CN108822674A - Automobile-used aqueous assorted metal flash paint of a kind of three-wheel and preparation method thereof - Google Patents
Automobile-used aqueous assorted metal flash paint of a kind of three-wheel and preparation method thereof Download PDFInfo
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- CN108822674A CN108822674A CN201810291853.3A CN201810291853A CN108822674A CN 108822674 A CN108822674 A CN 108822674A CN 201810291853 A CN201810291853 A CN 201810291853A CN 108822674 A CN108822674 A CN 108822674A
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- 239000003973 paint Substances 0.000 title claims abstract description 41
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 26
- 239000002184 metal Substances 0.000 title claims abstract description 26
- 238000002360 preparation method Methods 0.000 title claims abstract description 11
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 31
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 29
- 239000002966 varnish Substances 0.000 claims abstract description 25
- 239000004925 Acrylic resin Substances 0.000 claims abstract description 19
- 229920000178 Acrylic resin Polymers 0.000 claims abstract description 19
- 239000002518 antifoaming agent Substances 0.000 claims abstract description 19
- 229920000728 polyester Polymers 0.000 claims abstract description 19
- 229920003180 amino resin Polymers 0.000 claims abstract description 16
- 239000008367 deionised water Substances 0.000 claims abstract description 15
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 15
- 239000003002 pH adjusting agent Substances 0.000 claims abstract description 15
- 239000000080 wetting agent Substances 0.000 claims abstract description 15
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000006184 cosolvent Substances 0.000 claims abstract description 13
- 239000002270 dispersing agent Substances 0.000 claims abstract description 13
- 125000001841 imino group Chemical group [H]N=* 0.000 claims abstract description 10
- 239000002994 raw material Substances 0.000 claims description 16
- 239000003086 colorant Substances 0.000 claims description 8
- 239000006185 dispersion Substances 0.000 claims description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 4
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 4
- 239000002002 slurry Substances 0.000 claims description 4
- 239000000126 substance Substances 0.000 claims description 4
- -1 Phosphoric acid lipid Chemical class 0.000 claims description 3
- 239000006260 foam Substances 0.000 claims description 3
- IDQBJILTOGBZCR-UHFFFAOYSA-N 1-butoxypropan-1-ol Chemical compound CCCCOC(O)CC IDQBJILTOGBZCR-UHFFFAOYSA-N 0.000 claims description 2
- UEEJHVSXFDXPFK-UHFFFAOYSA-N N-dimethylaminoethanol Chemical compound CN(C)CCO UEEJHVSXFDXPFK-UHFFFAOYSA-N 0.000 claims description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 2
- 229920001577 copolymer Polymers 0.000 claims description 2
- 229960002887 deanol Drugs 0.000 claims description 2
- 239000012972 dimethylethanolamine Substances 0.000 claims description 2
- 235000019441 ethanol Nutrition 0.000 claims description 2
- 239000003112 inhibitor Substances 0.000 claims description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N phosphoric acid Substances OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 2
- 239000000758 substrate Substances 0.000 claims description 2
- 238000000576 coating method Methods 0.000 description 14
- 239000011248 coating agent Substances 0.000 description 13
- 239000012855 volatile organic compound Substances 0.000 description 9
- 230000000694 effects Effects 0.000 description 8
- 238000004519 manufacturing process Methods 0.000 description 7
- 229920005989 resin Polymers 0.000 description 6
- 239000011347 resin Substances 0.000 description 6
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
- 239000006115 industrial coating Substances 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 3
- 239000000853 adhesive Substances 0.000 description 3
- 230000001070 adhesive effect Effects 0.000 description 3
- 239000012752 auxiliary agent Substances 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 239000000049 pigment Substances 0.000 description 3
- 238000006116 polymerization reaction Methods 0.000 description 3
- 229920006337 unsaturated polyester resin Polymers 0.000 description 3
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 description 2
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 238000012946 outsourcing Methods 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 229920005862 polyol Polymers 0.000 description 2
- 150000003077 polyols Chemical class 0.000 description 2
- 230000036632 reaction speed Effects 0.000 description 2
- 229910052709 silver Inorganic materials 0.000 description 2
