CN108838361A - A kind of casting method of die casting - Google Patents

A kind of casting method of die casting Download PDF

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Publication number
CN108838361A
CN108838361A CN201811026374.5A CN201811026374A CN108838361A CN 108838361 A CN108838361 A CN 108838361A CN 201811026374 A CN201811026374 A CN 201811026374A CN 108838361 A CN108838361 A CN 108838361A
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parts
casting
coating
die
melting point
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CN108838361B (en
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于会明
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Anhui Zhenli Auto Parts Co ltd
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ANHUI HUIMING MACHINERY MANUFACTURING Co Ltd
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D17/00Pressure die casting or injection die casting, i.e. casting in which the metal is forced into a mould under high pressure
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22CFOUNDRY MOULDING
    • B22C3/00Selection of compositions for coating the surfaces of moulds, cores, or patterns

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  • Mechanical Engineering (AREA)
  • Mold Materials And Core Materials (AREA)

Abstract

The invention belongs to casting technology fields, and in particular to a kind of casting method of die casting, including:(1) ingredient weighs raw material according to the composition of casting, melts, refines in smelting furnace, refining, and adjusting component obtains molten alloy;(2) mold prepares, and prepares metal die according to the shape of casting to be cast, mold is preheating to 80~120 DEG C, is then placed in dip-coating in compression mod coating, dries at a temperature of being then transferred to 60~80 DEG C;(3) ready mold in step (2) is preheating to 300~350 DEG C, into preheated mold, die cast obtains casting by molten alloy casting in step (1);In casting method provided by the invention, improved compression mod coating has good thermal stability and antiscour oxidability under the washing away of high temperature metal liquid, ensure that the compression mod through coating dip coating provided by the invention has preferable casting ability, cast(ing) surface is avoided various defects occur, it is ensured that the quality of casting.

Description

A kind of casting method of die casting
Technical field
The invention belongs to casting technology fields, and in particular to a kind of casting method of die casting.
Background technique
Compression casting is a kind of by liquid or semi-solid-state metal or alloy, or liquid metal or conjunction containing reinforcer phase Gold, the type for being packed into die-casting die under high pressure with higher speed is intracavitary, and metal or alloy is made to solidify formation casting under stress The casting method of part.The wirking pressure of die casting is 4~500Mpa, and metal filling velocity is 0.5~120m/s, and therefore, high pressure is high Speed is the fundamental difference of casting die Yu other casting methods.
In press casting procedure, in order to avoid casting and die-casting die soldering, reduces the frictional resistance of casting ejection and avoid pressing Casting mold is excessively heated and uses coating, to generally requiring to include for coating:1) at high temperature, there is good lubricity;2) it waves Hair point is low, and at 100~150 DEG C, diluent can volatilize quickly;3) there is no corrosiveness to die-casting die and die casting;4) performance Stablizing diluent in air should not volatilize excessively and retrogradation;5) pernicious gas will not be precipitated at high temperature;It 6) will not be in die casting Mold cavity surface generates incrustation.
The superiority and inferiority of coating can be directly related to the surface quality of die casting, or even influence the service life of die-casting die.Closely Nian Lai, with the continuous development of die-casting technique, die casting is enlarged, structure is complicated changes, to the quality requirement of die casting coating It is higher and higher, meanwhile, the strength built a resource-conserving and environment-friendly society pushes, and the requirement for water based paint is also got over Come higher, but existing water based paint is difficult to meet wanting for enlarged die casting at film strength and stability in die-casting die It asks, needs sustained improvement.
Summary of the invention
The purpose of the present invention is to provide a kind of casting methods of die casting to reduce pressure by the improvement to die-casting process The surface defect of casting improves the quality of die casting.
To achieve the goals above, the present invention is achieved by the following scheme:
A kind of casting method of die casting, includes the following steps:
(1) ingredient weighs raw material according to the composition of casting, melts, refines in smelting furnace, refining, and adjusting component obtains molten Melt shape alloy;
(2) mold prepares, and prepares metal die according to the shape of casting to be cast, mold is preheating to 80~120 DEG C, is connect Dip-coating in merging compression mod coating, dried at a temperature of being then transferred to 60~80 DEG C;
(3) ready mold in step (2) is preheating to 300~350 DEG C, by molten alloy casting in step (1) Into preheated mold, die cast obtains casting;
The feedstock composition for being used to prepare the compression mod coating includes the raw material of following parts by weight:Mullite powder 45~ 60 parts, 5~15 parts of carbon source, 10~15 parts of glass powder with low melting point, 18~30 parts of magnesia, 30~45 parts of inorganic binder, go from 80~100 parts of sub- water.
