CN101948231B - High-concentration sludge anaerobic digestion process for mechanical pre-dehydration of sludge - Google Patents

High-concentration sludge anaerobic digestion process for mechanical pre-dehydration of sludge Download PDF

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Publication number
CN101948231B
CN101948231B CN2010105049976A CN201010504997A CN101948231B CN 101948231 B CN101948231 B CN 101948231B CN 2010105049976 A CN2010105049976 A CN 2010105049976A CN 201010504997 A CN201010504997 A CN 201010504997A CN 101948231 B CN101948231 B CN 101948231B
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sludge
dehydration
anaerobic digestion
concentration
tank
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CN101948231A (en
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李子富
荀磊
尹福斌
王婷婷
靳昕
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Nanjing Yanjiang Resources Ecological Science Research Institute Co ltd
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University of Science and Technology Beijing USTB
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    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00—Treatment of sludge; Devices therefor
    • C02F11/02—Biological treatment
    • C02F11/04—Anaerobic treatment; Production of methane by such processes
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00—Treatment of sludge; Devices therefor
    • C02F11/12—Treatment of sludge; Devices therefor by de-watering, drying or thickening
    • C02F11/121—Treatment of sludge; Devices therefor by de-watering, drying or thickening by mechanical de-watering
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00—Biological treatment of water, waste water, or sewage
    • C02F3/28—Anaerobic digestion processes
    • C02F3/2813—Anaerobic digestion processes using anaerobic contact processes

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Molecular Biology (AREA)
  • Hydrology & Water Resources (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Chemistry (AREA)
  • Treatment Of Sludge (AREA)

Abstract

The invention relates to a high-concentration sludge anaerobic digestion treatment process for carrying out mechanical pre-dehydration on sludge, which comprises the following specific processes: feeding the sludge with high water content into a concentration tank, reducing the water content of the sludge to 97% after concentration treatment, and refluxing supernatant to a sewage treatment system; mechanically pre-dehydrating the concentrated sludge until the water content is about 88-90%, then introducing the pre-dehydrated sludge into a CSTR reactor for anaerobic digestion, wherein the sludge digestion is carried out under the condition of high concentration. The sludge after anaerobic digestion is further dehydrated, and the water content of the treated sludge cake is about 75 percent. The invention has the advantages and positive effects that: by adopting the technical scheme, the sludge dewatering effect is good, the volume of the sludge anaerobic digestion tank is greatly reduced, and the capital investment and the operation cost of a sewage treatment plant are reduced; the pre-dehydration of the sludge can improve the organic matter load in the sludge, and the subsequent treatment by adopting a CSTR anaerobic digestion tank suitable for high-concentration solid materials is beneficial to the resource utilization of the sludge.