- 239000004332 silver Substances 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- 244000025254 Cannabis sativa Species 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- IPGANOYOHAODGA-UHFFFAOYSA-N dilithium;dimagnesium;dioxido(oxo)silane Chemical compound [Li+].[Li+].[Mg+2].[Mg+2].[O-][Si]([O-])=O.[O-][Si]([O-])=O.[O-][Si]([O-])=O IPGANOYOHAODGA-UHFFFAOYSA-N 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000007667 floating Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 235000003642 hunger Nutrition 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 238000007665 sagging Methods 0.000 description 1
- 229910052594 sapphire Inorganic materials 0.000 description 1
- 239000010980 sapphire Substances 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000007592 spray painting technique Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D151/00—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
- C09D151/08—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D17/00—Pigment pastes, e.g. for mixing in paints
- C09D17/001—Pigment pastes, e.g. for mixing in paints in aqueous medium
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/38—Paints containing free metal not provided for above in groups C09D5/00 - C09D5/36
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/20—Diluents or solvents
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/45—Anti-settling agents
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
- C08K2003/0806—Silver
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Paints Or Removers (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Abstract
The invention discloses a kind of automobile-used aqueous assorted metal flash paint of three-wheel, the component including following parts by weight：Basic varnish 64.2-93 parts, 4-7 parts of aqueous coated silver powder, 2-5 parts of cosolvent, 0.1-0.3 parts of dispersing agent, aqueous assorted mill base 5-15 parts of self-control；Basic varnish, the component including following parts by weight：Waterborne polyester is 30-40 parts acrylic resin modified, 1.5-2.5 parts of pH adjusting agent, 0.3-0.5 parts of defoaming agent, 3-5 parts of coalescing agent, 0.2-0.5 parts of wetting agent, 0.2-0.5 parts of levelling agent, CAB 1-2 parts aqueous, 20-30 parts of deionized water, 8-12 parts of high imino group Amino resin.The preparation method of the automobile-used aqueous assorted metal flash paint of three-wheel is also disclosed in the present invention.The automobile-used aqueous assorted metal flash paint organic volatile of three-wheel of the invention is low, workability is excellent, metal sense is strong, overall cost is relatively low.
Description
Technical field
The present invention relates to the automobile-used aqueous assorted metal flash paints of technical field of coatings more particularly to a kind of three-wheel.
Background technique
Overwhelming majority tricycle manufacturing enterprise is mainly using being solvent type industrial coating at present.With people to environment and
The pay attention to day by day of health, water paint have been more and more widely used, and traditional solvent type coating is being produced and used
The pollution that the volatile organic substance (VolatileOrganic Compounds, VOC) discharged in journey generates, becomes at present
The city primary pollution source after vehicle exhaust is come, constantly improve and perfect with Environmental Protection in China laws and regulations is mandatory
Have become trend of the times using environment-friendly type industrial coating.And prior development direction of the aqueous industrial coating as environment-friendly type coating
One of, the application in tricycle industry has boundless market.But there are silver powder azimuth zerosets, attached for traditional water paint
Put forth effort poor, application property not as good as oil paint, product stability is poor and production process is complicated the disadvantages of.For the environmental protection act of response country
And the Policy Conditions of energy-saving and emission-reduction develop a low VOC for the coating specification of electro-tricycle
(99999VOC) discharge, the aqueous industrial coating that silver powder directional, adhesive force is good, workability is excellent are significant.
There are the following problems for the existing automobile-used metallized coating of three-wheel：
For the existing automobile-used metallized coating of three-wheel based on solvent type, it is high to need to solve to paint VOC content, it is seriously polluted and
The problem of fire hazard；Gloss, the metal-like of existing water paint product have a certain gap compared with solvent based product, cause
Decorative effect is poor；The application property of existing water paint product does not have traditional oily paint application property good, and live Spray Painter is caused to contradict the heart
Reason is than more serious；Existing water paint production toning process uses outsourcing mill base, compatibility and product stability with system
It is poor, and product cost is higher.
