CN108823456A - A kind of no nickel will not be to the corrosion-resistant jewellery 18K platinum material of skin allergy - Google Patents
A kind of no nickel will not be to the corrosion-resistant jewellery 18K platinum material of skin allergy Download PDFInfo
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- CN108823456A CN108823456A CN201810772790.3A CN201810772790A CN108823456A CN 108823456 A CN108823456 A CN 108823456A CN 201810772790 A CN201810772790 A CN 201810772790A CN 108823456 A CN108823456 A CN 108823456A
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C1/00—Making non-ferrous alloys
- C22C1/02—Making non-ferrous alloys by melting
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C5/00—Alloys based on noble metals
- C22C5/02—Alloys based on gold
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22F—CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
- C22F1/00—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
- C22F1/14—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of noble metals or alloys based thereon
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Abstract
The invention discloses a kind of no nickel will not be to the corrosion-resistant jewellery 18K platinum material of skin allergy.According to weight percent, the ingredient of the alloy is:Li:0.5-0.8wt.%,Ru:0.3-0.5wt.%,Os:0.2-0.4wt.%,Sn:6.0-8.0wt.%,In:10.0-12.0wt.%,Ag:5.0-8.0wt.%, surplus are gold.The patent solves in current K platinum generally containing the nickel element that can make us generating allergy.By the not nickeliferous human body friendly K platinum material of the optimization of alloying component and innovative development, the development bottleneck in field of jewelry is effectively breached.It is contemplated that the implementation and industrialization of the material can obtain plentiful and substantial economic gain and social benefit.
Description
Technical field
The present invention relates to technical field of alloy, specifically, being related to a kind of billon.
Background technique
Gold is a kind of precious metal, is that the mankind have found and one of the metal developed and used earliest.It is production jewellery and
The important source material of coin, and be the important stockpile of country, element is famous with the king of metal.It is not considered only as fine and rich
Symbol, but also with its distinctive value, the life brought benefit to the mankind.One important applied field of gold is decoration material
Material, including jewellery etc..Gold can be also used for daily necessities, such as gold-plated clock and watch, belt fastener, lighter, pen.Clock and watch kingdom is auspicious
Scholar country is little, but its ornaments industry is measured with gold up to 40 tons or so, wherein 95% is used in watchmaking every year.A Japanese only hand
1 year consumption gold salt of Watch Factory is equivalent to 680 kilograms of gold of consumption just up to 1 ton.The purposes of gold is more and more wider, and consumption is also more next
It is bigger, thus cause countries in the world to the especially deeply concerned and keen interest of gold.
Soft gold is easily deformed, and is also easy to wear.Therefore, people begin to attempt to be added in proof gold a small amount of
Other alloying elements increase the hardness of gold, wherein silver, copper, zinc etc. are all that existing frequently-used be added in gold increases intensity
With the metal of toughness.It joined the gold of alloying element, that is, billon.Determine the position processed of gold content in billon in English
It is Karat, it can also abbreviation K by head word.Therefore, ornamental billon is also known as karat gold.The color of billon is with alloy
The selection of element is different and has very big change.When copper is added in gold, red gold is just formd;It joined silver, nickel or palladium are just
Form platinum.
K platinum is not the lower platinum of purity.That is, K platinum not platiniferous.Since platinum output is rare,
Expensive, in addition fusing point is high, thus general country seldom produces real K platinum with platinum.In general, select gold and palladium or
The Metal Meltings such as nickel, silver, copper, zinc are referred to as K platinum at a kind of white alloy, and by it.So K platinum is with gold and palladium
Or white alloy made of the Metal Meltings such as nickel, silver, copper, zinc.More precisely, K platinum should be known as the billon of white.?
In purity, rare degree, durability and natural color and gloss, white karat gold can not all be mentioned in the same breath with platinum.But due to tool
The standby value preserving of the white gloss and gold of platinum, K platinum after the advent of just obtained great market and welcome, and in world's model
The very big market sales volume is achieved in enclosing.
Due to having used nickel as element is brightened in K platinum, the jewellery allergic reaction as caused by nickel has become entire society
The problem of must all facing.For fashionable jewellery consumer, the nickel allergic constitution of itself becomes their bad dream.
