Disclosure of Invention
In order to solve all or part of the problems, the invention provides a method for greatly reducing the content of dioxin toxic cancerogenic substances in the purified flue gas; and the flue gas purification technology for obviously reducing the cooling water requirement.
According to a first aspect of the present invention there is provided a flue gas cleaning system in a continuous feed electric arc furnace comprising: one end of the water-cooling elbow is communicated with the smoke outlet of the scrap steel preheating section of the electric arc furnace in a sealing way, so that the smoke temperature is reduced, and the transportation pipeline is prevented from being burnt due to too high smoke temperature; the sedimentation chamber is sealed at the other end of the water-cooling elbow, and the sedimentation chamber is filled with the water-cooling elbow, so that large-particle smoke dust in the smoke is sunk, and deposition in the bag type dust collector is reduced; the lower end of the heat preservation flue is communicated with the upper part of the settling chamber in a sealing way, so that the high-temperature time of the flue gas is prolonged, and the decomposition rate of dioxin toxic cancerogenic substances in the flue gas is improved; an evaporative cooling tower having a flue gas inlet and a flue gas outlet, wherein the upper end of the insulating flue is in sealed communication with the flue gas inlet of the evaporative cooling tower; the bag type dust collector is provided with a smoke inlet and a smoke outlet, wherein the smoke inlet of the bag type dust collector is communicated with the smoke outlet of the evaporative cooling tower in a sealing way; and the discharge device is communicated with the flue gas outlet of the bag type dust collector.
In a further technical scheme, the upper part of the bag type dust collector can be provided with a plurality of compressed air inlets, and the lower part of the bag type dust collector is correspondingly provided with a plurality of dust collecting funnels. That is, the compressed air introduction ports are provided in one-to-one correspondence with the dust collection funnels.
In a further technical scheme, the flue gas purification system can further comprise a conveyor and an ash storage bin, wherein the conveyor is arranged below the dust collection hoppers and is used for conveying dust collected on the dust collection hoppers to the ash storage bin. In this case, a bucket elevator may be further included to carry dust from the conveyor into the ash bin.
In a further technical scheme, the exhaust device comprises a smoke exhaust fan and a chimney, and a smoke outlet of the evaporative cooling tower is sequentially communicated with the smoke exhaust fan and the chimney in a sealing mode.
In a further technical scheme, a pipeline provided with a mixing air valve is communicated between the flue gas inlet of the bag type dust collector and the flue gas outlet of the evaporative cooling tower in a sealing way.
In a further technical scheme, the heat preservation flue is a flue with refractory materials inside.
According to a second aspect of the present invention, there is provided a method of cleaning flue gas in a continuous feed electric arc furnace, comprising: flue gas from a smoke outlet of a scrap steel preheating section of the electric arc furnace enters a settling chamber after passing through a water-cooling elbow; the flue gas after sedimentation and pre-dust removal in the sedimentation chamber enters an evaporative cooling tower through a heat preservation flue; introducing flue gas exiting the evaporative cooling tower into a bag house; and then sending the flue gas from the bag filter to a discharge device.
In a further technical scheme, the flue gas temperature near the flue gas outlet of the scrap steel preheating section of the electric arc furnace is 700-1000 ℃; and the flue gas is cooled to 200-250 ℃ in the evaporative cooling tower at 200-400 ℃/s.
In a further technical scheme, when the temperature of the flue gas entering the bag type dust collector exceeds a first set temperature, the air mixing valve is automatically opened; and when the temperature of the flue gas entering the bag type dust collector is reduced to a second set temperature, the air mixing valve is automatically closed. The first set temperature is preferably 230℃and the second set temperature is preferably 200 ℃.
In a further technical scheme, the bag type dust collector adopts a high-temperature resistant filter material, and the filtering area reaches 11000 square meters.
The flue gas purification system in the continuous feeding electric arc furnace of the first aspect of the invention and the flue gas purification method in the continuous feeding electric arc furnace of the second aspect of the invention can reduce dioxin toxic cancerogenic substances in the flue gas by arranging a heat preservation flue and an evaporative cooling tower to enable the flue gas to be subjected to heat preservation and quenching treatment. A large amount of high-temperature flue gas generated in the smelting process of the electric arc furnace sequentially passes through a water-cooling elbow, a settling chamber, a heat preservation flue, an evaporative cooling tower, a bag type dust collector and a discharge device. The flue gas enters a settling chamber through a water-cooling elbow, and particles in the flue gas are settled and pre-dedusted in the settling chamber; the flue gas enters an evaporative cooling tower through a heat preservation flue, and dioxin toxic cancerogenic substances in the flue gas are basically decomposed and destroyed in the heat preservation flue, so that the evaporative cooling tower rapidly cools (quenches) the flue gas, the synthetic reaction time of the dioxin toxic cancerogenic substances in the flue gas is shortened, namely the production of the dioxin toxic cancerogenic substances is reduced, and the environment is protected; and finally, the flue gas enters a bag type dust collector to carry out fine dust removal, and then is discharged at high altitude through a discharge device. The flue gas purification system in the continuous charging electric arc furnace adopts the heat preservation flue and the evaporative cooling tower, so that the cooling water requirement is greatly reduced, and the construction cost of water treatment facilities and the water treatment operation cost are also reduced.
