CN108795541A - A kind of lubricant composition and preparation method thereof and its application method - Google Patents
A kind of lubricant composition and preparation method thereof and its application method Download PDFInfo
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- CN108795541A CN108795541A CN201810763487.7A CN201810763487A CN108795541A CN 108795541 A CN108795541 A CN 108795541A CN 201810763487 A CN201810763487 A CN 201810763487A CN 108795541 A CN108795541 A CN 108795541A
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
- C10M2203/06—Well-defined aromatic compounds
- C10M2203/065—Well-defined aromatic compounds used as base material
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
- C10M2205/0206—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers used as base material
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
- C10M2207/128—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids containing hydroxy groups; Ethers thereof
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/22—Heterocyclic nitrogen compounds
- C10M2215/223—Five-membered rings containing nitrogen and carbon only
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2217/04—Macromolecular compounds from nitrogen-containing monomers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2217/045—Polyureas; Polyurethanes
- C10M2217/0456—Polyureas; Polyurethanes used as thickening agents
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/10—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring
- C10M2219/102—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring containing sulfur and carbon only in the ring
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2227/00—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions
- C10M2227/06—Organic compounds derived from inorganic acids or metal salts
- C10M2227/061—Esters derived from boron
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2227/00—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions
- C10M2227/06—Organic compounds derived from inorganic acids or metal salts
- C10M2227/066—Organic compounds derived from inorganic acids or metal salts derived from Mo or W
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2010/00—Metal present as such or in compounds
- C10N2010/02—Groups 1 or 11
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/04—Detergent property or dispersant property
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/10—Inhibition of oxidation, e.g. anti-oxidants
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2050/00—Form in which the lubricant is applied to the material being lubricated
- C10N2050/10—Semi-solids; greasy
Abstract
The invention discloses a kind of lubricant composition and preparation method thereof and its application methods, belong to lubricating grease field.It includes thickening agent, further includes the base oil containing nonpolar alkyl naphthalenes oil and the additive with the compound packet of antifriction antiwear；Compound antifriction antiwear includes extreme pressure anti-wear additives, esters anti-friction agent and oil soluble polyether.Nonpolar alkyl naphthalenes oil and oil soluble polyether possess extremely strong dissolubility in the lubricating grease of the present invention, are fully dissolved to additive, are conducive to that antiwear and friction-reducing additive is allowed to play effect；Furthermore, a small amount of oil soluble polyether is used as additive, also has the effect of antifriction, there is remarkable antiwear and antifriction effect with lubricating grease under the synergistic effect of extreme pressure anti-wear additives and esters anti-friction agent in the compound packet of antifriction antiwear, is enabled, so that lubricating grease will not be aoxidized because of the high temperature of frictional heat, significantly extend the service life of lubricant composition, it is cost-effective in use, lubricating grease dosage is few in electric tool cylinder.
Description
Technical field
The invention belongs to lubricating grease fields, specifically, being related to a kind of lubricant composition and preparation method thereof and its making
Use method.
Background technology
Hmp grease currently used for electricity, pneumatic tool cylinder mainly has bentonite thickened agent lubricant grease, compound lithium base
Lubricating grease, polyurea grease and lithium base grease.Now it is widely used in the lubricating grease of cylinder：Bentonite, complex lithium grease,
Polyurea grease, can high temperature impact resistance, but since antiwear and friction reduction property is not sufficiently effective, and greasy property is not as good as lithium base grease,
For lubricating grease in cylinder barrel after piston ring continuous work, frictional heat amount is big, and temperature is often higher than 200 DEG C, after continuous high temperature use
Lubricating grease is easily hardened, and then easily generates coking carbon distribution, after long-term continue working, has cylinder barrel inner wall and pulls phenomenon, sternly
Ghost image rings the cylinder operation service life.
Phenomenon universal at present is poor with domestic extreme pressure compound lithium base grease extreme-pressure anti-wear antifriction performance, causes equipment
Frequent shutdown, greasing, influence production efficiency, improve production cost, and waste of energy pollutes environment, and more important is cause
Equipment is seriously worn, and improves the maintaining cost of equipment.Some Enterprises imported product (such as Mobil XHP222 thus
Lubricating grease) it is expensive, cost is too high.
In the prior art, the mechanical stability of lithium saponify is good, thixotropic property is excellent, but also due to antiwear and antifriction and antioxygen
Performance is insufficient, and leading to lubricant composition, service life is that the technology that this field is faced is asked less than 60h in the cylinder
Topic.
In order to solve easy oil dripping when lubricating grease uses at high temperature, loss is easy coking and carbon distribution, and causes equipment damage
The problem of, Chinese patent notification number：CN101445759B, the day for announcing：The patent document of 2012-01-11 discloses a kind of superelevation
Temperature lubricating grease and production method, lubricating grease include following components：Component ratio by mass number meter：The synthesizing ester oil is taken to be：
50~80 parts, SiO 2 powder be 1~10 part, antiwear additive is：1~5 part, graphite be：1~30 part, metal powder be：1~10
Part, boron nitride are：1~10 part, antioxidant be 0.1~0.5 part；SiO 2 powder is that the oleophylic of vapor phase method production is nano level
Silica；Graphite is aquadag, and aquadag granularity is：1~10 μm；The granularity of boron nitride is：1~20 μm；Gold
Belong to powder granularity be：50~200 μm；Antiwear additive is eutectic spin；Metal powder is copper powder or silver powder or bronze or iron powder or zinc
One or more of powder mixture；Synthesizing ester oil, SiO 2 powder are added in reaction kettle, agitated, heating,
Reaction, heat preservation；Antiwear additive, aquadag, metal powder, boron nitride, antioxidant is added, then is sufficiently stirred reflux；Filtering, is ground to
Finished product.The lubricating grease of the invention has a good high temperature resistance, under high temperature not oil dripping, will not be lost in, noncoking, not carbon distribution.By
In being thickened Esters oil using silica inorganic thickening agent, as basic lubricating grease, and a variety of high temperature additive graphite, gold is added
Belong to powder, boron nitride and be made, it is ensured that the lubrication under ultra-high temperature condition prevents bearing to be sintered；It disclosure satisfy that privileged sites, high temperature
The lubrication at position, and the service life of equipment can be extended.But the invention is only by organic synthesis Esters oil and inorganic material
Heat safe feature solves the problems, such as that lubricating grease is easy carbon distribution, without fundamentally solving lubricating grease antiwear and friction reduction property, and should
Metal powder etc. is added in lubricating grease, causes lubricating grease easily to aoxidize in use, after still be easy to causeing continuous high temperature use
Lubricating grease is easily hardened, and then easily generates coking carbon distribution, after long-term continue working, has equipment inner wall and pulls phenomenon, serious shadow
Ring service life of structure.
