CN108821620A - The continuous producing apparatus of free water rotating crystal method production high strength gypsum - Google Patents
The continuous producing apparatus of free water rotating crystal method production high strength gypsum Download PDFInfo
- Publication number
- CN108821620A CN108821620A CN201810967403.1A CN201810967403A CN108821620A CN 108821620 A CN108821620 A CN 108821620A CN 201810967403 A CN201810967403 A CN 201810967403A CN 108821620 A CN108821620 A CN 108821620A
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- China
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- high strength
- tank
- producing apparatus
- strength gypsum
- collet
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229910052602 gypsum Inorganic materials 0.000 title claims abstract description 57
- 239000010440 gypsum Substances 0.000 title claims abstract description 56
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 28
- 238000000034 method Methods 0.000 title claims abstract description 26
- 239000013078 crystal Substances 0.000 title claims abstract description 25
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 23
- 239000000463 material Substances 0.000 claims abstract description 23
- 239000002002 slurry Substances 0.000 claims abstract description 22
- 238000001035 drying Methods 0.000 claims abstract description 11
- 238000000605 extraction Methods 0.000 claims abstract description 10
- 238000007599 discharging Methods 0.000 claims abstract description 7
- 238000003860 storage Methods 0.000 claims abstract description 6
- 238000011049 filling Methods 0.000 claims abstract description 4
- 239000002828 fuel tank Substances 0.000 claims abstract description 4
- 239000007921 spray Substances 0.000 claims abstract description 4
- 239000000203 mixture Substances 0.000 claims description 4
- 238000003756 stirring Methods 0.000 claims description 4
- 229920002472 Starch Polymers 0.000 claims 1
- 235000019698 starch Nutrition 0.000 claims 1
- 238000010924 continuous production Methods 0.000 abstract description 8
- 239000010865 sewage Substances 0.000 abstract description 5
- 230000008901 benefit Effects 0.000 abstract description 4
- 238000004134 energy conservation Methods 0.000 abstract description 3
- 239000000126 substance Substances 0.000 description 8
- 238000010438 heat treatment Methods 0.000 description 7
- 238000002156 mixing Methods 0.000 description 6
- 239000003607 modifier Substances 0.000 description 5
- 239000007791 liquid phase Substances 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 229920002545 silicone oil Polymers 0.000 description 4
- 238000001694 spray drying Methods 0.000 description 4
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- 239000003546 flue gas Substances 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- PASHVRUKOFIRIK-UHFFFAOYSA-L calcium sulfate dihydrate Chemical group O.O.[Ca+2].[O-]S([O-])(=O)=O PASHVRUKOFIRIK-UHFFFAOYSA-L 0.000 description 2
- 239000006071 cream Substances 0.000 description 2
- 238000002425 crystallisation Methods 0.000 description 2
- 230000008025 crystallization Effects 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 150000004683 dihydrates Chemical class 0.000 description 2
- 239000000428 dust Substances 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- 239000004575 stone Substances 0.000 description 2
- 239000005662 Paraffin oil Substances 0.000 description 1
- 230000003698 anagen phase Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000006477 desulfuration reaction Methods 0.000 description 1
- 230000023556 desulfurization Effects 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 238000011031 large-scale manufacturing process Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B11/00—Calcium sulfate cements
- C04B11/26—Calcium sulfate cements strating from chemical gypsum; starting from phosphogypsum or from waste, e.g. purification products of smoke
- C04B11/262—Calcium sulfate cements strating from chemical gypsum; starting from phosphogypsum or from waste, e.g. purification products of smoke waste gypsum other than phosphogypsum
- C04B11/264—Gypsum from the desulfurisation of flue gases
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
Abstract
The invention belongs to the technical fields of high strength gypsum production, specifically disclose a kind of continuous producing apparatus of free water rotating crystal method production high strength gypsum, the continuous producing apparatus includes slurry can and turn brilliant drying device, turning brilliant drying device includes the tank body that side is provided with collet, oil expansion tank is connected with above collet, oil expansion tank is connected by overflow pipe and oil filling pipe with storage fuel tank, conveying coil pipe is provided in collet, slurry can is connected by feed pump with the feed inlet of conveying coil pipe, the discharge port of conveying coil pipe is connected with the fog-spray nozzle for being set to tank body internal upper part, top of the tank air outlet is provided with dust-extraction unit, tank base is provided with material outlet and discharging device, wind stopping device is provided at material outlet.Using production equipment of the invention, it can be achieved that the continuous production of high strength gypsum, has energy conservation, advantage at low cost, the production equipment occupied area is small, and high-efficient, yield is high, while not having sewage handling problem.
