CN108849990A - A kind of agricultural medicine fertilizer composition of pyraclostrobin-containing and its application - Google Patents
A kind of agricultural medicine fertilizer composition of pyraclostrobin-containing and its application Download PDFInfo
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- CN108849990A CN108849990A CN201810677358.6A CN201810677358A CN108849990A CN 108849990 A CN108849990 A CN 108849990A CN 201810677358 A CN201810677358 A CN 201810677358A CN 108849990 A CN108849990 A CN 108849990A
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/44—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids
- A01N37/46—N-acyl derivatives
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/14—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings
- A01N43/16—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings with oxygen as the ring hetero atom
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
- A01N47/24—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing the groups, or; Thio analogues thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
- A01N65/03—Algae
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05F—ORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
- C05F11/00—Other organic fertilisers
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G5/00—Fertilisers characterised by their form
- C05G5/20—Liquid fertilisers
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- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
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- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
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- Biotechnology (AREA)
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- Natural Medicines & Medicinal Plants (AREA)
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- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a kind of agricultural medicine fertilizer composition of pyraclostrobin-containing and its applications.The agricultural medicine fertilizer composition includes active constituent and auxiliary element；The active constituent is formed by by pyraclostrobin, Metalaxyl-M and marine algae extract.Present invention is generally directed to the higher industrial crops of the added values such as fruits and vegetables, by a large amount of lab screening and field control effectiveness test, it was found that the bactericidal composition of pyraclostrobin and Metalaxyl-M can be used not only for the disease control of most of industrial crops, simultaneously and after marine algae extract mixture, moreover it is possible to the double effects of sterilization and fertilizer can be played.Utilize the abundant nutritions such as alginic acid contained in marine algae extract element and plant hormone, it improves the drought resisting of plant, resist cold, disease resistance, and it is compared than chemical fertilizer is used alone with pesticide after the two compounding, no matter all increase significantly in terms of insecticidal effect, crop yield, and accumulation to pesticide residues in vegetables medicine and chemical fertilizer and remain the effect being substantially reduced, medicine section fertilizer is saved, to crop safety height.
Description
Technical field
The present invention relates to pesticides and fertilizer composition, belong to medicine fertilizer technology field, and in particular to a kind of pyraclostrobin-containing
Agricultural medicine fertilizer composition and its application.
Background technique
At present for being agriculturally also easy to produce the disease control of resistance, the pesticide species for using the mechanism of action different carry out mixture
It is optimal selection, if proportion is rationally, can produce significant synergistic effect, field control effect is made to be substantially better than each list
The effect of agent.Fungicide containing single active ingredient is usually present certain defect, continuous several times in agricultural disease prevention and treatment
Using not only making pathogen be also easy to produce drug resistance, and easily cause the pollution to food and environment.Medicine fertilizer is to mix pesticide and fertilizer
It closes, and fertilizer and pesticide is stable at the mixture formed in specific compound system by processing, have and kill suppression crop disease
The function that insect pest and plant growth are adjusted, and nutrition can be provided for crops, also have sometimes and provides nutrient to crops, mentions
The function of high fertilizer efficiency and pesticide utilization rate.
Pyraclostrobin belongs to methoxy acrylic, is a kind of novel spectrum fungicide, has broader sterilization
General and higher bactericidal activity is widely used in the prevention and treatment of fruit tree, vegetables, flowers and field crops disease.Its wide sterilization spectrum,
Target fungus is more, immunity is strong, promote crop anti-adversity, promotes the function of this kind of fungicide of plant growth, anti-aging etc. all
It can be verified.
Metalaxyl-M is high-efficiency low-toxicity, belongs to the synthetic inhibitor of acid amide fungicides rRNA I.Absorbability special efficacy
Fungicide has protection and therapeutic effect, can be absorbed by the root, stem and leaf of plant, and Water Transportation in object therewith, and is transferred to
Each organ of plant.There is Bidirectional Conduction performance, the lasting period 10-14 days, the soil treatment lasting period can be more than 2 months.To downy mildew
Bacterium, phytophthora germ, vegetables caused by rotten mildew fungus, fruit tree, tobacco, oil plant, cotton, the crop diseases such as grain have efficient.
