CN108795472A - A kind of the thermal cracking liquefaction system and its oil-producing technique of serialization - Google Patents

A kind of the thermal cracking liquefaction system and its oil-producing technique of serialization Download PDF

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Publication number
CN108795472A
CN108795472A CN201810414951.1A CN201810414951A CN108795472A CN 108795472 A CN108795472 A CN 108795472A CN 201810414951 A CN201810414951 A CN 201810414951A CN 108795472 A CN108795472 A CN 108795472A
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China
Prior art keywords
cracker
connect
oil
thermal cracking
agitating device
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CN201810414951.1A
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Chinese (zh)
Inventor
陈亦力
骆江州
肖宏康
李新涛
李天玉
李绍伟
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Beijing Originwater Membrane Technology Co Ltd
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Beijing Originwater Membrane Technology Co Ltd
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Priority to CN201810414951.1A priority Critical patent/CN108795472A/en
Publication of CN108795472A publication Critical patent/CN108795472A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G1/00Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
    • C10G1/10Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal from rubber or rubber waste
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G1/00Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
    • C10G1/002Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal in combination with oil conversion- or refining processes
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G1/00Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
    • C10G1/02Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal by distillation
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10Feedstock materials
    • C10G2300/1003Waste materials
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10Feedstock materials
    • C10G2300/1011Biomass
    • C10G2300/1014Biomass of vegetal origin

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Processing Of Solid Wastes (AREA)

Abstract

Thermal cracking liquefaction system of the present invention, including material elevator, pre- agitating device, feeding equipment, cracker, acid gas absorption tower, condenser, gs-oil separator, accumulator tank and fuel gas generation device;Material elevator is connect with pre- agitating device, pre- agitating device is connect with feeding equipment, feeding equipment is connect with cracker, cracker is connect with acid gas absorption tower, acid gas absorption tower is connect with condenser, and condenser is connect with accumulator tank, and accumulator tank is connect with gs-oil separator, gs-oil separator is connect with fuel gas generation device, and fuel gas generation device is connect with cracker.The present invention is greatly improved the resource utilizations such as waste film wire, reduces environmental pollution, and effectively reduces hand labor intensity;Oil-producing technique of the present invention reduces condensed-nuclei aromatics content in Pyrolysis fuel oil PFO to a certain extent, so as to improve the quality of fuel oil obtained by waste film wire Direct Pyrolysis.