On the 11st nd Annual Meeting collection of Fuels And Lubricants branch of Chinese automobile Engineering society, Sinopec lubricating oil is public
Wear-resistant, the Mechanism of Friction Reduction present Research of lube oil additive are analyzed in director city application study center, and article shows various
Synergistic effect of the additive on extreme pressure anti-wear is significantly increased to the extruding abrasion resistance of lubricating grease, simple to use one or two kinds
Additive cannot meet using needs.In practical applications, often multiple additives are used in combination, and ZDDP is lubricating oil
In the most widely used additive, the research in relation to ZDDP and the composite performance of some other additive is also very much.Document is aobvious
Show, ZDDP exists with many additives such as borate, overbased sulfonate, organic-molybdenum salt in wear resistence cooperates with work well
With.
Chinese patent publication No.：CN108164559A, date of publication：The patent document of 2018-06-15 discloses a kind of sulfonation
Two (2- ethylhexyls)-phosphordithiic acid oxygen molybdenum extreme-pressure anti-wear anti-friction agents and the lubricating grease containing the anti-friction agent, this sulfonation
The mixing of two (2- ethylhexyls)-phosphordithiic acid oxygen molybdenum extreme-pressure anti-wear anti-friction agents is toluene, n-butanol, 2-Ethylhexyl Alcohol, heating
To 50 DEG C, adding phosphorus pentasulfide, to obtain celadon D2EHDTPA transparency liquid spare；Separately with sodium hydroxide solution, molybdenum trioxide
Reaction, after with sulfuric acid be acidified to pH value be 1.5 or so, the toluene solution of D2EHDTPA is added dropwise, is reacted at 90 DEG C at least 4 hours,
It is cooling, it filters, is fully washed with methanol, Tan solid extreme-pressure anti-wear anti-friction agent is obtained after dry.Then the extreme-pressure anti-wear is utilized
Anti-friction agent and other components prepare lubricating grease so that lubricating grease sintering load PD values can reach 400kgf, more similar than market
Product improves 20%-30%；Maximum nonseizure load PB value 121kgf, 10-15% is improved than market similar product.But
The invention has the following insufficient：1) wear-resistant friction reducer preparation process is complicated, is not easy to obtain；2) lubricating grease of the invention is only
Make the present invention by a kind of sulfonation two (2- ethylhexyls)-effect of anti-friction agent of phosphordithiic acid oxygen molybdenum extreme-pressure anti-wear anti-friction agent
Lubricating grease have higher extreme pressure and antiwear behavior, improve the service life of lubricating grease, reduce the abrasion to equipment, the profit
The performance indicator of consistent lubricant is still to be improved.
Invention content
1, it to solve the problems, such as
It is oxidizable when there is anti-wear and wear-resistant performance insufficient, applied at elevated temperature for lubricating grease in the prior art, this
A kind of lubricant composition of invention offer and preparation method thereof and its application method.The lubricating grease of the present invention is by additive and base
Synergistic effect between plinth oil and between each additive, significantly improves the antifriction antioxidant effect of lubricating grease, and friction coefficient is low
In common product in the market, the liter heat that piston ring is brought with cylinder barrel friction can be largely reduced, to reduce lubricating grease
The oxidation rate of composition ensures cylinder wall lubrication oil film thickness, the working life of cylinder is made to dramatically increase 2-20 times, uses this
The lubricant composition of invention can reduce dosage, save cost.
2, technical solution
To solve the above problems, the present invention adopts the following technical scheme that.
A kind of lubricant composition, including thickening agent further include the base oil containing nonpolar alkyl naphthalenes oil and are carried
The additive of the compound packet of antifriction antiwear；
The compound antifriction antiwear includes extreme pressure anti-wear additives, esters anti-friction agent and oil soluble polyether.
Preferably, the base oil is nonpolarity PAO synthetic oils, nonpolar alkyl naphthalenes oil and polarity Esters oil composition
Miscella；The extreme pressure anti-wear additives include ZnDTP, MoDTP one of which or both combination, the esters antifriction
Agent is that organic molybdates esters, organic boric acid ester or polyester are one such.
Preferably, the base oil, the thickening agent and the additive are based on following parts by weight：
100 parts of base oil
6-16 parts of thickening agent
2-35 parts of additive
Preferably, the weight accounting of nonpolar alkyl naphthalenes oil is 5%~36% in the base oil.
Preferably, the thickening agent is one kind in 12- hydroxy lithium stearates, lithium-complex, poly- carbamido thickening agent.
Preferably, the extreme pressure anti-wear additives further include having olefine sulfide.
Preferably, the additive further includes having one or more of antioxidant, matal deactivator and oiliness improver group
It closes.
Preferably, the antioxidant includes amine type antioxidant.
A kind of preparation method of lubricant composition, specifically includes following steps：
Step 1：The 30%~40% of whole base oil formula ratios is added in reaction kettle, is warming up to 70 DEG C~110 DEG C,
Thickening agent is added and carries out insulation reaction 1~4 hour；
Step 2：Composition in step 1 is warming up to 110 DEG C~130 DEG C again to be carried out dehydrating；
Step 3：200 DEG C~220 DEG C refinings are continuously heating to the composition in step 2 reaction kettle；
Step 4：Composition in step 3 is chilled to 70 DEG C~140 DEG C, additive and 30%~40% is added and matches
Side's amount base oil；
Step 5：Equal fat processing is carried out to the composition in step 4, the adjustment of 20%~40% formula ratio base oil is added
The cone penetration of lubricant composition obtains lubricating grease finished product to claimed range.
A kind of application method of lubricant composition, will before electric tool manufacture using lubricant composition obtained
The lubricant composition is applied to electric tool cylinder inner wall, and lubricating grease applying amount is the 1/3~2/3 of volume of cylinder.