Alga fertilizer contains the plant growth and development that is conducive to largely extracted from seaweed using natural seaweed as primary raw material
Natural bioactivity substance and seaweed absorb from ocean and are enriched in intracorporal mineral nutrient element, including algal polysaccharides,
Phenols poly-compounds, mannitol, glycine betaine, plant growth regulating substance (basic element of cell division, gibberellin, auxin and fall off
Acid etc.) and the microelements such as nitrogen, phosphorus, potassium and iron, boron, molybdenum, iodine.It can promote plant growth, enhance Nutrient Absorption, reinforce nutrient
It utilizes, promotes the uniform growth of root, leaf, flower, fruit.
Traditional medicine fertilizer is usually to add pesticide in compound fertilizer to form, and is not both cooperateed with efficiently between fertilizer and pesticide
Synergistic effect, while a large amount of inorganic ion contained in fertilizer is also possible to generate negative impact to the drug effect of pesticide.
Summary of the invention
In view of the deficiencies of the prior art, the purpose of the present invention is to provide a kind of combinations of the agricultural medicine fertilizer of pyraclostrobin-containing
Object and its application, the agricultural medicine fertilizer composition have pesticide and fertilizer double effects, and pesticide and fertilizer compounding after mutually it
Between have the function of synergy.
A kind of agricultural medicine fertilizer composition of pyraclostrobin-containing, including active constituent and auxiliary element；The active constituent
It is formed by by pyraclostrobin, Metalaxyl-M and marine algae extract.
The agricultural medicine fertilizer composition of above-mentioned pyraclostrobin-containing as improved, including it is following according to parts by weight
Component：Pyraclostrobin 1-40%, Metalaxyl-M 1-40%, marine algae extract 1-50%, surplus are auxiliary element.
It is further improved to be, the agricultural medicine fertilizer composition of above-mentioned pyraclostrobin-containing, including it is following according to parts by weight
Component：Pyraclostrobin 5-20%, Metalaxyl-M 5-20%, marine algae extract 5-15%, surplus are auxiliary element.
The dosage form of the agricultural medicine fertilizer composition of above-mentioned pyraclostrobin-containing is missible oil, granule, wettable powder, water and milk
Agent, microemulsion, water dispersible granules, suspending agent, suspoemulsion or microcapsule suspending agent.
Application of the agricultural medicine fertilizer composition of above-mentioned pyraclostrobin-containing in industrial crops insect pest.
It is that the industrial crops are Kiwi berry as improved, the insect pest is Kiwi berry gray mold.
Beneficial effect：
Compared with prior art, advantage of the invention is that：
1, medicine fertilizer composition of the invention has effects that more, influence needed for can preventing and treating multiple diseases and supplementing duty plant
Element, while crop anti-adversity and crop quality can also be improved；
2, the significant effect of sterilization, volume increase and chemical fertilizer utilization ratio can significantly improve the preventive effect of microbicide compositions, promote plant
Absorption to nutrition can reduce the usage amount of pesticide and fertilizer, achieve the purpose that two subtract；
3, it is not easy that germ is made to generate resistance, product of the invention is using plurality of raw materials, and a variety of modes of action are not easy to produce germ
Raw drug resistance；
4, there are also algal polysaccharides abundant for marine algae extract contained by product of the invention, can be with pyrazoles ethofenprox and smart first frost
Spirit synergistic effect, improves the anti-adversity ability of crop.
Specific embodiment
The present invention is further described in detail below by specific embodiment.