Show that considerable part wears the jewellery that nickeliferous K platinum closes preparation and pain redness, blister disease easily occurs according to use both domestic and external
Shape.These people can also cause allergic reaction after contacting skin to coin, belt joint or even telephone set.Reason is that, these
Article contains nickel, the most common skin contact allergin in industrial production.Scientific the father-in-law has been obtained in international coverage
Recognize studies have shown that nickel can be attached in the special immune system protein matter of one kind, which participates in the harmful invasion of body identification
During substance.In the internal of impacted people, immune system can be nickel as a kind of infectious substance, when immune system is anti-
When answering too drastic, body just will appear a series of classical symptoms, such as it is scorching hot, itch, red and swollen, blister.That is, nickel source is attached to
After on bioprotein, a series of biochemical reaction will be caused.It can discharge some molecular signals, blood flow is caused to increase,
Tissue leakage, immunocyte pour in, and ultimately form infection.Although immune response is the act of self-defence of body, it is passed through
It is often accompanied by some side effects.
Thus, in jewellery industry, exploitation and industrialization it is a kind of with K platinum color without nickel billon have it is extremely existing
Real market significance.It can be by the thermodynamics and kinetics means of bottom to alloy material by advanced design of material technology
Material is innovated, and has very big market value to the solution and industrialization of the low-temperature brittle fracture problem of the red gold of 10K.In face of day
The domestic and international market competition for becoming fierce, it is necessary to which paces of accelerating restructuring, this is not only China's jewellery industry survival and development
Needs and world today's related fields development trend.Briefly, system is broken through by technological innovation and optimization design
About 18K platinum in China produces and uses development bottleneck.
Summary of the invention
The purpose of the present invention is to overcome the deficiency in the prior art, and providing a kind of no nickel will not be to the corrosion-resistant jewellery of skin allergy
With 18K platinum material.
To achieve the goals above, the present invention adopts the following technical scheme that：
A kind of no nickel will not be to the corrosion-resistant jewellery 18K platinum material of skin allergy.By weight percentage, the group of alloy becomes
Li:0.5-0.8wt.%,Ru:0.3-0.5wt.%,Os:0.2-0.4wt.%,Sn:6.0-8.0wt.%,In:10.0-12.0wt.%,
Ag:5.0-8.0wt.%, surplus are gold.
A kind of above-mentioned no nickel will not be to the corrosion-resistant jewellery 18K platinum material of skin allergy.Preparation method, including it is as follows
Step：As above the raw material matched is added in the electric induction furnace of argon gas protection, and uses graphite crucible;It is used after metal molten
The argon gas of low discharge is protected, and big air-flow is avoided to make the serious scaling loss of alloying element;10 minutes are kept the temperature at 1200 degree when melting, by height
Frequency induction furnace electromagnetic agitation is uniform;1 minute, which is kept the temperature, at 1200 degree after mixing evenly and is cast comes out of the stove;Billon casting uses diameter
The punching block of 50-100mm, and cooled down by the way of water cooling.Resulting ingot casting is rolled at room temperature, rolls lower amount per pass
For 30-40%;It is 380 degree per intermediate anneal temperature after rolling twice, keeps the temperature 0.5 hour;Finally by material be rolled into a thickness of
The golden plate of 10-20mm;It in jewellery forming process, needs to carry out intermediate annealing process, eliminates the stress in process;Its
In, homogenization temperature is 350 degree, and the time is 1-2 hours.
Compared with prior art, the present invention has the advantages that：
（1）In the billon manufacturing field of jewellery, frequent needing to add alloying elements and promoted due to process aspect
The performance of billon.Wherein, nickel is the metal of the increase jewellery brightness used for a long time, has been indispensable in K platinum
Composition.After nickel is added to billon, not only nickel itself has the characteristic of low price, it is also possible that billon finally has
Intensity is higher, and melting temperature is lower, the more preferable feature of mobility.Nickel is traditionally exactly the brightening agent of gold, in field of jewelry
People are generally acknowledged that when the ingredient of nickel is obtained with the alloy close to white in 9-12wt.%.But it is had in this alloy
Model casting is used, the reason is that nickel is also good hardening element.While increasing alloy rigidity, it is significantly reduced
Toughness.In addition, the addition of nickel is but also jewellery have the anaphylactogen to human allergy with K platinum.Groups of people have changed head in wearing
After decorations, it may appear that apparent allergic phenomena.In order to solve these problems, the market occupancy volume of K platinum is improved, this patent provides
A kind of not nickeliferous K platinum, and the material has excellent corrosion resistance.
