CN108802617B - Test method for semi-finished battery cell - Google Patents
Test method for semi-finished battery cell Download PDFInfo
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- CN108802617B CN108802617B CN201710312182.XA CN201710312182A CN108802617B CN 108802617 B CN108802617 B CN 108802617B CN 201710312182 A CN201710312182 A CN 201710312182A CN 108802617 B CN108802617 B CN 108802617B
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- G01R31/12—Testing dielectric strength or breakdown voltage ; Testing or monitoring effectiveness or level of insulation, e.g. of a cable or of an apparatus, for example using partial discharge measurements; Electrostatic testing
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- G01R31/1263—Testing dielectric strength or breakdown voltage ; Testing or monitoring effectiveness or level of insulation, e.g. of a cable or of an apparatus, for example using partial discharge measurements; Electrostatic testing of components, parts or materials of solid or fluid materials, e.g. insulation films, bulk material; of semiconductors or LV electronic components or parts; of cable, line or wire insulation
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Abstract
Description
技术领域technical field
本发明关于一种电池芯半成品测试方法,特别是一种测试电池芯半成品的绝缘程度的电池芯半成品测试方法。The present invention relates to a method for testing semi-finished products of battery cells, in particular to a method for testing semi-finished products of battery cells for testing the insulation degree of semi-finished products of battery cells.
背景技术Background technique
近年来电子产业蓬勃发展,各式电子设备相当地普及。对于各项可携式电子设备的制造来说,最重要的莫过于是体积的小型化,以及重量的减轻。为提供电器用品携带的便利性,进而减少外在环境对提供电能的限制,电池已经成为极为普遍的电能储存装置,以随时提供电能。In recent years, the electronic industry has developed vigorously, and various electronic devices have become quite popular. For the manufacture of various portable electronic devices, the most important thing is the miniaturization of the volume and the reduction of the weight. In order to provide the convenience of carrying electrical appliances and reduce the restriction on the supply of electrical energy by the external environment, the battery has become an extremely common electrical energy storage device to provide electrical energy at any time.
现今大部分的可携式电子设备,皆以采用可重复使用、具有大容量体积与大质量能量密度的锂离子二次电池为主。锂电池主要由多个正极片、负极片以及隔离膜堆叠而成一电池芯半成品,再于电池芯中注入电解液,以制成锂电池完成品。在这样的结构下,电池芯的正负极之间的距离相当重要。目前电池芯的正负极的距离主要通过隔离膜来撑开。但于制造工艺中,可能因材料裁切毛边、于卷绕过程中飞入的异物或者是材料厚度不均,使得两极间局部距离不足而导致短路。Most of today's portable electronic devices mainly use reusable lithium-ion secondary batteries with large capacity and high energy density. The lithium battery is mainly composed of a plurality of positive electrode sheets, negative electrode sheets and separators to form a semi-finished battery cell, and then the electrolyte is injected into the battery core to make the finished lithium battery. Under such a structure, the distance between the positive and negative electrodes of the battery cell is quite important. At present, the distance between the positive and negative electrodes of the battery cell is mainly extended by the separator. However, in the manufacturing process, there may be a short circuit due to insufficient local distance between the two poles due to material cutting burrs, foreign objects flying in during the winding process, or uneven thickness of the material.
在制造工艺上,虽然会对电池芯进行绝缘程度测试,但目前主要是通过长时间连续耐压测试(Hi-pot Test)来确认绝缘效果。这样的测试方式需要较长的能量转换时间,且待测物的电容误差不小(±20%)容易造成误判。此外,电池芯半成品的稳态电压与充电过程放电的电压之间的数量级差异不大,有无法判别之虞。In the manufacturing process, although the insulation level of the battery cells will be tested, the insulation effect is mainly confirmed by a long-term continuous withstand voltage test (Hi-pot Test). Such a test method requires a long energy conversion time, and the capacitance error of the object to be tested is not small (±20%), which is likely to cause misjudgment. In addition, the order of magnitude difference between the steady-state voltage of the semi-finished battery cell and the voltage discharged during the charging process is not large, and there is a possibility that it cannot be discriminated.
发明内容SUMMARY OF THE INVENTION
本发明在于提供一种电池芯半成品测试方法,以克服传统电池芯半成品测试方法的测试时间较长、容易误判或无法判别瑕疵的问题。The present invention provides a method for testing semi-finished products of battery cells, so as to overcome the problems of long testing time, easy misjudgment or inability to identify defects in the traditional testing methods for semi-finished products of battery cells.