The agricultural medicine fertilizer composition that 1 weight fraction of embodiment is 3%, dosage form is missible oil
1 part of part pyraclostrobin, 1 part of Metalaxyl-M are dissolved completely in 5 parts of N-Methyl pyrrolidones at normal temperature, cream is added
4 parts of agent alkyl phenol polyoxyethylene ether, 4 parts of alkyl benzene calcium sulfonate, 1 part of marine algae extract is added, remaining is supplied with solvent naphtha,
Obtain the agricultural medicine fertilizer composition that creamy weight fraction is 3%.
The agricultural medicine fertilizer composition that 2 weight fraction of embodiment is 6%, aqueous emulsion
2 parts of part pyraclostrobins, 2 parts of Metalaxyl-Ms are dissolved completely in 5 parts of N-Methyl pyrrolidones at normal temperature and 10 parts molten
In agent oil, 4 parts of emulsifier alkyl phenol polyoxyethylene ether are added, 4 parts of alkyl benzene calcium sulfonate, adds 1 part of marine algae extract, the third three
4 parts of alcohol, 0.4 part of defoaming agent mixing, remaining adds water polishing to 100%, is uniformly mixed through high speed shear and is to get weight fraction
6% agricultural medicine fertilizer composition, aqueous emulsion.
The agricultural medicine fertilizer composition that 3 weight fraction of embodiment is 10%, aqueous emulsion
4 parts of part pyraclostrobins, 4 parts of Metalaxyl-Ms are dissolved completely in 5 parts of N-Methyl pyrrolidones at normal temperature and 15 parts molten
In agent oil, 6 parts of emulsifier alkyl phenol polyoxyethylene ether are added, 6 parts of alkyl benzene calcium sulfonate, adds 2 parts of marine algae extracts, the third three
4 parts of alcohol, 0.4 part of defoaming agent mixing, remaining adds water polishing to 100%, is uniformly mixed through high speed shear and is to get to weight fraction
10% agricultural medicine fertilizer composition, aqueous emulsion.
The agricultural medicine fertilizer composition that 4 weight fraction of embodiment is 10%, microemulsion
3 parts of part pyraclostrobins, 3 parts of Metalaxyl-Ms are dissolved completely in 10 parts of N-Methyl pyrrolidones and 3 parts of rings at normal temperature
In hexanone, 8 parts of emulsifier alkyl phenol polyoxyethylene ether are added, 8 parts of alkyl benzene calcium sulfonate, adds 4 parts of marine algae extracts, the third three
4 parts of alcohol, 0.4 part of defoaming agent mixing, remaining adds water polishing to 100%, is uniformly mixed to get being 10% to weight fraction
Agricultural medicine fertilizer composition, aqueous emulsion.
The agricultural medicine fertilizer composition that 5 weight fraction of embodiment is 20%, suspoemulsion
At normal temperature in 7.5 parts of pyraclostrobins, 7.5 parts of Metalaxyl-Ms and 5 parts of marine algae extracts, alkyl phenol polyoxy second is added
4 parts of alkene ether, 4 parts of polycarboxylate, 2 parts of alkyl naphthalene formaldehyde condensate sulfonate, 1 part of white carbon black, 0.5 part of xanthan gum, aluminium-magnesium silicate
0.4,0.4 part of part preservative, 4 parts of propylene glycol, 0.5 part of defoaming agent mixing, add water polishing to 100%, be added in sand mill into
Row grinding, makes partial size at 5 μm hereinafter, obtained sample is the agricultural medicine fertilizer composition of weight fraction 20%, suspoemulsion.
The agricultural medicine fertilizer composition that 6 weight fraction of embodiment is 30%, suspoemulsion
Under room temperature in 10 parts of pyraclostrobins, 10 parts of Metalaxyl-Ms and 10 parts of marine algae extracts, alkylphenol-polyethenoxy is added
4 parts of ether, 4 parts of polycarboxylate, 2 parts of alkyl naphthalene formaldehyde condensate sulfonate, 1 part of white carbon black, 0.5 part of xanthan gum, aluminium-magnesium silicate
0.4,0.4 part of part preservative, 4 parts of propylene glycol, 0.5 part of defoaming agent mixing, add water polishing to 100%, be added in sand mill into
Row grinding, makes partial size at 5 μm hereinafter, obtained sample is the agricultural medicine fertilizer composition of weight fraction 30%, suspoemulsion.