（2）The material has and K platinum similarly white color and good physical property, cheap price, lower
Liquidus temperature, good mechanical and casting character and good bleaching effect.It is a kind of more satisfactory nickeliferous White gold
The substitute of alloy.As alloy content is in the variation of optimization range, the mechanical performance of the alloy can be carried out significantly
Adjustment.Meanwhile the alloy due to liquidus curve it is relatively low, 850 degree or so, thus be suitable for casting.The gold of present patent application protection
Alloy refines crystal grain.In addition, hot cracking tendency is big when the alloy can solve casting, casting cavity and loose obvious product
The technical problems such as yield rate is low.Smelting processing method is simple, and production cost is relatively low, reduces to equipment requirement.
（3）The aerial corrosion resistance of the alloy belongs to compared with stabilizing material, belongs to stable profile in weak acid, weak base sweat
Material, corrosion resistance is by being added the higher alloying element of thermodynamic stability.In corrosive environment, the protective film of passivation can be formed,
This film is in different media, since unpolarizing is as a result, to showing different corrosion resistances, to strong acid,
The corrosion resistance of strong basicity sweat is also more stable.Alloy corrosion rate under maritime environment is 1.410-4Mm/, thus
Being used in 10 under relevant environment using the jewellery of material preparation does not all have apparent corrosion phenomenon.It is contemplated that should
The implementation and industrialization of material obtain excellent economic benefit and social benefit after all.
Specific embodiment
Embodiment 1
A kind of no nickel will not be to the corrosion-resistant jewellery 18K platinum material of skin allergy.By weight percentage, the group of alloy becomes
Li:0.5wt.%,Ru:0.3wt.%,Os:0.2wt.%,Sn:6.0wt.%,In:10.0wt.%,Ag:5.0wt.%, surplus are gold.
A kind of above-mentioned no nickel will not include the following steps the preparation method of the corrosion-resistant jewellery 18K platinum material of skin allergy：It will be as
The raw material of upper proportion is added in the electric induction furnace of argon gas protection, and uses graphite crucible;Using low discharge after metal molten
Argon gas protection, avoids big air-flow from making the serious scaling loss of alloying element;10 minutes are kept the temperature at 1200 degree when melting, leans on Efco-Northrup furnace
Electromagnetic agitation is uniform;1 minute, which is kept the temperature, at 1200 degree after mixing evenly and is cast comes out of the stove;Billon casting uses diameter 50-100mm
Punching block, and cooled down by the way of water cooling.Resulting ingot casting is rolled at room temperature, rolling lower amount per pass is 30-
40%;It is 380 degree per intermediate anneal temperature after rolling twice, keeps the temperature 0.5 hour;Finally material is rolled into a thickness of 10-20mm
Golden plate;It in jewellery forming process, needs to carry out intermediate annealing process, eliminates the stress in process;Wherein, it homogenizes
Temperature is 350 degree, and the time is 1-2 hours.
The material has and K platinum similarly white color and good physical property, cheap price, lower liquid phase
Line temperature, good mechanical and casting character and good bleaching effect.It is a kind of more satisfactory nickeliferous white gold alloy
Substitute.As alloy content is in the variation of optimization range, the mechanical performance of the alloy can be adjusted significantly.
Meanwhile the alloy due to liquidus curve it is relatively low, 850 degree or so, thus be suitable for casting.The billon of present patent application protection makes
Crystal grain is refined.In addition, hot cracking tendency is big when the alloy can solve casting, casting cavity and loose obvious product yield rate
Low technical problem.Smelting processing method is simple, and production cost is relatively low, reduces to equipment requirement.The alloy is in air
Corrosion resistance belong to compared with stabilizing material, belong to stable type material in weak acid, weak base sweat, corrosion resistance is steady by thermodynamics is added
Qualitative higher alloying element.In corrosive environment, can be formed passivation protective film, this film in different media, due to
Unpolarizing as a result, to showing different corrosion resistances, it is also relatively steady to the corrosion resistance of strong acid, strong basicity sweat
It is fixed.Alloy corrosion rate under maritime environment is 1.410-4Mm/, thus using the jewellery of material preparation in phase
Using in 10 under cyclization border does not all have apparent corrosion phenomenon.
Embodiment 2
A kind of no nickel will not be to the corrosion-resistant jewellery 18K platinum material of skin allergy.By weight percentage, the group of alloy becomes
Li:0.8wt.%,Ru:0.5wt.%,Os:0.4wt.%,Sn:8.0wt.%,In:12.0wt.%,Ag:8.0wt.%, surplus are gold.
