CN108821495A - A kind of heating wire pickle liquor harmless treatment process and system - Google Patents

A kind of heating wire pickle liquor harmless treatment process and system Download PDF

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Publication number
CN108821495A
CN108821495A CN201810829953.7A CN201810829953A CN108821495A CN 108821495 A CN108821495 A CN 108821495A CN 201810829953 A CN201810829953 A CN 201810829953A CN 108821495 A CN108821495 A CN 108821495A
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CN
China
Prior art keywords
harmless treatment
heating wire
waste liquid
pickle liquor
steam
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810829953.7A
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Chinese (zh)
Inventor
叶明华
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Changshu City Co Ltd Of Electrothermal Alloy Material Factory
Original Assignee
Changshu City Co Ltd Of Electrothermal Alloy Material Factory
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by Changshu City Co Ltd Of Electrothermal Alloy Material Factory filed Critical Changshu City Co Ltd Of Electrothermal Alloy Material Factory
Priority to CN201810829953.7A priority Critical patent/CN108821495A/en
Publication of CN108821495A publication Critical patent/CN108821495A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/02Treatment of water, waste water, or sewage by heating
    • C02F1/04Treatment of water, waste water, or sewage by heating by distillation or evaporation
    • C02F1/048Purification of waste water by evaporation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D46/00Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/002Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by condensation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/001Processes for the treatment of water whereby the filtration technique is of importance
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G7/00Incinerators or other apparatus for consuming industrial waste, e.g. chemicals
    • F23G7/04Incinerators or other apparatus for consuming industrial waste, e.g. chemicals of waste liquors, e.g. sulfite liquors
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2201/00Apparatus for treatment of water, waste water or sewage
    • C02F2201/002Construction details of the apparatus
    • C02F2201/007Modular design

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Water Supply & Treatment (AREA)
  • General Engineering & Computer Science (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Mechanical Engineering (AREA)
  • Vaporization, Distillation, Condensation, Sublimation, And Cold Traps (AREA)

Abstract

The invention discloses a kind of heating wire pickle liquor harmless treatment process and systems.The processing step is divided into waste collection, waste liquid concentration and three step of harmless treatment, the waste collection step refers to that factory in production concentrates on waste liquid in the exhausted bath box of designated position, waste liquid concentration step refers to, and liquid is concentrated by means such as evaporations for the heating wire pickle liquor in the exhausted bath box, the steam that evaporation process generates need to discharge after the harmless treatment of condensation filtering, the harmless treatment of concentrate is to sinter concentrate into cake mass by high temperature incineration.Wherein the gas of loss is discharged again after being adsorbed by the adsorbent equipment purification being arranged above incinerator.By the above-mentioned means, the present invention can clear up in time the waste liquid generated in production, centralized processing prevents the pollution of the environment.

