CN108862975A - A kind of sludge anaerobic processing method and system - Google Patents

A kind of sludge anaerobic processing method and system Download PDF

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Publication number
CN108862975A
CN108862975A CN201811099938.8A CN201811099938A CN108862975A CN 108862975 A CN108862975 A CN 108862975A CN 201811099938 A CN201811099938 A CN 201811099938A CN 108862975 A CN108862975 A CN 108862975A
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CN
China
Prior art keywords
sludge
pyrohydrolysis
pond
outlet
anaerobic
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CN201811099938.8A
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Chinese (zh)
Inventor
王学科
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New Ingegneria Ambientale Srl In Tianjin One
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New Ingegneria Ambientale Srl In Tianjin One
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Priority to CN201811099938.8A priority Critical patent/CN108862975A/en
Publication of CN108862975A publication Critical patent/CN108862975A/en
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00Treatment of sludge; Devices therefor
    • C02F11/10Treatment of sludge; Devices therefor by pyrolysis
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00Treatment of sludge; Devices therefor
    • C02F11/02Biological treatment
    • C02F11/04Anaerobic treatment; Production of methane by such processes
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00Treatment of sludge; Devices therefor
    • C02F11/12Treatment of sludge; Devices therefor by de-watering, drying or thickening

Abstract

The present invention provides a kind of sludge anaerobic processing method and system, it is high for the content of organic matter in conventional anaerobic digestion biogas residue, the big problem of biogas residue yield carries out pyrohydrolysis pretreatment to sludge, hydrolyzate is used for anaerobic digestion, biogas residue is back to pyrohydrolysis stage, pyrohydrolysis sludge outlet has outlet sludge quantity few, and outlet moisture percentage in sewage sludge is low, the outlet sludge content of organic matter is low, and system produces the high advantage of biogas rate.