本发明公开了一种电池芯半成品测试方法,所述的电池芯半成品测试方法适用于电池芯半成品。电池芯半成品包括一第一电极与一第二电极。一第一电极与一第二电极交错层叠设置。一第一电极与一第二电极之间设置有绝缘层。一第一电极连接第一导接部,一第二电极连接第二导接部。于电池芯半成品测试方法中,当第一导接部与第二导接部的电压差小于电压门槛值时,以定电流对电池芯半成品充电。当第一导接部与第二导接部的电压差大于等于电压门槛值时,以定电压对电池芯半成品充电。于开始充电的预设时间区间后,取得于预设时间区间中以定电流对电池芯半成品充电的总电量。判断总电量是否大于电量门槛值。当总电量大于电量门槛值,判断电池芯半成品的绝缘程度不良。The invention discloses a method for testing semi-finished products of battery cores, and the method for testing semi-finished products of battery cores is suitable for semi-finished products of battery cores. The semi-finished battery cell includes a first electrode and a second electrode. A first electrode and a second electrode are alternately stacked. An insulating layer is disposed between a first electrode and a second electrode. A first electrode is connected to the first conductive portion, and a second electrode is connected to the second conductive portion. In the battery cell semi-finished product testing method, when the voltage difference between the first conducting portion and the second conducting portion is less than a voltage threshold, the battery cell semi-finished product is charged with a constant current. When the voltage difference between the first conducting portion and the second conducting portion is greater than or equal to a voltage threshold, the semi-finished battery cell is charged with a constant voltage. After the preset time interval for starting charging, the total amount of electricity charged to the semi-finished battery cell with a constant current in the preset time interval is obtained. Determine whether the total power is greater than the power threshold. When the total power is greater than the power threshold, it is judged that the insulation degree of the semi-finished battery cell is poor.
综合以上所述,本发明提出一种电池芯半成品测试方法,藉由判断以定电流对电池芯半成品充电的总充电量是否大于电量门槛值,以判别电池芯半成品的绝缘程度是否符合要求。藉此,除了节省了测试时间之外,更提供了一种定量的分析手段。In view of the above, the present invention proposes a method for testing semi-finished battery cells, by judging whether the total charge amount of the semi-finished battery cells charged with a constant current is greater than the power threshold value, so as to determine whether the insulation degree of the semi-finished battery cells meets the requirements. In this way, in addition to saving testing time, it also provides a quantitative analysis method.
附图说明Description of drawings
图1A为根据本发明一实施例所绘示的理想的电池芯半成品的结构示意图。FIG. 1A is a schematic structural diagram of an ideal semi-finished battery cell according to an embodiment of the present invention.
图1B为根据本发明一实施例所绘示的有瑕疵的电池芯半成品的结构示意图。FIG. 1B is a schematic structural diagram of a defective semi-finished battery cell according to an embodiment of the present invention.
图2A为根据本发明一实施例所绘示的对理想的电池芯半成品充电时的电压差示意图。2A is a schematic diagram of a voltage difference when charging an ideal semi-finished battery cell according to an embodiment of the present invention.
图2B为根据本发明一实施例所绘示的对非理想的电池芯半成品充电时的电压差示意图。FIG. 2B is a schematic diagram of the voltage difference when charging a non-ideal semi-finished battery cell according to an embodiment of the present invention.
图2C为根据本发明另一实施例所绘示的对非理想的电池芯半成品充电时的电压差示意图。2C is a schematic diagram of a voltage difference when charging a non-ideal semi-finished battery cell according to another embodiment of the present invention.
图3为根据本发明一实施例所绘示的电池芯半成品测试方法的方法流程图。3 is a method flowchart of a method for testing a semi-finished battery cell according to an embodiment of the present invention.
图4A为根据图2A对应实施例中以定电流对理想的电池芯半成品充电所消耗的总电量的示意图。4A is a schematic diagram of the total power consumed by charging an ideal semi-finished battery cell with a constant current according to the embodiment corresponding to FIG. 2A .
图4B为根据图2B对应实施例中以定电流对非理想的电池芯半成品充电所消耗的总电量的示意图。FIG. 4B is a schematic diagram of the total power consumed by charging a semi-finished battery cell with a constant current according to the embodiment corresponding to FIG. 2B .
图4C为根据图2C对应实施例中以定电流对非理想的电池芯半成品充电所消耗的总电量的示意图。FIG. 4C is a schematic diagram of the total amount of power consumed by charging a semi-finished battery cell with a constant current according to the embodiment corresponding to FIG. 2C .
图5为根据本发明另一实施例所绘示的电池芯半成品测试方法的部分步骤的方法流程图。FIG. 5 is a method flow chart of some steps of a method for testing a semi-finished battery cell according to another embodiment of the present invention.
图6为根据本发明另一实施例所绘示的对电池芯半成品充电时的电压差示意图。6 is a schematic diagram of a voltage difference when charging a semi-finished battery cell according to another embodiment of the present invention.
图7为根据本发明又一实施例所绘示的电池芯半成品测试方法的部分步骤的方法流程图。FIG. 7 is a method flow chart of some steps of a method for testing a semi-finished battery cell according to another embodiment of the present invention.