In further technical solution, the granularity of the mullite powder is 250~300 mesh.
In further technical solution, the granularity of the magnesia is 200~300 mesh.
In further technical solution, the feedstock composition for being used to prepare the compression mod coating includes following weight The raw material of part:50~55 parts of mullite powder, 8~12 parts of carbon source, 12~14 parts of glass powder with low melting point, 22~25 parts of magnesia, nothing 35~40 parts of machine binder, 85~95 parts of deionized water.
In further technical solution, the feedstock composition for being used to prepare the compression mod coating includes following weight The raw material of part:53 parts of mullite powder, 13 parts of glass powder with low melting point, 24 parts of magnesia, 38 parts of inorganic binder, is gone at 10 parts of carbon source 90 parts of ionized water.
Compared with prior art, the present invention has the following technical effects:
In casting method provided by the invention, in the coating of compression mod, carbon-coated mullite powder, carbon packet burr knot The glass powder with low melting point and magnesia of structure are formed by composite granule and expand with excellent heat storage capacity and lower line Coefficient has good thermal stability and antiscour oxidability under the washing away of high temperature metal liquid, ensures that through this The compression mod for inventing the coating dip coating provided has preferable casting ability, and cast(ing) surface is avoided various defects occur, it is ensured that The quality of casting.
Other features and advantages of the present invention will be described in detail in subsequent specific embodiment.
Specific embodiment
In order to be easy to understand the technical means, the creative features, the aims and the efficiencies achieved by the present invention, tie below Specific embodiment is closed, the present invention is furture elucidated.
The present invention provides a kind of casting methods of die casting, include the following steps:
(1) ingredient weighs raw material according to the composition of casting, melts, refines in smelting furnace, refining, and adjusting component obtains molten Melt shape alloy;
(2) mold prepares, and prepares metal die according to the shape of casting to be cast, mold is preheating to 80~120 DEG C, is connect Dip-coating in merging compression mod coating, dried at a temperature of being then transferred to 60~80 DEG C;
(3) ready mold in step (2) is preheating to 300~350 DEG C, by molten alloy casting in step (1) Into preheated mold, die cast obtains casting;
The feedstock composition for being used to prepare the compression mod coating includes the raw material of following parts by weight:Mullite powder 45~ 60 parts, 5~15 parts of carbon source, 10~15 parts of glass powder with low melting point, 18~30 parts of magnesia, 30~45 parts of inorganic binder, go from 80~100 parts of sub- water.
The preparation method of the compression mod coating includes the following steps:
(1) it carries out mullite powder and glass powder with low melting point to be mixed to get mixed powder, be then added into mixed powder The aqueous solution of carbon source is stirred and is warming up to 60~90 DEG C, so that mullite powder is uniformly dispersed with glass powder with low melting point, obtains Mixed slurry;
(2) continue the mixed slurry in whipping step (1), dry and obtained containing clad under conditions of 90~100 DEG C Mullite powder and glass powder with low melting point, then through in vacuum, carbonization obtains carbon-coated mullite at 400~500 DEG C Powder and glass powder with low melting point;
(3) inorganic binder is weighed by formula ratio, be then dispersed into deionized water, then sequentially added in step (2) Carbon-coated mullite powder and glass powder with low melting point, the magnesia being prepared, high-speed stirred are uniformly mixed it to get described Coating.
Heretofore described glass powder with low melting point is different from traditional glass powder, is a kind of using relatively environment-friendly material Through mixing, melting copolymerization crystallizes generated silica boron metalloid salt under high temperature environment, with the significant of ultralow temperature melting Feature, fusing point is generally at 380~780 DEG C;Specifically, if the trade mark of Guangzhou song Lin Er new material Co., Ltd production is D240 The glass powder with low melting point of (400 DEG C of melting temperature), D245 (450 DEG C of melting temperature), D250 (500 DEG C of melting temperature).
