind of recycling drop system of blocking water can be avoided effectively during conventional surfactants construct at the scene
When not enough causing Efficient Adhesive Promotion undesirable due to matching liquid water salt ionic concentration or be fresh water with liquid water, KCL need to be manually prepared in advance
The drawbacks of aqueous solution.
It is further detailed below with reference to attached drawing.
Detailed description of the invention
Fig. 1 is to drop the core damage that blocks water to test micro-structure diagram before and after rock core end face.
Fig. 2 is to drop the temperature resistant capability test curve figure that blocks water.
Specific embodiment
Embodiment 1:
In order to overcome the problems, such as that existing resistance-reducing yield is low, the row's of helping performance is poor, salt resistant character is poor, the invention proposes the repeatable benefits of one kind
It is blocked water system with drop, is mainly used for long celebrating fine and close oil gas sandstone reservoir volume fracturing transformation.The drop, which blocks water, can increase in system 10s
It is thick, drain can be returned with liquid in 100000ppm with clear water or salt content, site operation is using online mixture, according to construction need
Asking may be implemented low viscosity to highly viscous moment and converts, and have preferable effect of increasing production.
One kind is reusable to drop the system that blocks water, it is formulated in following mass component ratio:
Friction reducer:1.5 part;
Regulator:1 part;
Surplus is with liquid water.
Heretofore described friction reducer is 40~55% surfactants, 4~15%, 10~20% solvent of salicylic acid, surplus
For water.The solvent is one or more mixtures of methanol, isobutanol, ethylene glycol, glycerol.The surfactant is ten
One of dialkyl group tertiary amine oxide, oleamide diemethylamine, erucyl amide diemethylamine or a variety of mixtures.It is described
Regulator be acidity.The liquid water of matching is the fracturing outlet liquid of clear water or salt content in 100000ppm.The saliferous
Measuring fracturing outlet liquid in 100000ppm is that drop blocks water and returns drain, corruption or uncorrupted guanidine glue returns that drain, corruption has become
Matter or uncorrupted EM series return drain or stratum pumping water or output water.
A kind of recycling drop that the present invention prepares blocks water as faintly acid to neutrality.The drop blocks water online mixed when site operation
Match, prepare drop and block water the system thickening time lower than 10s, and the drop of online mixture blocks water 1.3~30mPas of system viscosity.This hair
The reusable drop of the bright offer system that blocks water more routinely drops and blocks water in water hardness, spoilage organisms tolerance level, soda acid adaptability, contains
Salt amount, taking grittiness etc., performance is more excellent, and there is adaptable water quality, low frictional resistance, Low Damage, height to prevent swollen, Gao Zhupai
The characteristics of, being blocked water using the reusable drop can be achieved online mixture construction, save in advance with liquid and continuous mixing device, tool
There is biggish popularization and application foreground.
Embodiment 2:
On the basis of based on the above embodiment, in the present embodiment, one kind is reusable to drop the system that blocks water, it is by following quality
Component ratio is formulated:
Friction reducer:1 part;
Regulator:0.5 part;
Surplus is with liquid water.
Book friction reducer as described in the examples be 40~55% surfactants, 4~15%, 10~20% solvent of salicylic acid,
Surplus is water.The solvent is one or more mixtures of methanol, isobutanol, ethylene glycol, glycerol.The surfactant
For one of dodecyl tertiary amine oxide, oleamide diemethylamine, erucyl amide diemethylamine or a variety of mixtures.
