CN108819593A - No-slot laser electrochemical aluminium thermoprinting film - Google Patents
No-slot laser electrochemical aluminium thermoprinting film Download PDFInfo
- Publication number
- CN108819593A CN108819593A CN201810727108.9A CN201810727108A CN108819593A CN 108819593 A CN108819593 A CN 108819593A CN 201810727108 A CN201810727108 A CN 201810727108A CN 108819593 A CN108819593 A CN 108819593A
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- CN
- China
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- parts
- layer
- acrylic resin
- color layers
- butanone
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
- B44C1/00—Processes, not specifically provided for elsewhere, for producing decorative surface effects
- B44C1/16—Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like
- B44C1/165—Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like for decalcomanias; sheet material therefor
- B44C1/17—Dry transfer
- B44C1/1712—Decalcomanias applied under heat and pressure, e.g. provided with a heat activable adhesive
- B44C1/1729—Hot stamping techniques
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D161/00—Coating compositions based on condensation polymers of aldehydes or ketones; Coating compositions based on derivatives of such polymers
- C09D161/20—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
- C09D161/26—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with heterocyclic compounds
- C09D161/28—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with heterocyclic compounds with melamine
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Laminated Bodies (AREA)
Abstract
The invention discloses a kind of no-slot laser electrochemical aluminium thermoprinting films, it includes：Sequentially connected basal layer, peeling layer, color layers, electroplated layer and glue layer from top to bottom；The acrylic resin coating containing filler nanometer silica is provided between color layers and the electroplated layer；The peeling layer comprises the following components in parts by weight：20-35 parts of melamine resin, 1-6 parts of fluoro epoxies, 2-7 parts of ethyl alcohol, 27-40 parts of butanone, 20-45 parts of butyl ester, 15-45 parts of toluene；The color layers comprise the following components in parts by weight：12-17 parts of amino acrylic resin, methylhydroxy be 13-17 parts acrylic resin modified, 3-7 parts of nitrocotton, 35-45 parts of butanone, 20-25 parts of butyl ester, 3-7 parts of pigment.The present invention is able to solve product peeling in molding and glues version problem, and modified removing layer material can be effectively reduced the hot peeling force of continuous thermoprint.Color layers can improve resin to the wetability of toner, and the coating appearance levelling effect is good, and molding effect is more preferable.The blocking film for needing to waste because jumping version seam is solved simultaneously, saves cost.
Description
Technical field
The present invention relates to electrochemical aluminium thermoprinting technical field of membrane, and in particular to a kind of no-slot laser electrochemical aluminium thermoprinting film.
Background technique
Blocking film, which refers to, combines laser hologram electrification aluminium film with thermoprint technology, is formed in printed matter surface bright and colourful
Laser holographic mark and space pattern anti-counterfeiting mark technology.This technology can increase laser cryptography and back side tamper-evident
Layer, for the anti-fake of certificate, card, bill, trade mark etc..If plus this anti-counterfeiting mark, its is anti-fake on product external packaging
Dynamics is that present single laser holographic anti counterfeiting label cannot compare.Furthermore it is possible to be to produce according to the requirement of different user
Product make special edition laser hologram electrification aluminium film.Due to special edition pattern production in contain the particular requirement of businessman, then incorporate constantly
The laser holography of development.Either the anti-fake supply and marketing mode of special edition or its decorative effect are all more skillful.
In packaging industry, laser anti-counterfeiting technology has started a revolution, anti-fake electrochemical aluminium thermoprinting technology on packaging material
With laser electrochemical aluminum thin film using more and more, dosage also increases substantially year by year, but prepares in laser electrochemical aluminum thin film
In the process, mostly using polyester film as basement membrane, one layer of even spread or multilayer have different chemical property coating on it
Coating, then can usually be encountered in the production process of hot moulding using hot moulding and hot stamping technique completion whole preparation process
The phenomenon that viscous version peeling.
Summary of the invention
The present invention overcomes the deficiencies in the prior art, mention a kind of no-slot laser electrochemical aluminium thermoprinting film.
In order to solve the above technical problems, the present invention uses following technical scheme：
A kind of no-slot laser electrochemical aluminium thermoprinting film, it includes：From top to bottom sequentially connected basal layer, peeling layer, color layers,
Electroplated layer and glue layer；The acrylic resin containing filler nanometer silica is provided between color layers and the electroplated layer to apply
Layer；The peeling layer comprises the following components in parts by weight：20-35 parts of melamine resin, 1-6 parts of fluoro epoxies,
2-7 parts of ethyl alcohol, 27-40 parts of butanone, 20-45 parts of butyl ester, 15-45 parts of toluene；The color layers include following parts by weight
Component：12-17 parts of amino acrylic resin, methylhydroxy be 13-17 parts acrylic resin modified, 3-7 parts of nitrocotton, butanone 35-
45 parts, 20-25 parts of butyl ester, 3-7 parts of pigment.
Further technical solution is that the peeling layer comprises the following components in parts by weight：Melamine resin 27
Part, 4 parts of fluoro epoxies, 5 parts of ethyl alcohol, 37 parts of butanone, 35 parts of butyl ester, 25 parts of toluene.
Further technical solution is that the color layers comprise the following components in parts by weight：Amino acrylic resin 13
Part, methylhydroxy is 15 parts acrylic resin modified, 4 parts of nitrocotton, 41 parts of butanone, 25 parts of butyl ester, 5 parts of pigment.