Summary of the invention
In order to overcome the disadvantages of the above prior art, the present invention provides a kind of low VOC (VOC) discharges, construction
It has excellent performance, the automobile-used aqueous assorted metal flash paint of metal sense is strong, overall cost is relatively low three-wheel and preparation method thereof.
In order to solve the above technical problems, the present invention adopts the following technical scheme that：
A kind of automobile-used aqueous assorted metal flash paint of three-wheel, the component including following parts by weight：
Basic varnish 64.2-93 parts, 4-7 parts of aqueous coated silver powder, 2-5 parts of cosolvent, 0.1-0.3 parts of dispersing agent, water
Property colors make by oneself mill base 5-15 parts；
Basic varnish, the component including following parts by weight：
Waterborne polyester is 30-40 parts acrylic resin modified, 1.5-2.5 parts of pH adjusting agent, 0.3-0.5 parts of defoaming agent, forms a film
It is 3-5 parts of auxiliary agent, 0.2-0.5 parts of wetting agent, 0.2-0.5 parts of levelling agent, CAB 1-2 parts aqueous, 20-30 parts of deionized water, Gao Ya
8-12 parts of amino Amino resin.
Preferably, the component including following parts by weight：
78.6 parts of basic varnish, 5.5 parts of aqueous coated silver powder, 3.5 parts of cosolvent, 0.2 part of dispersing agent, aqueous colors are certainly
10 parts of mill base processed；
Basic varnish, the component including following parts by weight：
Waterborne polyester is 35 parts acrylic resin modified, 2 parts of pH adjusting agent, 0.4 part of defoaming agent, 4 parts of coalescing agent, wetting agent
0.35 part, 0.35 part of levelling agent, 1.5 parts of aqueous CAB, 25 parts of deionized water, 10 parts of high imino group Amino resin.
Preferably, the acrylic resin modified AC-8200 for the auspicious chemical industry of Shanghai timely rain of the waterborne polyester, using phthalic anhydride and
Cis-butenedioic anhydride and polyol reaction are made unsaturated polyester resin, then with acrylic monomers, styrene polymerization, by unsaturated polyester resin
Hydroxyl is provided, coating richness is good, gloss is high, adhesive force is strong, silver powder directional effect is good.
Preferably, the pH adjusting agent is dimethylethanolamine.
Preferably, the defoaming agent be phosphoric acid lipid hydrophobicity defoam foam inhibitor, as MOUSSEX company 941PL (
Aqueous body coating system, a small amount of addition will not influence paint film appearance, and have good defoaming foam inhibition effect), organic silicon
Defoaming agent, such as defoaming of (BIC Corp) BYK act on auxiliary agent B YK-028 or BYK024, and two types defoaming agent is used in mixed way, than
Example is 1:1 or so.
Preferably, the coalescing agent is the one or more of isopropanol, propandiol butyl ether, ethyl alcohol.
Preferably, the substrate wetting agents are the wetting agent of Siloxane-Oxyalkylene Copolymers class, such as (Digao) TEGO
One or both of the AFCONA-3031 of Tego-100, (angstrom husband's Kona) AFCONA.Two kinds of auxiliary agents can play increasing and slide
Agent, the effect of levelling agent reach paint film and seem more plentiful.
Preferably, wherein aqueous assorted self-control mill base, mainly includes the component of following mass fraction：
Waterborne polyester is 10-15 parts acrylic resin modified, 0.5-0.8 parts of pH adjusting agent, 0.3-0.5 parts of defoaming agent, dispersion
5-10 parts of agent, assorted toner 30-50 parts, 0.5-1 parts of anti-settling agent, 3-5 parts of cosolvent, 20-30 parts of deionized water.
