CN108834692A - A method of environment-friendly type fiber crops mulch is prepared using lapping-hot pressing composite algorithm - Google Patents

A method of environment-friendly type fiber crops mulch is prepared using lapping-hot pressing composite algorithm Download PDF

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Publication number
CN108834692A
CN108834692A CN201810428844.4A CN201810428844A CN108834692A CN 108834692 A CN108834692 A CN 108834692A CN 201810428844 A CN201810428844 A CN 201810428844A CN 108834692 A CN108834692 A CN 108834692A
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China
Prior art keywords
starch
lapping
hot pressing
film
hot
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CN201810428844.4A
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Chinese (zh)
Inventor
刘明洋
张斌
郁崇文
杨建平
高丙文
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Donghua University
National Dong Hwa University
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Donghua University
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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01GHORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
    • A01G13/00Protecting plants
    • A01G13/02Protective coverings for plants; Coverings for the ground; Devices for laying-out or removing coverings
    • A01G13/0256Ground coverings
    • A01G13/0268Mats or sheets, e.g. nets or fabrics
    • A01G13/0275Films
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/12Layered products comprising a layer of synthetic resin next to a fibrous or filamentary layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/32Layered products comprising a layer of synthetic resin comprising polyolefins
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B3/00Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form
    • B32B3/10Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a discontinuous layer, i.e. formed of separate pieces of material
    • B32B3/12Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a discontinuous layer, i.e. formed of separate pieces of material characterised by a layer of regularly- arranged cells, e.g. a honeycomb structure
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B33/00Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/06Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the heating method
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/10Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the pressing technique, e.g. using action of vacuum or fluid pressure
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04Interconnection of layers
    • B32B7/10Interconnection of layers at least one layer having inter-reactive properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B9/00Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
    • B32B9/04Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B9/00Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
    • B32B9/04Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B9/047Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material made of fibres or filaments
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/06Vegetal fibres
    • B32B2262/062Cellulose fibres, e.g. cotton
    • B32B2262/065Lignocellulosic fibres, e.g. jute, sisal, hemp, flax, bamboo
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/50Properties of the layers or laminate having particular mechanical properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/716Degradable

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  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Fluid Mechanics (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Environmental Sciences (AREA)
  • Protection Of Plants (AREA)

Abstract

Lapping-hot pressing composite algorithm preparation environment-friendly type fiber crops mulch method is utilized the invention discloses a kind of, which is characterized in that by the removal of impurities of jute noil fiber opening, combing, obtains the thin net of tossa;By the thin net of tossa cross lapping in length and breadth, hot-pressing processing is carried out with starch/LDPE film;Organosilicon waterproof coating, hot repressing light processing are sprayed on film.In the present invention starch/LDPE film Starch Fraction can complete natural degradation, LDPE part at high temperature can be melt bonded, without adding adhesive, obtained mulch environment-friendly degradable.Meanwhile flaxen fiber is at low cost, mechanical property is good, composite membrane has excellent mechanical property, makes full use of the discarded noil of jute mill to be prepared for low cost, degradable numb mulch, solves the problems, such as the difficult to degrade of plastic film.