The regulator is acidity.The liquid water of matching is that the pressure break of clear water or salt content in 100000ppm returns row
Liquid.Fracturing outlet liquid of the salt content in 100000ppm is that drop blocks water and returns that drain, corruption or uncorrupted guanidine glue have returned
Drain, putrid and deteriorated or uncorrupted EM series return drain or stratum pumping water or output water.The present invention prepares a kind of heavy
It is multiple to be blocked water using drop as faintly acid to neutrality.The drop blocks water online mixture when site operation, prepares drop and blocks water the system thickening time
Lower than 10s, and the drop of online mixture blocks water 1.3~30mPas of system viscosity.Reusable drop provided by the invention blocks water
System more routinely drop block water water hardness, spoilage organisms tolerance level, soda acid adaptability, salt content, take in terms of performance more
It is excellent, and have the characteristics that adaptable water quality, low frictional resistance, Low Damage, height prevent swollen, the high row of helping, it is reusable using this
Drop, which blocks water, can be achieved online mixture construction, save in advance with liquid and continuous mixing device.
Embodiment 3:
In the present embodiment, one kind is reusable to drop the system that blocks water, it is formulated in following mass component ratio:
Friction reducer:0.2 part;
Surplus is with liquid water.
Wherein, friction reducer is 40~55% surfactants, 4~15%, 10~20% solvent of salicylic acid, and surplus is water.This reality
Applying and choosing friction reducer in example is 50% surfactant, salicylic acid 10%, and 15% solvent, surplus is water.The solvent is methanol, different
Butanol, ethylene glycol, glycerol one or more mixtures.The surfactant is dodecyl tertiary amine oxide, oleic acid acyl
One of amine diemethylamine, erucyl amide diemethylamine or a variety of mixtures.The liquid water of matching is clear water or saliferous
Measure the fracturing outlet liquid in 100000ppm.Fracturing outlet liquid of the salt content in 100000ppm is to drop the row of returning that blocks water
Liquid, corruption or uncorrupted guanidine glue return drain, putrid and deteriorated or uncorrupted EM series returns drain or stratum pumping water or
Output water.The drop blocks water online mixture the present invention during on-site construction, prepares drop and blocks water the system thickening time lower than 10s, and
The drop of line mixture blocks water 1.3~30mPas of system viscosity.
It is provided by the invention it is reusable drop block water system more routinely drop block water water hardness, spoilage organisms tolerance level,
Soda acid adaptability, salt content, taking grittiness etc., performance is more excellent, and have adaptable water quality, low frictional resistance, Low Damage,
Height prevents the characteristics of swollen, high row of helping, and being blocked water using the reusable drop can be achieved online mixture construction, saves in advance with liquid and company
Continuous mixing device.
Embodiment 4:
It blocks water system the present embodiment provides a kind of reusable drop, it is to be prepared by following components in following mass component ratio
It forms:
Friction reducer:0.2 part;
Regulator:0.4 part;
Surplus is clear water.
In the present embodiment, described one kind is reusable to drop the system thickening time 5s that blocks water, under the normal temperature condition of ground,
Viscosity is 1.8954mPas, resistance-reducing yield 57%, anti-dilative 85.5%.
In the present embodiment, the friction reducer be by mass ratio be 45% dodecyl tertiary amine oxide, 10% salicylic acid, 15%
The mixture of isobutanol and 25% deionized water composition.The regulator is acidity.
Embodiment 5:
It blocks water system the present embodiment provides a kind of reusable drop, it is to be prepared by following components in following mass component ratio
It forms:
Friction reducer:0.3 part;
Regulator:0.2 part;
Surplus is 6620mg/L fracturing outlet liquid, returns drain ingredient and is shown in Table 1.
1 6620mg/L fracturing outlet liquid water analysis data of table
In the present embodiment, described one kind is reusable to drop block water system thickening time 4s, under the normal temperature condition of ground, viscosity
For 2.4565mPas, resistance-reducing yield 67%.
In the present embodiment, it is 55% oleamide diemethylamine and erucyl amide third that the friction reducer, which is by mass ratio,
Mixture, 4% salicylic acid of base dimethylamine compounding, 20% cosolvent(Methanol:Glycerol=4:1, it is mass ratio)With 21% deionized water
The mixture of composition.The regulator is acidity, is finally adjusted to faintly acid and causes neutrality.