Waterborne polyester in preferred aqueous assorted self-control mill base is acrylic resin modified automobile-used aqueous each with above-mentioned three-wheel
Resin in the basic varnish components of non-ferrous metal flash of light is identical, participates in grinding using portion body resin and makes assorted mill base, can
To improve wetability and good dispersibility to pigment particles, pigment particles are wrapped between molecular resin well, are mentioned
The extended storage stability of high colour paste system；Simultaneously because using identical with the varnish components of aqueous assorted flash metal luster basis
Matrix resin makes mill base, and the compatibility between assorted mill base and basic varnish can be improved, reduce and produce in mill base addition system
The problem of raw mill base is returned slightly and is flocculated.
Preferably, the dispersing agent is EFKA4585, it is the water soluble acrylic acid using the polymerization of controllable free-radical technology
Block copolymer type dispersing agent has efficient pigment dispersion stability, and has good compatibility with various water-based systems.
Preferably, the anti-settling agent isW2N, it is artificial synthesized lithium magnesium silicate, is that one kind is used for
The inorganic rheological agent of water paint can make aqueous coating system obtain stronger pseudoplastic fluid dynamic characteristic, can make coating system
There is higher viscosity under low sheraing effect, so anti-settling, anti-sag, shelf stability and dewatering shrinkage are all under control.
A kind of preparation method of the automobile-used aqueous assorted metal flash paint of three-wheel, includes the following steps：
1., the preparation of basic varnish：
Step a：Stock pot is added according to raw material proportioning that waterborne polyester is acrylic resin modified, PH regulator, cosolvent
In, revolving speed 300-600r/min disperses 5-10 minutes；
Step b：Deionized water, defoaming agent, wetting agent, levelling agent are sequentially added according to raw material proportioning, revolving speed 600-
800r/min disperses 10-20 minutes；
Step c：High imino group Amino resin, aqueous CAB are sequentially added according to raw material proportioning, revolving speed 800-
1000r/min disperses 10-15 minutes, and basis varnish is made；
2., the preparation of aqueous assorted self-control mill base：
Step a：According to raw material proportioning, stock pot is added in waterborne polyester is acrylic resin modified, pH adjusting agent, cosolvent
In, revolving speed 300-600r/min disperses 5-10 minutes；
Step b：Deionized water, defoaming agent, dispersing agent are sequentially added according to raw material proportioning, revolving speed 600-800r/min points
It dissipates 10-20 minutes；
Step c：Toner, anti-settling agent are slowly added to according to raw material proportioning, revolving speed 1000-1200r/min disperses 10-20 points
Clock；
Step d：By stock obtained slurry fineness of grind to 5 μm hereinafter, placing spare to get to aqueous self-control colors color
Slurry；
3., the modulation of the automobile-used aqueous assorted metal flash paint of three-wheel：
Step a：Aqueous coated silver powder, cosolvent and dispersing agent are added in paint pot according to raw material proportioning, stirring is equal
It is even, static soak 30-60 minutes；
Step b：Basic varnish is added in the paint pot of step a according to raw material proportioning, revolving speed 600-800r/min dispersion
10-15 minutes；
Step c：It mixes colours according to template, is separately added into required aqueous assorted self-control mill base；
Step d：After coloration compliance, it is filtered and is packed with 100 mesh filter clothes.