Description
Technical field
The invention belongs to the technical fields of high strength gypsum production, and in particular, to a kind of free water rotating crystal method production is high-strength
The continuous producing apparatus of gypsum.
Background technique
As country is to power environment protection, especially raising of the reduction sulfur dioxide to atmosphere pollution attention degree, China's fire
Means of flue gas desulfurization of power plant transformation enters the fast growth phase.Thereby produce a large amount of desulfurized gesso of flue gas.Present China every year there are about
8000000 tons of desulfurized gesso of flue gas outputs, if desulfurizer is all installed by whole thermal power plant of China, desulfurized gypsum yield will increase severely super
Cross 40,000,000 tons.A large amount of desulfurized gypsums face the predicament stacked, filled due to that can not dissolve, and affect ecological environment and electricity
Factory's safe operation.Comprehensive utilization of resources to desulfurized gypsum is a problem in the urgent need to address.
The main component of desulfurized gypsum is calcium sulphate dihydrate(CaSO4·2H2O), desulfurized gypsum, which is produced as building gypsum, is
One of important use of desulfurized gypsum, i.e. desulfurized gypsum are cleaned, are homogenized, after removal of impurities, and under different crystallization conditions, tool can be made
There are the β type gypsum and α type gypsum of higher-value.Wherein, there are mainly two types of the production technologies of alpha type high-strength gypsum, first is that blocky steam
Press it is steam-cured, first is that liquid phase method produce.
Steam-cured blocky steam pressure is that the certain crystal modifier solution of dihydrate gypsum raw material and gypsum weight ratio is sent into mixing apparatus
In, it is uniformly mixed and is directly loadable into the preferable accumulator of permeability, which is sent into and turns brilliant device equipment, is set to crystalline substance is turned
It is passed through saturated steam in standby, turn brilliant equipment keeps dihydrate gypsum complete under the conditions of saturated steam medium is with temperature in heat-insulation pressure keeping
At crystalline substance is turned, the mixed type crystal that there is the polymorphic based on column crystal size class to match is formed, the material for completing to turn brilliant goes out to turn
It is sent into drying equipment after brilliant equipment and dries attachment removal water, and obtains α high strength gypsum after grinding, the blocky steam-cured method of steam pressure is simple, benefit
In large-scale production, the scale that cost, apparatus adaptability are wide, process is simple, realize technique, raising production efficiency can be reduced.
But product performance index is unstable, fluctuation is larger, thus needs to carry out final products adequately mixing and mixing, to guarantee
The consistency of properties of product.
Producing alpha gypsum powder by liquid phase method is the land plaster by raw gypsum crushing grinding at fineness in certain granules distribution, so
Blend together certain density Gypsum slurry, and heat temperature raising with water in blending tank afterwards, the Gypsum slurry after being mixed through shurry pump into
Enter to turn in brilliant device, is crystallized for the first time under the action of 90-150 DEG C of temperature, pressure 0.3-0.5MPa and crystal modifier, generate α stone
Cream slurry.The α gypsum slurry of generation enters through stock pump again in another turn of brilliant device, in 110-150 DEG C of temperature, pressure 0.3-0.4MPa
With secondary crystallization is carried out under the action of crystal modifier, 100% α gypsum slurry can be generated.It separated in α gypsum slurry, be dried to obtain
100% α gypsum crystal particle.Alpha gypsum powder purity is high, the properties of product of liquid phase method production are stablized.But the α of liquid phase method production
Gypsum, since slurry needs to be dehydrated and clean, the consumption of water is bigger, and the energy consumption that product drying needs is also bigger, while water
Processing is also current more insoluble problem.
In addition, existing high strength gypsum production equipment includes material blending tank, turn brilliant device, drying equipment etc., using current
Equipment cannot achieve continuous production, low efficiency.
Summary of the invention
For above situation, the object of the present invention is to provide a kind of continuous productions of free water rotating crystal method production high strength gypsum
Equipment, by setting structure reasonably integrated high strength gypsum process units, it can be achieved that high strength gypsum continuous production, while nothing
The problem of sewage generates, and sewage treatment is not present, production cost reduces.
In order to achieve the above object, the present invention is achieved by the following technical solutions:
Free water rotating crystal method produces the continuous producing apparatus of high strength gypsum, which includes slurry can and turn brilliant dry
Device, described turn of brilliant drying device include the tank body that side is provided with collet, and oil expansion tank, expansion oil are connected with above collet
Case is connected by overflow pipe and oil filling pipe with storage fuel tank, is provided with conveying coil pipe in collet, slurry can pass through feed pump with it is defeated
The feed inlet of charging tray pipe is connected, and the discharge port of conveying coil pipe is connected with the fog-spray nozzle for being set to tank body internal upper part, and top of the tank goes out
Air port is provided with dust-extraction unit, and tank base is provided with material outlet and discharging device, is provided with wind stopping device at material outlet.