Detailed Description
Embodiments of the technical scheme of the present invention will be described in detail below with reference to the accompanying drawings. The following examples are only for more clearly illustrating the technical aspects of the present invention, and thus are merely examples, and are not intended to limit the scope of the present invention.
Fig. 1 shows a flue gas cleaning system 100 in a continuous feed electric arc furnace in accordance with an embodiment of the present invention. As shown in fig. 1, the flue gas cleaning system 100 according to the embodiment of the present invention mainly includes: the device comprises a water-cooling elbow 2, a settling chamber 3, a heat preservation flue 4, an evaporative cooling tower 5, a bag type dust collector 6 and a discharge device. One end of the water-cooling elbow 2 is communicated with the smoke outlet 1 of the scrap steel preheating section of the electric arc furnace in a sealing way, and the other end of the water-cooling elbow is communicated with the sedimentation chamber 3 in a sealing way. The insulating flue 4 is arranged to have a lower end and an upper end, the lower end of the insulating flue 4 being in sealed communication with the upper part of the settling chamber 3, the upper end of the insulating flue 4 being in sealed communication with the flue gas inlet of the evaporative cooling tower 5. The bag filter 6 has a flue gas inlet and a flue gas outlet, wherein the flue gas inlet is in sealed communication with the flue gas outlet of the evaporative cooling tower 5, and the flue gas outlet is in communication with the discharge device.
The flue gas purification system 100 in the continuous charging electric arc furnace of the first aspect of the invention and the flue gas purification method in the continuous charging electric arc furnace of the second aspect of the invention can reduce dioxin toxic cancerogenic substances in the flue gas by arranging the heat preservation flue 4 and the evaporative cooling tower 5 to enable the flue gas to be subjected to heat preservation and quenching treatment. A large amount of high-temperature flue gas generated in the smelting process of the electric arc furnace sequentially passes through the water-cooling elbow 2, the sedimentation chamber 3, the heat preservation flue 4, the evaporative cooling tower 5, the bag type dust collector 6 and the discharge device. The flue gas enters a settling chamber 3 through a water-cooling elbow 2, and particles in the flue gas are settled and pre-dedusted in the settling chamber 3, wherein a warmer can be further arranged in the settling chamber 3, when the temperature of the flue gas is less than 700 ℃, the warmer is automatically opened, and when the temperature of the flue gas is more than 750 ℃, the warmer is automatically closed, so that the temperature of the flue gas before entering a heat preservation flue is ensured to be more than 700 ℃; the flue gas enters the evaporative cooling tower 5 through the heat preservation flue 4, and the heat preservation flue 4 is a flue with refractory materials inside, so that the flue gas is prevented from burning and is heat-preserved. The toxic and cancerogenic substances of the dioxin in the flue gas are basically decomposed and destroyed in the heat preservation flue 4, the evaporative cooling tower 5 rapidly cools (quenches) the flue gas, the synthetic reaction time of the toxic and cancerogenic substances of the dioxin in the flue gas is shortened, namely the toxic and cancerogenic substances of the dioxin are reduced, and the environment is protected; and finally, the flue gas enters a bag type dust collector 6 for fine dust removal, and then is discharged at high altitude through a discharge device. The flue gas purification system in the continuous charging electric arc furnace adopts the heat preservation flue 4 and the evaporative cooling tower 5, so that the cooling water requirement is greatly reduced, and the construction cost of water treatment facilities and the water treatment operation cost are also reduced.
