CN108864351A - A kind of methacrylate architectural waterproof material - Google Patents
A kind of methacrylate architectural waterproof material Download PDFInfo
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- CN108864351A CN108864351A CN201810606479.1A CN201810606479A CN108864351A CN 108864351 A CN108864351 A CN 108864351A CN 201810606479 A CN201810606479 A CN 201810606479A CN 108864351 A CN108864351 A CN 108864351A
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- methacrylate
- waterproof material
- architectural waterproof
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
- C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
- C08L33/10—Homopolymers or copolymers of methacrylic acid esters
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2227—Oxides; Hydroxides of metals of aluminium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The present invention relates to construction material production field, specially a kind of methacrylate architectural waterproof material.The invention proposes a kind of methacrylate architectural waterproof materials, and based on parts by weight, raw material includes:35-50 parts of methacrylate, 20-30 parts of stearic acid, 4-9 parts of phthalate anhydride, 10-16 parts of portland cement, 4-6 parts of Petropols, 4-8 parts of nitrile rubber, 8-14 parts of glass fibre, 4-10 parts of diethylenetriamine, 5-11 parts of acrylate, 8-16 parts of miberal powder, 3-6 parts of rosin, 2-4 parts of anhydrous calcium chloride, 2-6 parts of adhesive, 2-6 parts of activating agent, 2-4 parts of stabilizer, 1-3 parts of fire retardant, 1-3 parts of antioxidant etc..Methacrylate architectural waterproof material of the invention has excellent waterproof performance, and crack resistence, anti-softening performance are good, and resistance to compression, anti-permeability performance are high, and stability is good, non-aging.
Description
Technical field
The present invention relates to construction material production field, specially a kind of methacrylate architectural waterproof material.
Background technique
With economic rapid development, increasingly reduction, the continuous improvement of living condition of land resource, the high level of building
Change, high quality is inexorable trend;On the other hand, subway, Tunnel Engineering increase increasingly, and many tier 2 cities have also been built in subway
If ranks.So the quality of architectural waterproof material plays a crucial role the construction quality of these architectural engineerings, it is
It is related to the use value, use condition and sanitary condition of building, influences production activity, the quality of working life of people.
Architectural waterproof material is divided into rigid waterproofing and flexible water according to the difference of principle and mode of appearance.Rigid waterproofing master
Will be using mortar, concrete or mixed with the mortar of additive or the rigid material of coagulation great soil group, but this kind of waterproof material is crisp
Property is big, has the characteristics that crack resistance is poor;Flexible water mainly includes various waterproof rolls, anti-using flexible waterproof material
Water paint and sealing material etc., but the durability of this kind of flexible water is poor, is easy and basal plane removes the phenomenon that generating two layers of skin,
And it is at high cost.
Summary of the invention
For the above-mentioned problems in the prior art, a kind of methacrylate buildings waterproof material proposed by the present invention
Material, with excellent waterproof performance, and crack resistence, anti-softening performance are good, are not easy soften and generate slight crack, resistance to compression, impermeability
Can be high, stability is good, non-aging.
The purpose of the present invention can be achieved through the following technical solutions:
A kind of methacrylate architectural waterproof material, based on parts by weight, raw material includes:
35-50 parts of methacrylate, 20-30 parts of stearic acid, 4-9 parts of phthalate anhydride, 10-16 parts of portland cement,
It is 4-6 parts of Petropols, 4-8 parts of nitrile rubber, 8-14 parts of glass fibre, 4-10 parts of diethylenetriamine, 5-11 parts of acrylate, right
6-10 parts of phenylenediamine, 2-4 parts of styrene, 6-12 parts of hydroxyethyl cellulose, 7-13 parts of talcum powder, 8-16 parts of miberal powder, rosin 3-6
Part, 2-4 parts of anhydrous calcium chloride, 2-6 parts of adhesive, 5-9 parts of bentonite, 2-6 parts of activating agent, 2-4 parts of stabilizer, fire retardant 1-3
Part, 1-3 parts of antioxidant.
Preferably, a kind of methacrylate architectural waterproof material, based on parts by weight, raw material includes:
42 parts of methacrylate, 25 parts of stearic acid, 7 parts of phthalate anhydride, 13 parts of portland cement, 5 parts of Petropols,
6 parts of nitrile rubber, 11 parts of glass fibre, 7 parts of diethylenetriamine, 8 parts of acrylate, 8 parts of p-phenylenediamine, 3 parts of styrene, hydroxyl second
9 parts of base cellulose, 12 parts of miberal powder, 5 parts of rosin, 3 parts of anhydrous calcium chloride, 4 parts of adhesive, 7 parts of bentonite, is lived at 10 parts of talcum powder
Property 4 parts of agent, 3 parts of stabilizer, 2 parts of fire retardant, 2 parts of antioxidant.