The selected acrylic resin modified AC-8200 for the auspicious chemical industry of Shanghai timely rain of waterborne polyester, the resin in the present invention
Unsaturated polyester resin is made using phthalic anhydride and cis-butenedioic anhydride and polyol reaction, then with acrylic monomers, styrene polymerization, by insatiable hunger
Hydroxyl is provided with polyester resin, coating richness is good, gloss is high, adhesive force is strong, silver powder directional effect is good, the water paint of preparation
VOC≤40g/L, smell is very low, prevents pollution environment.The amino resins of selection is that part Amino resin compounds full first
Etherified amino resins, will slowly compared to reaction speed for the Amino resin of part is used alone, and baking temperature is suitable；And
Compared to being used alone, reaction speed for full Amino resin is fast, and reaction temperature compares full methyl-etherified amino tree
It wants low for rouge, can also improve the flexibility and shock resistance of whole paint film with energy saving, be highly suitable for more
The mostly roasting high-temperature baking amino-stoving varnish system of Tu.Mill base is using self-control mill base, compared to can both reduce production for outsourcing mill base
The overall cost of product improves product competition advantage；Can be improved the compatibility of mill base and base paint again, promoted product stability and
Quality；
Compared with prior art, advantageous effects of the invention：
1, select water-based system make high-temperature baking metallized coating, using water as diluent, low-carbon environment-friendly, it is non-ignitable not
It is quick-fried, prevent coating and uses security risk；
2, water-borne dispersions system is selected, coating VOC content≤120g/L itself, smell is very low, than existing water solubility
Resin system is more environmentally-friendly；
3, gloss of film and metal-like can compare favourably with oil paint, and decorative effect is strong；
4, application property is excellent, and spraying paint film is not easy sagging and floating, and spray painting worker is easily accepted by；
5, production method is by the way of basic varnish+appropriate silver powder+colors self-control mill base, and production efficiency is fast, and product is raw
Finished product sheet is low.
Specific embodiment
The beneficial effect that embodiment provides in order to better illustrate the present invention, is illustrated below by embodiment is further
Explanation.
Now the proportion of embodiment 1-4 is listed as follows：
1 embodiment 1-4 each component content of table
Wherein：
Basic varnish includes in embodiment 1：Waterborne polyester is 37 parts acrylic resin modified, 2 parts of pH adjusting agent, defoaming agent
0.4 part, 4 parts of coalescing agent, 0.3 part of wetting agent, 0.3 part of levelling agent, 1 part of aqueous CAB, 27 parts of deionized water, high imino group first
10 parts of etherified amino resins；
Basic varnish includes in embodiment 2：Waterborne polyester is 38 parts acrylic resin modified, 2 parts of pH adjusting agent, defoaming agent
0.4 part, 4 parts of coalescing agent, 0.3 part of wetting agent, 0.3 part of levelling agent, 1 part of aqueous CAB, 28 parts of deionized water, high imino group first
11 parts of etherified amino resins；
Basic varnish includes in embodiment 3：Waterborne polyester is 37 parts acrylic resin modified, 2 parts of pH adjusting agent, defoaming agent
0.3 part, 3.8 parts of coalescing agent, 0.4 part of wetting agent, 0.3 part of levelling agent, 1 part of aqueous CAB, 28 parts of deionized water, high imino group
12 parts of Amino resin.
Basic varnish includes in embodiment 4：Waterborne polyester is 37 parts acrylic resin modified, 2 parts of pH adjusting agent, defoaming agent
0.4 part, 4 parts of coalescing agent, 0.4 part of wetting agent, 0.5 part of levelling agent, 1.5 parts of aqueous CAB, 27 parts of deionized water, high imino group
10 parts of Amino resin.
Embodiment 1 is the dedicated finishing coat of aqueous tricycle (it is blue to dodge silver-colored ice), and embodiment 2 is the dedicated finishing coat of aqueous tricycle (soil
Bold and unconstrained gold), embodiment 3 is the dedicated finishing coat of aqueous tricycle (it is sapphire blue to dodge silver), and embodiment 4 is that the dedicated finishing coat of aqueous tricycle (dodges
Silver is grass green).
The aqueous dedicated finishing coat testing result of tricycle provided by 1-4 of the embodiment of the present invention is as shown in table 2.
2 embodiment 1-4 performance test results of table
The automobile-used aqueous assorted metal flash paint of three-wheel provided by the invention, organic volatile (VOC) discharge low, workability
It is excellent, metal sense is strong, overall cost is relatively low, production method is convenient and efficient.