Description

Mud is carried out the high concentration sludge Anaerobic Digestion technology of the pre-dehydration of machinery
Technical field
The invention belongs to technical field of sludge treatment, relate to a kind of dewatering technology of mud that before the sludge digestion unit, adds pre-dewatering unit.
Background technology
In recent years, people are more and more higher to the requirement of environmental quality, and the management of various countries' environmental pollution is also constantly strengthened, and the biochemical processing of municipal wastewater and other organic sewages obtains general cognitive and popularization, yet these sewage treatment process can produce a large amount of residual active sludges.For the treatment and disposal of these residual active sludges, all relate to the thickening of mud.
In traditional dewatering technology of mud, general employing is carried out mud earlier and is concentrated, and carries out mechanical dehydration after the sludge digestion again.It is bulky to exist the anaerobic sludge digestion pond, and initial cost and running cost are higher, and the sludge dewatering effect is relatively poor, and the moisture percentage in sewage sludge height after the processing is unfavorable for the problems such as disposal that mud is follow-up.And the heat that usually produces in the winter time the time can not satisfy the insulation demand of anaerobic digester own.
Li Yaxin etc. [1](Li Yaxin; Yue Xiuping. flocculation agent is to the strengthening effect [J] of high-rate anaerobic reactor granular sludge. Environmental Pollution and Control; 2004; 26 (5): 333~335) studied the influence of flocculation agent to granular sludge in the anaerobic reactor; discovery can promote the growth of anaerobic digestion bacterium under the effect of an amount of flocculation agent.Li Baoshi [2](Li Baoshi. add the influence [D] that inert particulate and flocculation agent form anaerobic grain sludge under the normal temperature lower concentration water inlet condition. Chinese Marine University's environmental engineering, 2009.) inquired into and add the influence of flocculation agent to methanogenesis activity, after discovery adds the cationic quaternary ammonium salt flocculation agent, can improve the activity of anaerobic sludge, promote the activity of methanogen.Shi Yuejin [3](Shi Yuejin. the dehydration of sludge from wastewater treatment plant, anaerobic digestion and anaerobic composting [D]. environmental engineering system of Zhejiang Polytechnical University, 1999.) discover that when moisture percentage in sewage sludge was 86% left and right sides, the anaerobic sludge digestion effect was best, gas production rate is also the highest.Luo Gang etc. [4](Luo Gang, Xie Li, Zhou Qi, Sang Wenjing, Sun Jiawei. high temperature anaerobic CSTR reactor for treatment cassava alcohol waste water research [J]. Chinese water supply and drainage, 2008,24 (9): 13~16) studies show that, the anaerobism CSTR reactor that moves under the hot conditions can bear higher organic loading, can reach 14kgCOD/ (m 3D), have very strong anti impulsion load ability and anti-pH changing capability.
Summary of the invention
In order to address the above problem, the purpose of this invention is to provide and a kind ofly can significantly reduce the sewage water ratio, reduce the high concentration sludge Anaerobic Digestion technology of sludge volume, can obviously reduce investment and working cost, can reduce greenhouse gas emission simultaneously,
The high concentration sludge Anaerobic Digestion technology that mud is carried out the pre-dehydration of machinery of production renewable energy source.
Technical scheme of the present invention is: the high concentration sludge Anaerobic Digestion technology to mud carries out the pre-dehydration of machinery may further comprise the steps:
1. mud concentrates: the residue water ratio 99% above mud of sewage work is sent into the gravity concentration basin by sludge pump, and the moisture percentage in sewage sludge after concentrated is generally 97%, and when its water ratio reduced to 97% by 99%, the volume of mud can narrow down to original 1/3.Separated liquid supernatant is through being back to Sewage treatment systems;
2. mud dewaters in advance: described concentrated back mud is entered the dehydration machine room, dewatered by mechanical sludge dewatering equipment, the control moisture percentage in sewage sludge is 88%~90%;
3. anaerobic sludge digestion: the mud after the described dehydration is squeezed in the CSTR anaerobic sludge digester by sludge pump, kept that mixture pH carries out anaerobic digestion in the reactor under the condition of high temperature (about 60 ℃) about 7.0.
4. sludge dewatering: with sludge pump postdigestive mud is sent in the mechanical dewatering equipment, dehydration again, the final moisture content of the cake that generates further reduces, and is beneficial to the follow-up disposal of mud.
Advantage of the present invention and positively effect:
1. sludge dewatering is respond well, and sludge reduction is obvious;
2. take up an area of and lack, cost is low.The moisture percentage in sewage sludge that enters digester descends, and reduces the volume in anaerobic sludge digestion pond greatly, reduces the initial cost and the running cost of sewage work;
3. the pre-dehydration to mud can improve organic loading in the mud, is adopting the CSTR anaerobic digester that is suitable for the high concentrated, solid material to handle the advantage that then can give full play to this technology thereafter;
4. the ultimate disposal cost is low, reduces transportation cost, saves the landfill expense;
5. be beneficial to the recycling of mud, as marsh gas power generation, composting, agricultural, do building materials etc.
Description of drawings
Fig. 1 carries out the process flow sheet of the sludge anaerobic treatment process of the pre-dehydration of machinery to mud for the present invention.
Embodiment
Further specify the present invention by the following examples.
Mud concentrates: the excess sludge of sewage work (water ratio is more than 99%), and rely on sludge pump to send into the gravity concentration basin, the moisture percentage in sewage sludge after concentrating is generally 97%, and when its water ratio reduced to 97% by 99%, the volume of mud can narrow down to original 1/3.Separated liquid supernatant is through being back to Sewage treatment systems.
Mud dewaters in advance: concentrate back mud and enter the dehydration machine room, dewatered by mechanical sludge dewatering equipment, the control moisture percentage in sewage sludge is about 88%~90%.
Anaerobic sludge digestion: the mud after dehydration is squeezed into by sludge pump in the CSTR anaerobic sludge digester.Moisture percentage in sewage sludge after the pre-dehydration is lower, about 88%~90%, compares with traditional technology, can reduce the volume of anaerobic digester greatly, has improved the anaerobic digestion efficient and the unit volume biogas output of mud.
Sludge dewatering: with sludge pump postdigestive mud is sent in the mechanical dewatering equipment, dehydration again, the final moisture content of the cake that generates further reduces, and is beneficial to the follow-up disposal of mud.

Claims (4)