In the present invention, by coating one layer of carbon source on the surface of mullite powder and glass powder with low melting point, then through vacuum atmosphere Calcination processing under enclosing coats to form one layer of carbon-coating on the surface of mullite powder, and since the fusing point of glass powder with low melting point is lower, The glass powder with low melting point of carbon source is coated under the conditions of vacuum, along with the formation of carbon-coating, glass powder with low melting point also starts The microdilatancy of volume is melted and is occurred, and due to the control of calcination temperature, is intersected with the melting temperature of glass powder with low melting point, Respectively there is with discrete state and puncture carbon-coating in some oligomers in glass powder with low melting point, form " burr " structure.The present invention In the compression mod coating of offer, carbon-coated mullite powder, the glass powder with low melting point of carbon packet burr structure and magnesia institute The composite granule of formation has excellent heat storage capacity and lower linear expansion coefficient, the tool under the washing away of high temperature metal liquid There are good thermal stability and antiscour oxidability, ensuring that has through the compression mod of coating dip coating provided by the invention Preferable casting ability, avoids cast(ing) surface from various defects occur, it is ensured that the quality of casting.
The present invention does not do particular determination to the carbon source, can be well known to those skilled in the art, specifically, institute The carbon source stated is starch, such as glutinous rice starch, cornstarch, pea starch, tapioca, starch from sweet potato, soybean starch, sorghum One of starch or more than one mixture, the starch at 90 DEG C before use, be gelatinized.
The present invention does not do particular determination to the inorganic binder, can be well known to those skilled in the art, tool Body, the inorganic binder is cementitious materials, silicon dioxide gel, the gold such as alkali silicate, phosphate, alumino-silicate Belong to alkoxide etc., preferably waterglass.
Further, according to the present invention, the granularity of heretofore described mullite powder is 250~300 mesh.
The granularity of heretofore described magnesia is 200~300 mesh.
Within the above range by the granularity of control mullite powder and magnesia, it can be ensured that painting of the dip-coating in die-casting die The degree of packing of layer, it is ensured that preferable erosion resistibility.
Under the conditions of, according to the invention it is preferred to, it includes following heavy for being used to prepare the feedstock composition of the compression mod coating Measure the raw material of part:50~55 parts of mullite powder, 8~12 parts of carbon source, 12~14 parts of glass powder with low melting point, 22~25 parts of magnesia, 35~40 parts of inorganic binder, 85~95 parts of deionized water.
It is further preferred that the feedstock composition for being used to prepare the compression mod coating includes the original of following parts by weight Material:53 parts of mullite powder, 10 parts of carbon source, 13 parts of glass powder with low melting point, 24 parts of magnesia, 38 parts of inorganic binder, deionized water 90 parts.
By the way that the content of raw material each in the feedstock composition for being used to prepare compression mod coating is limited to above-mentioned model In enclosing, it can be ensured that the coating for obtaining good combination property improves the quality of casting.
According to the present invention, in the preparation method of the compression mod coating, in the step (2), the limit of vacuum It is scheduled in the speed for improving carbon-coating formation, meanwhile, under vacuum conditions, the glass powder with low melting point of melting punctures carbon-coating faster, Promote the formation of burr structure.Under optimum condition, the vacuum includes:Vacuum degree is 0.1~0.45Mpa.
The advantages of die casting casting method provided in order to further illustrate the present invention, the present invention also provides a kind of magnaliums The pressure casting method of alloy components, includes the following steps:
S1:Ingredient, by the composition of magnesium alloy part:Al:9%;Cr:1.6%;Ce:2.6%;Si:4.2%;Ni: 0.6%;Zn:0.7%;Mn:0.15%;RE:0.3%;Surplus is Mg, and the percentage composition is weight percent;Weigh pure magnesium Ingot, Mg-Al intermediate alloy, Mg-Si intermediate alloy, Mg-Zn intermediate alloy, Mg-Cr intermediate alloy, pure Zn, pure Ce carry out ingredient, 750 DEG C of melting 50min are warming up in smelting furnace;Using CO2+SF4 protective atmosphere melting, CO2: SF6=150-200: 1 (body Product ratio), then temperature is adjusted to 710-720 DEG C and is refined and is refined, 20-30min is refined and refine;It is adjusted to be designated as After point, molten alloy is obtained, it is to be cast;
S2:Mold prepares, and prepares metal die according to the shape of casting to be cast, mold is preheating to 80~120 DEG C, is connect Dip-coating in merging compression mod coating, dried at a temperature of being then transferred to 60~80 DEG C;
S3:Mold ready in step S2 is preheating to 350 DEG C, by molten alloy casting in step S1 to preheated Mold in, die cast obtains casting.