The deviation of the using temperature and the design temperature of the bag filter 6 can cause serious consequences, and the high-temperature gas must be cooled to below the temperature which can be born by the filter material; in order to prevent condensation, the gas temperature must be kept above the dew point (the temperature at which the air is cooled to saturation is called dew point temperature, abbreviated as dew point, in the case where the water vapor content in the air is constant and the air pressure is kept constant). In the embodiment, a pipeline provided with a mixing air valve 7 is in sealing communication between the flue gas inlet of the bag type dust collector 6 and the flue gas outlet of the evaporative cooling tower 5. When the temperature of the flue gas entering the bag type dust collector 6 exceeds a first set temperature, the air mixing valve 7 is automatically opened, so that wild air enters, the temperature of the flue gas is reduced to a second set temperature, and the air mixing valve 7 is automatically closed. The temperature of the flue gas entering the bag filter 6 is ensured to be lower than the bearable temperature of the filter material and higher than the dew point. In general, the bag house 6 for the treatment of high temperature gases is expensive and requires a high cost for air cooling facilities such as the evaporative cooling tower 5. The present invention determines the cooling method according to the temperature and air quantity formed by the production process, and takes the size and the dimension of the bag filter 6 into consideration to prepare the most economical treatment temperature. The first set temperature is preferably set to 230 ℃, and the second set temperature is preferably set to 200 ℃. The air mixing valve 7 is arranged to control the temperature of the flue gas entering the bag filter 6 to be 200-230 ℃ and increase the working stability of the bag filter 6.
The bag collector 6 is provided with a plurality of compressed air inlets at its upper part and a plurality of dust collecting funnels at its lower part. The compressed air inlet and the dust collecting hopper are arranged in one-to-one correspondence, so that the working efficiency of the bag type dust collector 6 is improved. The baghouse 6 may preferably be a low pressure pulse baghouse. A conveyor 10 can be arranged below a row of dust collecting funnels of the bag type dust collector 6, and dust leaked by the dust collecting funnels is sent to a bucket elevator 11 through the conveyor 10 and is sent to an ash storage bin 12 again, so that the automation level of the flue gas purification system 100 is improved. The bag type dust collector 6 can adopt high temperature resistant filter materials, and the filtering area can reach 11000m 2 The filtering effect on the smoke is improved.
The exhaust device comprises a smoke exhaust fan 8 and a chimney 9, wherein the smoke exhaust fan 8 discharges the smoke from the bag filter 6 into the chimney 9 for discharging. The smoke exhaust fan 8 can adopt a frequency converter to regulate speed and save energy so as to meet the requirement of air quantity change under different working conditions of the discharge device and achieve the purposes of energy saving and consumption reduction.
The purification steps of the flue gas purification system of the present invention are briefly described below. Taking 220 ton continuous charging Consdi electric arc furnace as an example, the flue gas amount in the furnace is 200000-300000Nm according to the material type 3 And/h, the temperature of the flue gas is 1000-1200 ℃, and the dust concentration of the flue gas is aboutAt 8g/Nm 3 。
When the high-temperature flue gas is continuously fed through Consedi, the scrap steel is preheated, and the temperature at the smoke outlet 1 of the scrap steel preheating section is 700-1000 ℃. The high-temperature flue gas enters a sedimentation chamber 3 with the flow of 20m multiplied by 7m multiplied by 10m through a water cooling elbow 2 for sedimentation, the flue gas after sedimentation and pre-dust removal in the sedimentation chamber 3 is sent into an evaporative cooling tower 5 through a heat preservation flue 4, and the temperature of the flue gas in the evaporative cooling tower 5 is quenched to 200-250 ℃ at the speed of 200-400 ℃/s. The flue gas after rapid cooling enters a bag type dust collector 6 for fine dust removal. The low temperature smoke volume after cooling and dedusting reaches the standard is 70-75 multiplied by 10 4 m 3 And/h, driving the smoke exhaust fan 8 to discharge high altitude through a chimney 9 with the height of 28-30m by a 1750kW variable frequency motor. When the temperature of the flue gas is abnormal and exceeds 230 ℃ which is the highest set temperature of the bag-type dust collector 6, the air mixing valve 7 at the upstream of the bag-type dust collector 6 is automatically opened to mix wild air; when the temperature of the flue gas is reduced to 200 ℃, the air mixing valve 7 is automatically closed.
Example 1
The temperature at the smoke outlet 1 of the scrap steel preheating section is 700 ℃, high-temperature smoke enters the sedimentation chamber 3 through the water-cooling elbow 2 to carry out sedimentation pre-dust removal, then enters the evaporative cooling tower 5 through the heat preservation flue 4, the toxic and cancerogenic substances of dioxin in the smoke are basically decomposed and destroyed by the heat preservation flue 4, the evaporative cooling tower 5 is quenched to 200 ℃ at the speed of 200 ℃/s, the synthetic reaction time of the toxic and cancerogenic substances of the dioxin in the smoke is shortened, and the toxic and cancerogenic substances of the dioxin are reduced. The flue gas after rapid cooling enters a bag type dust collector 6 for fine dust removal, and finally the temperature of the flue gas is 76 ℃ and the dust concentration is 8.2mg/Nm 3 Containing 0.38mg/Nm of dioxin 3 Reaching the emission standard.
