CN108831615B - Water-blocking composite cable for offshore oil platform - Google Patents

Water-blocking composite cable for offshore oil platform Download PDF

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Publication number
CN108831615B
CN108831615B CN201810525372.4A CN201810525372A CN108831615B CN 108831615 B CN108831615 B CN 108831615B CN 201810525372 A CN201810525372 A CN 201810525372A CN 108831615 B CN108831615 B CN 108831615B
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framework
cable
cable core
conductor
water
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CN108831615A (en
Inventor
董吟梅
陆秀国
杨茂明
王友香
郭宗亚
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Anhui Huining Electric and Measuring Appliance Co Ltd
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Anhui Huining Electric and Measuring Appliance Co Ltd
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B7/00Insulated conductors or cables characterised by their form
    • H01B7/17Protection against damage caused by external factors, e.g. sheaths or armouring
    • H01B7/18Protection against damage caused by wear, mechanical force or pressure; Sheaths; Armouring
    • H01B7/1805Protections not provided for in groups H01B7/182 - H01B7/26
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00Processes of treating or compounding macromolecular substances
    • C08J3/24Crosslinking, e.g. vulcanising, of macromolecules
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B7/00Insulated conductors or cables characterised by their form
    • H01B7/0045Cable-harnesses
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B7/00Insulated conductors or cables characterised by their form
    • H01B7/17Protection against damage caused by external factors, e.g. sheaths or armouring
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B7/00Insulated conductors or cables characterised by their form
    • H01B7/17Protection against damage caused by external factors, e.g. sheaths or armouring
    • H01B7/28Protection against damage caused by moisture, corrosion, chemical attack or weather
    • H01B7/282Preventing penetration of fluid, e.g. water or humidity, into conductor or cable
    • H01B7/2825Preventing penetration of fluid, e.g. water or humidity, into conductor or cable using a water impermeable sheath
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B7/00Insulated conductors or cables characterised by their form
    • H01B7/17Protection against damage caused by external factors, e.g. sheaths or armouring
    • H01B7/29Protection against damage caused by extremes of temperature or by flame
    • H01B7/295Protection against damage caused by extremes of temperature or by flame using material resistant to flame
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/04Homopolymers or copolymers of ethene
    • C08J2323/06Polyethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K13/00Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
    • C08K13/02Organic and inorganic ingredients
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/34Silicon-containing compounds
    • C08K3/36Silica
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/38Boron-containing compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/05Alcohols; Metal alcoholates
    • C08K5/053Polyhydroxylic alcohols
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/10Esters; Ether-esters
    • C08K5/101Esters; Ether-esters of monocarboxylic acids
    • C08K5/103Esters; Ether-esters of monocarboxylic acids with polyalcohols

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Organic Insulating Materials (AREA)

Abstract

The invention discloses a water-blocking composite cable for an offshore oil platform, wherein a cable core comprises a framework, the framework comprises two partially overlapped square frameworks, the framework of the overlapped part is a main framework, the framework of the non-overlapped part is an auxiliary framework, and the main framework and the auxiliary framework are of an integrated structure; the cable is characterized in that a power wire core is arranged in the main framework, a control wire core and a communication wire core are respectively arranged in each auxiliary framework, and the outer side of the cable core is sequentially coated with a crosslinked polyethylene inner sheath, a steel belt woven armor layer and a crosslinked polyethylene outer sheath from inside to outside. The cable is provided with the framework, the framework comprises two partially overlapped square frameworks, the framework of the overlapped part is a main framework, the framework of the non-overlapped part is an auxiliary framework, the main framework and the auxiliary framework respectively play a good role in protecting the power wire core, the control wire core and the communication wire core, and meanwhile, the compression resistance and the tensile resistance of the cable can be improved.