Embodiment 1
A kind of compression mod coating, the feedstock composition for being used to prepare the compression mod coating includes following parts by weight Raw material:53 parts of mullite powder (300 mesh), 10 parts of glutinous rice starch, glass powder with low melting point (sing the limited public affairs of Lin Er new material purchased from Guangzhou Department, trade mark D240) 13 parts, 24 parts of magnesia (300 mesh), 38 parts of waterglass, 90 parts of deionized water.
The preparation method of the coating includes the following steps:
(1) it carries out mullite powder and glass powder with low melting point to be mixed to get mixed powder, it is water-soluble to be subsequently added into glutinous rice starch Liquid (mass fraction 20%) is stirred and is warming up to 80 DEG C, so that mullite powder is uniformly dispersed with glass powder with low melting point, obtains Mixed slurry;
(2) continue the mixed slurry in whipping step (1), drying obtains not coming containing clad under conditions of 90 DEG C Mountain flour and glass powder with low melting point, then in the atmosphere that vacuum degree is 0.30Mpa, carbonization obtains carbon-coated not next at 450 DEG C Mountain flour and glass powder with low melting point;
(3) waterglass is weighed by formula ratio, be then dispersed into deionized water, then sequentially add preparation in step (2) Obtained carbon-coated mullite powder and glass powder with low melting point, magnesia, high-speed stirred are uniformly mixed it to get the painting Material.
Embodiment 2
A kind of compression mod coating, the feedstock composition for being used to prepare the compression mod coating includes following parts by weight Raw material:50 parts of mullite powder (300 mesh), 8 parts of glutinous rice starch, glass powder with low melting point (sing the limited public affairs of Lin Er new material purchased from Guangzhou Department, trade mark D240) 12 parts, 22 parts of magnesia (300 mesh), 35 parts of waterglass, 85 parts of deionized water.
The preparation method of the coating includes the following steps:
(1) it carries out mullite powder and glass powder with low melting point to be mixed to get mixed powder, it is water-soluble to be subsequently added into glutinous rice starch Liquid (mass fraction 20%) is stirred and is warming up to 80 DEG C, so that mullite powder is uniformly dispersed with glass powder with low melting point, obtains Mixed slurry;
(2) continue the mixed slurry in whipping step (1), drying obtains not coming containing clad under conditions of 90 DEG C Mountain flour and glass powder with low melting point, then in the atmosphere that vacuum degree is 0.30Mpa, carbonization obtains carbon-coated not next at 450 DEG C Mountain flour and glass powder with low melting point;
(3) waterglass is weighed by formula ratio, be then dispersed into deionized water, then sequentially add preparation in step (2) Obtained carbon-coated mullite powder and glass powder with low melting point, magnesia, high-speed stirred are uniformly mixed it to get the painting Material.
Embodiment 3
A kind of compression mod coating, the feedstock composition for being used to prepare the compression mod coating includes following parts by weight Raw material:55 parts of mullite powder (300 mesh), 12 parts of glutinous rice starch, glass powder with low melting point (sing the limited public affairs of Lin Er new material purchased from Guangzhou Department, trade mark D240) 14 parts, 25 parts of magnesia (300 mesh), 40 parts of waterglass, 95 parts of deionized water.
The preparation method of the coating includes the following steps:
(1) it carries out mullite powder and glass powder with low melting point to be mixed to get mixed powder, it is water-soluble to be subsequently added into glutinous rice starch Liquid (mass fraction 20%) is stirred and is warming up to 80 DEG C, so that mullite powder is uniformly dispersed with glass powder with low melting point, obtains Mixed slurry;
(2) continue the mixed slurry in whipping step (1), drying obtains not coming containing clad under conditions of 90 DEG C Mountain flour and glass powder with low melting point, then in the atmosphere that vacuum degree is 0.30Mpa, carbonization obtains carbon-coated not next at 450 DEG C Mountain flour and glass powder with low melting point;
(3) waterglass is weighed by formula ratio, be then dispersed into deionized water, then sequentially add preparation in step (2) Obtained carbon-coated mullite powder and glass powder with low melting point, magnesia, high-speed stirred are uniformly mixed it to get the painting Material.