3, advantageous effect
Compared with the prior art, beneficial effects of the present invention are：
(1) a kind of lubricant composition of the invention, including base oil, thickening agent and additive, wherein base oil select
An oily part based on nonpolar alkyl naphthalenes oil, compound antifriction antiwear in additive includes extreme pressure anti-wear additives, ester
Based friction reducing agent and oil soluble polyether, nonpolar alkyl naphthalenes oil and oil soluble polyether possess extremely strong dissolubility, on the one hand exist
Under the collaboration of the two, additive is fully dissolved, being more advantageous to allow has effects that the additive of antifriction antiwear property plays；
On the other hand, a small amount of oil soluble polyether is used as additive, it may have the effect of antifriction, in the compound packet of antifriction antiwear
Extreme pressure anti-wear additives and esters anti-friction agent synergistic effect under, enable lubricating grease that there is remarkable antiwear and antifriction effect so that
Lubricating grease will not be aoxidized because of the high temperature of frictional heat, significantly extend the service life of lubricant composition；
(2) a kind of lubricant composition of the invention, the nonpolar alkyl naphthalenes oil of use have additive splendid
Dissolubility and its own nonpolar characteristic, enable the additive in lubricant composition to be fully adsorbed in friction subtabulation
Face, the additive for being more advantageous to antifriction antiwear property play effect；Furthermore the naphthalene nucleus chemistry knot that nonpolar alkyl naphthalenes oil has
Structure, based on an oily part but also lubricant composition has remarkable antioxygenic property, ensure that cylinder lubricating oil
Film thickness makes the working life of cylinder dramatically increase 2-20 times, is up to for more than 200 a hours；
(3) a kind of lubricant composition of the invention selects nonpolarity PAO synthetic oils, nonpolar alkyl naphthalenes oil and pole
Property Esters oil miscella based on oil so that in practical electric tool life test, in the coking of piston and cylinder inner wall
Carbon deposit object greatly reduces compared with the lubricant for using other mineral base oils, Synthin base oil；And non-pole in base oil
Property alkyl naphthalenes oil weight accounting be 5%~36%, ensure lubricating grease miscella spatter property while, in turn ensure lubrication
Degree；
(4) a kind of lubricant composition of the invention, selects organic molybdates esters, organic boric acid ester, polyester as anti-friction agent
There is wear-resistant, antifriction, raising with extreme pressure anti-wear additives, such as thiophosphate, thiocarbamate, thiadiazolidine radical derivative
The synergistic effects such as extreme pressure value, esters anti-friction agent not sulfur-bearing, P elements reduce the usage amount of sulfate-phosphate class additive, therefore can
To reduce sulphur in lubricating grease, phosphorus and the content of metallic element, there is the good feature of environmental protection；
(5) a kind of lubricant composition of the invention selects 12- hydroxy lithium stearates, lithium-complex or the thickening of polyureas base
A kind of as thickening agent in agent, lithium base grease has multiple-effect long after added with antioxidant, antirust agent and extreme pressure agent
The characteristics of service life, and it is versatile, calcium-base grease and sodium base grease can be replaced；Poly- carbamido thickening agent both be free of metal from
Son breaches deficiency of the soap grease metal ion to base oil catalytic action, and has special crystal and colloform texture, right
Metal surface has extremely strong adhesive force, stable organic matter and oxide protective layer is generated in metal surface, it is therefore prevented that between metal
Be in direct contact, to reduce friction coefficient, greatly reduce abrasion；
(6) the amine type antioxidant of a kind of lubricant composition of the invention, selection has the longevity compared to other antioxidants
Long feature is ordered, and the generation of greasy filth carbon distribution can be slowed down；
(7) a kind of lubricant composition of the invention, extreme pressure anti-wear additives further include having olefine sulfide, under worst hot case,
When load is high, olefine sulfide can make up the short slab of the former other extreme pressure anti-wear additives as a kind of extreme pressure anti-wear additives, play anti-
Mill acts on, and provides safeguard for the normal work of lubricating grease；
(8) a kind of lubricant composition of the invention, additive further includes having antioxidant, matal deactivator and oiliness improver
One or more of combination, advanced optimize the performance of lubricating grease, improve the quality of lubricant composition, extend lubricating grease
Service life；
(9) application method of a kind of lubricant composition of the invention, it is of the invention under the requirement of identical lubrication task
Lubricant composition only needs to smear the 1/3~2/3 of volume of cylinder on electric tool cylinder inner wall, reduces cost.
Specific implementation mode
A kind of lubricant composition of the present invention, including thickening agent, further include the basis containing nonpolar alkyl naphthalenes oil
Oil and the additive with the compound packet of antifriction antiwear；Compound antifriction antiwear includes that extreme pressure anti-wear additives, esters anti-friction agent and oil are molten
Property polyethers.Base oil, thickening agent and additive are based on following parts by weight：
100 parts of base oil
6-16 parts of thickening agent
2-35 parts of additive
The present invention is added oil soluble polyether as additive, and dosage is smaller；And by oil soluble polyether and nonpolar alkane
Synergistic effect between base naphthalenes oil allow lubricant composition have extremely strong dissolubility, it is compound to antifriction antiwear packet and other add
Add agent fully to dissolve, ensures the lubricant composition of the present invention in technique at 40 DEG C, kinematic viscosity 12mm2/s-9000mm2/
S, forms lubricating film between the parts surface of relative motion at this time, and the OK range of kinematic viscosity makes lubricating film both will not be because
It is excessively thin so that electric tool is from operating, will not be blocked up because of oil film, cold-starting encounters difficulties, and the generation of oil film will not be with
Additive generates competitive Adsorption so that metal friction subtabulation can be farthest adsorbed in by playing the additive of antiwear and antifriction
Face, the lubricating film reduce the generation overheated between friction, abrasion and moving component so that the antiwear and antifriction of lubricant composition
Significant effect is promoted, and the presence of lubricating film reduces the temperature of cylinder surfaces, and then reduces the formation of coking carbon deposit.With this
Meanwhile the friction coefficient of polar oil soluble polyether itself is extremely low, has effects that antifriction；One as the compound packet of antifriction antiwear
It is mutually cooperateed between part, oil soluble polyether and extreme pressure anti-wear additives and esters anti-friction agent, enables lubricating grease that there is the wear-resistant of brilliance
Friction reducing effect significantly extends lubricant composition so that lubricating grease will not be aoxidized because of the high temperature of frictional heat
Service life.
And polyethers can be decomposed into the mixture of alkylene oxides organic matter, strand relative growth, with existing profit at high temperature
Low component is volatile in consistent lubricant, and high component is easy carbonization, coking is compared, and the oil-soluble that lubricant composition of the invention is added is poly-
Ether sacrifices the characteristic of oneself as additive so that lubricant composition hardly stays carbon distribution when in use.And nonpolar alkyl
The naphthalene nucleus chemical constitution that naphthalenes oil has, based on an oily part but also lubrication group composition have it is remarkable anti-oxidant
Performance ensure that cylinder lubrication oil film thickness, and the working life of cylinder is made to dramatically increase 2-20 times, be up to for more than 200 a hours.
It should also be noted that, by test of many times, base oil selection passes through nonpolarity PAO synthetic oils, nonpolar alkyl
The miscella of naphthalenes oil and polarity Esters oil composition possesses preferable antiwear and antifriction effect；Extreme pressure anti-wear additives select abrasion resistance excellent
Different ZnDTP, MoDTP one of which or both combines.
During cylinder continuous work, due to frictional heat, so that heat has little time the heat exchange with lubricant to consume
It dissipates, internal cylinder temperature can exceed that 200 DEG C.As a result, the coking carbon deposit object on piston and cylinder surface is largely formed, Jin Erke
To lead to the ring bonding or ultimate failure of such as piston ring.The additive of lubricant composition conventionally used for cylinder such as sulfate
Ash content, phosphate ash content, sulphur and phosphorus concentrate may play the role of cylinder in-lubricant catalysis oxidation and aggravation coking product
The increase of charcoal adversely affects the spatter property of cylinder, it is therefore desirable to reduce in electric tool cylinder and be formed on piston knot
Burnt carbon deposit object.The esters anti-friction agent of the present invention selects not phosphorous, element sulphur organic molybdates esters, organic boric acid ester or polyester wherein
One kind, reduce the usage amount of sulfate-phosphate class additive, therefore containing for sulphur in lubricating grease, phosphorus and metallic element can be reduced
Amount has the good feature of environmental protection.And experiment and user experience are found, it is a certain proportion of non-when being added in lubricant composition
Polarity alkyl naphtalene oil in electric tool life test, in the coking carbon deposit object of piston and cylinder inner wall and uses it in wherein
His mineral base oil, Synthin base oil lubricant compared to greatly reducing.Nonpolar alkyl naphthalene in the base oil of the present invention
The weight accounting of class oil is 5%~36%, and further ensures the spatter property of lubricant composition, is primarily due in height
Under warm working condition, the high easily junction coke carbon distribution of hydrocarbon accounting；But too high levels also result in lubricant composition
Lubricity is insufficient.