Description

A method of environment-friendly type fiber crops mulch is prepared using lapping-hot pressing composite algorithm
Technical field
The present invention relates to a kind of methods of numb mulch that environment-friendly type degradable is prepared using lapping-hot pressing composite algorithm, belong to Agricultural mulching technical field.
Background technique
Plastic film has the effects that promote crop growth, increases yield, heat and moisture preserving, insect prevention, is widely used in existing Generation agricultural.But plastic film is difficult natural degradation, seriously pollutes environment;In addition, remaining in farmland after will cause soil Structure is destroyed, and crop growthing development is influenced.
Currently, studies in China personnel are dedicated to developing degradable mulch, but there are still biggish limitations.As light degradation is moulded Material film can only degrade in the sunlight, but be difficult to control degradation rate, and be embedded to underground and be no different with common plastics mulch;Biodegrade Mulch, such as polylactic acid mulch, cost is too high, can not promote the use of.Therefore, developing low-cost, can the mulch of natural degradation be one The work that item is of practical significance with application value very much.
China's hemp resource is abundant, and the development with science and technology with the improvement of people ' s living standards, Bast Fiber Textiles Type increases, and resulting crudefiber crop waste material also increases, and therefore, the ring of low cost is manufactured using the noil fiber that jute mill discards Guarantor's type fiber crops mulch is conducive to make full use of flaxen fiber, reduces the wasting of resources, has weight to the sustainable development of China's fiber crops planting industry Meaning is wanted, the attention of Minister Agriculture of China is received.
The patent of invention " environment-friendly type fiber crops mulch and its manufacturing process " of publication number CN1559176, it is gentle using combing networking The secondary net-forming process of networking is flowed, fibrilia net is made, by its chemical adhesion at flaxen fiber film, water-proofing treatment is carried out to flaxen fiber film And satinage, so that fiber crops mulch be made.Film made from the invention is harder, can only be used as seedling film, can not be as covering mulch It uses;Simultaneously as water-proofing treatment uses organic fluorine coating, residuals can generate danger to crops and human body Evil.
The patent of invention " sisal fiber enhances environmental protection starch mulch and preparation method thereof " of publication number CN107189108A, makes With graft modified starch, modified sisal hemp, type low density polyethylene resin and other auxiliary agents, the side being blow molded using melting extrusion Method is prepared for sisal fiber enhancing Environment protection mulch film.The invention need to be modified starch, sisal hemp, complex process, higher cost, It is difficult to promote the use of.
Summary of the invention
The technical problem to be solved by the present invention is to:Existing agricultural mulching quality is harder, pollute environment, complex process, at The problems such as this is high.
To solve the above-mentioned problems, the technical solution adopted by the present invention is as follows:
A method of environment-friendly type fiber crops mulch is prepared using lapping-hot pressing composite algorithm, which is characterized in that including following step Suddenly:
Step 1):Jute noil fiber opening is cleaned;
Step 2):Noil fiber combing after shredding is cleaned, obtains the thin net of tossa;
Step 3):By the thin net of tossa cross lapping in length and breadth, the fibrilia net being evenly distributed;
Step 4):Fibrilia net and starch/LDPE film are subjected to hot-pressing processing;
Step 5):Organosilicon waterproof coating is sprayed on the film made from step 4);
Step 6):Film made from step 4) is subjected to hot pressing light processing.
Preferably, the fibrilia net in the step 4) and the mass content of starch in starch/LDPE film are 65-75%, The mass content that LDPE contains is 25-35%.
Preferably, in the step 4) when hot-pressing processing, upper layer and lower layer are fibrilia net, one layer of centre is starch/LDPE Film.
Preferably, the temperature of hot-pressing processing is 120-130 DEG C, pressure 2-6MPa, time 120- in the step 4) 300s。
The raw material that the present invention uses is that jute mill discards noil and starch/LDPE film.Discarded noil distribution of lengths is wide, long fine Dimension can be greater than 20mm, and staple fiber some be only 1-2mm, middle short fiber may not apply to lapping.It is prepared using noil fiber Mulch it is relatively thin, good permeability, mechanical property is good, but membrane micropore is more causes heat insulation effect poor.The degradation of starch/LDPE film and Heat insulation effect is preferable, but poor mechanical property, cracky.The present invention is first by tossa networking, then in length and breadth by tossa net Cross lapping obtains the fibrilia net of certain grammes per square metre, and the fibrilia net of different grammes per square metres is hot-pressed onto starch/LDPE film, can be obtained To different reinforcing effects.
The present invention uses the compound fibrilia net of pressure sintering and starch/LDPE film, the portion LDPE under high temperature in starch/LDPE film Divide and play melt bonded effect, no longer needs to addition adhesive.Using upper layer and lower layer fibrilia net, the one layer of starch/LDPE in centre " sandwich " composite algorithm of film, obtained composite membrane flaxen fiber are evenly distributed, good mechanical properties, and have preferable heat preservation Effect and gas permeability, the advantages of two kinds of films can be given full play to.
To make mulch have excellent waterproofness, the present invention carries out the processing of organosilyl surface waterproof coating, the painting to mulch Layer is harmless and environmentally friendly.
The raw material that the present invention uses is discarded noil and starch/LDPE film, has accomplished recycling for bast fibre spinning waste, is led to It crosses that jute is discarded noil by compound embrane method and starch/LDPE film is combined with each other, has both effectively enhanced starch/LDPE film mechanics Performance solves starch/LDPE film dynamic performance defect, but have the advantages that low cost, can natural degradation.This method operation The advantages of simplicity is easily implemented, and the mulch prepared has plastic film and numb mulch concurrently, has the sustainable development of China's agricultural Significance.
Specific embodiment
In order to make the present invention more obvious and understandable, it is hereby described in detail below with preferred embodiment.
Embodiment 1
A method of environment-friendly type fiber crops mulch is prepared using lapping-hot pressing composite algorithm:
Jute mill jute is discarded into noil and first carries out shredding removal of impurities processing, is then combed, it is thin to obtain uniform fiber Fibrous web is paved into 10g/m by net in transmission net2Tossa net.By a 10g/m2Tossa net laterally put It sets, is laid in vulcanizer hot pressing area in the following, being then 16.4g/m by grammes per square metre2Starch/LDPE film (starch quality content is 70%, LDPE mass content are 30%) to be placed on above jute fibre web, another 10g/m2Jute fibre web it is placed longitudinally, paving On starch film.It is 120 DEG C, hot pressing pressure 2MPa, hot pressing time 120s that hot pressing temperature, which is arranged, in vulcanizing press, hot pressing Composite membrane is made.By the organic hydroxy silicate sprayed surface of composite membrane mass concentration 20%, dosage 6mL/m2, most afterwards through 120 DEG C press polish rod press polish obtain finished product mulch.
Embodiment 2
A method of environment-friendly type fiber crops mulch is prepared using lapping-hot pressing composite algorithm:
Jute mill jute is discarded into noil and first carries out shredding removal of impurities processing, is then combed, it is thin to obtain uniform fiber Fibrous web is paved into 15g/m by net in transmission net2Tossa net.By a 15g/m2Tossa net laterally put It sets, is laid in vulcanizer hot pressing area in the following, being then 16.4g/m by grammes per square metre2Starch/LDPE film (starch quality content is 65%, LDPE mass content are 35%) to be placed on above jute fibre web, another 15g/m2Jute fibre web it is placed longitudinally, paving On starch film.It is 125 DEG C, hot pressing pressure 4MPa, hot pressing time 180s that hot pressing temperature, which is arranged, in vulcanizing press, hot pressing Composite membrane is made.By the organic hydroxy silicate sprayed surface of composite membrane mass concentration 20%, dosage 6mL/m2, most afterwards through 120 DEG C press polish rod press polish obtain finished product mulch.
Embodiment 3
A method of environment-friendly type fiber crops mulch is prepared using lapping-hot pressing composite algorithm:
Jute mill jute is discarded into noil and first carries out shredding removal of impurities processing, is then combed, it is thin to obtain uniform fiber Fibrous web is paved into 20g/m by net in transmission net2Tossa net.By a 20g/m2Tossa net laterally put It sets, is laid in vulcanizer hot pressing area in the following, being then 16.4g/m by grammes per square metre2Starch/LDPE film (starch quality content is 75%, LDPE mass content are 25%) to be placed on above jute fibre web, another 20g/m2Jute fibre web it is placed longitudinally, paving On starch film.It is 130 DEG C, hot pressing pressure 6MPa, hot pressing time 300s that hot pressing temperature, which is arranged, in vulcanizing press, hot pressing Composite membrane is made.By the organic hydroxy silicate sprayed surface of composite membrane mass concentration 20%, dosage 8mL/m2, most afterwards through 130 DEG C press polish rod press polish obtain finished product mulch.
Environment-friendly type fiber crops mulch product made from embodiment 1-3 is subjected to correlation test, test result is as shown in table 1.
Table 1
Performance Embodiment 1 Embodiment 2 Embodiment 3 Common ground film
Thickness (mm) 0.19 0.199 0.211 0.108
Grammes per square metre (g/m2) 35.85 47.49 56.35 16.75
Tensile strength (N/m) 820 1030 1320 210
Tearing strength (N) 5.87 7.96 10.69 1.6
Bursting strength (N) 36.64 49.24 58.93 11.5
Air penetrability (mm/s) 17.08 14.23 12.23 0
Note:Common ground film uses the PE mulch of Baoding Bao Chuan agricultural film Science and Technology Ltd. production;Measuring instrument is:It is thick Degree:YG141N digital textile thickness gauge;Grammes per square metre:FA2004A electronic balance;Tensile strength:YG026MB-250 electronics strength Instrument;Tearing strength:YG026MB-250 electronics strength tester;Bursting strength:YG026MB-250 electronics strength tester;Air penetrability: YG461E air permeability tester.