其中,附图标记:Among them, reference numerals:
10 电池芯半成品10 semi-finished battery cells
C1 第一导接部C1 first lead
C2 第二导接部C2 second lead
CC、CCI、CC1、CC2、CC2’ 电流充电区间CC, CCI, CC1, CC2, CC2’ current charging interval
CV、CVI、CV1、CV2、CV2’ 电压充电区间CV, CVI, CV1, CV2, CV2’ voltage charging range
E1a、E1b、E1c、E1d、E1e 第一电极E1a, E1b, E1c, E1d, E1e First electrode
E2a、E2b、E2c、E2d 第二电极E2a, E2b, E2c, E2d Second electrode
ti、t1、t2、t3、t4 时间点ti, t1, t2, t3, t4 time points
Tdef1、Tdef2、Tdef3、Tdef3’、Tdef3” 预设时间区间Tdef1, Tdef2, Tdef3, Tdef3’, Tdef3” preset time interval
Tref 参考时间区间Tref reference time interval
Ttest 实际测试区间Ttest actual test interval
Vth 电压门槛值Vth voltage threshold
具体实施方式Detailed ways
以下在实施方式中详细叙述本发明的详细特征以及优点,其内容足以使任何本领域技术人员了解本发明的技术内容并据以实施,且根据本说明书所公开的内容、申请专利范围及图式,任何本领域技术人员可轻易地理解本发明相关的目的及优点。以下的实施例进一步详细说明本发明的观点,但非以任何观点限制本发明的范畴。The detailed features and advantages of the present invention are described in detail in the following embodiments, and the content is sufficient to enable any person skilled in the art to understand the technical content of the present invention and implement it accordingly, and according to the content disclosed in this specification, the scope of the patent application and the drawings , any person skilled in the art can easily understand the related objects and advantages of the present invention. The following examples further illustrate the concept of the present invention in further detail, but are not intended to limit the scope of the present invention in any way.
本发明提供了一种电池芯半成品测试方法,所述的电池芯半成品测试方法适用于电池芯半成品。请参照图1A以对电池芯半成品进行简要说明,图1A为根据本发明一实施例所绘示的电池芯半成品的结构示意图。一电池芯半成品10具有一第一电极与一第二电极。在图1所示的实施例中,举第一电极E1a、E1b、E1c、E1d、E1e与第二电极E2a、E2b、E2c、E2d为例进行说明,但是第一电极与第二电极的数量并不以此为限。于实务上,第一电极与第二电极之间设置有绝缘层以隔离第一电极与第二电极,然为求图式简明易懂,在此并不对绝缘层多加赘述。The present invention provides a method for testing semi-finished products of battery cores, and the method for testing semi-finished products of battery cores is suitable for semi-finished products of battery cores. Please refer to FIG. 1A for a brief description of the semi-finished battery cell. FIG. 1A is a schematic structural diagram of the semi-finished battery cell according to an embodiment of the present invention. A battery cell
电池芯半成品10的第一电极E1a、E1b、E1c、E1d、E1e连接于第一导接部C1,第二电极E2a、E2b、E2c、E2d连接于第二导接部C2。于实务上,第一导接部C1与第二导接部C2例如为导电材料所制成,且第一导接部C1与第二导接部C2例如是以夹持、焊接或是其他的方式连接于各第一电极或第二电极。换句话说,第一电极E1a、E1b、E1c、E1d、E1e藉由第一导接部C1彼此电性连接,第二电极E2a、E2b、E2c、E2d藉由第二导接部C2彼此电性连接。第一电极E1a、E1b、E1c、E1d、E1e例如为电池的阳极或阴极的其中之一,第二电极E2a、E2b、E2c、E2d例如为电池的阳极或阴极的其中之另一。The first electrodes E1a, E1b, E1c, E1d, E1e of the
理想上,电池芯半成品的结构应如图1A所示,亦即,电池芯半成品的各第一电极与各第二电极彼此并不相接触,或者说第一电极E1a、E1b、E1c、E1d、E1e中的任一与第二电极E2a、E2b、E2c、E2d中的任一之间并无短路的情况。但于实务上,在制造工艺中有可能因为材料毛边、绝缘层厚度不均或是异物而使得电池芯半成品的部分第一电极与部分第二电极短路。请一并参照图1B以举例说明非理想的电池芯半成品的一种情况,图1B为根据本发明一实施例所绘示的有瑕疵的电池芯半成品的结构示意图。电池芯半成品10’的结构大致上相仿于电池芯半成品10的结构。与图1A不同的是,电池芯半成品10’的结构中存在有异物P。异物P位于电池芯半成品10’的第一电极E1b与第二电极E2b之间。异物P接触第一电极E1b与第二电极E2b,而使得第一电极E1b与第二电极E2b短路。Ideally, the structure of the semi-finished battery cell should be as shown in FIG. 1A , that is, the first electrodes and the second electrodes of the semi-finished battery cell are not in contact with each other, or the first electrodes E1a, E1b, E1c, E1d, There is no short circuit between any one of E1e and any one of the second electrodes E2a, E2b, E2c, and E2d. However, in practice, some of the first electrodes and some of the second electrodes of the semi-finished battery cell may be short-circuited during the manufacturing process due to material burrs, uneven thickness of the insulating layer, or foreign matter. Please refer to FIG. 1B to illustrate an example of a non-ideal semi-finished battery cell. FIG. 1B is a schematic structural diagram of a defective semi-finished battery cell according to an embodiment of the present invention. The structure of the semi-finished battery cell 10' is substantially similar to the structure of the