Example two
The temperature at the smoke outlet 1 of the scrap steel preheating section is 900 ℃, high-temperature smoke enters the sedimentation chamber 3 through the water-cooling elbow 2 to carry out sedimentation pre-dust removal, then enters the evaporative cooling tower 5 through the heat preservation flue 4, the heat preservation flue 4 enables dioxin toxic cancerogenic substances in the smoke to be basically decomposed and destroyed, the evaporative cooling tower 5 is quenched to 210 ℃ at the speed of 300 ℃/s, and the dioxin toxic cancerogenic substances in the smoke are shortenedThe synthesis reaction time is reduced, namely, the production of dioxin toxic cancerogenic substances is reduced. The flue gas after rapid cooling enters a bag type dust collector 6 for fine dust removal, and finally the temperature of the flue gas is 79 ℃, and the dust concentration is 8.9mg/Nm 3 0.42mg/Nm of toxic cancerogenic substance containing dioxin 3 Reaching the emission standard.
Example III
The temperature at the smoke outlet 1 of the scrap steel preheating section is 1000 ℃, high-temperature smoke enters the sedimentation chamber 3 through the water-cooling elbow 2 to carry out sedimentation pre-dust removal, then enters the evaporative cooling tower 5 through the heat preservation flue 4, the toxic and cancerogenic substances of dioxin in the smoke are basically decomposed and destroyed by the heat preservation flue 4, the evaporative cooling tower 5 is quenched to 228 ℃ at the speed of 400 ℃/s, the synthetic reaction time of the toxic and cancerogenic substances of the dioxin in the smoke is shortened, and the toxic and cancerogenic substances of the dioxin are reduced. The flue gas after rapid cooling enters a bag type dust collector 6 for fine dust removal, and finally the temperature of the flue gas is 83 ℃ and the dust concentration is 8.6mg/Nm 3 0.41mg/Nm of toxic carcinogen containing dioxin 3 Reaching the emission standard.
Example IV
The temperature at the smoke outlet 1 of the scrap steel preheating section is 1022 ℃, high-temperature smoke enters the sedimentation chamber 3 through the water-cooling elbow 2 for sedimentation pre-dedusting, then enters the evaporative cooling tower 5 through the heat preservation flue 4, the toxic and cancerogenic substances of dioxin in the smoke are basically decomposed and destroyed by the heat preservation flue 4, the evaporative cooling tower 5 is quenched to 260 ℃ at the speed of 400 ℃/s, and the synthetic reaction time of the toxic and cancerogenic substances of dioxin in the smoke is shortened, namely the toxic and cancerogenic substances of dioxin are reduced. Because 260 ℃ is higher than 230 ℃, the air mixing valve 7 at the upstream of the bag-type dust collector 6 is automatically opened to mix wild air, when the temperature of the flue gas is reduced to 200 ℃, the air mixing valve 7 is automatically closed, the flue gas after rapid cooling enters the bag-type dust collector 6 to carry out fine dust removal, and finally the temperature of the flue gas is 85 ℃, and the dust concentration is 7.9mg/Nm 3 0.47 mg/Nm of toxic cancerogenic substance containing dioxin 3 Reaching the emission standard.
It is noted that unless otherwise indicated, technical or scientific terms used herein should be given the ordinary meaning as understood by one of ordinary skill in the art to which this invention belongs. In the description of the present invention, the meaning of "plurality" is two or more unless specifically defined otherwise.
In the present invention, unless explicitly specified and limited otherwise, the terms "connected," "connected," and the like are to be construed broadly, and may be fixedly connected, detachably connected, or integrally formed, for example; can be mechanically or electrically connected; can be directly connected or indirectly connected through an intermediate medium, and can be communicated with the inside of two elements or the interaction relationship of the two elements. The specific meaning of the above terms in the present invention can be understood by those of ordinary skill in the art according to the specific circumstances.
Finally, it should be noted that: the above embodiments are only for illustrating the technical solution of the present invention, and not for limiting the same; although the invention has been described in detail with reference to the foregoing embodiments, it will be understood by those of ordinary skill in the art that: the technical scheme described in the foregoing embodiments can be modified or some or all of the technical features thereof can be replaced by equivalents; such modifications and substitutions do not depart from the spirit of the invention, and are intended to be included within the scope of the appended claims and description. In particular, the technical features mentioned in the respective embodiments may be combined in any manner as long as there is no structural conflict. The present invention is not limited to the specific embodiments disclosed herein, but encompasses all technical solutions falling within the scope of the claims.