The preparation method of the lubricant composition of the present invention, specifically includes following steps：
Step 1：The 30%~40% of whole base oil formula ratios is added in reaction kettle, is warming up to 70 DEG C~110 DEG C,
Thickening agent is added and carries out insulation reaction 1~4 hour；
Step 2：Composition in step 1 is warming up to 110 DEG C~130 DEG C again to be carried out dehydrating；
Step 3：200 DEG C~220 DEG C refinings are continuously heating to the composition in step 2 reaction kettle；
Step 4：Composition in step 3 is chilled to 70 DEG C~140 DEG C, additive and 30%~40% is added and matches
Side's amount base oil；Base oil of this step oil-soluble polyethers as additive at this moment with 30%~40% is added together；
Step 5：Equal fat processing is carried out to the composition in step 4, the adjustment of 20%~40% formula ratio base oil is added
The cone penetration of lubricant composition obtains lubricating grease finished product to claimed range, in order to meet lubricant composition in cylinder
Mobility, resistance of start when returning to work after overcoming cylinder to stop work, the cone penetration of lubricant composition is between 28mm~38.5mm
It is more suitable.
Lubricant composition when in use, before electric tool manufacture, is applied to electricity by the lubricant composition of the present invention
Power driven tools cylinder inner wall, lubricating grease applying amount are the 1/3~2/3 of volume of cylinder.After cylinder works long hours, lubricating grease can damage
Consumption, a small amount of lubricating grease for staying in participation friction, lubrication between the lubricating grease in cylinder, especially piston ring and cylinder inner wall are working
State possible coking carbon deposit at a high temperature of generating increases resistance for cylinder inner wall friction, further also increases lubricant loss.?
Using same weight lubricating grease when, lubricant composition of the invention because performance raising, have lower friction coefficient,
And there are remarkable antioxygenic property and detergent-dispersant performance, generate indivisible coking, lubricant composition of the invention is than general
There is longer lubrication interval in the case of the same dosage of logical lubricating grease, so as to postpone supplemental lubrication fat, reduce lubrication
Fat dosage, and lubricant effect more more excellent than common lubricant fat can be obtained.
With reference to specific embodiment, the present invention will be described in detail.
First test group：
Embodiment 1
A kind of lubricant composition of the present embodiment, including poly- carbamido thickening agent 195g；
Further include base oil 3000g, wherein nonpolar alkyl naphtalene oil accounts for 30%, is 900g, nonpolar PAO synthetic oils and pole
Property Esters oil takes 1800g and 300g respectively；
Further include the additive with the compound packet of antifriction antiwear, wherein extreme-pressure wear-resistant agent selects ZnDTP30g, organic molybdic acid
Ester 18g, oil soluble polyether 360g.To advanced optimize the performance of lubricating grease, the quality of lubricant composition is improved, lubrication is extended
Amine antioxidants 36g is added in the service life of fat, the present embodiment, and benzotriazole derivative 3g, oiliness improver 18g, wherein antioxidant are removed
Amine antioxidants, can also be phenol type antioxidant, phenol amine type antioxidant, sulphur phosphorous antioxidant, dialkyl dithio amino first
One or more of acid esters antioxidant is composed, can also be by alkyl diphenylamine, double dodecyl diphenylamines, octyl/
One or more of amyl diphenylamines, dioctyl diphenylamine, 2,6-di-tert-butyl p-cresol and thiobisphenol are composed,
This is not described one by one, and amine type antioxidant has the characteristics that long lifespan, and can slow down greasy filth carbon distribution compared to other antioxidants
Generation；Benzotriazole derivative is one kind of matal deactivator, and matal deactivator can be benzotriazole derivative, thiadiazoles alkyl
One or both of derivative combines, and does not describe one by one herein；Lubricating grease when in use, mainly connects with metallic rubbing pairs
It touches, therefore lubricant composition also needs to play antirust, anti-corrosive to metal first, therefore antirust agent 30g is added；Under worst hot case,
When load is high, to ensure that the normal work of lubricant composition, lubricant composition of the invention are additionally added olefine sulfide
60g, olefine sulfide can make up the former other extreme pressure anti-wear additives as a kind of extreme pressure anti-wear additives and be possible to failure at high temperature
Short slab plays wear-resistant effect.
A kind of preparation method of lubricant composition of the present embodiment, specifically includes following steps：
Step 1：The 3000g base oils for allocating the present embodiment, by the mixed base oil formula ratio formed in the present embodiment
30%, i.e. 900g are added in reaction kettle, are warming up to 70 DEG C, and poly- carbamido thickening agent is added and carries out insulation reaction 1 hour；
Step 2：Composition in step 1 is warming up to 110 DEG C again to be carried out dehydrating；
Step 3：200 DEG C of refinings are continuously heating to the composition in step 2 reaction kettle；
Step 4：Composition in step 3 is chilled to 70 DEG C, adds all additives and 900g in the present embodiment
Formula ratio base oil；
Step 5：Equal fat processing is carried out to the composition in step 4, that is, remaining 1200g base oils adjustment lubrication is added
The cone penetration of oil/fat composition is 36mm at 25 DEG C, obtains lubricating grease finished product.
Lubricant composition when in use, is applied to electric tool cylinder inner wall by the lubricant composition of the present invention, is applied
The amount of smearing is the 1/3 of volume of cylinder, and carries out life test to lubricant composition, and sintering load reaches 450kgf.
Performance characterization, testing machine test load are carried out to the lubricant composition of the present embodiment by friction wear testing machine
40kgf, rotating speed 1200rpm, Oil-temperature control test 60min, obtain the friction coefficient of the lubricant composition of the present embodiment at 75 DEG C
It is 0.054, wear scar diameter 0.576mm.
Embodiment 2
A kind of lubricant composition of the present embodiment, including 12- hydroxy lithium stearate thickening agents 360g；
Further include base oil 3000g, wherein nonpolar alkyl naphtalene oil accounts for 19%, is 570g, nonpolar PAO synthetic oils and pole
Property Esters oil takes 2130g and 300g respectively；
Further include the additive with the compound packet of antifriction antiwear, wherein extreme-pressure wear-resistant agent selects MoDTP60g, organic boronic
Ester 39g, oil soluble polyether 210g；Amine antioxidants 36g, benzotriazole derivative 3g, oiliness improver 18g, antirust agent 30g；Vulcanize alkene
Hydrocarbon 75g.
