CN108863124A - A kind of high-performance cement made using mill tailings - Google Patents
A kind of high-performance cement made using mill tailings Download PDFInfo
- Publication number
- CN108863124A CN108863124A CN201810956047.3A CN201810956047A CN108863124A CN 108863124 A CN108863124 A CN 108863124A CN 201810956047 A CN201810956047 A CN 201810956047A CN 108863124 A CN108863124 A CN 108863124A
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- CN
- China
- Prior art keywords
- mill tailings
- tailing
- cement
- clinker
- performance cement
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B7/00—Hydraulic cements
- C04B7/345—Hydraulic cements not provided for in one of the groups C04B7/02 - C04B7/34
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B7/00—Hydraulic cements
- C04B7/14—Cements containing slag
- C04B7/147—Metallurgical slag
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B7/00—Hydraulic cements
- C04B7/24—Cements from oil shales, residues or waste other than slag
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P40/00—Technologies relating to the processing of minerals
- Y02P40/10—Production of cement, e.g. improving or optimising the production methods; Cement grinding
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Soil Conditioners And Soil-Stabilizing Materials (AREA)
Abstract
The invention discloses a kind of high-performance cements made using mill tailings, the high-performance cement is by clinker, mill tailings, anhydrous calcium chloride and eggshell powder is agitated is made after mixing, its raw material forms by mass percentage, including clinker 50 ~ 60%, anhydrous calcium chloride 3 ~ 6%, eggshell powder 5% ~ 10%, mill tailings 20% ~ 35%；The mill tailings is to climb steel Tailing of titanium separation.Bending strength of cement, the compression strength of mill tailings production of the present invention are all improved, and floating powder phenomenon will not occur.
Description
Technical field
The present invention relates to mill tailings process fields, and in particular to a kind of high-performance cement made using mill tailings.
Background technique
Mill tailings refers to raw ore after sorting operation is handled, and main component is enriched in concentrate, some processes
After neutralisation treatment, remaining this portion very low containing useful component after the submember of ore or other associated metals are also recycled
Divide product, or is true tailings.It still is difficult to the useful component extracted containing state-of-the-art in mill tailings, but in the future
It is likely to become the raw material of recycling.
With the development of economy, mineral products demand is increased considerably, Mining Development scale increases therewith, the ore dressing of generation
Tailing quantity will be continuously increased；In addition many available metallic ore grades increasingly reduce, growing in order to meet mineral products
Demand, ore dressing scale is increasing, therefore the milltailings quantity generated will also increase significantly, and the tailing largely stored up,
Many problems are caused to mining industry, environment and economy etc., are mainly had：
(1) mineral resources are taken seriously.Due to not only containing the useful constituents such as the metallic ore that can be selected again and nonmetallic ore in tailing, and
And the true tailings that can not be selected again also has many purposes, therefore the useful constituent quantity wasted in tailing is considerable
's.
(2) a large amount of soils of stockpiling tailing occupancy, stockpiling investment are huge.Both at home and abroad for the processing of tailing, no matter in tailing
Whether valuable mineral has recovery value, is stored up on ground.The stockpiling of tailing not only occupies a large amount of arable land, also
It is easy to cause mine environmental pollution, soil erosion, vegetation deterioration etc..
(3) influence of the tailing to natural ecological environment.Influence of the tailing to natural ecological environment is in particular in：1. tailing
It easily flows and collapses when stockpiling leakage, cause vegetation deterioration and casualty accident, especially easily cause to collapse and come down in rainy season.Tailings Dam
Dam body is higher, and there are hidden dangers.2. tailing ingredient and residual beneficiation reagent are serious to the destruction of ecological environment, especially contain
The tailing of heavy metal, wherein sulfide, which generates acid water and further drenches, soaks heavy metal, and loss will cause entire ecological environment
Harm.
Currently, being with using the several method of simple possible the most to tailing improvement：First is that earthing is built up fields.Compare in soil
Sufficient area can be used 10-20 centimetres of native method of pressure and then be planted, and earthing is built up fields, and is brought more land under cultivation, this side
Method is suitable for the Tailings Dam in mountain valley shape.For many years, this method has been affirmed.But also there is the soil layer because of pressure relatively thin, cause
Dust secondary hazards.Organic-biological is followed by made full use of, in degradable solidification waste material selection, matrix, selection neutron absorption
Substance can be used in mill tailings.It overcomes and occupies a large amount of soil layers, is limited by tailing shape and administer the drawbacks such as inconvenience.Simultaneously
In terms of be also well worth doing.