Embodiment 4
A kind of compression mod coating, the feedstock composition for being used to prepare the compression mod coating includes following parts by weight Raw material:45 parts of mullite powder (300 mesh), 5 parts of glutinous rice starch, glass powder with low melting point (sing the limited public affairs of Lin Er new material purchased from Guangzhou Department, trade mark D240) 10 parts, 18 parts of magnesia (300 mesh), 30 parts of waterglass, 80 parts of deionized water.
The preparation method of the coating includes the following steps:
(1) it carries out mullite powder and glass powder with low melting point to be mixed to get mixed powder, it is water-soluble to be subsequently added into glutinous rice starch Liquid (mass fraction 20%) is stirred and is warming up to 80 DEG C, so that mullite powder is uniformly dispersed with glass powder with low melting point, obtains Mixed slurry;
(2) continue the mixed slurry in whipping step (1), drying obtains not coming containing clad under conditions of 90 DEG C Mountain flour and glass powder with low melting point, then in the atmosphere that vacuum degree is 0.30Mpa, carbonization obtains carbon-coated not next at 450 DEG C Mountain flour and glass powder with low melting point;
(3) waterglass is weighed by formula ratio, be then dispersed into deionized water, then sequentially add preparation in step (2) Obtained carbon-coated mullite powder and glass powder with low melting point, magnesia, high-speed stirred are uniformly mixed it to get the painting Material.
Embodiment 5
A kind of compression mod coating, the feedstock composition for being used to prepare the compression mod coating includes following parts by weight Raw material:60 parts of mullite powder (300 mesh), 15 parts of glutinous rice starch, glass powder with low melting point (sing the limited public affairs of Lin Er new material purchased from Guangzhou Department, trade mark D240) 15 parts, 30 parts of magnesia (300 mesh), 45 parts of waterglass, 100 parts of deionized water.
The preparation method of the coating includes the following steps:
(1) it carries out mullite powder and glass powder with low melting point to be mixed to get mixed powder, it is water-soluble to be subsequently added into glutinous rice starch Liquid (mass fraction 20%) is stirred and is warming up to 80 DEG C, so that mullite powder is uniformly dispersed with glass powder with low melting point, obtains Mixed slurry;
(2) continue the mixed slurry in whipping step (1), drying obtains not coming containing clad under conditions of 90 DEG C Mountain flour and glass powder with low melting point, then in the atmosphere that vacuum degree is 0.30Mpa, carbonization obtains carbon-coated not next at 450 DEG C Mountain flour and glass powder with low melting point;
(3) waterglass is weighed by formula ratio, be then dispersed into deionized water, then sequentially add preparation in step (2) Obtained carbon-coated mullite powder and glass powder with low melting point, magnesia, high-speed stirred are uniformly mixed it to get the painting Material.
Embodiment 6
Such as the compression mod coating and preparation method thereof that embodiment 1 provides, unlike, the granularity of the mullite powder is 250 mesh;Remaining is constant, and coating is prepared.
Embodiment 7
Such as the compression mod coating and preparation method thereof that embodiment 1 provides, unlike, the granularity of the magnesia is 250 mesh;Remaining is constant, and coating is prepared.
Embodiment 8
Such as the compression mod coating and preparation method thereof that embodiment 1 provides, unlike, the granularity of the magnesia is 200 mesh;Remaining is constant, and coating is prepared.
Embodiment 9
Such as the compression mod coating and preparation method thereof that embodiment 1 provides, unlike, the preparation method of the coating In, in step (2), calcination processing under conditions of vacuum degree is 0.10Mpa;Remaining is constant, and coating is prepared.
Embodiment 10
Such as the compression mod coating and preparation method thereof that embodiment 1 provides, unlike, the preparation method of the coating In, in step (2), calcination processing under conditions of vacuum degree is 0.45Mpa;Remaining is constant, and coating is prepared.