Description

Water-blocking composite cable for offshore oil platform
Technical Field
The invention relates to the technical field of cables, in particular to a water-blocking composite cable for an offshore oil platform.
Background
China has a long coastline and a wide sea area, the marine oil resources are rich, the exploitation project is increasing day by day, the number of the marine oil platforms is increasing continuously, and the matched cables for the marine oil platforms are also developed greatly. The cable for the offshore oil platform can provide a stable and reliable platform for communication between islands and continents, between islands, defense at home and abroad, signal transmission and the like. The flame-retardant shielding cable for the switch cabinet is indispensable for power supply, and the highest voltage class of the power cable is 30kV in the most common IEC60092-354 and NEK606 standards at present. With the increasing of installed power, it is a necessary trend to increase the supply voltage, and the 30kV flame-retardant shielding cable for the switch cabinet cannot meet the use requirements.
In the GB/T12706.3-2008 standard, the requirement of a rated voltage 35kV cable is stipulated, and the cable is suitable for a power distribution network or an industrial device which is laid fixedly and is not suitable for special environments of ships or oceans. The installation service environment of the cable for the offshore oil platform is very harsh, such as solar sunshine, sea wind, seawater salt, high and low temperature, the requirement on the bending radius of the cable is higher, the requirement on tensile water resistance is good, the cable also needs to meet the requirements on low smoke, zero halogen, slurry resistance and the like, and the cable in the prior art cannot meet the requirements well and needs to be improved.
Disclosure of Invention
The invention aims to make up the defects of the prior art and provides a water-blocking composite cable for an offshore oil platform.
The invention is realized by the following technical scheme:
the utility model provides an offshore oil platform is with compound cable that blocks water which characterized in that: the cable comprises a cable core, wherein the cable core comprises a framework, the framework comprises two partially overlapped square frameworks, the framework of the overlapped part is a main framework, the framework of the non-overlapped part is an auxiliary framework, and the main framework and the auxiliary framework are of an integrated structure; the power cable core is arranged in the main framework, a control cable core and a communication cable core are respectively arranged in each auxiliary framework, the control cable core comprises two conductors I, each conductor I is respectively coated with a silicon rubber insulating layer and twisted in pair, a water-blocking aramid yarn wrapping layer I is coated outside the twisted conductors I, the communication cable core comprises a conductor II, the conductors are twisted with two round polyurethane elastomers after being coated with ethylene propylene rubber insulating layers, the twisted conductors are coated with a water-blocking aramid yarn wrapping layer II, the power cable core comprises a conductor III, the conductor III is sequentially coated with a water-blocking aramid yarn wrapping layer III and a copper wire woven independent shielding layer from inside to outside; the outer side of the cable core is sequentially coated with a crosslinked polyethylene inner sheath, a steel strip woven armor layer and a crosslinked polyethylene outer sheath from inside to outside.
A marine oil platform with compound cable that blocks water, its characterized in that: the first conductor, the second conductor and the third conductor adopt copper conductors.
A marine oil platform with compound cable that blocks water, its characterized in that: the cross-sectional shapes of the power wire core and the control wire core are circular.
A marine oil platform with compound cable that blocks water, its characterized in that: the cross-sectional shape of the communication wire core is oval.
The cross-linked polyethylene is prepared from the following raw materials in parts by weight:
200 parts of high-density polyethylene 170-containing material, 3-4 parts of pentaerythritol, 10-16 parts of nano silicon dioxide, 0.7-1 part of sorbitan monooleate, 2-5 parts of fluoroboric acid, 0.01-0.02 part of catalyst and 2-3 parts of diisocyanate.
The catalyst is p-toluenesulfonic acid.
The preparation method of the crosslinked polyethylene comprises the following steps:
(1) mixing nano silicon dioxide and fluoboric acid, stirring for 10-20 minutes at the temperature of 60-70 ℃, adding the mixture into deionized water 13-20 times the weight of the mixture, stirring uniformly, adding pentaerythritol and a catalyst, raising the temperature to 90-95 ℃, stirring for 1-2 hours at the temperature of heat preservation, performing suction filtration, washing the precipitate with water, and drying at normal temperature to obtain active nano silicon dioxide;
(2) mixing high-density polyethylene, sorbitan monooleate, active nano-silica and diisocyanate, uniformly stirring, feeding into an extruder, performing melt extrusion, and cooling to obtain the crosslinked polyethylene.
The invention has the advantages that:
the cable is provided with the framework, the framework comprises two square frameworks which are partially overlapped, the framework of the overlapped part is a main framework, the framework of the non-overlapped part is an auxiliary framework, the main framework and the auxiliary framework respectively play a good role in protecting a power wire core, a control wire core and a communication wire core, and the compression resistance and the tension resistance of the cable can be improved;
according to the invention, the nano silicon dioxide is treated by the fluoboric acid and then is blended and esterified with the pentaerythritol, so that the surface activity of the nano silicon dioxide is fully improved, the dispersion compatibility of the nano silicon dioxide in a polymer matrix is improved, the mechanical stability of a finished product material is improved, and meanwhile, the introduced fluoboric ions can effectively improve the hydrophobic property of the surface of the sheath material and improve the impermeability.
Drawings
FIG. 1 is a schematic structural diagram of the present invention.
Detailed Description
As shown in fig. 1, the water-blocking composite cable for the offshore oil platform comprises a cable core, wherein the cable core comprises a framework, the framework comprises two partially overlapped square frameworks, the overlapped part of the framework is a main framework 1, the non-overlapped part of the framework is an auxiliary framework 2, and the main framework 1 and the auxiliary framework 2 are of an integrated structure; the power cable comprises a main framework 1, a power cable core is arranged in each auxiliary framework 2, each control cable core and a communication cable core are arranged in each auxiliary framework 2 respectively, each control cable core comprises two conductors 3, each conductor 3 is coated with a silicone rubber insulating layer 4 and is twisted in pair, a waterproof aramid yarn wrapping layer 5 is coated outside each twisted pair of two conductors 3, each communication cable core comprises a conductor 6, each conductor 6 is coated with an ethylene propylene rubber insulating layer 7 and then is twisted with two round polyurethane elastomers 8, a waterproof aramid yarn wrapping layer 9 is coated outside each twisted conductor 6, each power cable core comprises a conductor 10, each conductor 10 is sequentially coated with a waterproof aramid yarn wrapping layer 11 and a copper wire braided independent shielding layer 12 from inside to outside; the outer side of the cable core is coated with a crosslinked polyethylene inner sheath 13, a steel strip woven armor layer 14 and a crosslinked polyethylene outer sheath 15 from inside to outside in sequence.
The conductors 3, 6, 10 are copper conductors.
The cross-sectional shapes of the power wire core and the control wire core are circular.
The cross-sectional shape of the communication wire core is oval.
The cross-linked polyethylene is prepared from the following raw materials in parts by weight:
high-density polyethylene 170, pentaerythritol 3, nano-silica 10, sorbitan monooleate 0.7, fluoroboric acid 2, catalyst 0.01 and diisocyanate 2.
The catalyst is p-toluenesulfonic acid.
The preparation method of the crosslinked polyethylene comprises the following steps:
(1) mixing nano silicon dioxide and fluoboric acid, keeping the temperature at 60 ℃ and stirring for 10 minutes, adding the mixture into deionized water 13 times the weight of the mixture, stirring uniformly, adding pentaerythritol and a catalyst, raising the temperature to 90 ℃, keeping the temperature and stirring for 1 hour, performing suction filtration, washing precipitates with water, and drying at normal temperature to obtain active nano silicon dioxide;
(2) mixing high-density polyethylene, sorbitan monooleate, active nano-silica and diisocyanate, uniformly stirring, feeding into an extruder, performing melt extrusion, and cooling to obtain the crosslinked polyethylene.