Finally use tailings utilization construction material.Certain silica sands, sandstone or vein quartz can be utilized in mine tailing.With tailing system
Brick is also to add a certain amount of lime using method well and adobe is made, be then fed into carbonizing chamber, is passed through CO2 and is carbonized into brick,
Not only increase the pressure of brick, reduction takes soil to ruin ground, and economic benefit is also considerable.Tailing can also manufacture plate glass and
Various heat preservations, heat-insulated, acoustic material.It has also been utilized in addition, extracting useful metal technology from tailing.Prior art benefit at present
Make cement material with mill tailings, the cement produced has good folding compressive property, however, its setting time compared with
It is long, it is easy to produce floating powder, and for a long time get off that certain heavy metal the amount of dissolution can be generated, surrounding enviroment is easily caused to destroy.
Therefore, in view of the above-mentioned problems, develop it is a kind of it is economic and environment-friendly, setting time is short, heavy metal is not easy the utilization dissolved out
The method of mill tailings production cement is of great significance.
Summary of the invention
It is an object of the invention to：In view of the above problems, a kind of high-performance made using mill tailings is provided
Cement improves the intensity of cement entirety so as to avoid using the dissolution of the heavy metal of the cement of mill tailings production.
The technical solution adopted by the present invention is as follows：The present invention utilizes the high-performance cement of mill tailings production, ripe by cement
Material, mill tailings, anhydrous calcium chloride and eggshell powder is agitated is made after mixing, raw material forms by mass percentage
Meter, including clinker 50 ~ 60%, anhydrous calcium chloride 3 ~ 6%, eggshell powder 5% ~ 10%, mill tailings 20% ~ 35%；The mine
Tailing is to climb steel Tailing of titanium separation.Climb steel Tailing of titanium separation and contain the various metals such as V, Ti, Co, Ni, Ga, Sc, main mineral constituent by
Silicate, aluminosilicate, carbonate and trace metallic mineral composition, chemical component is with SiO2、Fe2O3、TiO2、CaO、MgO、
Al2O3、K2O、Na2It is the important raw mineral materials of the industry such as building, ceramics, glass based on O.Steel Tailing of titanium separation is climbed in the application selection
As main cement raw material, the cement performance produced not only conforms with the regulation of GB1346-77, and is better than general cement, but
It is that cement use can lead to the problem of heavy metal dissolution and floating powder after a long time.The main component of eggshell powder is calcium carbonate, is contained
There is the colloid substance of a small amount of eggshell theca interna, eggshell powder is added in cement making process, is able to ascend making for finished cement
With viscosity, while the dissolution of lower cement heavy metal.
Preferably, the clinker is Portland clinker, and the mill tailings is to climb steel after extracting titanium oxide
Tailing of titanium separation.
Preferably, the eggshell powder is obtained after physical method is smashed and ground by useless eggshell, and screening partial size is 0.2 ~
0.6mm。
Preferably, described climb steel Tailing of titanium separation, anhydrous calcium chloride mixed with the advanced row of eggshell powder pretreatment after add
Into clinker, the pretreatment is heat treatment.Heat treatment can make to form hybrid system between raw material, promote whole knot
Performance is closed, the property of finished cement manufactured in this way is also more stable, more durable.
Preferably, the heat treatment temperature is 70 ~ 90 DEG C, and the processing time is 1 ~ 2h.
Preferably, the steel Tailing of titanium separation of climbing uses after screening, and the screening partial size is 0.5 ~ 0.8mm.
In conclusion by adopting the above-described technical solution, the beneficial effects of the invention are as follows：
1. the present invention is using the cement of mill tailings production, while avoiding mill tailings pollution environment, cement has high-strength
Spend mechanical performance.
2. using the cement of mill tailings production floating powder phenomenon, the metal dissolving of mine metal tailings will not occur for the present invention
It measures almost nil.
3. the present invention is decreased using the setting time of the cement of mill tailings production, the quick of construction ensure that
Property.
Specific embodiment
In order to make the objectives, technical solutions, and advantages of the present invention clearer, with reference to embodiments, to the present invention
It is further elaborated.It should be appreciated that the specific embodiments described herein are merely illustrative of the present invention, it is not used to
Limit the present invention.
Deposit that cost is high, take up a large area, the heavy metal of the inside easily causes environment dirty due to climbing current the pushing away of steel Tailing of titanium separation
The problem of dye, the present invention select the primary raw material for climbing steel Tailing of titanium separation as production cement, add clinker production cement,
Not only it had solved the problems, such as that mine metal tailings were intractable, but also has saved the dosage of clinker.However, only with clinker and
It is low to climb the strength of cement that steel Tailing of titanium separation is produced, and easily floats powder and is also easy to produce heavy metal leachable, therefore, it is necessary in cement material
Addition some addition powder in material the inside enhance the strength of cement produced and caking ability to be promoted, and avoid generating floating powder and metal object
Dissolve out phenomenon.