Embodiment described above is only that preferred embodiment of the invention is described, and is not carried out to the scope of the present invention
It limits, without departing from the spirit of the design of the present invention, those of ordinary skill in the art make technical solution of the present invention
Various changes and improvements, should all fall into claims of the present invention determine protection scope in.
Claims (9)
1. a kind of automobile-used aqueous assorted metal flash paint of three-wheel, which is characterized in that the component including following parts by weight：
Basic varnish 64.2-93 parts, 4-7 parts of aqueous coated silver powder is 2-5 parts of cosolvent, 0.1-0.3 parts of dispersing agent, aqueous each
Color makes mill base 5-15 parts by oneself；
Basic varnish, the component including following parts by weight：
Waterborne polyester is 30-40 parts acrylic resin modified, 1.5-2.5 parts of pH adjusting agent, 0.3-0.5 parts of defoaming agent, coalescing agent
3-5 parts, it is 0.2-0.5 parts of wetting agent, 0.2-0.5 parts of levelling agent, CAB 1-2 parts aqueous, 20-30 parts of deionized water, high imino group
8-12 parts of Amino resin.
2. the automobile-used aqueous assorted metal flash paint of three-wheel according to claim 1, which is characterized in that including following parts by weight
Several components：
78.6 parts of basic varnish, 5.5 parts of aqueous coated silver powder, 3.5 parts of cosolvent, 0.2 part of dispersing agent, aqueous assorted self-control color
10 parts of slurry；
Basic varnish, the component including following parts by weight：
Waterborne polyester is 35 parts acrylic resin modified, 2 parts of pH adjusting agent, 0.4 part of defoaming agent, 4 parts of coalescing agent, wetting agent 0.35
Part, 0.35 part of levelling agent, 1.5 parts of aqueous CAB, 25 parts of deionized water, 10 parts of high imino group Amino resin.
3. the automobile-used aqueous assorted metal flash paint of three-wheel according to claim 1, which is characterized in that the waterborne polyester
The acrylic resin modified AC-8200 for the auspicious chemical industry of Shanghai timely rain.
4. the automobile-used aqueous assorted metal flash paint of three-wheel according to claim 1, which is characterized in that the pH adjusting agent
For dimethylethanolamine.
5. the automobile-used aqueous assorted metal flash paint of three-wheel according to claim 1, which is characterized in that the defoaming agent is
Phosphoric acid lipid hydrophobicity defoams foam inhibitor, and the substrate wetting agents are the wetting agent of Siloxane-Oxyalkylene Copolymers class.
6. the automobile-used aqueous assorted metal flash paint of three-wheel according to claim 1, which is characterized in that the coalescing agent
For the one or more of isopropanol, propandiol butyl ether, ethyl alcohol.
7. the automobile-used aqueous assorted metal flash paint of three-wheel according to claim 1, which is characterized in that the aqueous colors are certainly
Mill base processed, the component including following parts by weight：
Waterborne polyester is 10-15 parts acrylic resin modified, 0.5-0.8 parts of pH adjusting agent, 0.3-0.5 parts of defoaming agent, dispersing agent 5-
10 parts, assorted toner 30-50 parts, 0.5-1 parts of anti-settling agent, 3-5 parts of cosolvent, 20-30 parts of deionized water.