一种对污泥进行机械预脱水的高浓度污泥厌氧消化处理工艺,其特征在于,具体工艺步骤如下: A high-concentration sludge anaerobic digestion process for mechanical pre-dehydration of sludge, characterized in that the specific process steps are as follows: 1.污泥重力浓缩的工艺: 1. Sludge gravity concentration process: 将污水处理厂二沉池排出的含水率在99%以上的剩余污泥,送入污泥重力浓缩池,污泥依靠刮泥机刮集到重力浓缩池中心,然后由排泥管排出,由污泥泵送至脱泥机房的调节池或储泥池,浓缩后污泥的含水率为97%,上清液被分离出来回流至污水处理系统; The remaining sludge with a moisture content of more than 99% discharged from the secondary sedimentation tank of the sewage treatment plant is sent to the sludge gravity concentration tank. The sludge is pumped to the regulating tank or sludge storage tank in the desilting machine room. The moisture content of the concentrated sludge is 97%, and the supernatant is separated and returned to the sewage treatment system; 2.机械脱水设备进行污泥预脱水的工艺: 2. Mechanical dehydration equipment for sludge pre-dehydration process: 将经重力浓缩池浓缩后的污泥送入脱水机房,通过机械脱水设备进行脱水,使得污泥含水率控制在88%~90%,上清液经过清洗装置处理后的水回流至污水处理系统; The sludge concentrated in the gravity concentration tank is sent to the dehydration machine room, and dewatered by mechanical dehydration equipment, so that the moisture content of the sludge is controlled at 88% to 90%, and the supernatant is returned to the sewage treatment system after being treated by the cleaning device ; 3.污泥厌氧消化CSTR工艺: 3. Sludge anaerobic digestion CSTR process: 经压滤脱水后的污泥由污泥泵打入CSTR厌氧消化池中,维持反应器中混合物pH在7.0,在60℃下进行厌氧消化; The sludge after pressure filtration and dehydration is pumped into the CSTR anaerobic digester by the sludge pump, and the pH of the mixture in the reactor is maintained at 7.0, and anaerobic digestion is performed at 60°C; 4.污泥脱水工艺: 4. Sludge dewatering process: 用污泥泵将消化后的污泥送入机械脱水设备中,再一次进行脱水,最终生成的污泥含水率为75%。 The digested sludge is sent to the mechanical dehydration equipment with a sludge pump, and dehydrated again, and the moisture content of the final sludge is 75%.
CN2010105049976A 2010-10-14 2010-10-14 High-concentration sludge anaerobic digestion process for mechanical pre-dehydration of sludge Expired - Fee Related CN101948231B (en)

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PCT/CN2010/080412 WO2012048504A1 (en) 2010-10-14 2010-12-28 Anaerobic digestion treatment process for high concentration sludge obtained from sludge mechanical predehydration

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CN102730916B (en) * 2012-06-01 2014-08-27 南京国能环保工程有限公司 Treatment process of in-depth dehydration and resource utilization for sludge
CN102923859B (en) * 2012-11-29 2014-07-30 华纺股份有限公司 Process for treating high-concentration printing-dyeing desizing waste water and aerobic excess sludge
CN102923922B (en) * 2012-11-29 2014-04-16 华纺股份有限公司 Technology for anaerobic treatment of high concentration desizing wastewater through utilizing pulverized fuel ash
CN102936084B (en) * 2012-11-29 2014-04-16 华纺股份有限公司 Printing and dyeing wastewater treatment process without sludge discharge
CN103435240A (en) * 2013-08-02 2013-12-11 轻工业环境保护研究所 Fermentation and re-dewatering method of dewatered sludge
CN103482846B (en) * 2013-09-18 2014-12-03 华南理工大学 Sludge dehydrating method and device
CN103951148B (en) * 2014-04-23 2016-05-04 江苏康泰环保设备有限公司 A kind of plant's ight soil utilization system and method
CN104310739B (en) * 2014-10-20 2016-11-23 同济大学 A kind of method promoting polycyclic aromatic hydrocarbons in sludge anaerobic degradation
CN104310741A (en) * 2014-11-13 2015-01-28 轻工业环境保护研究所 Hydrolytic acidification re-dehydration method for dehydrated sludge
CN106630507B (en) * 2016-11-15 2023-05-02 南京绿新能源研究院有限公司 Integrated equipment for anaerobic digestion of dehydrated excess sludge and operation method thereof
CN106380055B (en) * 2016-11-16 2023-04-07 南京大学宜兴环保研究院 Device for anaerobic digestion of sludge and operation method thereof
CN107226602A (en) * 2017-06-09 2017-10-03 李超 A kind of sludge anaerobic digestion system and method for sludge treatment based on bioleaching
CN108383348A (en) * 2018-04-11 2018-08-10 华南理工大学 A kind of device and method of sludge high temperature anaerobic digestion producing methane
CN111732324A (en) * 2020-07-15 2020-10-02 赵誉 Electromagnetic Homogeneous Catalytic Sludge Dewatering Process and System
CN113072275A (en) * 2021-04-01 2021-07-06 新疆碧水源环境资源股份有限公司 Novel water treatment process for sludge synergism
CN114105427A (en) * 2021-12-22 2022-03-01 北京首创污泥处置技术有限公司 System and method for improving sludge aerobic fermentation treatment efficiency
CN116835854B (en) * 2023-03-13 2025-11-11 中冶生态环保集团有限公司 Method for separating fine silt from sludge

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Inventor after: Li Zifu

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Address after: 210047 No. 606 Ningliu Road, Changlu Street, Jiangbei New District, Nanjing City, Jiangsu Province

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