The agricultural medicine fertilizer composition that 7 weight fraction of embodiment is 35%, water dispersible granules
At normal temperature by 15 parts of pyraclostrobins, 5 parts of marine algae extracts, 5 parts of starch, 6 parts of polycarboxylates, 3 parts of alkyl naphthalene formaldehydes
2 parts, 49 parts condensate sulfonates, white carbon black diatomite are added in pulverizer and are pulverized and mixed, and 15 parts of smart first frosts are then added
Spirit and 10 parts of water are stirred, and are added in Squeezinggranulator are granulated after mixing.In 60 DEG C of conditions after the completion of granulation
Lower drying is sieved after 90 minutes to get the agricultural medicine fertilizer composition for being 35% to weight fraction, water dispersible granules.
The agricultural medicine fertilizer composition that 8 weight fraction of embodiment is 40%, suspoemulsion
Under room temperature in 15 parts of pyraclostrobins, 15 parts of Metalaxyl-Ms and 10 parts of marine algae extracts, alkylphenol-polyethenoxy is added
4 parts of ether, 4 parts of polycarboxylate, 2 parts of alkyl naphthalene formaldehyde condensate sulfonate, 1 part of white carbon black, 0.5 part of xanthan gum, aluminium-magnesium silicate
0.4,0.4 part of part preservative, 4 parts of propylene glycol, 0.5 part of defoaming agent mixing, add water polishing to 100%, be added in sand mill into
Row grinding, makes partial size at 5 μm hereinafter, obtained sample is the agricultural medicine fertilizer composition of weight fraction 40%, suspoemulsion.
Bioassay
Gray mold prevention and treatment and the volume increase field trial of Kiwi berry, test are carried out using the agricultural medicine fertilizer composition of the embodiment of the present invention
Place is located at two river village Chinese gooseberry garden of Sichuan Province Pujiang County；Each agricultural medicine fertilizer composition handle as follows.Handle 1-8：System
The medicine fertilizer composition of agent embodiment 1-8；Processing 9：Weight fraction is 30% pyraclostrobin Metalaxyl-M water dispersible granules
(15%+15%) processing 10：Weight fraction is 30% marine algae extract Water soluble fertilizer, each 200 times of processing dilution, swollen in Kiwi berry
Fruiting period is carried out using processing, 5 plants of each experimental plot fruit tree, and each cell water consumption is 3L, according to water consumption and extension rate
Calculate dosage, cell random alignment.10 days after application, 20 days, 30 days, respectively investigate Kiwi berry gray mold harm feelings
Condition, investigation Kiwi berry increases production situation when harvest.
The present invention passes through a large amount of lab screening and field control effectiveness test, finds the sterilization of pyraclostrobin and Metalaxyl-M
Composition can be used not only for the disease control of most of industrial crops, at the same with after marine algae extract mixture, moreover it is possible to can play
The double effects of sterilization and fertilizer.Utilize the abundant nutritions such as alginic acid contained in marine algae extract element and plant hormone, energy
It enough improves the drought resisting of plant, resist cold, disease resistance, and compared than chemical fertilizer is used alone with pesticide after the two compounding, no matter killed
Worm effect all increases significantly in terms of crop yield, and accumulation to pesticide residues in vegetables medicine and chemical fertilizer and remaining is substantially reduced
Effect, reduce use cost, section medicine section fertilizer, to crop safety height, and germ is not likely to produce drug resistance.
The foregoing is only a preferred embodiment of the present invention, the scope of protection of the present invention is not limited to this, it is any ripe
Know those skilled in the art within the technical scope of the present disclosure, the letter for the technical solution that can be become apparent to
Altered or equivalence replacement are fallen within the protection scope of the present invention.