Claims (4)

1. a kind of utilize lapping-hot pressing composite algorithm preparation environment-friendly type fiber crops mulch method, which is characterized in that include the following steps:
Step 1):Jute noil fiber opening is cleaned;
Step 2):Noil fiber combing after shredding is cleaned, obtains the thin net of tossa;
Step 3):By the thin net of tossa cross lapping in length and breadth, the fibrilia net being evenly distributed;
Step 4):Fibrilia net and starch/LDPE film are subjected to hot-pressing processing;
Step 5):Organosilicon waterproof coating is sprayed on the film made from step 4);
Step 6):Film made from step 4) is subjected to hot pressing light processing.
2. utilizing lapping-hot pressing composite algorithm preparation environment-friendly type fiber crops mulch method as described in claim 1, which is characterized in that The mass content of starch is 65-75%, the mass content that LDPE contains in fibrilia net and starch/LDPE film in the step 4) For 25-35%.
3. utilizing lapping-hot pressing composite algorithm preparation environment-friendly type fiber crops mulch method as described in claim 1, which is characterized in that In the step 4) when hot-pressing processing, upper layer and lower layer are fibrilia net, one layer of centre is starch/LDPE film.
4. utilizing lapping-hot pressing composite algorithm preparation environment-friendly type fiber crops mulch method as described in claim 1, which is characterized in that The temperature of hot-pressing processing is 120-130 DEG C, pressure 2-6MPa, time 120-300s in the step 4).
CN201810428844.4A 2018-05-07 2018-05-07 A method of environment-friendly type fiber crops mulch is prepared using lapping-hot pressing composite algorithm Pending CN108834692A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109566214A (en) * 2019-01-07 2019-04-05 东华大学 A kind of degradable agricultural film and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109566214A (en) * 2019-01-07 2019-04-05 东华大学 A kind of degradable agricultural film and preparation method thereof

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