A kind of above-mentioned no nickel will not include the following steps the preparation method of the corrosion-resistant jewellery 18K platinum material of skin allergy：It will be as
The raw material of upper proportion is added in the electric induction furnace of argon gas protection, and uses graphite crucible;Using low discharge after metal molten
Argon gas protection, avoids big air-flow from making the serious scaling loss of alloying element;10 minutes are kept the temperature at 1200 degree when melting, leans on Efco-Northrup furnace
Electromagnetic agitation is uniform;1 minute, which is kept the temperature, at 1200 degree after mixing evenly and is cast comes out of the stove;Billon casting uses diameter 50-100mm
Punching block, and cooled down by the way of water cooling.Resulting ingot casting is rolled at room temperature, rolling lower amount per pass is 30-
40%;It is 380 degree per intermediate anneal temperature after rolling twice, keeps the temperature 0.5 hour;Finally material is rolled into a thickness of 10-20mm
Golden plate;It in jewellery forming process, needs to carry out intermediate annealing process, eliminates the stress in process;Wherein, it homogenizes
Temperature is 350 degree, and the time is 1-2 hours.
The material has and K platinum similarly white color and good physical property, cheap price, lower liquid phase
Line temperature, good mechanical and casting character and good bleaching effect.It is a kind of more satisfactory nickeliferous white gold alloy
Substitute.As alloy content is in the variation of optimization range, the mechanical performance of the alloy can be adjusted significantly.
Meanwhile the alloy due to liquidus curve it is relatively low, 850 degree or so, thus be suitable for casting.The billon of present patent application protection makes
Crystal grain is refined.In addition, hot cracking tendency is big when the alloy can solve casting, casting cavity and loose obvious product yield rate
Low technical problem.Smelting processing method is simple, and production cost is relatively low, reduces to equipment requirement.The alloy is in air
Corrosion resistance belong to compared with stabilizing material, belong to stable type material in weak acid, weak base sweat, corrosion resistance is steady by thermodynamics is added
Qualitative higher alloying element.In corrosive environment, can be formed passivation protective film, this film in different media, due to
Unpolarizing as a result, to showing different corrosion resistances, it is also relatively steady to the corrosion resistance of strong acid, strong basicity sweat
It is fixed.Alloy corrosion rate under maritime environment is 1.410-4Mm/, thus using the jewellery of material preparation in phase
Using in 10 under cyclization border does not all have apparent corrosion phenomenon.
Embodiment 3
A kind of no nickel will not be to the corrosion-resistant jewellery 18K platinum material of skin allergy.By weight percentage, the group of alloy becomes
Li:0.6wt.%,Ru:0.4wt.%,Os:0.3wt.%,Sn:6.5wt.%,In:11.0wt.%,Ag:6.0wt.%, surplus are gold.
A kind of above-mentioned no nickel will not include the following steps the preparation method of the corrosion-resistant jewellery 18K platinum material of skin allergy：It will be as
The raw material of upper proportion is added in the electric induction furnace of argon gas protection, and uses graphite crucible;Using low discharge after metal molten
Argon gas protection, avoids big air-flow from making the serious scaling loss of alloying element;10 minutes are kept the temperature at 1200 degree when melting, leans on Efco-Northrup furnace
Electromagnetic agitation is uniform;1 minute, which is kept the temperature, at 1200 degree after mixing evenly and is cast comes out of the stove;Billon casting uses diameter 50-100mm
Punching block, and cooled down by the way of water cooling.Resulting ingot casting is rolled at room temperature, rolling lower amount per pass is 30-
40%;It is 380 degree per intermediate anneal temperature after rolling twice, keeps the temperature 0.5 hour;Finally material is rolled into a thickness of 10-20mm
Golden plate;It in jewellery forming process, needs to carry out intermediate annealing process, eliminates the stress in process;Wherein, it homogenizes
Temperature is 350 degree, and the time is 1-2 hours.
The material has and K platinum similarly white color and good physical property, cheap price, lower liquid phase
Line temperature, good mechanical and casting character and good bleaching effect.It is a kind of more satisfactory nickeliferous white gold alloy
Substitute.As alloy content is in the variation of optimization range, the mechanical performance of the alloy can be adjusted significantly.