Claims (6)
1. a kind of agricultural medicine fertilizer composition of pyraclostrobin-containing, which is characterized in that including active constituent and auxiliary element；It is described
Active constituent is formed by by pyraclostrobin, Metalaxyl-M and marine algae extract.
2. a kind of agricultural medicine fertilizer composition of pyraclostrobin-containing according to claim 1, which is characterized in that including following
Component according to parts by weight：Pyraclostrobin 1-40%, Metalaxyl-M 1-40%, marine algae extract 1-50%, furtherance supplemented by surplus
Point.
3. a kind of agricultural medicine fertilizer composition of pyraclostrobin-containing according to claim 1, which is characterized in that including following
Component according to parts by weight：Pyraclostrobin 5-20%, Metalaxyl-M 5-20%, marine algae extract 5-15%, furtherance supplemented by surplus
Point.
4. a kind of agricultural medicine fertilizer composition of pyraclostrobin-containing according to claim 1, which is characterized in that described agricultural
The dosage form of medicine fertilizer composition is missible oil, granule, wettable powder, aqueous emulsion, microemulsion, water dispersible granules, suspending agent, outstanding cream
Agent or microcapsule suspending agent.
5. based on a kind of agricultural medicine fertilizer composition of pyraclostrobin-containing described in claim 1 in industrial crops insect pest
Using.
6. application according to claim 5, which is characterized in that the industrial crops are Kiwi berry, and the insect pest is macaque
Peach gray mold.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201810677358.6A CN108849990A (en) | 2018-06-27 | 2018-06-27 | A kind of agricultural medicine fertilizer composition of pyraclostrobin-containing and its application |
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| CN201810677358.6A CN108849990A (en) | 2018-06-27 | 2018-06-27 | A kind of agricultural medicine fertilizer composition of pyraclostrobin-containing and its application |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110250170A (en) * | 2019-06-06 | 2019-09-20 | 上海明德立达生物科技有限公司 | A kind of preparation method and application of Metalaxyl-M pyraclostrobin microcapsule suspending agent |
| CN112851430A (en) * | 2021-02-03 | 2021-05-28 | 天津市汉邦植物保护剂有限责任公司 | Seaweed fertilizer and pesticide mixed composition and application thereof |
| WO2024047060A1 (en) * | 2022-08-31 | 2024-03-07 | Syngenta Crop Protection Ag | Agrochemical formulation |
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| CN102696645A (en) * | 2012-05-09 | 2012-10-03 | 广东中迅农科股份有限公司 | Pesticide composition containing pyraclostrobin and metalaxyl |
| CN105409990A (en) * | 2015-12-19 | 2016-03-23 | 青岛奥迪斯生物科技有限公司 | Sterilization composition containing pyraclostrobin and efficient metalaxyl-M |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN102696645A (en) * | 2012-05-09 | 2012-10-03 | 广东中迅农科股份有限公司 | Pesticide composition containing pyraclostrobin and metalaxyl |
| CN105409990A (en) * | 2015-12-19 | 2016-03-23 | 青岛奥迪斯生物科技有限公司 | Sterilization composition containing pyraclostrobin and efficient metalaxyl-M |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110250170A (en) * | 2019-06-06 | 2019-09-20 | 上海明德立达生物科技有限公司 | A kind of preparation method and application of Metalaxyl-M pyraclostrobin microcapsule suspending agent |
| CN110250170B (en) * | 2019-06-06 | 2021-03-02 | 上海明德立达生物科技有限公司 | Preparation method and application of metalaxyl-M-pyraclostrobin microcapsule suspending agent |
| CN112851430A (en) * | 2021-02-03 | 2021-05-28 | 天津市汉邦植物保护剂有限责任公司 | Seaweed fertilizer and pesticide mixed composition and application thereof |
| WO2024047060A1 (en) * | 2022-08-31 | 2024-03-07 | Syngenta Crop Protection Ag | Agrochemical formulation |
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Application publication date: 20181123 |