A kind of preparation method of lubricant composition of the present embodiment, specifically includes following steps：
Step 1：The 3000g base oils for allocating the present embodiment, by the mixed base oil formula ratio formed in the present embodiment
35%, i.e. 1050g are added in reaction kettle, are warming up to 90 DEG C, and 12- hydroxy lithium stearate thickening agents are added and carry out insulation reaction 2.5
Hour；
Step 2：Composition in step 1 is warming up to 120 DEG C again to be carried out dehydrating；
Step 3：210 DEG C of refinings are continuously heating to the composition in step 2 reaction kettle；
Step 4：Composition in step 3 is chilled to 105 DEG C, add in the present embodiment all additives and
1050g formula ratio base oils；
Step 5：Equal fat processing is carried out to the composition in step 4, that is, remaining 900g base oils adjustment lubrication is added
The cone penetration of oil/fat composition is 28.1mm at 25 DEG C, obtains lubricating grease finished product.
Lubricant composition when in use, is applied to electric tool cylinder inner wall by the lubricant composition of the present invention, is applied
The amount of smearing is the 1/2 of volume of cylinder, and carries out life test to lubricant composition, and sintering load reaches 520kgf.
Performance characterization, testing machine test load are carried out to the lubricant composition of the present embodiment by friction wear testing machine
40kgf, rotating speed 1200rpm, Oil-temperature control test 60min, obtain the friction coefficient of the lubricant composition of the present embodiment at 75 DEG C
It is 0.059, wear scar diameter 0.525mm.
Embodiment 3
A kind of lubricant composition of the present embodiment, including lithium-complex thickening agent 480g；
Further include base oil 3000g, wherein nonpolar alkyl naphtalene oil accounts for 6%, is 180g, nonpolar PAO synthetic oils and pole
Property Esters oil takes 2520g and 300g respectively；
Further include the additive with the compound packet of antifriction antiwear, wherein extreme-pressure wear-resistant agent selects ZnDTP75g, it should be noted that
Be composition that extreme-pressure wear-resistant agent can also select both ZnDTP and MoDTP, do not describe one by one herein.Polyester 150g, oil are molten
Property polyethers 90g；Amine antioxidants 36g, benzotriazole derivative 3g, oiliness improver 18g, antirust agent 30g；Olefine sulfide 105g.
A kind of preparation method of lubricant composition of the present embodiment, specifically includes following steps：
Step 1：The 3000g base oils for allocating the present embodiment, by the mixed base oil formula ratio formed in the present embodiment
40%, i.e. 1200g are added in reaction kettle, are warming up to 110 DEG C, and lithium-complex thickening agent is added and carries out insulation reaction 4 hours；
Step 2：Composition in step 1 is warming up to 130 DEG C again to be carried out dehydrating；
Step 3：220 DEG C of refinings are continuously heating to the composition in step 2 reaction kettle；
Step 4：Composition in step 3 is chilled to 140 DEG C, add in the present embodiment all additives and
1200g formula ratio base oils；
Step 5：Equal fat processing is carried out to the composition in step 4, that is, remaining 600g base oils adjustment lubrication is added
The cone penetration of oil/fat composition is 33.4mm at 25 DEG C, obtains lubricating grease finished product.
Lubricant composition when in use, is applied to electric tool cylinder inner wall by the lubricant composition of the present invention, is applied
The amount of smearing is the 2/3 of volume of cylinder, and carries out life test to lubricant composition, and sintering load reaches 620kgf.
Performance characterization, testing machine test load are carried out to the lubricant composition of the present embodiment by friction wear testing machine
40kgf, rotating speed 1200rpm, Oil-temperature control test 60min, obtain the friction coefficient of the lubricant composition of the present embodiment at 75 DEG C
It is 0.068, wear scar diameter 0.503mm.
The performance characterization of 1 first test group lubricant composition of table
Second test group：
Embodiment 4
A kind of lubricant composition of the present embodiment, including poly- carbamido thickening agent 180g；
Further include base oil 3000g, wherein nonpolar alkyl naphtalene oil accounts for 5%, is 150g, nonpolar mineral oil and polarity ester
Class oil does not take 1650g and 1200g；
Further include the additive with the compound packet of antifriction antiwear, wherein extreme-pressure wear-resistant agent selects ZnDTP30g, organic molybdic acid
Ester 18g, oil soluble polyether 360g；Amine antioxidants 36g, benzotriazole derivative 3g, oiliness improver 18g, antirust agent 30g；Vulcanize alkene
Hydrocarbon 60g.
A kind of preparation method of lubricant composition of the present embodiment, specifically includes following steps：
Step 1：The 3000g base oils for allocating the present embodiment, by the mixed base oil formula ratio formed in the present embodiment
30%, i.e. 900g are added in reaction kettle, are warming up to 70 DEG C, and poly- carbamido thickening agent is added and carries out insulation reaction 1 hour；
Step 2：Composition in step 1 is warming up to 110 DEG C again to be carried out dehydrating；
Step 3：200 DEG C of refinings are continuously heating to the composition in step 2 reaction kettle；
Step 4：Composition in step 3 is chilled to 70 DEG C, adds all additives and 900g in the present embodiment
Formula ratio base oil；
Step 5：Equal fat processing is carried out to the composition in step 4, that is, remaining 1200g base oils adjustment lubrication is added
The cone penetration of oil/fat composition is 36mm at 25 DEG C, obtains lubricating grease finished product.
Lubricant composition when in use, is applied to electric tool cylinder inner wall by the lubricant composition of the present invention, is applied
The amount of smearing is the 1/3 of volume of cylinder, and carries out life test, sintering load 390kgf to lubricant composition.
Performance characterization, testing machine test load are carried out to the lubricant composition of the present embodiment by friction wear testing machine
40kgf, rotating speed 1200rpm, Oil-temperature control test 60min, obtain the friction coefficient of the lubricant composition of the present embodiment at 75 DEG C
It is 0.072, wear scar diameter 0.608mm.
Embodiment 5
A kind of lubricant composition of the present embodiment, including poly- carbamido thickening agent 360g；
Further include base oil 3000g, wherein nonpolar alkyl naphtalene oil accounts for 20%, is 600g, nonpolar mineral oil and polarity
Esters oil takes 1650g and 750g respectively；
Further include the additive with the compound packet of antifriction antiwear, wherein extreme-pressure wear-resistant agent selects ZnDTP60g, organic boronic
Ester 69g, oil soluble polyether 210g；Amine antioxidants 36g, benzotriazole derivative 3g, oiliness improver 18g, antirust agent 30g；Vulcanize alkene
Hydrocarbon 75g.