于实务上,依据当下的物理条件,异物P是有可能随机移动的。因此,第一电极E1b与第二电极E2b的短路情况的开始时间、持续时间与电极间的导通程度则视异物P的材质、大小或与电极的接触情况而有所变化。也就是说,即使电池芯半成品的结构中存在有异物,异物也不一定总是会导致短路情况,且每次发生短路的相对时间也不一定相同。是故,于实务上亟需一种电池芯半成品的测试方法以辨识出电池芯半成品的绝缘程度,甚至量化出电池芯半成品的绝缘程度。后续以电池芯半成品10代表理想的电池芯半成品,并以电池芯半成品10’代表非理想的电池芯半成品来进行说明。In practice, according to the current physical conditions, it is possible for the foreign object P to move randomly. Therefore, the start time, duration and conduction degree of the short circuit between the first electrode E1b and the second electrode E2b vary depending on the material and size of the foreign object P or the contact with the electrodes. That is to say, even if there are foreign objects in the structure of the semi-finished battery cell, the foreign objects may not always cause a short circuit, and the relative time of each short circuit is not necessarily the same. Therefore, in practice, there is an urgent need for a testing method for semi-finished battery cells to identify the degree of insulation of semi-finished battery cells, and even to quantify the degree of insulation of semi-finished battery cells. In the following, the battery cell
请先参照图2A以说明对理想的电池芯半成品充电时的情况,图2A为根据本发明一实施例所绘示的对电池芯半成品10充电时的电压差示意图。更具体地来说,图2A用以示意对电池芯半成品10充电时,第一导接部C1与第二导接部C2之间的电压差变化,或者说是任一第一电极与任一第二电极之间的电压差。其中,图2A中的横轴为时间,纵轴为所述的电压差的电压值。图2A中定义有定电流充电区间CCI与定电压充电区间CVI。如字面文义,于定电流充电区间CCI中,以定电流对电池芯半成品10充电。于定电压充电区间CVI中,以定电压对电池芯半成品10充电。Please refer to FIG. 2A to describe the situation of charging an ideal battery cell semi-finished product. FIG. 2A is a schematic diagram of the voltage difference when charging the battery cell
在图2A所示的实施例中,先以定电流对电池芯半成品10充电。当电压差大于等于电压门槛值Vth时,改为以定电压对电池芯半成品10充电。在此实施例中,电池芯半成品10的电压差在时间点ti被充至电压门槛值。因此,时间点ti之前为定电流充电区间CCI,时间点ti之后为定电压充电区间CVI。对应于不同的充电方式,电池芯半成品10的电压差于定电流充电区间CCI中的部分为斜率固定的斜直线,而电池芯半成品10的电压差于定电压充电区间CVI中的部分为斜率为0的水平直线。In the embodiment shown in FIG. 2A , the
请再参照图2B以说明对非理想的电池芯半成品充电时的情况。图2B为根据本发明一实施例所绘示的对电池芯半成品10’充电时的电压差示意图。在图2B中,同时绘示出理想与非理想的情况,其中以粗线表示电池芯半成品10’的电压差,并以细线表示电池芯半成品10的电压差,以相互对照。图2B中的电池芯半成品10的电压差即为图2A中的电池芯半成品10的电压差。对应于电池芯半成品10’的电压差,图2B中更定义有定电流充电区间CC1与定电压充电区间CV1。时间点t2之前为定电流充电区间CC1,时间点t2之后为定电压充电区间CV1。Please refer to FIG. 2B again to illustrate the situation of charging a non-ideal semi-finished battery cell. FIG. 2B is a schematic diagram of the voltage difference when charging the semi-finished battery cell 10' according to an embodiment of the present invention. In FIG. 2B, ideal and non-ideal conditions are simultaneously depicted, wherein the voltage difference of the semi-finished battery cell 10' is represented by a thick line, and the voltage difference of the
在图2B所述的实施例中,先以定电流对电池芯半成品10’充电。在图2B所示的实施例中,在时间点t1暂时发生短路的情况。其中,时间点t1先于时间点ti。因此,于时间点t1之前,电池芯半成品10’的电压差以固定的电压增加率(图中为固定斜率)上升。然而,当电池芯半成品10’的结构于时间点t1发生了如图1B所示的短路情况时,在以定电流对电池芯半成品10’充电的同时,电池芯半成品10’的部分电极亦不正常地放电,从而使电池芯半成品10’的电压差于时间点t1附近快速下降。而在时间点t1之后,短路情况因为实际的物理条件而被排除,被以定电流充电的电池芯半成品10’的电压差重新以固定的电压增加率上升。直到时间点t2,电池芯半成品10’的电压差被充至电压门槛值Vth,此时,改以定电压对电池芯半成品10’充电。In the embodiment shown in FIG. 2B , the semi-finished battery cell 10' is first charged with a constant current. In the embodiment shown in FIG. 2B , a short circuit situation temporarily occurs at time point t1 . Among them, the time point t1 precedes the time point ti. Therefore, before the time point t1, the voltage difference of the semi-finished battery cell 10' increases at a constant voltage increase rate (a constant slope in the figure). However, when the structure of the