Description

A kind of heating wire pickle liquor harmless treatment process and system
Technical field
The present invention relates to field of environment protection, more particularly to a kind of heating wire pickle liquor harmless treatment process and are System.
Background technique
Three industrial wastes are waste water, exhaust gas and waste residue, wherein it is especially maximum with harm of the waste water to environment, it is raw at heating wire scene Show particularly evident in production, heating wire has one of etching procedures, need to take out the sull on heating wire surface by pickling, If washed waste liquid fruit direct emission is very big to environmental pressure, professional institution's processing is asked together again if be collected into after washing every time Occupy a large amount of production site and artificial energy.
Summary of the invention
The invention mainly solves the technical problem of providing a kind of heating wire pickle liquor harmless treatment process and system, Can the heating wire pickle liquor to produced on-site handle, reduce heating wire pickle liquor to the pressure of environment.
In order to solve the above technical problems, one technical scheme adopted by the invention is that:
A kind of technique innoxious for heating wire pickle liquor is provided, the technique includes:Waste collection, waste liquid concentration and nothing Evilization handles three processing steps, and the waste collection step, which refers to, focuses on designated treatment region for the waste liquid, described useless Liquid concentration step, which refers to, tentatively removes moisture therein by evaporation for the waste liquid, facilitates next step harmless treatment, described Harmless treatment step includes two parts, and first part refers to by condensing and being filtered to remove the harmful substance in steam, and second Part refers to through high temperature incineration, and the concentrate is become to the ash content of environmental sound.
In order to solve the above technical problems, another technical solution used in the present invention is:
A kind of heating wire pickle liquor innocuity disposal system, the heating wire pickle liquor innocuity disposal system packet are provided It includes:Waste collecting device, waste liquid enrichment facility and harmless treatment device, the waste collecting device are exhausted bath box, described useless There is pipeline connection between liquid case and waste liquid enrichment facility, waste liquid delivery pump, the waste liquid concentration dress are set in the connecting pipe Set and waste liquid be concentrated by evaporation mode, the harmless treatment device by steam harmless treatment device and concentrate without Evilization processing unit composition, the steam harmless treatment device includes condensation separator, the condensation separating unit and evaporation There is pipeline to be connected between device, the concentration liquid pollution-free device is sintering furnace, and concentrate is put into after taking out in vaporising device It is sintered in ware, the sintering ware can be placed in the burner hearth of sintering furnace.
In a preferred embodiment of the present invention, the vaporising device is evaporating kettle, and the evaporating kettle includes upper cover and this Inlet, agitating paddle and steam (vapor) outlet, the steam outlet are arranged on the upper lid and is equipped with vacuum pump, the evaporation for body Turbulent flow piece is set on kettle ontology, and heating region is arranged in the evaporating kettle bottom, and liquid outlet is also disposed at the evaporating kettle bottom.
In a preferred embodiment of the present invention, magnetic double level gauge is set on the evaporating kettle.
In a preferred embodiment of the present invention, the condensation separating unit is helix tube condenser, the condensation separation Device is helix tube condenser, and coolant liquid is full of in the condenser, hollow spiral copper pipe is arranged among the condenser, steams Vapour passes through from the spiral copper pipe, and steam inlet, condensation-water drain and gas outlet are arranged on the spiral copper pipe, condenser Active carbon filter is installed on condensed water water inlet.
In a preferred embodiment of the present invention, air filter is installed in the gas outlet of the condensation separating unit.
In a preferred embodiment of the present invention, the sintering furnace is electric furnace, and the sintering temperature is described greater than 1000 DEG C Gas-filtering device is set in sintering furnace flue.
In a preferred embodiment of the present invention, the flue of the sintering furnace is connected with vaporising device heating region.