Description

A kind of sludge anaerobic processing method and system
Technical field
The present invention relates to sludge treatment field more particularly to a kind of sludge anaerobic processing methods and system.
Background technique
Sludge is the by-product of sewage treatment, and yield is big and disposition rate is low, and China's Treatment of Sludge mode mainly has landfill, heap The modes such as fertilizer, natural desiccation, burning.Treatment of Sludge mode in China's is still based on landfill at present, China's urban wastewater treatment in addition Enterprise's disposing capacity is insufficient, disposition means fall behind, and the processing that a large amount of sludge are not standardized directly results in " secondary dirt Dye " seriously threatens ecological environment generation, not only reduces the effective processing capacity of sewage treatment facility, and to ecological ring Border constitutes a serious threat, while also resulting in the significant wastage of resource.Anaerobic sludge digestion is carried out using amphimicrobe and anaerobic bacteria Anaerobic biochemical reaction decomposes the organic substance in sludge, realizes a kind of sludge treatment technique of sludge stabilizing, dirt may be implemented The minimizing of mud processing, stabilisation, innoxious and recycling, reduce greenhouse gas emission, treatment scale is bigger, process synthesis Benefit is more obvious.
Anaerobic digestion generates biogas while removing organic matter, that there are digestive efficiencies is low for traditional anaerobic digestion process, The problems such as residence time is long, operating cost is high, this is because sludge hydrolytic process limits the speed of anaerobic digestion, sludge hot water Solution is a kind of efficient sludge pre-treatment techniques, and the dehydration of sludge is improved while effectively improving digestive efficiency and biogas output Performance.However, the content of organic matter is still higher in pyrohydrolysis sludge anaerobic biogas residue, and since content of beary metal is high, organic matter contains Amount is high, can not resource utilization.
Summary of the invention
The present invention provides a kind of sludge anaerobic processing method and system, for the content of organic matter in conventional anaerobic digestion biogas residue Height, the big problem of biogas residue yield carry out pyrohydrolysis pretreatment to sludge, hydrolyzate are used for anaerobic digestion, biogas residue is back to heat Hydrolysis stage, pyrohydrolysis sludge outlet have outlet sludge quantity few, and outlet moisture percentage in sewage sludge is low, the outlet sludge content of organic matter Low, system produces the high advantage of biogas rate.
The technical solution adopted by the present invention is that:
A kind of sludge anaerobic processing method, includes the following steps:
Municipal sludge progress is quenched, adjusts its moisture content to 90% ~ 93%;Sludge after quenched carries out pyrohydrolysis, by sludge solid phase In organic matter be discharged into liquid phase;Sludge after pyrohydrolysis is dehydrated, the aqueous solution of abjection after conditioning after disappear into sludge Change pond and carry out anaerobic digestion, dewatered sludge forms mud cake outward transport;Anaerobic digestion generates biogas, and biogas residue is discharged, biogas residue into Enter to re-start pyrohydrolysis reaction in pyrohydrolysis pond;Biogas slurry a part of anaerobic digestion discharge enters quenched pond and is used for conditioning of mud Moisture content, a part qualified discharge after sewage treatment.
Preferably, the pH of the pyrohydrolysis reaction is 7.5 to 11.
Preferably, the pH of the sludge digestion reaction is 7 to 9.
A kind of sludge anaerobic processing system, including:
Quenched pond is used for conditioning of mud moisture content;Pyrohydrolysis pond is used for sludge hot hydrolysis, import and the quenched pond Outlet is connected;Dehydration device, is used for pyrohydrolysis sludge dewatering, and import is connected with pyrohydrolysis pond outlet;Conditioner, The conditioning of hydrolyzate for the abjection of pyrohydrolysis sludge, import are connected with the liquid outlet of the dehydration device;Sludge disappears Change pond, reacted for anaerobic sludge digestion, import is connected with the outlet of the conditioner, solid outlet and the hot water Xie Chi is connected, and liquid outlet is connected with the quenched pond;Sewage-treatment plant, import and the sludge digestion tank liquid Body outlet is connected.
Beneficial effects of the present invention are:
1, the present invention provides a kind of sludge anaerobic processing method and system, after carrying out pyrohydrolysis processing to sludge, will hydrolyze Liquid is reacted for anaerobic digestion, had both been improved the efficiency that organic matter is converted into methane, and had been also reduced anaerobism tank volume.
2, the content of organic matter is higher in anaerobism biogas residue, is back to pyrohydrolysis stage, and the organic matter in system obtains further It utilizes, improves the total yield methane quantity of system.
3, the content of organic matter is lower in the sludge after pyrohydrolysis, and the dehydration property after pyrohydrolysis is good, hot water Outlet sludge of the sludge as whole system after solution, has the characteristics that yield is few, the content of organic matter is low, dehydration property is good.
Detailed description of the invention
In order to more clearly explain the embodiment of the invention or the technical proposal in the existing technology, to embodiment or will show below There is attached drawing needed in technical description to be briefly described, it should be apparent that, the accompanying drawings in the following description is only this Some embodiments of invention without any creative labor, may be used also for those of ordinary skill in the art To obtain other drawings based on these drawings.
Fig. 1 is a kind of schematic diagram of sludge anaerobic processing system of the present invention.
Specific embodiment
Following will be combined with the drawings in the embodiments of the present invention, and technical solution in the embodiment of the present invention carries out clear, complete Site preparation description, it is clear that described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.It is based on Embodiment in the present invention, it is obtained by those of ordinary skill in the art without making creative efforts every other Embodiment shall fall within the protection scope of the present invention.
The technical solution adopted by the present invention is that:
A kind of sludge anaerobic processing method, includes the following steps:
Municipal sludge progress is quenched, adjusts its moisture content to 90% ~ 93%;Sludge after quenched carries out pyrohydrolysis, by sludge solid phase In organic matter be discharged into liquid phase;Sludge after pyrohydrolysis is dehydrated, the aqueous solution of abjection after conditioning after disappear into sludge Change pond and carry out anaerobic digestion, dewatered sludge forms mud cake outward transport;Anaerobic digestion generates biogas, and biogas residue is discharged, biogas residue into Enter to re-start pyrohydrolysis reaction in pyrohydrolysis pond;Biogas slurry a part of anaerobic digestion discharge enters quenched pond and is used for conditioning of mud Moisture content, a part qualified discharge after sewage treatment.
Preferably, the pH of the pyrohydrolysis reaction is 7.5 to 11.
Preferably, the pH of the sludge digestion reaction is 7 to 9.
A kind of sludge anaerobic processing system, including:
Quenched pond is used for conditioning of mud moisture content;Pyrohydrolysis pond is used for sludge hot hydrolysis, import and the quenched pond Outlet is connected;Dehydration device, is used for pyrohydrolysis sludge dewatering, and import is connected with pyrohydrolysis pond outlet;Conditioner, The conditioning of hydrolyzate for the abjection of pyrohydrolysis sludge, import are connected with the liquid outlet of the dehydration device;Sludge disappears Change pond, reacted for anaerobic sludge digestion, import is connected with the outlet of the conditioner, solid outlet and the hot water Xie Chi is connected, and liquid outlet is connected with the quenched pond;Sewage-treatment plant, import and the sludge digestion tank liquid Body outlet is connected.
Embodiment 1
Certain municipal sludge, the content of organic matter 42% adjust its moisture content to 90%, it is quenched after sludge carry out pyrohydrolysis, heat The sludge content of organic matter after hydrolysis is 29%, and the sludge after pyrohydrolysis is dehydrated, and the aqueous solution of abjection enters sludge digestion tank Anaerobic digestion is carried out, dewatered sludge forms mud cake outward transport;Anaerobic digestion generates biogas, gas production 41.26Nml/g, row Biogas residue out, the content of organic matter of biogas residue are 59%, and for biogas residue after being dehydrated, it is aqueous for conditioning of mud that a part of water enters quenched pond Rate, a part of water enter sewage-treatment plant, and qualified discharge after processing, dewatered biogas residue enters pyrohydrolysis pond, after quenched Sludge carry out pyrohydrolysis reaction together.
Embodiment 2
Certain municipal sludge, the content of organic matter 27% adjust its moisture content to 93%, it is quenched after sludge carry out pyrohydrolysis, heat The sludge content of organic matter after hydrolysis is 15%, and the sludge after pyrohydrolysis is dehydrated, and the aqueous solution of abjection enters sludge digestion tank Anaerobic digestion is carried out, dewatered sludge forms mud cake outward transport;Anaerobic digestion generates biogas, gas production 31.71Nml/g, row Biogas residue out, the biogas residue content of organic matter are 44%, and after being dehydrated, a part of water enters quenched pond and is used for conditioning of mud moisture content biogas residue, A part of water enters sewage-treatment plant, qualified discharge after processing, and dewatered biogas residue enters pyrohydrolysis pond, with it is quenched after dirt Mud carries out pyrohydrolysis reaction together.
Embodiment 3
Certain municipal sludge, the content of organic matter 55% adjust its moisture content to 92%, it is quenched after sludge carry out pyrohydrolysis, heat The sludge content of organic matter after hydrolysis is 33%, and the sludge after pyrohydrolysis is dehydrated, and the aqueous solution of abjection enters sludge digestion tank Anaerobic digestion is carried out, dewatered sludge forms mud cake outward transport;Anaerobic digestion generates biogas, gas production 52.18Nml/g, row Biogas residue out, the biogas residue content of organic matter are 62%, and after being dehydrated, a part of water enters quenched pond and is used for conditioning of mud moisture content biogas residue, A part of water enters sewage-treatment plant, qualified discharge after processing, and dewatered biogas residue enters pyrohydrolysis pond, with it is quenched after dirt Mud carries out pyrohydrolysis reaction together.