8. the automobile-used aqueous assorted metal flash paint of three-wheel according to claim 7, which is characterized in that the dispersing agent is
EFKA4585, the anti-settling agent areW2N。
9. a kind of preparation method of the automobile-used aqueous assorted metal flash paint of three-wheel, which is characterized in that include the following steps：
1., the preparation of basic varnish：
Step a：According to raw material proportioning that waterborne polyester is acrylic resin modified, PH regulator, cosolvent are added in stock pot, turn
Fast 300-600r/min disperses 5-10 minutes；
Step b：Deionized water, defoaming agent, wetting agent, levelling agent are sequentially added according to raw material proportioning, revolving speed 600-800r/
Min disperses 10-20 minutes；
Step c：High imino group Amino resin, aqueous CAB are sequentially added according to raw material proportioning, revolving speed 800-1000r/
Min disperses 10-15 minutes, and basis varnish is made；
2., the preparation of aqueous assorted self-control mill base：
Step a：According to raw material proportioning, waterborne polyester is acrylic resin modified, pH adjusting agent, cosolvent are added in stock pot, are turned
Fast 300-600r/min disperses 5-10 minutes；
Step b：Deionized water, defoaming agent, dispersing agent are sequentially added according to raw material proportioning, revolving speed 600-800r/min dispersion
10-20 minutes；
Step c：Toner, anti-settling agent are slowly added to according to raw material proportioning, revolving speed 1000-1200r/min disperses 10-20 minutes；
Step d：By stock obtained slurry fineness of grind to 5 μm hereinafter, placing spare to get to aqueous self-control colors mill base；
3., the modulation of the automobile-used aqueous assorted metal flash paint of three-wheel：
Step a：Aqueous coated silver powder, cosolvent and dispersing agent are added in paint pot according to raw material proportioning, stirred evenly, it is quiet
Only impregnate 30-60 minutes；
Step b：Basic varnish is added in the paint pot of step a according to raw material proportioning, revolving speed 600-800r/min disperses 10-15
Minute；
Step c：It mixes colours according to template, is separately added into required aqueous assorted self-control mill base；
Step d：After coloration compliance, it is filtered and is packed with 100 mesh filter clothes.
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104789082A (en) * | 2015-04-28 | 2015-07-22 | 廊坊立邦涂料有限公司 | High-temperature-resistant amino baking varnish and preparation method thereof |
| CN106883715A (en) * | 2017-02-16 | 2017-06-23 | 河北晨阳工贸集团有限公司 | Truck hub water aluminum powder paint and preparation method thereof |
| CN107057511A (en) * | 2017-01-06 | 2017-08-18 | 河北晨阳工贸集团有限公司 | A kind of water-based silver powder amino-stoving varnish and preparation method thereof |
| CN107325661A (en) * | 2017-07-05 | 2017-11-07 | 河北晨阳工贸集团有限公司 | A kind of shared bicycle is with exempting from Lacquer finish high-temperature baking finish paint and preparation method thereof |
-
2018
- 2018-04-03 CN CN201810291853.3A patent/CN108822674A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104789082A (en) * | 2015-04-28 | 2015-07-22 | 廊坊立邦涂料有限公司 | High-temperature-resistant amino baking varnish and preparation method thereof |
| CN107057511A (en) * | 2017-01-06 | 2017-08-18 | 河北晨阳工贸集团有限公司 | A kind of water-based silver powder amino-stoving varnish and preparation method thereof |
| CN106883715A (en) * | 2017-02-16 | 2017-06-23 | 河北晨阳工贸集团有限公司 | Truck hub water aluminum powder paint and preparation method thereof |
| CN107325661A (en) * | 2017-07-05 | 2017-11-07 | 河北晨阳工贸集团有限公司 | A kind of shared bicycle is with exempting from Lacquer finish high-temperature baking finish paint and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 杨成德主编: "《涂料开发与试验》", vol. 1, 科学技术文献出版社, pages: 150 * |
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| CN109705712A (en) * | 2018-12-20 | 2019-05-03 | 丹东安邦涂料有限公司 | A kind of preparation method of aqueous wheel hub aluminium paint |
| CN110016259A (en) * | 2019-04-25 | 2019-07-16 | 河北晨阳工贸集团有限公司 | Aqueous industrial coating functionality mill base and preparation method thereof |
| CN111019442B (en) * | 2019-12-27 | 2022-06-28 | 立邦工业涂料(上海)有限公司 | High-concentration universal color paste and preparation method and application thereof |
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| CN115895358A (en) * | 2021-12-10 | 2023-04-04 | 江苏科祥防腐材料有限公司 | Water-based surface layer material for electric tricycle and preparation method thereof |
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