The beneficial effects of the invention are as follows:Technical solution provided by the invention be by will be first concentrated after waste collection, The concentrate is sintered again by electric furnace after concentration, removes all moisture and readily volatilized substance, it will originally On the one hand the clinker for becoming sintering to the great industrial acidic wastewater of environmental hazard eliminates waste liquid and endangers the acidity of environment, On the other hand, the clinker of remaining sintering can reuse again according to its ingredient.
Detailed description of the invention
Fig. 1 is the process route map of a preferred embodiment of the present invention;
Fig. 2 is the evaporating kettle schematic diagram of a preferred embodiment of the present invention;
Fig. 3 is the condenser schematic diagram of a preferred embodiment of the present invention.
The components in the drawings are labeled as follows:
1. kettle wall, 2. kettle covers, 3. inlets, 4. heating tubes, 5. steam outlet pipes, 6. turbulent flow pieces, 7. vacuum pumps, 8. stirring motors, 9. Agitating paddle, 10. concentrated solution outlets, 11. heating tube protective cradles, 12. steam inlet, 13. condensation-water drain, 14. gas outlets, 15. Cooling liquid inlet, 16. cooling liquid outlets, 17. pneumatic filters, 18. liquid filters.
Specific embodiment
The preferred embodiments of the present invention will be described in detail with reference to the accompanying drawing, so that advantages and features of the invention energy It is easier to be readily appreciated by one skilled in the art, so as to make a clearer definition of the protection scope of the present invention.
Attached drawing 1 is please referred to Fig. 3, a preferred embodiment of the present invention is:
A kind of technique innoxious for heating wire pickle liquor is provided, the technique includes:Waste collection, waste liquid concentration and nothing Evilization handles three processing steps, and the waste collection step, which refers to, focuses on designated treatment region for the waste liquid, described useless Liquid concentration step, which refers to, tentatively removes moisture therein by evaporation technology for the waste liquid, facilitates next step harmless treatment, The harmless treatment step includes two parts, and first part refers to by condensing and being filtered to remove the harmful substance in steam, Second part refers to through sintering, and the concentrate is become to the ash content of environmental sound.
Another preferred embodiment of the invention is:
A kind of system suitable for heating wire pickle liquor harmless treatment process is provided, the heating wire pickle liquor is innoxious Processing system includes:Waste collecting device, waste liquid enrichment facility and harmless treatment device, the waste collecting device are waste liquid Case has pipeline connection between the exhausted bath box and waste liquid enrichment facility, waste liquid delivery pump is arranged in the connecting pipe, described useless Liquid enrichment facility is concentrated waste liquid by evaporation mode, the harmless treatment device by steam harmless treatment device and Concentrate harmless treatment device composition, the steam harmless treatment device includes condensation separator, the condensation separation dress Set has pipeline to be connected between vaporising device, and the concentration liquid pollution-free device is sintering furnace, and concentrate takes from vaporising device It is put into after out in sintering ware, the sintering ware can be placed in the burner hearth of sintering furnace.
The vaporising device is evaporating kettle, and the evaporating kettle includes kettle cover 2 and kettle wall 1, and inlet is arranged on the kettle cover 2 3, agitating paddle 9 and steam outlet pipe 5 are equipped with vacuum pump 7 at the steam outlet pipe 5, turbulent flow piece 6, institute are arranged on the evaporating kettle kettle wall 1 Evaporating kettle bottom setting heating region is stated, the heating region is 4 electric heating tubes 4 arranged at the bottom, in the heating tube 4 Side's setting heating tube protective cradle 11, concentrated solution outlet 10 are also disposed at the evaporating kettle bottom close to 1 position of kettle wall.Pass through pumping Vacuum reduces steam pressure, and moisture is evaporated as early as possible, while turbulent flow piece 6 is added on the evaporating kettle kettle wall 1, increases stirred Liquid turbulence in journey, further speeds up evaporation process
Magnetic double level gauge is set on the evaporating kettle, facilitates operator from the external degree for grasping concentration.