Compared with prior art, the beneficial effects of the invention are as follows：No-slot laser electrochemical aluminium thermoprinting film of the present invention can solve
Certainly product peeling in molding glues version problem, and modified removing layer material can be effectively reduced the hot peeling force of continuous thermoprint, guarantee high
Fast thermoprint stability improves thermoprint speed.Color layers can improve resin to the wetability of toner, and the coating appearance levelling effect is good
, it is more preferable to be molded effect.Meanwhile using seamless technology, can save because version seam can affect wave due to appearance needs leapfrog
The blocking film taken saves cost for country.Seamless Technology design is to be made into overlapping in version seam and can't see in appearance up to cause
Obvious version seam, up to causing seamless effect.
Detailed description of the invention
Fig. 1 is the structural schematic diagram of one embodiment of the invention.
Specific embodiment
The present invention is further elaborated with reference to the accompanying drawing.
As shown in Figure 1, a kind of no-slot laser electrochemical aluminium thermoprinting film disclosed in the present embodiment, it includes：From top to bottom according to
Basal layer 1, peeling layer 2, color layers 3, electroplated layer 5 and the glue layer 6 of secondary connection；Specifically, the present embodiment is in color layers and institute
It states and is provided with the acrylic resin coating 4 containing filler nanometer silica between electroplated layer；Specifically, filler nanometer titanium dioxide
The acrylic resin coating 4 of silicon is that surface of semi-finished is attached to because of this layer of resin, obstruct be easy the semi-finished product of viscous version directly with molding
Nickel plate contact used, it is possible to prevente effectively from viscous version, while the layer also has good moldability, makes the feelings for being molded peeling haftplatte
Condition is resolved.The nano silica purity is 99% or more.
Further, peeling layer described in the present embodiment comprises the following components in parts by weight：27 parts of melamine resin,
4 parts of fluoro epoxies, 5 parts of ethyl alcohol, 37 parts of butanone, 35 parts of butyl ester, 25 parts of toluene；So as to which continuous scald is effectively reduced
Hot peeling force is printed, guarantees high speed thermoprint stability, improves thermoprint speed.
Further, color layers described in the present embodiment comprise the following components in parts by weight：13 parts of amino acrylic resin,
Methylhydroxy is 15 parts acrylic resin modified, 4 parts of nitrocotton, 41 parts of butanone, 25 parts of butyl ester, 5 parts of pigment.So that color layers can be with
Improve resin to the wetability of toner, the coating appearance levelling effect is good, and molding effect is more preferable.
Claims (3)
1. a kind of no-slot laser electrochemical aluminium thermoprinting film, it includes：Sequentially connected basal layer, peeling layer, color from top to bottom
Layer, electroplated layer and glue layer；It is characterized in that：It is provided between color layers and the electroplated layer containing filler nanometer silica
Acrylic resin coating；The peeling layer comprises the following components in parts by weight：20-35 parts of melamine resin, fluoro ring
1-6 parts of oxygen resin, 2-7 parts of ethyl alcohol, 27-40 parts of butanone, 20-45 parts of butyl ester, 15-45 parts of toluene；The color layers include
The component of following parts by weight：12-17 parts of amino acrylic resin, methylhydroxy be 13-17 parts acrylic resin modified, nitrocotton 3-
7 parts, 35-45 parts of butanone, 20-25 parts of butyl ester, 3-7 parts of pigment.
2. no-slot laser electrochemical aluminium thermoprinting film according to claim 1, it is characterised in that the peeling layer include with
The component of lower parts by weight：27 parts of melamine resin, 4 parts of fluoro epoxies, 5 parts of ethyl alcohol, 37 parts of butanone, butyl ester 35
Part, 25 parts of toluene.
3. no-slot laser electrochemical aluminium thermoprinting film according to claim 1, it is characterised in that the color layers include with
The component of lower parts by weight：13 parts of amino acrylic resin, methylhydroxy be 15 parts acrylic resin modified, 4 parts of nitrocotton, butanone 41
Part, 25 parts of butyl ester, 5 parts of pigment.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810727108.9A CN108819593A (en) | 2018-07-05 | 2018-07-05 | No-slot laser electrochemical aluminium thermoprinting film |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810727108.9A CN108819593A (en) | 2018-07-05 | 2018-07-05 | No-slot laser electrochemical aluminium thermoprinting film |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108819593A true CN108819593A (en) | 2018-11-16 |
Family
ID=64133833
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810727108.9A Withdrawn CN108819593A (en) | 2018-07-05 | 2018-07-05 | No-slot laser electrochemical aluminium thermoprinting film |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108819593A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110757976A (en) * | 2019-11-04 | 2020-02-07 | 中丰田光电科技(珠海)有限公司 | Processing technology of laser holographic anti-counterfeiting UV seamless film |
| CN115742593A (en) * | 2022-12-28 | 2023-03-07 | 佛山市金镭科技有限公司 | Production process of seamless laser alcohol-resistant electrochemical aluminum and electrochemical aluminum prepared by production process |
-
2018
- 2018-07-05 CN CN201810727108.9A patent/CN108819593A/en not_active Withdrawn
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110757976A (en) * | 2019-11-04 | 2020-02-07 | 中丰田光电科技(珠海)有限公司 | Processing technology of laser holographic anti-counterfeiting UV seamless film |
| CN110757976B (en) * | 2019-11-04 | 2021-09-24 | 中丰田光电科技(珠海)有限公司 | Processing technology of laser holographic anti-counterfeiting UV seamless film |
| CN115742593A (en) * | 2022-12-28 | 2023-03-07 | 佛山市金镭科技有限公司 | Production process of seamless laser alcohol-resistant electrochemical aluminum and electrochemical aluminum prepared by production process |
| CN115742593B (en) * | 2022-12-28 | 2023-07-18 | 佛山市金镭科技有限公司 | Production process of seamless laser alcohol-resistant electrochemical aluminum and electrochemical aluminum prepared by same |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| WW01 | Invention patent application withdrawn after publication | ||
| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20181116 |