CN108821620A - The continuous producing apparatus of free water rotating crystal method production high strength gypsum - Google Patents

The continuous producing apparatus of free water rotating crystal method production high strength gypsum Download PDF

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Publication number
CN108821620A
CN108821620A CN201810967403.1A CN201810967403A CN108821620A CN 108821620 A CN108821620 A CN 108821620A CN 201810967403 A CN201810967403 A CN 201810967403A CN 108821620 A CN108821620 A CN 108821620A
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China
Prior art keywords
high strength
tank
producing apparatus
strength gypsum
collet
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CN201810967403.1A
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CN108821620B (en
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范红旗
范国振
宋小四
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Hunan Jinfenghuang Building Material Household Integration Technology Co ltd
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Henan Green Material Energy Saving And Environmental Protection Technology Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B11/00Calcium sulfate cements
    • C04B11/26Calcium sulfate cements strating from chemical gypsum; starting from phosphogypsum or from waste, e.g. purification products of smoke
    • C04B11/262Calcium sulfate cements strating from chemical gypsum; starting from phosphogypsum or from waste, e.g. purification products of smoke waste gypsum other than phosphogypsum
    • C04B11/264Gypsum from the desulfurisation of flue gases

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)

Abstract

The invention belongs to the technical fields of high strength gypsum production, specifically disclose a kind of continuous producing apparatus of free water rotating crystal method production high strength gypsum, the continuous producing apparatus includes slurry can and turn brilliant drying device, turning brilliant drying device includes the tank body that side is provided with collet, oil expansion tank is connected with above collet, oil expansion tank is connected by overflow pipe and oil filling pipe with storage fuel tank, conveying coil pipe is provided in collet, slurry can is connected by feed pump with the feed inlet of conveying coil pipe, the discharge port of conveying coil pipe is connected with the fog-spray nozzle for being set to tank body internal upper part, top of the tank air outlet is provided with dust-extraction unit, tank base is provided with material outlet and discharging device, wind stopping device is provided at material outlet.Using production equipment of the invention, it can be achieved that the continuous production of high strength gypsum, has energy conservation, advantage at low cost, the production equipment occupied area is small, and high-efficient, yield is high, while not having sewage handling problem.