Preferably, the portland cement is the portland cement that strength grade is higher than 42.5 grades.
Preferably, the activating agent is fatty acid methyl ester APEO.
Preferably, the stabilizer is calcium-zinc composite stabilizing agent.
Preferably, the fire retardant is aluminium hydroxide.
Preferably, the antioxidant is Hinered phenols antioxidant or aromatic amine antioxidant.
Beneficial effects of the present invention:
A kind of methacrylate architectural waterproof material of the invention, have excellent waterproof performance, and crack resistence, prevent it is soft
It is good to change performance, is not easy the slight crack that softens and generate, resistance to compression, anti-permeability performance are high, and stability is good, non-aging.
Specific embodiment
In order to facilitate the understanding of those skilled in the art, the present invention is further illustrated combined with specific embodiments below.
Embodiment 1:
A kind of methacrylate architectural waterproof material, based on parts by weight, raw material includes:
50 parts of methacrylate, 30 parts of stearic acid, 4 parts of phthalate anhydride, strength grade are higher than 42.5 grades of silicate
16 parts of cement, 4 parts of Petropols, 4 parts of nitrile rubber, 14 parts of glass fibre, 10 parts of diethylenetriamine, 5 parts of acrylate, to benzene
6 parts of diamines, 4 parts of styrene, 6 parts of hydroxyethyl cellulose, 13 parts of talcum powder, 16 parts of miberal powder, 3 parts of rosin, 4 parts of anhydrous calcium chloride,
6 parts of adhesive, 5 parts of bentonite, 6 parts of fatty acid methyl ester APEO activating agent, 4 parts of calcium-zinc composite stabilizing agent, aluminium hydroxide
3 parts of fire retardant, Hinered phenols or 1 part of aromatic amine antioxidant.
Embodiment 2:
A kind of methacrylate architectural waterproof material, based on parts by weight, raw material includes:
35 parts of methacrylate, 20 parts of stearic acid, 9 parts of phthalate anhydride, strength grade are higher than 42.5 grades of silicate
10 parts of cement, 6 parts of Petropols, 8 parts of nitrile rubber, 8 parts of glass fibre, 4 parts of diethylenetriamine, 11 parts of acrylate, to benzene
10 parts of diamines, 2 parts of styrene, 12 parts of hydroxyethyl cellulose, 7 parts of talcum powder, 8 parts of miberal powder, 6 parts of rosin, 2 parts of anhydrous calcium chloride,
2 parts of adhesive, 9 parts of bentonite, 2 parts of fatty acid methyl ester APEO activating agent, 2 parts of calcium-zinc composite stabilizing agent, aluminium hydroxide
1 part of fire retardant, Hinered phenols or 3 parts of aromatic amine antioxidant.
Embodiment 3:
A kind of methacrylate architectural waterproof material, based on parts by weight, raw material includes:
40 parts of methacrylate, 28 parts of stearic acid, 7 parts of phthalate anhydride, strength grade are higher than 42.5 grades of silicate
15 parts of cement, 5 parts of Petropols, 7 parts of nitrile rubber, 10 parts of glass fibre, 5 parts of diethylenetriamine, 10 parts of acrylate, to benzene
7 parts of diamines, 3 parts of styrene, 10 parts of hydroxyethyl cellulose, 8 parts of talcum powder, 15 parts of miberal powder, 4 parts of rosin, 4 parts of anhydrous calcium chloride,
5 parts of adhesive, 6 parts of bentonite, 5 parts of fatty acid methyl ester APEO activating agent, 4 parts of calcium-zinc composite stabilizing agent, aluminium hydroxide
3 parts of fire retardant, Hinered phenols or 2 parts of aromatic amine antioxidant.
Embodiment 4:
A kind of methacrylate architectural waterproof material, based on parts by weight, raw material includes:
32 parts of methacrylate, 25 parts of stearic acid, 7 parts of phthalate anhydride, strength grade are higher than 42.5 grades of silicate
13 parts of cement, 5 parts of Petropols, 6 parts of nitrile rubber, 11 parts of glass fibre, 7 parts of diethylenetriamine, 8 parts of acrylate, to benzene
8 parts of diamines, 3 parts of styrene, 9 parts of hydroxyethyl cellulose, 10 parts of talcum powder, 12 parts of miberal powder, 5 parts of rosin, 3 parts of anhydrous calcium chloride,
4 parts of adhesive, 7 parts of bentonite, 4 parts of fatty acid methyl ester APEO activating agent, 3 parts of calcium-zinc composite stabilizing agent, aluminium hydroxide
2 parts of fire retardant, Hinered phenols or 2 parts of aromatic amine antioxidant.