Claims (1)

1. The utility model provides an offshore oil platform is with compound cable that blocks water which characterized in that: the cable comprises a cable core, wherein the cable core comprises a framework, the framework comprises two partially overlapped square frameworks, the framework of the overlapped part is a main framework, the framework of the non-overlapped part is an auxiliary framework, and the main framework and the auxiliary framework are of an integrated structure; the power cable core is arranged in the main framework, a control cable core and a communication cable core are respectively arranged in each auxiliary framework, the control cable core comprises two conductors I, each conductor I is respectively coated with a silicon rubber insulating layer and twisted in pair, a water-blocking aramid yarn wrapping layer I is coated outside the twisted conductors I, the communication cable core comprises a conductor II, the conductors are twisted with two round polyurethane elastomers after being coated with ethylene propylene rubber insulating layers, the twisted conductors are coated with a water-blocking aramid yarn wrapping layer II, the power cable core comprises a conductor III, the conductor III is sequentially coated with a water-blocking aramid yarn wrapping layer III and a copper wire woven independent shielding layer from inside to outside; the outer side of the cable core is sequentially coated with a crosslinked polyethylene inner sheath, a steel strip woven armor layer and a crosslinked polyethylene outer sheath from inside to outside;
the first conductor, the second conductor and the third conductor adopt copper conductors;
the cross sections of the power wire core and the control wire core are circular;
the cross section of the communication wire core is elliptical;
the cross-linked polyethylene is prepared from the following raw materials in parts by weight:
200 parts of high-density polyethylene 170-containing material, 3-4 parts of pentaerythritol, 10-16 parts of nano silicon dioxide, 0.7-1 part of sorbitan monooleate, 2-5 parts of fluoroboric acid, 0.01-0.02 part of catalyst and 2-3 parts of diisocyanate;
the catalyst is p-toluenesulfonic acid;
the preparation method of the crosslinked polyethylene comprises the following steps:
(1) mixing nano silicon dioxide and fluoboric acid, stirring for 10-20 minutes at the temperature of 60-70 ℃, adding the mixture into deionized water 13-20 times the weight of the mixture, stirring uniformly, adding pentaerythritol and a catalyst, raising the temperature to 90-95 ℃, stirring for 1-2 hours at the temperature of heat preservation, performing suction filtration, washing the precipitate with water, and drying at normal temperature to obtain active nano silicon dioxide;
(2) mixing high-density polyethylene, sorbitan monooleate, active nano-silica and diisocyanate, uniformly stirring, feeding into an extruder, performing melt extrusion, and cooling to obtain the crosslinked polyethylene.
CN201810525372.4A 2018-05-28 2018-05-28 Water-blocking composite cable for offshore oil platform Active CN108831615B (en)

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Application Number Priority Date Filing Date Title
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Application Number Priority Date Filing Date Title
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CN108831615B true CN108831615B (en) 2020-02-18

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Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3589320B2 (en) * 1995-06-22 2004-11-17 古河電気工業株式会社 Elevator cable
CN101894603A (en) * 2010-06-28 2010-11-24 湘潭市特种线缆有限公司 Deepwater carrying cable
CN204834111U (en) * 2015-07-17 2015-12-02 安徽电信器材贸易工业有限责任公司 Tensile is able to bear or endure crooked communication cable
CN206194405U (en) * 2016-11-30 2017-05-24 天长市徽宁电器仪表厂 High temperature resistant anti -interference computer cable

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