A kind of preparation method of lubricant composition of the present embodiment, specifically includes following steps：
Step 1：The 3000g base oils for allocating the present embodiment, by the mixed base oil formula ratio formed in the present embodiment
35%, i.e. 1050g are added in reaction kettle, are warming up to 90 DEG C, and 12- hydroxy lithium stearate thickening agents are added and carry out insulation reaction 2.5
Hour；
Step 2：Composition in step 1 is warming up to 120 DEG C again to be carried out dehydrating；
Step 3：210 DEG C of refinings are continuously heating to the composition in step 2 reaction kettle；
Step 4：Composition in step 3 is chilled to 105 DEG C, add in the present embodiment all additives and
1050g formula ratio base oils；
Step 5：Equal fat processing is carried out to the composition in step 4, that is, remaining 900g base oils adjustment lubrication is added
The cone penetration of oil/fat composition is 30.2mm at 25 DEG C, obtains lubricating grease finished product.
Lubricant composition when in use, is applied to electric tool cylinder inner wall by the lubricant composition of the present invention, is applied
The amount of smearing is the 1/2 of volume of cylinder, and carries out life test to lubricant composition, and sintering load reaches 480kgf.
Performance characterization, testing machine test load are carried out to the lubricant composition of the present embodiment by friction wear testing machine
40kgf, rotating speed 1200rpm, Oil-temperature control test 60min, obtain the friction coefficient of the lubricant composition of the present embodiment at 75 DEG C
It is 0.078, wear scar diameter 0.614mm.
Embodiment 6
A kind of lubricant composition of the present embodiment, including lithium-complex thickening agent 480g；
Further include base oil 3000g, wherein nonpolar alkyl naphtalene oil accounts for 30%, is 900g, nonpolar mineral oil and polarity
Esters oil takes 1650g and 450g respectively；
Further include the additive with the compound packet of antifriction antiwear, wherein extreme-pressure wear-resistant agent selects ZnDTP75g, polyester 150g,
Oil soluble polyether 90g；Amine antioxidants 36g, benzotriazole derivative 3g, oiliness improver 18g, antirust agent 30g；Olefine sulfide 105g.
A kind of preparation method of lubricant composition of the present embodiment, specifically includes following steps：
Step 1：The 3000g base oils for allocating the present embodiment, by the mixed base oil formula ratio formed in the present embodiment
40%, i.e. 1200g are added in reaction kettle, are warming up to 110 DEG C, and lithium-complex thickening agent is added and carries out insulation reaction 4 hours；
Step 2：Composition in step 1 is warming up to 130 DEG C again to be carried out dehydrating；
Step 3：220 DEG C of refinings are continuously heating to the composition in step 2 reaction kettle；
Step 4：Composition in step 3 is chilled to 140 DEG C, add in the present embodiment all additives and
1200g formula ratio base oils；
Step 5：Equal fat processing is carried out to the composition in step 4, that is, remaining 600g base oils adjustment lubrication is added
The cone penetration of oil/fat composition is 33.1mm at 25 DEG C, obtains lubricating grease finished product.
Lubricant composition when in use, is applied to electric tool cylinder inner wall by the lubricant composition of the present invention, is applied
The amount of smearing is the 2/3 of volume of cylinder, and carries out life test to lubricant composition, and sintering load reaches 540kgf.
Performance characterization, testing machine test load are carried out to the lubricant composition of the present embodiment by friction wear testing machine
40kgf, rotating speed 1200rpm, Oil-temperature control test 60min, obtain the friction coefficient of the lubricant composition of the present embodiment at 75 DEG C
It is 0.085, wear scar diameter 0.667mm.
The performance characterization of 2 second test group lubricant composition of table
Third test group：
Embodiment 7
A kind of lubricant composition of the present embodiment, including poly- carbamido thickening agent 180g；
Further include base oil 3000g, wherein nonpolar alkyl naphtalene oil accounts for 36%, is 1080g, and nonpolar PAO synthetic oils take
1920g；
Further include the additive with the compound packet of antifriction antiwear, wherein extreme-pressure wear-resistant agent selects ZnDTP30g, organic molybdic acid
Ester 18g, oil soluble polyether 330g；Amine antioxidants 36g, benzotriazole derivative 3g, oiliness improver 18g, antirust agent 30g；Vulcanize alkene
Hydrocarbon 60g.
A kind of preparation method of lubricant composition of the present embodiment, specifically includes following steps：
Step 1：The 3000g base oils for allocating the present embodiment, by the mixed base oil formula ratio formed in the present embodiment
30%, i.e. 900g are added in reaction kettle, are warming up to 70 DEG C, and poly- carbamido thickening agent is added and carries out insulation reaction 1 hour；
Step 2：Composition in step 1 is warming up to 110 DEG C again to be carried out dehydrating；
Step 3：200 DEG C of refinings are continuously heating to the composition in step 2 reaction kettle；
Step 4：Composition in step 3 is chilled to 70 DEG C, adds all additives and 900g in the present embodiment
Formula ratio base oil；
Step 5：Equal fat processing is carried out to the composition in step 4, that is, remaining 1200g base oils adjustment lubrication is added
The cone penetration of oil/fat composition is 36mm at 25 DEG C, obtains lubricating grease finished product.
Lubricant composition when in use, is applied to electric tool cylinder inner wall by the lubricant composition of the present invention, is applied
The amount of smearing is the 1/3 of volume of cylinder, and carries out life test to lubricant composition, and sintering load reaches 430kgf.
Performance characterization, testing machine test load are carried out to the lubricant composition of the present embodiment by friction wear testing machine
40kgf, rotating speed 1200rpm, Oil-temperature control test 60min, obtain the friction coefficient of the lubricant composition of the present embodiment at 75 DEG C
It is 0.056, wear scar diameter 0.575mm.
Embodiment 8
A kind of lubricant composition of the present embodiment, including 12- hydroxy lithium stearate thickening agents 360g；
Further include base oil 3000g, wherein nonpolar alkyl naphtalene oil accounts for 22%, is 660g, and nonpolar PAO synthetic oils take
2340g；
Further include the additive with the compound packet of antifriction antiwear, wherein extreme-pressure wear-resistant agent selects MoDTP60g, organic boronic
Ester 69g, oil soluble polyether 210g；Amine antioxidants 36g, benzotriazole derivative 3g, oiliness improver 18g, antirust agent 30g；Vulcanize alkene
Hydrocarbon 75g.
A kind of preparation method of lubricant composition of the present embodiment, specifically includes following steps：
Step 1：The 3000g base oils for allocating the present embodiment, by the mixed base oil formula ratio formed in the present embodiment
35%, i.e. 1050g are added in reaction kettle, are warming up to 90 DEG C, and 12- hydroxy lithium stearate thickening agents are added and carry out insulation reaction 2.5
Hour；
Step 2：Composition in step 1 is warming up to 120 DEG C again to be carried out dehydrating；
Step 3：210 DEG C of refinings are continuously heating to the composition in step 2 reaction kettle；
Step 4：Composition in step 3 is chilled to 105 DEG C, add in the present embodiment all additives and
1050g formula ratio base oils；
Step 5：Equal fat processing is carried out to the composition in step 4, that is, remaining 900g base oils adjustment lubrication is added
The cone penetration of oil/fat composition is 31.2mm at 25 DEG C, obtains lubricating grease finished product.