Above content is only to structure of the invention example and explanation, affiliated those skilled in the art couple
Described specific embodiment does various modifications or additions or is substituted in a similar manner, without departing from invention
Structure or beyond the scope defined by this claim, is within the scope of protection of the invention.
Claims (7)
1. a kind of methacrylate architectural waterproof material, which is characterized in that based on parts by weight, raw material includes:
35-50 parts of methacrylate, 20-30 parts of stearic acid, 4-9 parts of phthalate anhydride, 10-16 parts of portland cement, petroleum
4-6 parts of resin, 4-8 parts of nitrile rubber, 8-14 parts of glass fibre, 4-10 parts of diethylenetriamine, 5-11 parts of acrylate, to benzene two
6-10 parts of amine, 2-4 parts of styrene, 6-12 parts of hydroxyethyl cellulose, 7-13 parts of talcum powder, 8-16 parts of miberal powder, 3-6 parts of rosin, nothing
2-4 parts of water calcium chloride, 5-9 parts of bentonite, 2-6 parts of activating agent, 2-4 parts of stabilizer, 1-3 parts of fire retardant, resists 2-6 parts of adhesive
1-3 parts of oxidant.
2. a kind of methacrylate architectural waterproof material according to claim 1, which is characterized in that with parts by weight
Meter, raw material include:
42 parts of methacrylate, 25 parts of stearic acid, 7 parts of phthalate anhydride, 13 parts of portland cement, 5 parts of Petropols, butyronitrile
6 parts of rubber, 11 parts of glass fibre, 7 parts of diethylenetriamine, 8 parts of acrylate, 8 parts of p-phenylenediamine, 3 parts of styrene, ethoxy are fine
Tie up plain 9 parts, 10 parts of talcum powder, 12 parts of miberal powder, 5 parts of rosin, 3 parts of anhydrous calcium chloride, 4 parts of adhesive, 7 parts of bentonite, activating agent 4
Part, 3 parts of stabilizer, 2 parts of fire retardant, 2 parts of antioxidant.
3. a kind of methacrylate architectural waterproof material according to claim 1, which is characterized in that the silicate cement
Mud is the portland cement that strength grade is higher than 42.5 grades.
4. a kind of methacrylate architectural waterproof material according to claim 1, which is characterized in that the activating agent is
Fatty acid methyl ester APEO.
5. a kind of methacrylate architectural waterproof material according to claim 1, which is characterized in that the stabilizer is
Calcium-zinc composite stabilizing agent.
6. a kind of methacrylate architectural waterproof material according to claim 1, which is characterized in that the fire retardant is
Aluminium hydroxide.
7. a kind of methacrylate architectural waterproof material according to claim 1, which is characterized in that the antioxidant
For Hinered phenols antioxidant or aromatic amine antioxidant.
Priority Applications (1)
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CN201810606479.1A CN108864351A (en) | 2018-06-13 | 2018-06-13 | A kind of methacrylate architectural waterproof material |
Applications Claiming Priority (1)
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CN201810606479.1A CN108864351A (en) | 2018-06-13 | 2018-06-13 | A kind of methacrylate architectural waterproof material |
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CN108864351A true CN108864351A (en) | 2018-11-23 |
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CN201810606479.1A Withdrawn CN108864351A (en) | 2018-06-13 | 2018-06-13 | A kind of methacrylate architectural waterproof material |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN112341130A (en) * | 2020-10-16 | 2021-02-09 | 中国人民解放军军事科学院国防工程研究院 | Novel methyl ester waterproof material and preparation method thereof |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106116219A (en) * | 2016-06-17 | 2016-11-16 | 成都创意云科技有限公司 | A kind of architectural waterproof material and preparation method thereof |
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2018
- 2018-06-13 CN CN201810606479.1A patent/CN108864351A/en not_active Withdrawn
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN106116219A (en) * | 2016-06-17 | 2016-11-16 | 成都创意云科技有限公司 | A kind of architectural waterproof material and preparation method thereof |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN112341130A (en) * | 2020-10-16 | 2021-02-09 | 中国人民解放军军事科学院国防工程研究院 | Novel methyl ester waterproof material and preparation method thereof |
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Application publication date: 20181123 |