Embodiment 6:
It blocks water system the present embodiment provides a kind of reusable drop, it is to be prepared by following components in following mass component ratio
It forms:
Friction reducer:0.4 part;
Regulator:0.3 part;
Surplus is clear water.
In the present embodiment, described one kind is reusable to drop the system thickening time 10s that blocks water, in ground normal temperature condition
Under, viscosity 22.5236mPas, resistance-reducing yield 76%, anti-dilative 86.4%.
In the present embodiment, the friction reducer be by mass ratio be 40% oleamide diemethylamine, 7% salicylic acid, 20%
Cosolvent(Ethylene glycol:Glycerol:Isobutanol=2:1:5, it is mass ratio)With the mixture of 33% deionized water composition.The adjusting
Agent is acidity, is finally adjusted to faintly acid and causes neutrality.
Embodiment 7:
It blocks water system the present embodiment provides a kind of reusable drop, it is to be prepared by following components in following mass component ratio
It forms:
Friction reducer:1.0 part;
Regulator:0.2 part;
Surplus returns drain for 95666mg/L's, and ingredient is shown in Table 2.
2 95666mg/L fracturing outlet liquid water analysis data of table
In the present embodiment, described one kind is reusable to drop block water system thickening time 9s, under the normal temperature condition of ground, viscosity
For 19.8674mPas, resistance-reducing yield 73%.
In the present embodiment, it is 55% oleamide diemethylamine and erucyl amide third that the friction reducer, which is by mass ratio,
Mixture, 4.5% salicylic acid after base dimethylamine compounding, 18% cosolvent(Methanol:Glycerol:Isobutanol=5:1:2, it is mass ratio)With
The mixture of 22.5% deionized water composition.The regulator is acidity, is finally adjusted to faintly acid and causes neutrality.
Embodiment 8:
It blocks water system the present embodiment provides a kind of reusable drop, it is to be prepared by following components in following mass component ratio
It forms:
Friction reducer:1.5 part;
Regulator:0 part;
Surplus is 20000mg/L salt water
(Saline formulation is:Deionized water+0.5%KCL+0.8%Cacl2+0.7%Mgcl2).
In the present embodiment, the reusable system that blocks water that drops of described one kind thickens the time at high rigidity 4651mg/L
8s, under the normal temperature condition of ground, viscosity 28.5mPas, resistance-reducing yield 67%.
In the present embodiment, the friction reducer be by mass ratio be 47% erucyl amide diemethylamine, 8% salicylic acid, 20%
Cosolvent(Methanol:Glycerol=8:3, it is mass ratio)With the mixture of 25% deionized water composition.The regulator is acidity, most
It is adjusted to faintly acid eventually and causes neutrality.
Core damage data are shown in Table 3 and Fig. 1,76.2 DEG C of heatproof, drop the temperature resistant capability test curve that blocks water and see Fig. 2.Using sweeping
Retouch electron microscope(SEM)Under different amplification observe core damage experiment front/rear end pattern, and with do not hurt
The rock core end face comparison of evil experiment, with this more intuitive observation core damage rate situation.Experimental result is shown in Fig. 1 to drop the rock core that blocks water
Microstructure before and after damage experiment rock core end face, wherein(a)Not injure;(b)After injury.
The test of 3 breaking glue solution core damage of table
Core numbers |
Rock core type |
Original permeability K0(10-3μm2) |
Permeability K after injurya(10-3μm2) |
Core damage rate(%) |
1-11-38-2 |
Tight sand |
0.00071 |
0.00068 |
5.08 |
3-37-105-2 |
Tight sand |
0.02244 |
0.02130 |
5.07 |
The foregoing examples are only illustrative of the present invention, does not constitute the limitation to protection scope of the present invention, it is all with
Within the same or similar design of the present invention all belongs to the scope of protection of the present invention.
In exemplified as above return drain be only to of the invention for example, the technology is not limited only to enumerate in
Return drain, and term is industry essential term in the present invention, is for the reagent and method of detailed description in the present invention
The prior art, the present invention in will no longer be illustrated one by one.