请再参照图2C以说明对非理想电池芯半成品充电的另一种情况,图2C为根据本发明另一实施例所绘示的对非理想的电池芯半成品充电时的电压差示意图。于图2C中,亦同时绘示出理想与非理想的情况,其中以粗线表示电池芯半成品10’的电压差,并以细线表示电池芯半成品10的电压差。于图2C中,对应于电池芯半成品10’的电压差定义有定电流充电区间CC2、CC2’与定电压充电区间CV2、CV2’,定电流充电区间CC2先于定电压充电区间CV2,定电压充电区间CV2先于定电流充电区间CC2’,定电流充电区间CC2’先于定电压充电区间CV2’。定电流充电区间CC2在时间轴上位于时间点ti之前,定电压充电区间CV2在时间轴上位于时间点ti与时间点t3之间,定电流充电区间CC2’在时间轴上位于时间点t3与时间点t4之间,定电压充电区间CV2’在时间轴上位于时间点t4之后。Please refer to FIG. 2C again to illustrate another case of charging the non-ideal battery cell semi-finished product. FIG. 2C is a schematic diagram of the voltage difference when charging the non-ideal battery cell semi-finished product according to another embodiment of the present invention. In FIG. 2C , ideal and non-ideal conditions are also shown, wherein the voltage difference of the
在图2C所示的实施例中,电池芯半成品10’的电压差于时间点ti被充至电压门槛值Vth。短路情况发生于时间点t3,时间点t3在时间轴上位于时间点ti之后。电池芯半成品10’的电压差于时间点t3快速下降。由于电池芯半成品10’的电压差于时间点t3之后又小于电压门槛值Vth,因此重新以定电流对电池芯半成品10’进行充电。在时间点t3之后,短路情况因为实际的物理条件暂时排除,因此被以定电流充电的电池芯半成品10’的电压差重新以固定的电压增加率上升。直到时间点t4,电池芯半成品10’的电压差才再度被充至电压门槛值Vth。此时,重新以定电压对电池芯半成品10’进行充电。In the embodiment shown in FIG. 2C, the voltage difference of the battery cell semi-finished product 10' is charged to the voltage threshold Vth at the time point ti. The short-circuit situation occurs at time point t3, which is located after time point ti on the time axis. The voltage difference of the battery cell semi-finished product 10' drops rapidly at the time point t3. Since the voltage difference of the semi-finished battery cell 10' is smaller than the voltage threshold value Vth after the time point t3, the semi-finished battery cell 10' is charged again with a constant current. After the time point t3, the short-circuit situation is temporarily eliminated due to the actual physical conditions, so the voltage difference of the semi-finished battery cells 10' charged with a constant current increases again at a constant voltage increase rate. Until the time point t4, the voltage difference of the semi-finished battery cell 10' is not charged to the voltage threshold value Vth again. At this time, the semi-finished battery cell 10' is charged again with a constant voltage.
有鉴于上述的情况,本发明提供了一种电池芯半成品测试方法以检测出非理想的电池芯半成品测试方法,请参照图2以说明本发明所提供的电池芯半成品测试方法,图3为根据本发明一实施例所绘示的电池芯半成品测试方法的方法流程图。如图3所示,于步骤S101中,当第一导接部与第二导接部的电压差小于电压门槛值时,以定电流对电池芯半成品充电。于步骤S103中,当第一导接部与第二导接部的电压差大于等于电压门槛值时,以定电压对电池芯半成品充电。于步骤S105中,于开始充电的预设时间区间后,取得于预设时间区间中以定电流对电池芯半成品充电的总电量。于步骤S107中,判断总电量是否大于电量门槛值。于步骤S109中,当总电量大于电量门槛值,判断电池芯半成品的绝缘程度不良。藉由本发明所提供的电池芯半成品测试方法可测试出电池芯半成品在不同时间发生短路的情况,并给予一量化指标。以下分别就不同的情况进行说明。In view of the above situation, the present invention provides a method for testing semi-finished battery cells to detect non-ideal semi-finished battery cells. Please refer to FIG. 2 to illustrate the method for testing semi-finished batteries provided by the present invention. A method flowchart of a method for testing a semi-finished product of a battery cell according to an embodiment of the present invention. As shown in FIG. 3 , in step S101 , when the voltage difference between the first conducting portion and the second conducting portion is less than a voltage threshold, the semi-finished battery cell is charged with a constant current. In step S103, when the voltage difference between the first conducting portion and the second conducting portion is greater than or equal to the voltage threshold, the semi-finished battery cell is charged with a constant voltage. In step S105, after the preset time interval for starting charging, the total amount of electricity charged to the semi-finished battery cell with a constant current in the preset time interval is obtained. In step S107, it is determined whether the total power is greater than the power threshold. In step S109, when the total power is greater than the power threshold, it is determined that the insulation degree of the semi-finished battery cell is poor. The battery cell semi-finished product testing method provided by the present invention can test the short-circuit situation of the battery cell semi-finished product at different times, and give a quantitative index. The different situations are described below.