Description

The continuous producing apparatus of free water rotating crystal method production high strength gypsum
Technical field
The invention belongs to the technical fields of high strength gypsum production, and in particular, to a kind of free water rotating crystal method production is high-strength The continuous producing apparatus of gypsum.
Background technique
As country is to power environment protection, especially raising of the reduction sulfur dioxide to atmosphere pollution attention degree, China's fire Means of flue gas desulfurization of power plant transformation enters the fast growth phase.Thereby produce a large amount of desulfurized gesso of flue gas.Present China every year there are about 8000000 tons of desulfurized gesso of flue gas outputs, if desulfurizer is all installed by whole thermal power plant of China, desulfurized gypsum yield will increase severely super Cross 40,000,000 tons.A large amount of desulfurized gypsums face the predicament stacked, filled due to that can not dissolve, and affect ecological environment and electricity Factory's safe operation.Comprehensive utilization of resources to desulfurized gypsum is a problem in the urgent need to address.
The main component of desulfurized gypsum is calcium sulphate dihydrate(CaSO4·2H2O), desulfurized gypsum, which is produced as building gypsum, is One of important use of desulfurized gypsum, i.e. desulfurized gypsum are cleaned, are homogenized, after removal of impurities, and under different crystallization conditions, tool can be made There are the β type gypsum and α type gypsum of higher-value.Wherein, there are mainly two types of the production technologies of alpha type high-strength gypsum, first is that blocky steam Press it is steam-cured, first is that liquid phase method produce.
Steam-cured blocky steam pressure is that the certain crystal modifier solution of dihydrate gypsum raw material and gypsum weight ratio is sent into mixing apparatus In, it is uniformly mixed and is directly loadable into the preferable accumulator of permeability, which is sent into and turns brilliant device equipment, is set to crystalline substance is turned It is passed through saturated steam in standby, turn brilliant equipment keeps dihydrate gypsum complete under the conditions of saturated steam medium is with temperature in heat-insulation pressure keeping At crystalline substance is turned, the mixed type crystal that there is the polymorphic based on column crystal size class to match is formed, the material for completing to turn brilliant goes out to turn It is sent into drying equipment after brilliant equipment and dries attachment removal water, and obtains α high strength gypsum after grinding, the blocky steam-cured method of steam pressure is simple, benefit In large-scale production, the scale that cost, apparatus adaptability are wide, process is simple, realize technique, raising production efficiency can be reduced. But product performance index is unstable, fluctuation is larger, thus needs to carry out final products adequately mixing and mixing, to guarantee The consistency of properties of product.
Producing alpha gypsum powder by liquid phase method is the land plaster by raw gypsum crushing grinding at fineness in certain granules distribution, so Blend together certain density Gypsum slurry, and heat temperature raising with water in blending tank afterwards, the Gypsum slurry after being mixed through shurry pump into Enter to turn in brilliant device, is crystallized for the first time under the action of 90-150 DEG C of temperature, pressure 0.3-0.5MPa and crystal modifier, generate α stone Cream slurry.The α gypsum slurry of generation enters through stock pump again in another turn of brilliant device, in 110-150 DEG C of temperature, pressure 0.3-0.4MPa With secondary crystallization is carried out under the action of crystal modifier, 100% α gypsum slurry can be generated.It separated in α gypsum slurry, be dried to obtain 100% α gypsum crystal particle.Alpha gypsum powder purity is high, the properties of product of liquid phase method production are stablized.But the α of liquid phase method production Gypsum, since slurry needs to be dehydrated and clean, the consumption of water is bigger, and the energy consumption that product drying needs is also bigger, while water Processing is also current more insoluble problem.
In addition, existing high strength gypsum production equipment includes material blending tank, turn brilliant device, drying equipment etc., using current Equipment cannot achieve continuous production, low efficiency.
Summary of the invention
For above situation, the object of the present invention is to provide a kind of continuous productions of free water rotating crystal method production high strength gypsum Equipment, by setting structure reasonably integrated high strength gypsum process units, it can be achieved that high strength gypsum continuous production, while nothing The problem of sewage generates, and sewage treatment is not present, production cost reduces.
In order to achieve the above object, the present invention is achieved by the following technical solutions:
Free water rotating crystal method produces the continuous producing apparatus of high strength gypsum, which includes slurry can and turn brilliant dry Device, described turn of brilliant drying device include the tank body that side is provided with collet, and oil expansion tank, expansion oil are connected with above collet Case is connected by overflow pipe and oil filling pipe with storage fuel tank, is provided with conveying coil pipe in collet, slurry can pass through feed pump with it is defeated The feed inlet of charging tray pipe is connected, and the discharge port of conveying coil pipe is connected with the fog-spray nozzle for being set to tank body internal upper part, and top of the tank goes out Air port is provided with dust-extraction unit, and tank base is provided with material outlet and discharging device, is provided with wind stopping device at material outlet.
In the present invention, the slurry can is the slurry mix tank with stirring.By raw material, water and crystal modifier etc. in slurry can Mixing, and stir evenly.
According to the present invention, continuous producing apparatus is by using the tank body with collet(Side is double-deck tank body), pressing from both sides It realizes that the heating of material turns crystalline substance in set, generates high strength gypsum, while forming the place of spray drying in tank body, turn crystalline substance with heating A set of heating facility is shared, realizes the continuous production of high strength gypsum.Unnecessary in order to avoid heat scatters and disappears, it is preferable that tank body Top and bottom and the top surface of collet, bottom surface and lateral surface on be provided with insulating layer.
In the present invention, use oil for heat medium, i.e., fill with oil medium in collet, oil can be used conventional use of glycerol, Paraffin oil, methyl-silicone oil, phenyl silicone oil etc..Oil medium is realized in collet after being heated by heat-conducting oil furnace and is recycled.