Claims (4)

1. a kind of sludge anaerobic processing method, which is characterized in that include the following steps:
Municipal sludge progress is quenched, adjusts its moisture content to 90% ~ 93%;Sludge after quenched carries out pyrohydrolysis, by sludge solid phase In organic matter be discharged into liquid phase;Sludge after pyrohydrolysis is dehydrated, the aqueous solution of abjection after conditioning after disappear into sludge Change pond and carry out anaerobic digestion, dewatered sludge forms mud cake outward transport;Anaerobic digestion generates biogas, and biogas residue is discharged, biogas residue into Enter to re-start pyrohydrolysis reaction in pyrohydrolysis pond;Biogas slurry a part of anaerobic digestion discharge enters quenched pond and is used for conditioning of mud Moisture content, a part qualified discharge after sewage treatment.
2. a kind of sludge anaerobic processing method according to claim 1, which is characterized in that the pH of pyrohydrolysis reaction is 7.5 to 11.
3. a kind of sludge anaerobic processing method according to claim 1, which is characterized in that the pH of the sludge digestion reaction It is 7 to 9.
4. a kind of sludge anaerobic processing system, which is characterized in that including:
Quenched pond is used for conditioning of mud moisture content;Pyrohydrolysis pond is used for sludge hot hydrolysis, import and the quenched pond Outlet is connected;Dehydration device, is used for pyrohydrolysis sludge dewatering, and import is connected with pyrohydrolysis pond outlet;Conditioner, The conditioning of hydrolyzate for the abjection of pyrohydrolysis sludge, import are connected with the liquid outlet of the dehydration device;Sludge disappears Change pond, reacted for anaerobic sludge digestion, import is connected with the outlet of the conditioner, solid outlet and the hot water Xie Chi is connected, and liquid outlet is connected with the quenched pond;Sewage-treatment plant, import and the sludge digestion tank liquid Body outlet is connected.
CN201811099938.8A 2018-09-20 2018-09-20 A kind of sludge anaerobic processing method and system Pending CN108862975A (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109574465A (en) * 2019-01-20 2019-04-05 重庆大学 A method of it is carbonized based on low-temperature hydrothermal and supplements sewage treatment plant's carbon source
CN110002712A (en) * 2019-04-04 2019-07-12 杨洋 Sludge energy treatment process
CN110451758A (en) * 2019-08-22 2019-11-15 天津壹新环保工程有限公司 River bottom mud resource utilization method and system
CN112094005A (en) * 2020-09-08 2020-12-18 天津壹新环保工程有限公司 Alkaline pyrohydrolysis treatment method and system for sludge
CN113526806A (en) * 2020-04-15 2021-10-22 湖南军信环保股份有限公司 Sludge treatment method

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109574465A (en) * 2019-01-20 2019-04-05 重庆大学 A method of it is carbonized based on low-temperature hydrothermal and supplements sewage treatment plant's carbon source
CN110002712A (en) * 2019-04-04 2019-07-12 杨洋 Sludge energy treatment process
CN110451758A (en) * 2019-08-22 2019-11-15 天津壹新环保工程有限公司 River bottom mud resource utilization method and system
CN113526806A (en) * 2020-04-15 2021-10-22 湖南军信环保股份有限公司 Sludge treatment method
CN113526806B (en) * 2020-04-15 2022-03-11 湖南军信环保股份有限公司 Sludge treatment method
CN112094005A (en) * 2020-09-08 2020-12-18 天津壹新环保工程有限公司 Alkaline pyrohydrolysis treatment method and system for sludge

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