Comparative example 1
Such as the compression mod coating and preparation method thereof that embodiment 1 provides, unlike, it is used to prepare the compression mod and uses Glass powder with low melting point is not contained in the feedstock composition of coating;Remaining is constant, and coating is prepared.
Comparative example 2
Such as the compression mod coating and preparation method thereof that embodiment 1 provides, unlike, it is used to prepare the compression mod and uses Magnesia is not contained in the feedstock composition of coating;Remaining is constant, and coating is prepared.
Comparative example 3
Such as the compression mod coating and preparation method thereof that embodiment 1 provides, unlike, it is used to prepare the compression mod and uses The feedstock composition of coating includes the raw material of following parts by weight:53 parts of mullite powder (300 mesh), 3 parts of glutinous rice starch, low melting point glass Glass powder (singing Lin Er new material Co., Ltd, trade mark D240 purchased from Guangzhou) 8 parts, 24 parts of magnesia (300 mesh), 38 parts of waterglass, 90 parts of deionized water;Remaining is constant, and coating is prepared.
Test utilizes above-described embodiment 1-10, the phase for the casting that the mold after the coating dip coating of comparative example 1-3 is prepared Performance is closed, and to have brushed the coating of traditional silica flour and binder (waterglass) formation as a control group;By test result It is aggregated into table 1.
1, casting tensile strength
According to 2006 standard of GB/T1040, the INSTRON universal testing machine produced using Instron Corporation of the U.S. Test;
2, cast(ing) surface appearance
Method by visual observation evaluates the cast(ing) surface after demoulding from casting mold.Evaluation criteria is:
○:Expression does not have molding sand trace, is smooth face;
Δ:Expression can recognize molding sand trace slightly, be slightly smooth face;
╳:It indicates that molding sand trace is obvious, is coarse face.
Table 1:Magnesium alloy cast properties
Can be seen that casting method provided by the invention not only based on above-mentioned test data may insure the casting that casting obtains Part has preferable appearance, moreover it is possible to the further tensile strength for improving casting, it is ensured that the quality of casting.
Basic principles and main features and the features of the present invention of the invention have been shown and described above.The technology of the industry Personnel are it should be appreciated that the present invention is not limited to the above embodiments, and the above embodiments and description only describe this The principle of invention, without departing from the spirit and scope of the present invention, various changes and improvements may be made to the invention, these changes Change and improvement is both fallen in the range of claimed invention.The scope of protection of present invention is by appended claims And its equivalent thereof.

Claims (5)

1. a kind of casting method of die casting, it is characterised in that:Include the following steps:
(1) ingredient weighs raw material according to the composition of casting, melts, refines in smelting furnace, refining, and adjusting component obtains molten Alloy;
(2) mold prepares, and prepares metal die according to the shape of casting to be cast, mold is preheating to 80~120 DEG C, is then set Enter dip-coating in compression mod coating, is dried at a temperature of being then transferred to 60~80 DEG C;
(3) ready mold in step (2) is preheating to 300~350 DEG C, by molten alloy casting in step (1) in advance In the good mold of heat, die cast obtains casting;
The feedstock composition for being used to prepare the compression mod coating includes the raw material of following parts by weight:Mullite powder 45~60 Part, 5~15 parts of carbon source, 10~15 parts of glass powder with low melting point, 18~30 parts of magnesia, 30~45 parts of inorganic binder, deionization 80~100 parts of water.
2. the casting method of die casting according to claim 1, it is characterised in that:The granularity of the mullite powder is 250 ~300 mesh.
3. the casting method of die casting according to claim 1, it is characterised in that:The granularity of the magnesia be 200~ 300 mesh.
4. the casting method of die casting according to claim 1, it is characterised in that:It is used to prepare the compression mod coating Feedstock composition include following parts by weight raw material:50~55 parts of mullite powder, 8~12 parts of carbon source, glass powder with low melting point 12 ~14 parts, 22~25 parts of magnesia, 35~40 parts of inorganic binder, 85~95 parts of deionized water.
5. the casting method of die casting according to claim 1, it is characterised in that:It is used to prepare the compression mod coating Feedstock composition include following parts by weight raw material:53 parts of mullite powder, 10 parts of carbon source, 13 parts of glass powder with low melting point, oxidation 24 parts of magnesium, 38 parts of inorganic binder, 90 parts of deionized water.
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