请参照图4A,图4A为根据图2A对应实施例中以定电流对理想的电池芯半成品充电的充电电流示意图。图4A中的横轴为时间,纵轴为电流,且图4A中标示有预设时间区间Tdef1。参照如电池芯半成品测试方法的步骤S105,在图4A所示的实施例中,于开始充电的预设时间区间Tdef1后,取得于预设时间区间Tdef1中以定电流对电池芯半成品充电的总电量。于实务上,电流曲线下的面积即为以定电流对电池芯半成品10充电时所消耗的总电量。换句话说,当设定预设时间区间Tdef1不小于前述的定电流充电区间CCI,即可依据电流IC与时间参数取得对电池芯半成品充电的总电量。于实务上,可依据电流与时间而积分得实际的总电量。或者,当充电电流值已知时,可以统计以定电流对电池芯半成品10充电的总时间,再依据充电电流值与总时间取得所述的总电量。Please refer to FIG. 4A . FIG. 4A is a schematic diagram of a charging current for charging an ideal semi-finished battery cell with a constant current according to the embodiment corresponding to FIG. 2A . The horizontal axis in FIG. 4A is time, the vertical axis is current, and a preset time interval Tdef1 is marked in FIG. 4A . Referring to step S105 of the battery cell semi-finished product testing method, in the embodiment shown in FIG. 4A , after the preset time interval Tdef1 of starting charging, the total amount of charging the battery cell semi-finished product with a constant current in the preset time interval Tdef1 is obtained. power. In practice, the area under the current curve is the total amount of electricity consumed when charging the
请再参照图4B,图4B为根据图2B对应实施例中以定电流对非理想的电池芯半成品充电的充电电流的示意图。相仿于图2B,在图4B中以细线表示理想状况,并以粗线表示非理想状况。另一方面,图4B中标示有预设时间区间Tdef2。如前述地,由于电池芯半成品10’于时间点t1不正常放电,时间点T1在时间轴上位于时间点ti之前,使得定电流充电区间CC1较定电流充电区间CCI来得长。因此,粗线下的面积会大于细线下的面积,亦即,非理想状况下以定电流充电的所消耗的总电量大于理想状况下以定电流充电所消耗的总电量。因此,参照如电池芯半成品测试方法的步骤S107与步骤S109,当取得当次以定电流充电所消耗的总电量时,比较所述的总电量与一电量门槛值。当总电量大于电量门槛值时,代表总电量大于以定电流对理想的电池芯半成品充电所消耗的电量,此时,判断电池芯半成品的绝缘程度不良。Please refer to FIG. 4B again. FIG. 4B is a schematic diagram of a charging current for charging a semi-finished battery cell with a constant current according to the embodiment corresponding to FIG. 2B . Similar to FIG. 2B , in FIG. 4B , the ideal conditions are represented by thin lines, and the non-ideal conditions are represented by thick lines. On the other hand, a predetermined time interval Tdef2 is marked in FIG. 4B . As mentioned above, since the semi-finished battery cell 10' is abnormally discharged at the time point t1, the time point T1 is located before the time point ti on the time axis, so that the constant current charging interval CC1 is longer than the constant current charging interval CCI. Therefore, the area under the thick line is larger than the area under the thin line, that is, the total power consumed by charging with a constant current under non-ideal conditions is greater than the total power consumed by charging with a constant current under ideal conditions. Therefore, referring to steps S107 and S109 of the semi-finished battery cell testing method, when the total power consumed by the current charging at a constant current is obtained, the total power is compared with a power threshold. When the total power is greater than the power threshold, it means that the total power is greater than the power consumed by charging an ideal battery cell semi-finished product with a constant current. At this time, it is judged that the insulation degree of the battery cell semi-finished product is poor.
在一实施例中,预设时间区间Tdef2涵盖以定电压对电池芯半成品充电的时间区间的部分。也就是说,于图4B所示的实施例中,在由定电流充电切换为定电压充电的一段时间后才开始统计以定电流充电所消耗的总电量。于另一实施例中,在由定电流充电切换为定电压充电的同时触发相关测试电路统计以定电流充电所消耗的总电量。In one embodiment, the preset time interval Tdef2 covers a part of the time interval during which the semi-finished battery cell is charged with a constant voltage. That is to say, in the embodiment shown in FIG. 4B , after a period of time when the constant current charging is switched to the constant voltage charging, the total electricity consumed by the constant current charging is started to be counted. In another embodiment, when switching from constant current charging to constant voltage charging, a related test circuit is triggered to count the total power consumed by constant current charging.