Meanwhile the alloy due to liquidus curve it is relatively low, 850 degree or so, thus be suitable for casting.The billon of present patent application protection makes
Crystal grain is refined.In addition, hot cracking tendency is big when the alloy can solve casting, casting cavity and loose obvious product yield rate
Low technical problem.Smelting processing method is simple, and production cost is relatively low, reduces to equipment requirement.The alloy is in air
Corrosion resistance belong to compared with stabilizing material, belong to stable type material in weak acid, weak base sweat, corrosion resistance is steady by thermodynamics is added
Qualitative higher alloying element.In corrosive environment, can be formed passivation protective film, this film in different media, due to
Unpolarizing as a result, to showing different corrosion resistances, it is also relatively steady to the corrosion resistance of strong acid, strong basicity sweat
It is fixed.Alloy corrosion rate under maritime environment is 1.410-4Mm/, thus using the jewellery of material preparation in phase
Using in 10 under cyclization border does not all have apparent corrosion phenomenon.
Claims (3)
1. a kind of no nickel will not be to the corrosion-resistant jewellery 18K platinum material of skin allergy；By weight percentage, the composition of alloy
For Li:0.5-0.8wt.%,Ru:0.3-0.5wt.%,Os:0.2-0.4wt.%,Sn:6.0-8.0wt.%,In:10.0-
12.0wt.%,Ag:5.0-8.0wt.%, surplus are gold.
2. a kind of no nickel described in claim 1 will not be to the corrosion-resistant jewellery 18K platinum material of skin allergy, it is characterised in that packet
Include following smelting step：As above the raw material matched is added in the electric induction furnace of argon gas protection, and uses graphite crucible;Metal
It is protected after fusing using the argon gas of low discharge, big air-flow is avoided to make the serious scaling loss of alloying element;It is kept the temperature when melting at 1200 degree
It is 10 minutes, uniform by Efco-Northrup furnace electromagnetic agitation;1 minute, which is kept the temperature, at 1200 degree after mixing evenly and is cast comes out of the stove;Billon
Casting uses the punching block of diameter 50-100mm, and is cooled down by the way of water cooling.
3. will not be to the corrosion-resistant jewellery 18K platinum material of skin allergy according to a kind of no nickel described in claim 1, it is characterised in that
Comprising using step as follows：Resulting ingot casting is rolled at room temperature, rolling lower amount per pass is 30-40%;It is every to roll twice
Intermediate anneal temperature is 380 degree afterwards, keeps the temperature 0.5 hour;Material is finally rolled into the golden plate with a thickness of 10-20mm;In jewellery
It in forming process, needs to carry out intermediate annealing process, eliminates the stress in process;Wherein, homogenization temperature is 350 degree,
Time is 1-2 hours.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810772790.3A CN108823456A (en) | 2018-07-14 | 2018-07-14 | A kind of no nickel will not be to the corrosion-resistant jewellery 18K platinum material of skin allergy |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810772790.3A CN108823456A (en) | 2018-07-14 | 2018-07-14 | A kind of no nickel will not be to the corrosion-resistant jewellery 18K platinum material of skin allergy |
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| Publication Number | Publication Date |
|---|---|
| CN108823456A true CN108823456A (en) | 2018-11-16 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810772790.3A Withdrawn CN108823456A (en) | 2018-07-14 | 2018-07-14 | A kind of no nickel will not be to the corrosion-resistant jewellery 18K platinum material of skin allergy |
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| Country | Link |
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| CN (1) | CN108823456A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109957676A (en) * | 2019-03-29 | 2019-07-02 | 深圳市龙嘉珠宝实业有限公司 | A kind of rigid pure gold, preparation method and a kind of jewellery |
| CN112176215A (en) * | 2020-10-15 | 2021-01-05 | 深圳市宝瑞莱珠宝首饰有限公司 | Corrosion-resistant 18K gold for jewelry and process thereof |
-
2018
- 2018-07-14 CN CN201810772790.3A patent/CN108823456A/en not_active Withdrawn
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109957676A (en) * | 2019-03-29 | 2019-07-02 | 深圳市龙嘉珠宝实业有限公司 | A kind of rigid pure gold, preparation method and a kind of jewellery |
| CN112176215A (en) * | 2020-10-15 | 2021-01-05 | 深圳市宝瑞莱珠宝首饰有限公司 | Corrosion-resistant 18K gold for jewelry and process thereof |
| CN112176215B (en) * | 2020-10-15 | 2022-01-11 | 深圳市宝瑞莱珠宝首饰有限公司 | Corrosion-resistant 18K gold for jewelry and process thereof |
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Application publication date: 20181116 |