Conveying coil pipe in the present invention includes the conveying pipeline being connected along the multilayer that tank body is from top to bottom arranged, conveying pipeline is Continuously "" type pipe, and expansion arc is provided in the vertical pipe being spaced.By multilayer be connected to be vertically arranged "" type Pipe form conveying coil pipe, and be connected by circulation "" type pipe vertical pipe on be provided with expansion arc, to improve material defeated Fluency in charging tray pipe guarantees that material is realized during being continuously conveyed and turns crystalline substance.
Further, the feed inlet of conveying coil pipe is set to the top of collet, and the discharge port of conveying coil pipe is set to collet Lower part;Material is upper entering and lower leaving in the flow direction of expansion arc.The setting of expansion arc primarily to negative pressure formed therein that, Conducive to Flow of Goods and Materials.
In the present invention, dust-extraction unit is set in top of the tank gas outlet, on the one hand guarantees that formation is conducive to spray drying in tank Environment, on the other hand, avoid dust pollution, high strength gypsum sufficiently recycled.This field can be used in the dust-extraction unit Conventional use of dust-extraction unit, preferably bag filter.
Preferably, the discharging device is scraper plate, is connected with driving motor on scraper plate.Driving motor drives scraper plate, will do High strength gypsum powder after dry is scraped to material outlet and is discharged.
The invention also includes its for the continuous producing apparatus normal use that can make free water rotating crystal method production high strength gypsum Its component belongs to the conventional selection of this field.
Compared with prior art, beneficial point of the invention is:
Using production equipment of the invention, it can be achieved that the continuous production of high strength gypsum, has energy conservation, advantage at low cost, the life It is small to produce occupation area of equipment, high-efficient, yield is high, while not having sewage handling problem.
Detailed description of the invention
Fig. 1 is the structural schematic diagram for the continuous producing apparatus that 1 free water rotating crystal method of embodiment produces high strength gypsum.
Fig. 2 is the partial structural diagram of conveying coil pipe in embodiment 1.
Specific embodiment
Following will be combined with the drawings in the embodiments of the present invention, and technical solution in the embodiment of the present invention carries out clear, complete Site preparation description, it is clear that described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.
In the description of the present invention, it should be noted that the orientation or positional relationship of the instructions such as term " top " be based on Orientation or positional relationship shown in the drawings, is merely for convenience of description of the present invention and simplification of the description, rather than indication or suggestion institute The device or element of finger must have a particular orientation, be constructed and operated in a specific orientation, therefore should not be understood as to this hair Bright limitation.
Embodiment 1
As shown in Figs. 1-2, the continuous producing apparatus of free water rotating crystal method production high strength gypsum, the continuous producing apparatus include storage slurry Tank 1 and turn brilliant drying device, described turn of brilliant drying device include the tank body 3 that side is provided with collet 2, the top connection of collet 2 There is oil expansion tank 4, oil expansion tank 4 is connected by overflow pipe 5 and oil filling pipe 6 with storage fuel tank 7, and conveying disk is provided in collet 2 Pipe 8, slurry can 1 are connected by feed pump 9 with the feed inlet of conveying coil pipe 8, the discharge port of conveying coil pipe 8 be set to tank body 3 The fog-spray nozzle 10 of internal upper part is connected, and 3 top outlet inlet of tank body is provided with dust-extraction unit 11, and 3 bottom of tank body is provided with material outlet With discharging device 12, wind stopping device 13 is provided at material outlet.
Slurry can 1 is the slurry mix tank with stirring.Raw material, water and crystal modifier etc. are mixed in slurry can, and stirred Uniformly.Continuous producing apparatus is realized that the heating of material turns crystalline substance in collet 2, is generated high by using the tank body 3 with collet 2 Strong gypsum, while the place of spray drying is formed in tank body 3, turn crystalline substance with heating and share a set of heating facility, realizes high-strength stone The continuous production of cream.Unnecessary in order to avoid heat scatters and disappears, it is preferable that the top and bottom of tank body 3 and the top of collet 2 Insulating layer is provided on face, bottom surface and lateral surface.
It uses oil for heat medium, i.e., fills with oil medium in collet 2, oil medium uses methyl-silicone oil, and methyl-silicone oil oil is logical Circulation is realized in collet 2 after crossing heat-conducting oil furnace heating.
Conveying coil pipe 8 includes the conveying pipeline being connected along the multilayer that tank body 3 is from top to bottom arranged, conveying pipeline be it is continuous "" type pipe, and expansion arc 14 is provided in the vertical pipe being spaced.By multilayer be connected to be vertically arranged "" type pipe group At conveying coil pipe 8, and be connected by circulation "" type pipe vertical pipe on be provided with expansion arc 14, to improve material defeated Fluency in charging tray pipe 8 guarantees that material is realized during being continuously conveyed and turns crystalline substance.The feed inlet of conveying coil pipe 8 is set to The top of collet 2, the discharge port of conveying coil pipe 8 are set to the lower part of collet 2;Material is enterprising in the flow direction of expansion arc 14 Go out down.The setting of expansion arc 14 is primarily to negative pressure formed therein that, is conducive to Flow of Goods and Materials.
Dust-extraction unit 11 is set in 3 top gas outlet of tank body, on the one hand guarantees to form the environment for being conducive to spray drying in tank, On the other hand, dust pollution is avoided, high strength gypsum is sufficiently recycled.The dust-extraction unit 11 is bag filter.
Discharging device 12 is scraper plate, is connected with driving motor 15 on scraper plate.Driving motor 15 drives scraper plate, after drying High strength gypsum powder is scraped to material outlet and is discharged.
Using the production equipment, it can be achieved that the continuous production of high strength gypsum, has energy conservation, advantage at low cost, the production Occupation area of equipment is small, high-efficient, and yield is high, while not having sewage handling problem.
The embodiment of the present invention is described above, above description is exemplary, and non-exclusive, and also not It is limited to disclosed embodiment.Without departing from the scope and spirit of illustrated embodiment, for the art Many modifications and changes are obvious for those of ordinary skill.