In the present invention, the slurry can is the slurry mix tank with stirring.By raw material, water and crystal modifier etc. in slurry can
Mixing, and stir evenly.
According to the present invention, continuous producing apparatus is by using the tank body with collet(Side is double-deck tank body), pressing from both sides
It realizes that the heating of material turns crystalline substance in set, generates high strength gypsum, while forming the place of spray drying in tank body, turn crystalline substance with heating
A set of heating facility is shared, realizes the continuous production of high strength gypsum.Unnecessary in order to avoid heat scatters and disappears, it is preferable that tank body
Top and bottom and the top surface of collet, bottom surface and lateral surface on be provided with insulating layer.
In the present invention, use oil for heat medium, i.e., fill with oil medium in collet, oil can be used conventional use of glycerol,
Paraffin oil, methyl-silicone oil, phenyl silicone oil etc..Oil medium is realized in collet after being heated by heat-conducting oil furnace and is recycled.
Conveying coil pipe in the present invention includes the conveying pipeline being connected along the multilayer that tank body is from top to bottom arranged, conveying pipeline is
Continuously "" type pipe, and expansion arc is provided in the vertical pipe being spaced.By multilayer be connected to be vertically arranged "" type
Pipe form conveying coil pipe, and be connected by circulation "" type pipe vertical pipe on be provided with expansion arc, to improve material defeated
Fluency in charging tray pipe guarantees that material is realized during being continuously conveyed and turns crystalline substance.
Further, the feed inlet of conveying coil pipe is set to the top of collet, and the discharge port of conveying coil pipe is set to collet
Lower part;Material is upper entering and lower leaving in the flow direction of expansion arc.The setting of expansion arc primarily to negative pressure formed therein that,
Conducive to Flow of Goods and Materials.
In the present invention, dust-extraction unit is set in top of the tank gas outlet, on the one hand guarantees that formation is conducive to spray drying in tank
Environment, on the other hand, avoid dust pollution, high strength gypsum sufficiently recycled.This field can be used in the dust-extraction unit
Conventional use of dust-extraction unit, preferably bag filter.
Preferably, the discharging device is scraper plate, is connected with driving motor on scraper plate.Driving motor drives scraper plate, will do
High strength gypsum powder after dry is scraped to material outlet and is discharged.
The invention also includes its for the continuous producing apparatus normal use that can make free water rotating crystal method production high strength gypsum
Its component belongs to the conventional selection of this field.
Compared with prior art, beneficial point of the invention is:
Using production equipment of the invention, it can be achieved that the continuous production of high strength gypsum, has energy conservation, advantage at low cost, the life
It is small to produce occupation area of equipment, high-efficient, yield is high, while not having sewage handling problem.
Detailed description of the invention
Fig. 1 is the structural schematic diagram for the continuous producing apparatus that 1 free water rotating crystal method of embodiment produces high strength gypsum.
Fig. 2 is the partial structural diagram of conveying coil pipe in embodiment 1.
Specific embodiment
Following will be combined with the drawings in the embodiments of the present invention, and technical solution in the embodiment of the present invention carries out clear, complete
Site preparation description, it is clear that described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.
In the description of the present invention, it should be noted that the orientation or positional relationship of the instructions such as term " top " be based on
Orientation or positional relationship shown in the drawings, is merely for convenience of description of the present invention and simplification of the description, rather than indication or suggestion institute
The device or element of finger must have a particular orientation, be constructed and operated in a specific orientation, therefore should not be understood as to this hair
Bright limitation.
Embodiment 1
As shown in Figs. 1-2, the continuous producing apparatus of free water rotating crystal method production high strength gypsum, the continuous producing apparatus include storage slurry
Tank 1 and turn brilliant drying device, described turn of brilliant drying device include the tank body 3 that side is provided with collet 2, the top connection of collet 2
There is oil expansion tank 4, oil expansion tank 4 is connected by overflow pipe 5 and oil filling pipe 6 with storage fuel tank 7, and conveying disk is provided in collet 2
Pipe 8, slurry can 1 are connected by feed pump 9 with the feed inlet of conveying coil pipe 8, the discharge port of conveying coil pipe 8 be set to tank body 3
The fog-spray nozzle 10 of internal upper part is connected, and 3 top outlet inlet of tank body is provided with dust-extraction unit 11, and 3 bottom of tank body is provided with material outlet
With discharging device 12, wind stopping device 13 is provided at material outlet.