Lubricant composition when in use, is applied to electric tool cylinder inner wall by the lubricant composition of the present invention, is applied
The amount of smearing is the 1/2 of volume of cylinder, and carries out life test to lubricant composition, and sintering load reaches 490kgf.
Performance characterization, testing machine test load are carried out to the lubricant composition of the present embodiment by friction wear testing machine
40kgf, rotating speed 1200rpm, Oil-temperature control test 60min, obtain the friction coefficient of the lubricant composition of the present embodiment at 75 DEG C
It is 0.065, wear scar diameter 0.523mm.
Embodiment 9
A kind of lubricant composition of the present embodiment, including lithium-complex thickening agent 480g；
Further include base oil 3000g, wherein nonpolar alkyl naphtalene oil accounts for 5%, is 150g, and nonpolar PAO synthetic oils take
2850g；
Further include the additive with the compound packet of antifriction antiwear, wherein extreme-pressure wear-resistant agent selects ZnDTP75g, polyester 150g,
Oil soluble polyether 90g；Amine antioxidants 36g, benzotriazole derivative 3g, oiliness improver 18g, antirust agent 30g；Olefine sulfide 105g.
A kind of preparation method of lubricant composition of the present embodiment, specifically includes following steps：
Step 1：The 3000g base oils for allocating the present embodiment, by the mixed base oil formula ratio formed in the present embodiment
40%, i.e. 1200g are added in reaction kettle, are warming up to 110 DEG C, and lithium-complex thickening agent is added and carries out insulation reaction 4 hours；
Step 2：Composition in step 1 is warming up to 130 DEG C again to be carried out dehydrating；
Step 3：220 DEG C of refinings are continuously heating to the composition in step 2 reaction kettle；
Step 4：Composition in step 3 is chilled to 140 DEG C, add in the present embodiment all additives and
1200g formula ratio base oils；
Step 5：Equal fat processing is carried out to the composition in step 4, that is, remaining 600g base oils adjustment lubrication is added
The cone penetration of oil/fat composition is 33.8mm at 25 DEG C, obtains lubricating grease finished product.
Lubricant composition when in use, is applied to electric tool cylinder inner wall by the lubricant composition of the present invention, is applied
The amount of smearing is the 2/3 of volume of cylinder, and carries out life test to lubricant composition, and sintering load reaches 570kgf.
Performance characterization, testing machine test load are carried out to the lubricant composition of the present embodiment by friction wear testing machine
40kgf, rotating speed 1200rpm, Oil-temperature control test 60min, obtain the friction coefficient of the lubricant composition of the present embodiment at 75 DEG C
It is 0.077, wear scar diameter 0.501mm.
The performance characterization of 3 third test group lubricant composition of table
Control group：
Comparative example 1
This comparative example component proportion is substantially the same manner as Example 1, except that the base oil of this comparative example is by 2550g's
Nonpolar PAO synthetic oils and 450g polarity Esters oils composition.
A kind of preparation method of lubricant composition of this comparative example, specifically includes following steps：
Step 1：The 3000g base oils for allocating this comparative example, by the mixed base oil formula ratio formed in this comparative example
30%, i.e. 900g are added in reaction kettle, are warming up to 70 DEG C, and poly- carbamido thickening agent is added and carries out insulation reaction 1 hour；
Step 2：Composition in step 1 is warming up to 110 DEG C again to be carried out dehydrating；
Step 3：200 DEG C of refinings are continuously heating to the composition in step 2 reaction kettle；
Step 4：Composition in step 3 is chilled to 70 DEG C, adds all additives and 900g in this comparative example
Formula ratio base oil；
Step 5：Equal fat processing is carried out to the composition in step 4, that is, remaining 1200g base oils adjustment lubrication is added
The cone penetration of oil/fat composition is 35.8mm at 25 DEG C, obtains lubricating grease finished product.
Lubricant composition when in use, is applied to electric tool cylinder inner wall by the lubricant composition of the present invention, is applied
The amount of smearing is the 1/3 of volume of cylinder, and carries out life test to lubricant composition, and sintering load reaches 450kgf.
Performance characterization, testing machine test load are carried out to the lubricant composition of this comparative example by friction wear testing machine
40kgf, rotating speed 1200rpm, Oil-temperature control test 60min, obtain the friction coefficient of the lubricant composition of this comparative example at 75 DEG C
It is 0.084, wear scar diameter 0.584mm.
Comparative example 2
This comparative example component proportion is substantially the same manner as Example 4, except that the base oil of this comparative example is by 2250g's
Nonpolar mineral oil and 750g polarity Esters oils composition.
A kind of preparation method of lubricant composition of the present embodiment, specifically includes following steps：
Step 1：The 3000g base oils for allocating the present embodiment, by the mixed base oil formula ratio formed in the present embodiment
30%, i.e. 900g are added in reaction kettle, are warming up to 70 DEG C, and poly- carbamido thickening agent is added and carries out insulation reaction 1 hour；
Step 2：Composition in step 1 is warming up to 110 DEG C again to be carried out dehydrating；
Step 3：200 DEG C of refinings are continuously heating to the composition in step 2 reaction kettle；
Step 4：Composition in step 3 is chilled to 70 DEG C, adds all additives and 900g in the present embodiment
Formula ratio base oil；
Step 5：Equal fat processing is carried out to the composition in step 4, that is, remaining 1200g base oils adjustment lubrication is added
The cone penetration of oil/fat composition is 28.6mm at 25 DEG C, obtains lubricating grease finished product.
Lubricant composition when in use, is applied to electric tool cylinder inner wall by the lubricant composition of the present invention, is applied
The amount of smearing is the 1/3 of volume of cylinder, and carries out life test, sintering load 480kgf to lubricant composition.
Performance characterization, testing machine test load are carried out to the lubricant composition of the present embodiment by friction wear testing machine
40kgf, rotating speed 1200rpm, Oil-temperature control test 60min, obtain the friction coefficient of the lubricant composition of the present embodiment at 75 DEG C
It is 0.081, wear scar diameter 0.56mm.
Comparative example 3
This comparative example component proportion is substantially the same manner as Example 9, except that the base oil of this comparative example is 3000g's
Nonpolar PAO synthetic oils.
A kind of preparation method of lubricant composition of this comparative example, specifically includes following steps：
Step 1：The 3000g base oils for allocating this comparative example, by the mixed base oil formula ratio formed in this comparative example
40%, i.e. 1200g are added in reaction kettle, are warming up to 110 DEG C, and lithium-complex thickening agent is added and carries out insulation reaction 4 hours；
Step 2：Composition in step 1 is warming up to 130 DEG C again to be carried out dehydrating；
Step 3：220 DEG C of refinings are continuously heating to the composition in step 2 reaction kettle；
Step 4：Composition in step 3 is chilled to 140 DEG C, add in this comparative example all additives and
1200g formula ratio base oils；
Step 5：Equal fat processing is carried out to the composition in step 4, that is, remaining 600g base oils adjustment lubrication is added
The cone penetration of oil/fat composition is 33.2mm at 25 DEG C, obtains lubricating grease finished product.