Claims (8)

1. the continuous producing apparatus of free water rotating crystal method production high strength gypsum, it is characterised in that:The continuous producing apparatus includes storage It starches tank and turns brilliant drying device, described turn of brilliant drying device includes the tank body that side is provided with collet, is connected with above collet Oil expansion tank, oil expansion tank are connected by overflow pipe and oil filling pipe with storage fuel tank, and conveying coil pipe, slurry can are provided in collet It is connected by feed pump with the feed inlet of conveying coil pipe, the discharge port of conveying coil pipe and the fog-spray nozzle phase for being set to tank body internal upper part Even, top of the tank air outlet is provided with dust-extraction unit, and tank base is provided with material outlet and discharging device, sets at material outlet It is equipped with wind stopping device.
2. the continuous producing apparatus of free water rotating crystal method production high strength gypsum according to claim 1, it is characterised in that:Institute Stating slurry can is the slurry mix tank with stirring.
3. the continuous producing apparatus of free water rotating crystal method production high strength gypsum according to claim 1, it is characterised in that:Tank Insulating layer is provided on the top and bottom of body and the top surface of collet, bottom surface and lateral surface.
4. the continuous producing apparatus of free water rotating crystal method production high strength gypsum according to claim 1, it is characterised in that:Folder Oil medium is filled in set.
5. the continuous producing apparatus of free water rotating crystal method production high strength gypsum according to claim 1, it is characterised in that:Institute Stating conveying coil pipe includes the conveying pipeline being connected along the multilayer that tank body is from top to bottom arranged, conveying pipeline be it is continuous "" type pipe, And expansion arc is provided in the vertical pipe at interval.
6. the continuous producing apparatus of free water rotating crystal method production high strength gypsum, feature exist according to claim 1 or 5 In:The feed inlet of conveying coil pipe is set to the top of collet, and the discharge port of conveying coil pipe is set to the lower part of collet;Material is swollen Swollen section of flow direction is upper entering and lower leaving.
7. the continuous producing apparatus of free water rotating crystal method production high strength gypsum according to claim 1, it is characterised in that:Institute Stating dust-extraction unit is bag filter.
8. the continuous producing apparatus of free water rotating crystal method production high strength gypsum according to claim 1, it is characterised in that:Institute Stating discharging device is scraper plate, is connected with driving motor on scraper plate.
CN201810967403.1A 2018-08-23 2018-08-23 Continuous production equipment for producing high-strength gypsum by free water crystal transformation method Active CN108821620B (en)