Description

A kind of the thermal cracking liquefaction system and its oil-producing technique of serialization
Technical field
The present invention relates to thermal cracking liquefaction technical field more particularly to the thermal cracking liquefaction systems and its system of a kind of serialization Oily technique.
Background technology
By development in more than 50 years, membrane separation technique gradually moved to maturity from tender, and film is as membrane separation technique Core can be prepared by different materials, such as biomembrane and synthesis film.Synthesis film can be further divided into organic polymer films and inorganic Film, most important membrane material are organic matter i.e. polymer macromolecules.Wherein, it is made from raw material with Kynoar (PVDF) Hollow-fibre membrane has many advantages, such as that high intensity, chemically-resistant cleaning, resistance tocrocking are good, is widely used to water treatment by membrane field.
PVDF is about 3-7 as a kind of typical macromolecule resin material, service life.With pvdf membrane material Extensive use, also will produce a large amount of waste and old pvdf membrane silk and material block every year.Since PVDF has extremely strong chemical stability, Traditional fixed-end forces method can lead to more serious problem of environmental pollution if dealing with improperly.Therefore, it develops a kind of high The waste film wire and material block treatment process of effect have important practical significance.
Currently, being mainly to be combined by physical cleaning and chemolysis for the treatment process of waste film wire and material block Mode recycles waste film wire, material resin in the block, and the formation such as pore former, additive of addition proper content into recycling resin Spinning solution, to prepare PVDF hollow-fibre membranes again.Specific recovery process generally comprises:Film wire classification, cleaning, cutting, Medicine washes immersion, drying, stirring and dissolving, centrifuge separation feed liquid, feed liquid filtering and spinning process.
Although the regeneration recovery process of existing waste film wire and material block can alleviate the above problem to a certain extent, There are still some problems, is mainly manifested in the following aspects:
(1) the used waste film wire of engineering often pollutes more serious, and pollutant is in the attachment on waste film wire surface Power is stronger, therefore existing regeneration technology need to carry out prerinse to waste film wire, medicine washes the processes such as immersion, to cause hand labor The problems such as intensity is high, cleaning sullage discharge capacity is big;
(2) it is directed to existing production technology, the resin in organic solvent dissolving waste film wire need to be used, due to its volatility, Therefore can make to generate a certain amount of exhaust gas in production process, to cause environmental pollution;
(3) for belt material pvdf membrane silk, existing regeneration technology can only recycle PVDF resins, however for the another of waste film wire One important component support tube does not do any processing, still respective handling is carried out as solid waste, to cause The wasting of resources and environmental pollution.
Invention content
The present invention is to overcome prior art defect, proposes a kind of the waste film wire processing unit and its processing work of serialization Skill, can effectively solve that existing waste film wire treatment process hand labor intensity is high, environmental pollution is serious, resource utilization is low etc. asks Topic.
To achieve the goals above, this invention takes following technical solutions:
The present invention provides a kind of thermal cracking liquefaction systems of serialization, including material elevator, pre- agitating device, charging Device, cracker, acid gas absorption tower, condenser, gs-oil separator, accumulator tank and fuel gas generation device;
The material elevator is connect with the pre- agitating device, and the pre- agitating device is connect with the feeding equipment, The feeding equipment is connect with the cracker, and the cracker is connect with the acid gas absorption tower, the acidity Absorption column of gas is connect with the condenser, and the condenser is connect with the accumulator tank, the accumulator tank and the oil gas point It is connected from device, the gs-oil separator is connect with the fuel gas generation device, and the fuel gas generation device is connect with the cracker.
Further, the cracker is equipped with motor and slag-draining device, and the slag-draining device is helical structure, the row The screw diameter of slag device is gradually reduced, and the slag-draining device is equipped with storage tank.
Further, the cracker is internally provided with propeller structure, and the propeller structure includes impeller, institute It states and is provided with blow vent on impeller.
Further, the pre- agitating device is three-dimensional mixer or double-cone mixer.
Further, the acid gas absorption tower is packed tower or spray column.
Further, the feeding equipment is helical structure, and the screw diameter of the feeding equipment is gradually reduced.
The present invention also provides a kind of oil-producing techniques of the thermal cracking liquefaction system, include the following steps:
(1) using film wire, biomass and the material equal cutting and grinding of block at the particle of setting grain size as raw material, by the raw material into Row is dried;
(2) when the raw material after drying process being entered stirring setting in the pre- agitating device by the material elevator Between obtain mixed raw material;
(3) mixed raw material is entered by the feeding equipment in the cracker to the hot tearing for carrying out set temperature Solution processing;
(4) cracker is internally provided with propeller structure, the solid product warp of the propeller structure discharge The slag-draining device is crossed to flow into the storage tank;
(5) cracking gas that the cracker generates enters by oil gas vent carries out acid in the acid gas absorption tower Property gas removal;
(6) it is condensed to obtain liquid-fuel oil into the condenser by the cracking gas of the acid gas removal, The liquid-fuel oil flows into the accumulator tank;
(7) cracking gas not being condensed carries out after the gs-oil separator oil removing foam into the fuel gas generation device Power generation is handled, and is heated for cracking stock preheating and cracker.
Further, described (1) includes:
By film wire, the equal cutting and grinding of biomass at the particle that grain size is 1.0-3.0mm, panel cutting, which is ground into grain size, is The particle of 5-10mm, by after cutting and grinding film wire, biomass and material block in moisture content be reduced to 6-12%;
Further, described (2) include:
Raw material after drying process is entered by the material elevator in the pre- agitating device and stirs 15-20min Mixed raw material is obtained, the pre- agitating device is three-dimensional mixer or double-cone mixer.
Further, described (3) include:
The thermal cracking temperature of the cracker is 300-5000 DEG C, and the mode of heating of the cracker is electrical heating.
The present invention has the following advantages compared to existing waste film wire treatment process:
(1) hand labor intensity is small:Device of the present invention can realize continuous operation technique, mechanization degree compared with Height substantially reduces hand labor intensity;
(2) environmental pollution is small:Technique of the present invention no longer generates solid waste and exhaust gas;