Lubricant composition when in use, is applied to electric tool cylinder inner wall by the lubricant composition of the present invention, is applied
The amount of smearing is the 2/3 of volume of cylinder, and carries out life test to lubricant composition, and sintering load reaches 610kgf.
Performance characterization, testing machine test load are carried out to the lubricant composition of this comparative example by friction wear testing machine
40kgf, rotating speed 1200rpm, Oil-temperature control test 60min, obtain the friction coefficient of the lubricant composition of this comparative example at 75 DEG C
It is 0.094, wear scar diameter 0.578mm.
The performance characterization of 4 control group lubricant composition of table
Friction coefficient is relatively low in each embodiment of first test group, and sintering load is high, function admirable；Second test group
Each embodiment nonpolarity PAO synthetic oils are replaced using nonpolar mineral oil, because nonpolar mineral oil is closed relative to nonpolar PAO
Can be relatively low at oil lubricity, therefore friction coefficient is higher；Lubricant composition in each embodiment of third test group is not added
Polarity Esters oil causes the lubricity of lubricating grease inadequate, and opposite first test group, friction coefficient is improved to some extent.But
It is that whether nonpolar alkyl naphthalenes oil is added in the first test group, the second test group or third test group in base oil,
It can be seen by the content of table 1, table 2, table 3, compared with table 4, the lubricant compositions of three test groups all has lower
Friction coefficient, sintering load are also relatively high.
Cylinder is added to foregoing grease composition and carries out ultimate life test：
A, test condition：Cylinder continuous operation records cylinder continuous operation hourage, and dismantles cylinder and watch cylinder inner wall
Coking carbon distribution situation.
B, test object selects：
Three kinds of nonpolarity PAO synthetic oils, nonpolar alkyl naphthalenes oil and polarity Esters oil mixing are selected in first test group
Made of base oil, because of the equal higher price of this three classes oil, therefore choose the best lubrication prepared according to embodiment 1 of economy
Oil/fat composition injects electric tool cylinder and carries out life test.
Selected in second test group nonpolar mineral oil, the three kinds of oil mixing of nonpolar alkyl naphthalenes oil and polarity Esters oil and
At base oil because mineral base oil is cheap, high temperature performance, antioxygenic property respectively with nonpolar PAO synthetic oils,
The corresponding performance of polarity Esters oil greatly differs from each other, in order to obtain the lubricant composition of optimum performance, therefore selects performance
The lubricant composition injection electric tool cylinder of best embodiment 4 carries out life test.
The base oil for selecting nonpolarity PAO synthetic oils, nonpolar alkyl naphthalenes two kinds of oil of oil to mix in third test group, because
For the equal higher price of two classes oil, therefore it is electronic to choose the best lubricant composition injection prepared according to embodiment 9 of economy
Tool cylinder carries out life test.
C, test result is as shown in table 5：
5 life test of table compares
To sum up, in the first test group, lubricant composition friction coefficient is minimum, the service life longest in cylinder, and gas
Spatter property is good in cylinder；Without nonpolar alkyl naphthalenes oil in comparative example 1, halve compared to the first test group service life.
In second test group, lubricant composition friction coefficient is slightly higher, but high due to accounting for more nonpolar mineral oil
Warm antioxygenic property is poor, and after cylinder life test, cylinder inner wall carbon deposit is quite serious, and run time is shorter；In comparative example 2 not
The oil of naphthalenes containing nonpolar alkyl, service life reduce 2 times than the second test group.
In third test group, lubricant composition friction coefficient is relatively low, and service life is longer in cylinder, and in cylinder
Spatter property is good；In comparative example 3 about half is reduced without nonpolar alkyl naphthalenes oil, service life.
It is fed back according to user, lubricant composition of the invention has good anti-compared to market common lubricant fat
Antifriction performance is ground, and 2-20 times is dramatically increased using the working life of exhaust hood.
Schematically the present invention and embodiments thereof are described above, description is not limiting, so, if
Those skilled in the art are enlightened by it, without departing from the spirit of the invention, are not inventively designed
Go out technical solution similar with the technical solution and embodiment, is within the scope of protection of the invention.
Claims (10)
1. a kind of lubricant composition, including thickening agent, it is characterised in that：It further include the basis containing nonpolar alkyl naphthalenes oil
Oil and the additive with the compound packet of antifriction antiwear；
The compound antifriction antiwear includes extreme pressure anti-wear additives, esters anti-friction agent and oil soluble polyether.
2. a kind of lubricant composition according to claim 1, it is characterised in that：The base oil is nonpolarity PAO
The miscella of synthetic oil, nonpolar alkyl naphthalenes oil and polarity Esters oil composition；The extreme pressure anti-wear additives include
ZnDTP, MoDTP one of which or both combine, the esters anti-friction agent be organic molybdates esters, organic boric acid ester or polyester its
In one kind.
3. a kind of lubricant composition according to claim 1 or 2, it is characterised in that：It is the base oil, described thick
Agent and the additive are based on following parts by weight：
100 parts of base oil
6-16 parts of thickening agent
2-35 parts of additive.
4. a kind of lubricant composition according to claim 3, it is characterised in that：Nonpolar alkyl naphthalene in the base oil
The weight accounting of class oil is 5%~36%.
5. a kind of lubricant composition according to claim 1 or 2, it is characterised in that：The thickening agent is 12- hydroxyls
One kind in lithium stearate, lithium-complex, poly- carbamido thickening agent.
6. a kind of lubricant composition according to claim 2, it is characterised in that：The extreme pressure anti-wear additives further include having
Olefine sulfide.
7. a kind of lubricant composition according to claims 1 or 2 or 6, it is characterised in that：The additive further includes
There is the combination of one or more of antioxidant, matal deactivator and oiliness improver.
8. a kind of lubricant composition according to claim 7, it is characterised in that：The antioxidant includes amine type antioxygen
Agent.
9. a kind of preparation method of the lubricant composition described in claim 1-8 any one, it is characterised in that：It specifically includes
Following steps：
Step 1：The 30%~40% of whole base oil formula ratios is added in reaction kettle, is warming up to 70 DEG C~110 DEG C, is added
Thickening agent carries out insulation reaction 1~4 hour；
Step 2：Composition in step 1 is warming up to 110 DEG C~130 DEG C again to be carried out dehydrating；
Step 3：200 DEG C~220 DEG C refinings are continuously heating to the composition in step 2 reaction kettle；
Step 4：Composition in step 3 is chilled to 70 DEG C~140 DEG C, adds additive and 30%~40% formula ratio
Base oil；
Step 5：Equal fat processing is carried out to the composition in step 4,20%~40% formula ratio base oil adjustment lubrication is added
The cone penetration of oil/fat composition obtains lubricating grease finished product to claimed range.
10. a kind of application method of lubricant composition, it is characterised in that：Using as described in claim 1-8 any one
The lubricant composition is applied to electric tool cylinder inner wall by lubricant composition before electric tool manufacture, is lubricated
Fat applying amount is the 1/3~2/3 of volume of cylinder.
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