As a preferred embodiment, the present invention selects eggshell powder and anhydrous calcium chloride former as the addition of cement
Material.Eggshell powder is made of discarded eggshell crushing, and the main component of eggshell is calcium carbonate.It can be used for building use, both saved
Material can protect environment again, and eggshell internal layer has one layer of gluey membrane substance, can crush together with eggshell, calcium colloid substance
There is viscosity after meeting water, can be improved the binding performance between tailing and the ripe powder of cement, promote the viscosity of cement, through testing,
It can reduce the metal dissolving object using tailing production cement.The salt that anhydrous calcium chloride chloride ion and calcium ion are formed.It is anhydrous
Calcium chloride has strong hygroscopicity, additionally dust-proof as road for the desiccant of various substances, soil improvement agent, refrigerant, only
Aqua, upper paddle agent.It is a kind of widely used chemical reagent, medical material, food additives, feed addictive and manufacture gold
Belong to the raw material of calcium.
In the present invention, steel Tailing of titanium separation, anhydrous calcium chloride are climbed and mixes pretreatment with the advanced row of eggshell powder, when three kinds of powder
After the mixing of end, the bonding system for having high intensity, high mechanicalness and high anti-floating powder will form, in a preferred implementation
In example, carried out again after three kinds of mixed-powders are heat-treated using, the mixed-powder being mixed evenly is heated to 70 ~
90 DEG C of 1 ~ 2h of processing, then it is cooling after it is spare, the mixed-powder through Overheating Treatment has higher heat resistance, places weather overheat
The problem of causing cement to fall off.At this point, it is good total in mixed-powder after cooling addition clinker, will to will form one again
System is deposited, floating powder and metal object dissolution phenomenon hardly occur while making the cement produced that there is high-mechanical property.
Preferably, clinker in the present invention, climbing the mixing ratio of steel milltailings, eggshell powder and anhydrous calcium chloride
By percentage to the quality, including clinker 50 ~ 60% climbs steel Tailing of titanium separation 25% ~ 40%, eggshell powder 5 ~ 10%, anhydrous chlorine to example
Change calcium 3 ~ 6%, the finished cement produced within this range all has good mechanical performance, and there is no floating powder is existing
As the metallics in tailing also dissolves out phenomenon almost without generation.
Embodiment 1
One embodiment of the present of invention provides a kind of method using mill tailings production high-performance cement, includes the following steps：
Step 1 screens the steel Tailing of titanium separation of climbing after extraction titanium oxide, obtains partial size as 0.6mm and climbs steel Tailing of titanium separation
Fine sand；
Step 2 takes 3% anhydrous calcium chloride, 5% eggshell powder to climb steel Tailing of titanium separation with 32% and be mixed evenly, by 70 DEG C of heat
2h is handled, obtains mixed-powder after cooling；
Step 3 takes 60% clinker, mixed-powder obtained in step 2 is added in clinker, after mixing evenly
Obtain high-performance cement.
Another embodiment of the present invention proposes a kind of high-performance cement, is made by the method for embodiment 1.According to GB/
T17671 and GB/T 1346 tests the physical property of complex cement, and the heavy metal for testing complex cement according to GB/T 30810 is molten
Output, consumptive use of water normal consistence 24%, test result are：Presetting period 62min, final setting time 105min, volume stability close
Lattice, 3 days flexural strength 7.6MPa, 30 days flexural strength 9.3MPa, 3 days 34.5 MPa of compression strength, 30 days compression strength 70.6
MPa.Metal V, Ti, Co, Ni, Ga, Sc the amount of dissolution is respectively less than 0.02mg/mL, does not find floating powder.
Embodiment 2
One embodiment of the present of invention provides a kind of method using mill tailings production high-performance cement, includes the following steps：
Step 1 screens the steel Tailing of titanium separation of climbing after extraction titanium oxide, obtains partial size as 0.5mm and climbs steel Tailing of titanium separation
Fine sand；
Step 2 takes 6% anhydrous calcium chloride, 10% eggshell powder to climb steel Tailing of titanium separation with 25% and be mixed evenly, by 80 DEG C of heat
1.5h is handled, obtains mixed-powder after cooling；
Step 3 takes 59% clinker, mixed-powder obtained in step 2 is added in clinker, after mixing evenly
Obtain high-performance cement.
Another embodiment of the present invention proposes a kind of high-performance cement, is made by the method for embodiment 2.According to GB/
T17671 and GB/T 1346 tests the physical property of complex cement, and the heavy metal for testing complex cement according to GB/T 30810 is molten
Output, consumptive use of water normal consistence 24%, test result are：Presetting period 59min, final setting time 112min, volume stability close
Lattice, 3 days flexural strength 6.4MPa, 30 days flexural strength 8.5MPa, 3 days 32.1 MPa of compression strength, 30 days compression strength 69.8
MPa.Metal V, Ti, Co, Ni, Ga, Sc the amount of dissolution is respectively less than 0.01mg/mL, does not find floating powder.