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Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3437330A (en) * 1965-11-26 1969-04-08 Conzinc Riotinto Ltd Continuous production of alpha plaster
GB8723625D0 (en) * 1986-10-08 1987-11-11 Krc Umwelttechnik Gmbh Preparing alpha-calcium sulphate hemihydrate
AU3275100A (en) * 2000-03-21 2001-10-03 Elsamprojekt A/S Use, method and composition of organic acids in gypsum producing desulphurising plants
US20070172413A1 (en) * 2006-01-13 2007-07-26 John College System and method for the production of alpha type gypsum using heat recovery
CN101691286A (en) * 2009-10-12 2010-04-07 孙恩光 Alpha-type semi-hydrated gypsum autoclave and production method thereof
WO2014141926A1 (en) * 2013-03-13 2014-09-18 株式会社トクヤマ Method for continuously producing gypsum slurry
RU2558569C1 (en) * 2014-06-02 2015-08-10 Федеральное государственное бюджетное образовательное учреждение высшего профессионального образования Воронежский государственный университет инженерных технологий (ФГБОУ ВПО ВГУИТ) Alpha-gypsum dehydration apparatus
CN104986789A (en) * 2015-03-31 2015-10-21 高庆 Method for preparing alpha-semi-hydrated gypsum in controllable mode through acid wastewater produced by producing titanium dioxide
CN206692344U (en) * 2016-12-02 2017-12-01 周添明 One kind industrialization α high strength gypsum process units
CN209259947U (en) * 2018-08-23 2019-08-16 河南绿材节能环保科技有限公司 The continuous producing apparatus of free water rotating crystal method production high strength gypsum

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3437330A (en) * 1965-11-26 1969-04-08 Conzinc Riotinto Ltd Continuous production of alpha plaster
GB8723625D0 (en) * 1986-10-08 1987-11-11 Krc Umwelttechnik Gmbh Preparing alpha-calcium sulphate hemihydrate
AU3275100A (en) * 2000-03-21 2001-10-03 Elsamprojekt A/S Use, method and composition of organic acids in gypsum producing desulphurising plants
US20070172413A1 (en) * 2006-01-13 2007-07-26 John College System and method for the production of alpha type gypsum using heat recovery
CN101691286A (en) * 2009-10-12 2010-04-07 孙恩光 Alpha-type semi-hydrated gypsum autoclave and production method thereof
WO2014141926A1 (en) * 2013-03-13 2014-09-18 株式会社トクヤマ Method for continuously producing gypsum slurry
RU2558569C1 (en) * 2014-06-02 2015-08-10 Федеральное государственное бюджетное образовательное учреждение высшего профессионального образования Воронежский государственный университет инженерных технологий (ФГБОУ ВПО ВГУИТ) Alpha-gypsum dehydration apparatus
CN104986789A (en) * 2015-03-31 2015-10-21 高庆 Method for preparing alpha-semi-hydrated gypsum in controllable mode through acid wastewater produced by producing titanium dioxide
CN206692344U (en) * 2016-12-02 2017-12-01 周添明 One kind industrialization α high strength gypsum process units
CN209259947U (en) * 2018-08-23 2019-08-16 河南绿材节能环保科技有限公司 The continuous producing apparatus of free water rotating crystal method production high strength gypsum

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