Slurry can 1 is the slurry mix tank with stirring.Raw material, water and crystal modifier etc. are mixed in slurry can, and stirred
Uniformly.Continuous producing apparatus is realized that the heating of material turns crystalline substance in collet 2, is generated high by using the tank body 3 with collet 2
Strong gypsum, while the place of spray drying is formed in tank body 3, turn crystalline substance with heating and share a set of heating facility, realizes high-strength stone
The continuous production of cream.Unnecessary in order to avoid heat scatters and disappears, it is preferable that the top and bottom of tank body 3 and the top of collet 2
Insulating layer is provided on face, bottom surface and lateral surface.
It uses oil for heat medium, i.e., fills with oil medium in collet 2, oil medium uses methyl-silicone oil, and methyl-silicone oil oil is logical
Circulation is realized in collet 2 after crossing heat-conducting oil furnace heating.
Conveying coil pipe 8 includes the conveying pipeline being connected along the multilayer that tank body 3 is from top to bottom arranged, conveying pipeline be it is continuous "" type pipe, and expansion arc 14 is provided in the vertical pipe being spaced.By multilayer be connected to be vertically arranged "" type pipe group
At conveying coil pipe 8, and be connected by circulation "" type pipe vertical pipe on be provided with expansion arc 14, to improve material defeated
Fluency in charging tray pipe 8 guarantees that material is realized during being continuously conveyed and turns crystalline substance.The feed inlet of conveying coil pipe 8 is set to
The top of collet 2, the discharge port of conveying coil pipe 8 are set to the lower part of collet 2;Material is enterprising in the flow direction of expansion arc 14
Go out down.The setting of expansion arc 14 is primarily to negative pressure formed therein that, is conducive to Flow of Goods and Materials.
Dust-extraction unit 11 is set in 3 top gas outlet of tank body, on the one hand guarantees to form the environment for being conducive to spray drying in tank,
On the other hand, dust pollution is avoided, high strength gypsum is sufficiently recycled.The dust-extraction unit 11 is bag filter.
Discharging device 12 is scraper plate, is connected with driving motor 15 on scraper plate.Driving motor 15 drives scraper plate, after drying
High strength gypsum powder is scraped to material outlet and is discharged.
Using the production equipment, it can be achieved that the continuous production of high strength gypsum, has energy conservation, advantage at low cost, the production
Occupation area of equipment is small, high-efficient, and yield is high, while not having sewage handling problem.
The embodiment of the present invention is described above, above description is exemplary, and non-exclusive, and also not
It is limited to disclosed embodiment.Without departing from the scope and spirit of illustrated embodiment, for the art
Many modifications and changes are obvious for those of ordinary skill.
Claims (8)
1. the continuous producing apparatus of free water rotating crystal method production high strength gypsum, it is characterised in that:The continuous producing apparatus includes storage
It starches tank and turns brilliant drying device, described turn of brilliant drying device includes the tank body that side is provided with collet, is connected with above collet
Oil expansion tank, oil expansion tank are connected by overflow pipe and oil filling pipe with storage fuel tank, and conveying coil pipe, slurry can are provided in collet
It is connected by feed pump with the feed inlet of conveying coil pipe, the discharge port of conveying coil pipe and the fog-spray nozzle phase for being set to tank body internal upper part
Even, top of the tank air outlet is provided with dust-extraction unit, and tank base is provided with material outlet and discharging device, sets at material outlet
It is equipped with wind stopping device.
2. the continuous producing apparatus of free water rotating crystal method production high strength gypsum according to claim 1, it is characterised in that:Institute
Stating slurry can is the slurry mix tank with stirring.
3. the continuous producing apparatus of free water rotating crystal method production high strength gypsum according to claim 1, it is characterised in that:Tank
Insulating layer is provided on the top and bottom of body and the top surface of collet, bottom surface and lateral surface.
4. the continuous producing apparatus of free water rotating crystal method production high strength gypsum according to claim 1, it is characterised in that:Folder
Oil medium is filled in set.
5. the continuous producing apparatus of free water rotating crystal method production high strength gypsum according to claim 1, it is characterised in that:Institute
Stating conveying coil pipe includes the conveying pipeline being connected along the multilayer that tank body is from top to bottom arranged, conveying pipeline be it is continuous "" type pipe,
And expansion arc is provided in the vertical pipe at interval.