The condensation separating unit is helix tube condenser, is full of in condenser described in recirculated cooling water in the condenser Between hollow spiral copper pipe is set, steam passes through from the spiral copper pipe, and steam inlet 12, cold is arranged on the spiral copper pipe Condensate outlet 13 and gas outlet 14, the cooling water enters from cooling liquid inlet 15, goes out from cooling liquid outlet 16, and water vapour is from cold Condenser steam inlet 12 enters, and flows out from condensation-water drain 13 through the condensed condensed water of helix tube, the condensation-water drain Condensate collector is connect again after active carbon liquid filter 18 is installed on 13, and residual gas is escaped from gas outlet 14.The condensation Pneumatic filter 17 is installed, all steams that steam are by after separating and filtering, eliminating wherein has on the gas outlet of separator Evil chemical substance, reaching can be recycled after can recycling with the requirement of direct emission, condensed water therein.
The sintering furnace is common electric furnace, is connected with dedicated flue, and the sintering temperature is greater than 1000 DEG C, the sintering furnace Gas-filtering device is set in flue.
Another embodiment of the invention is:
A kind of system suitable for heating wire pickle liquor harmless treatment process is provided, the heating wire pickle liquor is innoxious Processing system includes:Waste collecting device, waste liquid enrichment facility and harmless treatment device, the waste collecting device are waste liquid Case has pipeline connection between the exhausted bath box and waste liquid enrichment facility, waste liquid delivery pump is arranged in the connecting pipe, described useless Liquid enrichment facility is concentrated waste liquid by evaporation mode, the harmless treatment device by steam harmless treatment device and Concentrate harmless treatment device composition, the steam harmless treatment device includes condensation separator, the condensation separation dress Set has pipeline to be connected between vaporising device, and the concentration liquid pollution-free device is sintering furnace, and concentrate takes from vaporising device It is put into after out in sintering ware, the sintering ware can be placed in the burner hearth of sintering furnace.
The vaporising device is evaporating kettle, and the evaporating kettle includes kettle cover 2 and kettle wall 1, and inlet is arranged on the kettle cover 2 3, agitating paddle 9 and steam outlet pipe 5 are equipped with vacuum pump 7 at the steam outlet pipe 5, turbulent flow piece 6, institute are arranged on the evaporating kettle kettle wall 1 Evaporating kettle bottom setting heating region is stated, the heating region is arranged to the heating chamber that front and back is connected to, leads to High Temperature Gas in heating chamber Body, concentrated solution outlet 10 are also disposed at the evaporating kettle bottom close to 1 position of kettle wall.It, will by vacuumizing reduction steam pressure Moisture evaporates as early as possible, while turbulent flow piece 6 is added on the evaporating kettle kettle wall 1, increases the liquid turbulence in whipping process, into one Step accelerates evaporation process
Magnetic double level gauge is set on the evaporating kettle, facilitates operator from the external degree for grasping concentration.
The condensation separating unit is helix tube condenser, is full of in condenser described in recirculated cooling water in the condenser Between hollow spiral copper pipe is set, steam passes through from the spiral copper pipe, and steam inlet 12, cold is arranged on the spiral copper pipe Condensate outlet 13 and gas outlet 14, the cooling water enters from cooling liquid inlet 15, goes out from cooling liquid outlet 16, and water vapour is from cold Condenser steam inlet 12 enters, and flows out from condensation-water drain 13 through the condensed condensed water of helix tube, the condensation-water drain Condensate collector is connect again after active carbon liquid filter 18 is installed on 13, and residual gas is escaped from gas outlet 14.The condensation Pneumatic filter 17 is installed, all steams that steam are by after separating and filtering, eliminating wherein has on the gas outlet of separator Evil chemical substance, reaching can be recycled after can recycling with the requirement of direct emission, condensed water therein.
The sintering furnace is common electric furnace, is connected with dedicated flue, and the sintering temperature is greater than 1000 DEG C, the sintering furnace Gas-filtering device is set in flue, and the flue is connected with evaporating kettle bottom-heated chamber, and the high-temperature gas in flue first passes through Again by pneumatic filter after the heating chamber, this design can maximumlly utilize the after-heat in electric furnace heating, environmental protection Efficiently.
The above description is only an embodiment of the present invention, is not intended to limit the scope of the invention, all to utilize this hair Equivalent structure or equivalent flow shift made by bright specification and accompanying drawing content is applied directly or indirectly in other relevant skills Art field, is included within the scope of the present invention.