Embodiment 3
One embodiment of the present of invention provides a kind of method using mill tailings production high-performance cement, includes the following steps：
Step 1 screens the steel Tailing of titanium separation of climbing after extraction titanium oxide, obtains partial size as 0.8mm and climbs steel Tailing of titanium separation
Fine sand；
Step 2 takes 4% anhydrous calcium chloride, 8% eggshell powder to climb steel Tailing of titanium separation with 40% and be mixed evenly, by 90 DEG C of heat
1h is handled, obtains mixed-powder after cooling；
Step 3 takes 48% clinker, mixed-powder obtained in step 2 is added in clinker, after mixing evenly
Obtain high-performance cement.
Another embodiment of the present invention proposes a kind of high strength cement, is made by the method for embodiment 3.According to GB/
T17671 and GB/T 1346 tests the physical property of complex cement, and the heavy metal for testing complex cement according to GB/T 30810 is molten
Output, consumptive use of water normal consistence 24%, test result are：Presetting period 68min, final setting time 109min, volume stability close
Lattice, 3 days flexural strength 8.5MPa, 30 days flexural strength 9MPa, 3 days 35.3 MPa of compression strength, 30 days compression strength 72.8
MPa.Metal V, Ti, Co, Ni, Ga, Sc the amount of dissolution is respectively less than 0.01mg/mL, does not find floating powder.
Principle and implementation of the present invention are described for specific embodiment used herein, above embodiments
Explanation be merely used to help understand method and its core concept of the invention.It should be pointed out that for the common of the art
, without departing from the principle of the present invention, can be with several improvements and modifications are made to the present invention for technical staff, these
Improvement and modification are also fallen within the protection scope of the claims of the present invention.
Claims (6)
1. a kind of high-performance cement made using mill tailings, which is characterized in that the high-performance cement is by clinker, mine
Mountain tailing, anhydrous calcium chloride and eggshell powder is agitated is made after mixing, raw material forms by mass percentage, including
Clinker 50 ~ 60%, anhydrous calcium chloride 3 ~ 6%, eggshell powder 5% ~ 10%, mill tailings 20% ~ 35%；The mill tailings is to climb
Steel Tailing of titanium separation.
2. the high-performance cement according to claim 1 made using mill tailings, which is characterized in that the clinker
For Portland clinker, the mill tailings is to climb steel Tailing of titanium separation after extracting titanium oxide.
3. the high-performance cement according to claim 1 made using mill tailings, which is characterized in that the eggshell powder
It is obtained after physical method is smashed and ground by useless eggshell, screening partial size is 0.2 ~ 0.6mm.
4. the high-performance cement according to claim 1 made using mill tailings, which is characterized in that the steel of climbing selects titanium
Tailing, anhydrous calcium chloride are then added in clinker after mixing pretreatment with the advanced row of eggshell powder, and the pretreatment is heat
Processing.
5. the high-performance cement according to claim 4 made using mill tailings, which is characterized in that the heat treatment temperature
Degree is 70 ~ 90 DEG C, and the processing time is 1 ~ 2h.
6. the high-performance cement according to claim 1 made using mill tailings, which is characterized in that the steel of climbing selects titanium
Tailing uses after screening, and the screening partial size is 0.5 ~ 0.8mm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810956047.3A CN108863124A (en) | 2018-08-21 | 2018-08-21 | A kind of high-performance cement made using mill tailings |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810956047.3A CN108863124A (en) | 2018-08-21 | 2018-08-21 | A kind of high-performance cement made using mill tailings |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108863124A true CN108863124A (en) | 2018-11-23 |
Family
ID=64321020
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810956047.3A Withdrawn CN108863124A (en) | 2018-08-21 | 2018-08-21 | A kind of high-performance cement made using mill tailings |
Country Status (1)
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109437642A (en) * | 2018-12-24 | 2019-03-08 | 烟台大学 | A kind of purposes of fowl egg-shell meal |
| JP2021143097A (en) * | 2020-03-12 | 2021-09-24 | 株式会社トクヤマ | Method for producing portland cement clinker |
-
2018
- 2018-08-21 CN CN201810956047.3A patent/CN108863124A/en not_active Withdrawn
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109437642A (en) * | 2018-12-24 | 2019-03-08 | 烟台大学 | A kind of purposes of fowl egg-shell meal |
| JP2021143097A (en) * | 2020-03-12 | 2021-09-24 | 株式会社トクヤマ | Method for producing portland cement clinker |
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Application publication date: 20181123 |