6. the continuous producing apparatus of free water rotating crystal method production high strength gypsum, feature exist according to claim 1 or 5
In:The feed inlet of conveying coil pipe is set to the top of collet, and the discharge port of conveying coil pipe is set to the lower part of collet;Material is swollen
Swollen section of flow direction is upper entering and lower leaving.
7. the continuous producing apparatus of free water rotating crystal method production high strength gypsum according to claim 1, it is characterised in that:Institute
Stating dust-extraction unit is bag filter.
8. the continuous producing apparatus of free water rotating crystal method production high strength gypsum according to claim 1, it is characterised in that:Institute
Stating discharging device is scraper plate, is connected with driving motor on scraper plate.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201810967403.1A CN108821620B (en) | 2018-08-23 | 2018-08-23 | Continuous production equipment for producing high-strength gypsum by free water crystal transformation method |
Applications Claiming Priority (1)
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CN201810967403.1A CN108821620B (en) | 2018-08-23 | 2018-08-23 | Continuous production equipment for producing high-strength gypsum by free water crystal transformation method |
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CN108821620A true CN108821620A (en) | 2018-11-16 |
CN108821620B CN108821620B (en) | 2024-02-02 |
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---|---|---|---|---|
US3437330A (en) * | 1965-11-26 | 1969-04-08 | Conzinc Riotinto Ltd | Continuous production of alpha plaster |
GB8723625D0 (en) * | 1986-10-08 | 1987-11-11 | Krc Umwelttechnik Gmbh | Preparing alpha-calcium sulphate hemihydrate |
AU3275100A (en) * | 2000-03-21 | 2001-10-03 | Elsamprojekt A/S | Use, method and composition of organic acids in gypsum producing desulphurising plants |
US20070172413A1 (en) * | 2006-01-13 | 2007-07-26 | John College | System and method for the production of alpha type gypsum using heat recovery |
CN101691286A (en) * | 2009-10-12 | 2010-04-07 | 孙恩光 | Alpha-type semi-hydrated gypsum autoclave and production method thereof |
WO2014141926A1 (en) * | 2013-03-13 | 2014-09-18 | 株式会社トクヤマ | Method for continuously producing gypsum slurry |
RU2558569C1 (en) * | 2014-06-02 | 2015-08-10 | Федеральное государственное бюджетное образовательное учреждение высшего профессионального образования Воронежский государственный университет инженерных технологий (ФГБОУ ВПО ВГУИТ) | Alpha-gypsum dehydration apparatus |
CN104986789A (en) * | 2015-03-31 | 2015-10-21 | 高庆 | Method for preparing alpha-semi-hydrated gypsum in controllable mode through acid wastewater produced by producing titanium dioxide |
CN206692344U (en) * | 2016-12-02 | 2017-12-01 | 周添明 | One kind industrialization α high strength gypsum process units |
CN209259947U (en) * | 2018-08-23 | 2019-08-16 | 河南绿材节能环保科技有限公司 | The continuous producing apparatus of free water rotating crystal method production high strength gypsum |
-
2018
- 2018-08-23 CN CN201810967403.1A patent/CN108821620B/en active Active
Patent Citations (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3437330A (en) * | 1965-11-26 | 1969-04-08 | Conzinc Riotinto Ltd | Continuous production of alpha plaster |
GB8723625D0 (en) * | 1986-10-08 | 1987-11-11 | Krc Umwelttechnik Gmbh | Preparing alpha-calcium sulphate hemihydrate |
AU3275100A (en) * | 2000-03-21 | 2001-10-03 | Elsamprojekt A/S | Use, method and composition of organic acids in gypsum producing desulphurising plants |
US20070172413A1 (en) * | 2006-01-13 | 2007-07-26 | John College | System and method for the production of alpha type gypsum using heat recovery |
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RU2558569C1 (en) * | 2014-06-02 | 2015-08-10 | Федеральное государственное бюджетное образовательное учреждение высшего профессионального образования Воронежский государственный университет инженерных технологий (ФГБОУ ВПО ВГУИТ) | Alpha-gypsum dehydration apparatus |
CN104986789A (en) * | 2015-03-31 | 2015-10-21 | 高庆 | Method for preparing alpha-semi-hydrated gypsum in controllable mode through acid wastewater produced by producing titanium dioxide |
CN206692344U (en) * | 2016-12-02 | 2017-12-01 | 周添明 | One kind industrialization α high strength gypsum process units |
CN209259947U (en) * | 2018-08-23 | 2019-08-16 | 河南绿材节能环保科技有限公司 | The continuous producing apparatus of free water rotating crystal method production high strength gypsum |
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