Claims (8)

1. a kind of technique innoxious for heating wire pickle liquor, which is characterized in that it is described for heating wire pickle liquor without The technique of the processing of evilization includes:Waste collection, waste liquid concentration and three processing steps of harmless treatment,
The waste collection step, which refers to, focuses on designated treatment region for the waste liquid,
The waste liquid concentration step, which refers to, tentatively removes moisture therein by evaporation mode for the waste liquid,
The harmless treatment step includes two parts, and first part refers to by condensing and being filtered to remove the nuisance in steam Matter, second part refers to through high temperature incineration, and impurity in the concentrate is sintered.
2. a kind of system suitable for heating wire pickle liquor harmless treatment process, which is characterized in that described to be used for heating wire The system of the innoxious processing of pickle liquor includes:Waste collecting device, waste liquid enrichment facility and harmless treatment device, it is described Waste collecting device is exhausted bath box, has pipeline connection between the exhausted bath box and waste liquid enrichment facility, sets in the connecting pipe Set waste liquid delivery pump, the waste liquid enrichment facility is concentrated waste liquid by evaporation mode, the harmless treatment device by Steam harmless treatment device and concentrate harmless treatment device composition, the steam harmless treatment device include condensation point From device, there is pipeline to be connected between the condensation separating unit and vaporising device, the concentration liquid pollution-free device is sintering furnace, dense Contracting liquid is put into sintering ware after taking out in vaporising device, and the sintering ware can be placed in the burner hearth of sintering furnace.
3. the system according to claim 2 suitable for heating wire pickle liquor harmless treatment process, which is characterized in that The vaporising device is evaporating kettle, and the evaporating kettle includes kettle cover and kettle wall, and inlet, agitating paddle are arranged on the kettle cover and goes out Steam pipe is equipped with vacuum pump on the steam outlet pipe, several turbulent flow pieces is arranged on the evaporating kettle kettle wall, the evaporating kettle bottom is set Heating region is set, liquid outlet is also disposed at the evaporating kettle bottom.
4. the system according to claim 3 suitable for heating wire pickle liquor harmless treatment process, which is characterized in that Magnetic double level gauge is set on the evaporating kettle.
5. heating wire pickle liquor innocuity disposal system according to claim 2, it is characterised in that the condensation separation Device is helix tube condenser, and coolant liquid is full of in the condenser, hollow spiral copper pipe is arranged among the condenser, steams Vapour passes through from the spiral copper pipe, and steam inlet, condensation-water drain and gas outlet are arranged on the spiral copper pipe, condenser Active carbon filter is installed on condensed water water inlet.
6. the system according to claim 2 suitable for heating wire pickle liquor harmless treatment process, which is characterized in that The gas outlet of the condensation separating unit is installed by air filter.
7. the system according to claim 2 suitable for heating wire pickle liquor harmless treatment process, which is characterized in that The sintering furnace is electric furnace, and the sintering temperature is greater than 1000 DEG C, gas-filtering device is arranged in the sintering furnace flue.
8. the process system according to claim 2 suitable for the harmless treatment of heating wire pickle liquor, which is characterized in that The flue of the sintering furnace is connected with vaporising device heating region.
CN201810829953.7A 2018-07-25 2018-07-25 A kind of heating wire pickle liquor harmless treatment process and system Pending CN108821495A (en)

Priority Applications (1)

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CN201810829953.7A CN108821495A (en) 2018-07-25 2018-07-25 A kind of heating wire pickle liquor harmless treatment process and system

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Application Number Priority Date Filing Date Title
CN201810829953.7A CN108821495A (en) 2018-07-25 2018-07-25 A kind of heating wire pickle liquor harmless treatment process and system

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CN108821495A true CN108821495A (en) 2018-11-16

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110294577A (en) * 2019-08-06 2019-10-01 台州市德长环保有限公司 A kind of processing system and its processing method of dangerous waste landfill percolate
CN113173673A (en) * 2021-05-10 2021-07-27 高梵(浙江)信息技术有限公司 Method and equipment for recycling wastewater generated in antibacterial treatment of down jacket fabric

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US20070170049A1 (en) * 2006-01-20 2007-07-26 Mansur Pierre G Multiple application purification and recycling device
CN102380276A (en) * 2011-09-05 2012-03-21 南京林业大学 Gas-solid-liquid separation and purification system for agricultural and forestry biomass material gasified gas
CN104944665A (en) * 2015-06-19 2015-09-30 浙江大学 Comprehensive resourceful treatment device and method for chlorohydric acid pickling waste liquid
CN204999987U (en) * 2015-10-09 2016-01-27 贵溪凌云铜业有限公司 Equipment of preparing of single nickel salt crystalline solid

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20070170049A1 (en) * 2006-01-20 2007-07-26 Mansur Pierre G Multiple application purification and recycling device
CN102380276A (en) * 2011-09-05 2012-03-21 南京林业大学 Gas-solid-liquid separation and purification system for agricultural and forestry biomass material gasified gas
CN104944665A (en) * 2015-06-19 2015-09-30 浙江大学 Comprehensive resourceful treatment device and method for chlorohydric acid pickling waste liquid
CN204999987U (en) * 2015-10-09 2016-01-27 贵溪凌云铜业有限公司 Equipment of preparing of single nickel salt crystalline solid

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110294577A (en) * 2019-08-06 2019-10-01 台州市德长环保有限公司 A kind of processing system and its processing method of dangerous waste landfill percolate
CN113173673A (en) * 2021-05-10 2021-07-27 高梵(浙江)信息技术有限公司 Method and equipment for recycling wastewater generated in antibacterial treatment of down jacket fabric

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