请一并参照图4C,图4C为根据图2C对应实施例中以定电流对非理想的电池芯半成品充电所消耗的总电量的示意图。如图4C所示,以定电流对电池芯半成品10’充电的电流曲线下的区域可分别定义为区域a1与区域a2。区域a1的面积与区域a2的面积的和即为以定电流对电池芯半成品10’充电所消耗的总电量。在一实施例中,在本发明所提供的电池芯半成品测试方法中,例如可在时间点T4之后统计在时间点T4之前以定电流充电所消耗的所有总电量,相当于区域a1的面积与区域a2的面积的和,并据以进行判断。从另一个角度来说,相当于统计预设时间区间Tdef3中以定电流充电所消耗的所有总电量。于另一实施例中,例如可在每次由定电流充电切换为定电压充电时都进行一次统计与判断。就图4C来说,例如可分别取得区域a1的面积与区域a2的面积,再计算出区域a1的面积与区域a2的面积的和,并判断此和值是否大于电量门槛值。或者,分别取得区域a1的面积与区域a2的面积,再分别就区域a1的面积与区域a2的面积比较于相应的门槛值。其中,区域a1的面积对应的门槛值例如为前述的电量门槛值,区域a2的面积对应的门槛值例如为0或一极小的值。从另一个角度来说,相当于统计预设时间区间Tdef3’中以定电流充电所消耗的电量与预设时间区间Tdef3”中以定电流充电所消耗的电量,再据以取得所述的总电量以进行判断。Please also refer to FIG. 4C . FIG. 4C is a schematic diagram of the total power consumed by charging the semi-finished battery cell with a constant current according to the embodiment corresponding to FIG. 2C . As shown in FIG. 4C , the regions under the current curve of charging the semi-finished battery cell 10' with a constant current can be respectively defined as region a1 and region a2. The sum of the area of the area a1 and the area of the area a2 is the total amount of electricity consumed by charging the semi-finished battery cell 10' with a constant current. In one embodiment, in the method for testing the semi-finished product of a battery cell provided by the present invention, for example, after the time point T4, all the total power consumed by charging with a constant current before the time point T4 can be counted, which is equivalent to the area of the area a1 and The sum of the areas of the area a2 is determined. From another perspective, it is equivalent to counting all the total power consumed by charging with a constant current in the preset time interval Tdef3. In another embodiment, for example, each time the constant current charging is switched to the constant voltage charging, statistics and judgment may be performed once. 4C, for example, the area of the area a1 and the area of the area a2 can be obtained respectively, and then the sum of the area of the area a1 and the area of the area a2 can be calculated, and it is judged whether the sum is greater than the electricity threshold value. Alternatively, the area of the area a1 and the area of the area a2 are obtained respectively, and then the area of the area a1 and the area of the area a2 are respectively compared with the corresponding threshold values. The threshold value corresponding to the area of the area a1 is, for example, the aforementioned electric power threshold value, and the threshold value corresponding to the area of the area a2 is, for example, 0 or a very small value. From another perspective, it is equivalent to count the power consumed by charging with constant current in the preset time interval Tdef3' and the power consumed by charging with constant current in the preset time interval Tdef3", and then obtain the total power for judgment.
相应于图4C所述的实施例,于一实施例中,本发明所提供的电池芯半成品测试方法更可包含以下步骤,请参照图5,图5为根据本发明又一实施例所绘示的电池芯半成品测试方法的部分步骤的方法流程图。于步骤S201中,统计预设时间区间中以定电流充电的多个电流充电时间。于步骤S203中,依据定电流与电流充电时间取得多个电流充电电量。于步骤S205中,判断每一电流充电电量是否大于对应的电量门槛值,当电流充电电量其中之一大于对应的电量门槛值时,判断电池芯半成品的绝缘程度不良。Corresponding to the embodiment shown in FIG. 4C , in one embodiment, the method for testing a semi-finished battery cell provided by the present invention may further include the following steps. Please refer to FIG. 5 , which illustrates another embodiment of the present invention. The method flow chart of the partial steps of the battery cell semi-finished product testing method. In step S201, a plurality of current charging times charged at a constant current in a preset time interval are counted. In step S203, a plurality of current charging quantities are obtained according to the constant current and the current charging time. In step S205, it is judged whether each current charging power is greater than the corresponding power threshold, and when one of the current charging power is greater than the corresponding power threshold, it is judged that the insulation degree of the semi-finished battery cell is poor.
如前述地,于本发明所提供的电池芯半成品测试方法中,判断总电量是否大于电量门槛值QREF,藉以判断电池芯半成品的绝缘程度。在一实施例中,所述的电量门槛值QREF例如是一理论上的理想充电总量加上一容忍值,理想充电总量可以是从学理、制造工艺参数或是从经验得来,或者例如为前述以定电流对电池芯半成品10充电至电压门槛值VTH所需的总电量。容忍值的大小为本领域技术人员可以实际所需自行定义,在此并不加以限制。As mentioned above, in the battery cell semi-finished product testing method provided by the present invention, it is determined whether the total power is greater than the power threshold value QREF, so as to judge the insulation degree of the battery cell semi-finished product. In one embodiment, the power threshold value QREF is, for example, a theoretical ideal charge amount plus a tolerance value, and the ideal charge amount may be obtained from theory, manufacturing process parameters, or experience, or, for example, It is the total amount of electricity required to charge the
在另一实施例中,所述的电量门槛值QREF例如是对电池芯半成品充电多次,并取其中一次以定电流充电的实验充电总量加上一容忍值而成。请参照如图6以对此进行说明,图6为根据本发明另一实施例所绘示的对电池芯半成品充电时的电压差示意图。在图6绘示有参考时间区间Tref与实际测试区间Ttest,实际测试区间Ttest的相关细节如前述,于此不再赘述。于参考时间区间Tref进行相仿于实际测试区间Ttest的充电步骤。更具体地来说,参考时间区间Tref中定义有定电流充电区间CCref与定电压充电区间CVref,于参考时间区间Tref中,先于定电流充电区间CCref中以定电流对待测的电池芯半成品充电,直到待测的电池芯半成品的电压差不小于前述的电压门槛值VTH。于定电压充电区间CCref中,以定电压对待测的电池芯半成品充电。其中,参考时间区间Tref中以定电量流充电所消耗的总电量被作为一参考总电量。此参考总电量加上容忍值即为前述的电量门槛值QREFIn another embodiment, the power threshold value QREF is obtained by charging the semi-finished battery cell for many times, and adding a tolerance value to the total experimental charge of one charging at a constant current. Please refer to FIG. 6 to illustrate this. FIG. 6 is a schematic diagram of a voltage difference when charging a semi-finished battery cell according to another embodiment of the present invention. FIG. 6 shows the reference time interval Tref and the actual test interval Ttest. The relevant details of the actual test interval Ttest are as described above, and will not be repeated here. A charging step similar to the actual test interval Ttest is performed in the reference time interval Tref. More specifically, the reference time interval Tref defines a constant current charging interval CCref and a constant voltage charging interval CVref. In the reference time interval Tref, the semi-finished battery cell to be tested is charged with a constant current before the constant current charging interval CCref. , until the voltage difference of the semi-finished battery cell to be tested is not less than the aforementioned voltage threshold VTH. In the constant voltage charging interval CCref, the semi-finished battery cell to be tested is charged at a constant voltage. The total power consumed by charging with a constant current in the reference time interval Tref is used as a reference total power. This reference total power plus the tolerance value is the aforementioned power threshold value QREF
相应于图6所示的实施例,在一实施例中,本发明所提供的电池芯半成品测试方法更可包括以下步骤以产生电量门槛值QREF。请参照图7,图7为根据本发明另一实施例所绘示的电池芯半成品测试方法的部分步骤的方法流程图。于步骤S301中,于参考时间区间中,当第一导接部与第二导接部的电压差小于电压门槛值时,以定电流对电池芯半成品充电,参考时间区间先于预设时间区间。于步骤S303中,于参考时间区间中,当第一导接部与第二导接部的电压差大于等于电压门槛值时,以定电压对电池芯半成品充电。于步骤S305中,取得于参考时间区间中以定电流对电池芯半成品充电的参考总电量,电量门槛值为参考总电量加上容忍值。Corresponding to the embodiment shown in FIG. 6 , in an embodiment, the method for testing a semi-finished battery cell provided by the present invention may further include the following steps to generate a power threshold value QREF. Please refer to FIG. 7 . FIG. 7 is a method flow chart illustrating some steps of a method for testing a semi-finished battery cell according to another embodiment of the present invention. In step S301, in the reference time interval, when the voltage difference between the first conducting portion and the second conducting portion is smaller than the voltage threshold, the semi-finished battery cell is charged with a constant current, and the reference time interval is earlier than the preset time interval . In step S303, in the reference time interval, when the voltage difference between the first conducting portion and the second conducting portion is greater than or equal to the voltage threshold, the semi-finished battery cell is charged with a constant voltage. In step S305 , the reference total power for charging the semi-finished battery cell with a constant current in the reference time interval is obtained, and the power threshold value is the reference total power plus the tolerance value.
综合以上所述,本发明提出一种电池芯半成品测试方法,藉由判断以定电流对电池芯半成品充电的总充电量是否大于电量门槛值,以判别电池芯半成品的绝缘程度是否符合要求。藉此,不但节省了测试时间,对于单机产品来说更可连续多次地进行测试来比对不同测试下的测试状况。此外,比起以往只能侦测出是否有短路状况的定性分析手法,藉由总充电量来进行判断更提供了一种定量的分析手段,相当具有实用性。In view of the above, the present invention proposes a method for testing semi-finished battery cells, by judging whether the total charge amount of the semi-finished battery cells charged with a constant current is greater than the power threshold value, so as to determine whether the insulation degree of the semi-finished battery cells meets the requirements. In this way, not only the test time is saved, but for a stand-alone product, the test can be performed several times in a row to compare the test conditions under different tests. In addition, compared with the qualitative analysis method that can only detect whether there is a short circuit in the past, the judgment based on the total charge amount provides a quantitative analysis method, which is quite practical.
以下在实施方式中详细叙述本发明的详细特征以及优点,其内容足以使任何本领域技术人员了解本发明的技术内容并据以实施,且根据本说明书所公开的内容、权利要求保护范围及附图,任何本领域技术人员可轻易地理解本发明相关的目的及优点。以下的实施例进一步详细说明本发明的观点,但非以任何观点限制本发明的范畴。The detailed features and advantages of the present invention are described in detail below in the embodiments, and the content is sufficient to enable any person skilled in the art to understand the technical content of the present invention and implement it accordingly, and according to the content disclosed in this specification, the protection scope of the claims and the appendix Figures, any person skilled in the art can easily understand the related objects and advantages of the present invention. The following examples further illustrate the concept of the present invention in further detail, but are not intended to limit the scope of the present invention in any way.
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