(3) resource utilization is high:The present invention, which can be handled waste film wire and material block by way of Pintsch process, is fired Oil, combustion gas and carbon black.Fuel oil can be used to Industrial Boiler heating, further can also obtain gasoline, diesel oil by catalytic pyrolysis Equal light-end products;Combustion gas can be used for generate electricity heating cracker and feeding preheating device;Solid product carbon black after cracking can Additive for making rubber product, can also pressure ball burning be used for industry heating, combustion heat value is suitable with coal.
The additional aspect of the present invention and advantage will be set forth in part in the description, these will become from the following description Obviously, or practice through the invention is recognized.
Description of the drawings
In order to illustrate the technical solution of the embodiments of the present invention more clearly, required use in being described below to embodiment Attached drawing be briefly described, it should be apparent that, drawings in the following description are only some embodiments of the invention, for this For the those of ordinary skill of field, without having to pay creative labor, other are can also be obtained according to these attached drawings Attached drawing.
Fig. 1 is the structural schematic diagram of thermal cracking liquefaction system described in the embodiment of the present invention.
【Reference numeral】
1- material elevators, the pre- agitating devices of 2-, 3- feeding equipments, 4- crackers, 5- acid gas absorption towers, 6- are cold Condenser, 7- gs-oil separators, 8- accumulator tanks, 9- fuel gas generation devices, 10- slag-draining devices, 11- storage tanks, 12- fire-proof motors.
Specific implementation mode
Embodiments of the present invention are described below in detail, the example of the embodiment is shown in the accompanying drawings, wherein from beginning Same or similar element or element with the same or similar functions are indicated to same or similar label eventually.Below by ginseng The embodiment for examining attached drawing description is exemplary, and is only used for explaining the present invention, and is not construed as limiting the claims.
Those skilled in the art of the present technique are appreciated that unless expressly stated, singulative " one " used herein, " one It is a ", " described " and "the" may also comprise plural form.It is to be further understood that is used in the specification of the present invention arranges It refers to there are the feature, integer, step, operation, element and/or component, but it is not excluded that presence or addition to take leave " comprising " Other one or more features, integer, step, operation, element, component and/or their group.It should be understood that when we claim member Part is " connected " or when " coupled " to another element, it can be directly connected or coupled to other elements, or there may also be Intermediary element.In addition, " connection " used herein or " coupling " may include being wirelessly connected or coupling.Wording used herein "and/or" includes any cell of one or more associated list items and all combines.
Those skilled in the art of the present technique are appreciated that unless otherwise defined, all terms used herein (including technology art Language and scientific terminology) there is meaning identical with the general understanding of the those of ordinary skill in fields of the present invention.Should also Understand, those terms such as defined in the general dictionary, which should be understood that, to be had and the meaning in the context of the prior art The consistent meaning of justice, and unless defined as here, will not be with idealizing or the meaning of too formal be explained.
For ease of the understanding to the embodiment of the present invention, done further by taking several specific embodiments as an example below in conjunction with attached drawing Explanation, and each embodiment does not constitute the restriction to the embodiment of the present invention.
Embodiment one
The present embodiment provides a kind of thermal cracking liquefaction system of serialization, concrete structure is as shown in Figure 1, include material lifting Machine 1, pre- agitating device 2, feeding equipment 3, cracker 4, acid gas absorption tower 5, condenser 6, gs-oil separator 7, oil-collecting Tank 8 and fuel gas generation device 9;
The material elevator 1 is connect with the pre- agitating device 2, and the pre- agitating device 2 connects with the feeding equipment 3 It connects, the feeding equipment 3 is connect with the cracker 4, and the cracker 4 is connect with the acid gas absorption tower 5, institute Acid gas absorption tower 5 is stated to connect with the condenser 6, the condenser 6 is connect with the accumulator tank 8, the accumulator tank 8 with The gs-oil separator 7 connects, and the gs-oil separator 7 is connect with the fuel gas generation device 9, the fuel gas generation device 9 and institute State the connection of cracker 4.
In the present embodiment, the cracker 4 is equipped with motor 12 and slag-draining device 10, and the slag-draining device 10 is spiral The screw diameter of structure, the slag-draining device 10 is gradually reduced, and the slag-draining device 10 is equipped with storage tank 11.The examination device 10 Similar to screw feeding device 3, it can realize that inclusion seal discharges by way of changing screw diameter;The motor 12 is anti- Quick-fried motor.
In the present embodiment, the cracker 4 is internally provided with propeller structure, and the propeller structure includes leaf It takes turns, blow vent is provided on the impeller.
In the present embodiment, the pre- agitating device 2 is three-dimensional mixer or double-cone mixer.
In the present embodiment, the acid gas absorption tower 5 is packed tower or spray column.
In the present embodiment, the feeding equipment 3 is helical structure, and the screw diameter of the feeding equipment 3 is gradually reduced; Since cracking stock has higher compression ratio, so screw feeding device is using the form being gradually reduced so that cracking stock It is constantly compressed in transportational process, to which the air of entrainment be discharged, realizes sealing charging, the auger conveyor is equipped with change Frequency fire-proof motor.
In the present embodiment, the condensing mode of the condenser both can single-stage condensation, the mode of multi-stage condensing can also be used, And it may be configured as different condensation temperature gradients.
Embodiment two
The oil-producing technique for present embodiments providing thermal cracking liquefaction system of the present invention, due in waste film wire and material block Polycyclic aromatic hydrocarbon containing high level is mainly manifested in fuel oil so as to cause fuel oil heaviness prepared by conventional cracking process Middle condensed-nuclei aromatics content is higher.In consideration of it, the mode that biomass is blended with waste film wire and material block is split in the present embodiment proposition Solution is cut off the chemical bond in macromolecular using high thermal energy, is allowed to improve cracking stock calorific value, and under conditions of anoxic It is converted into lower-molecular substance, the content of condensed-nuclei aromatics in Pyrolysis fuel oil PFO is reduced, finally improves oil quality, specifically include as follows Step:
(1) panel cutting is crushed into granulating by film wire, the equal cutting and grinding of biomass at the particle that grain size is 1.0-3.0mm Diameter is the particle of 5-10mm, processing is dried in film wire, biomass and the material block after cutting and grinding, drying process mode is: By after cutting and grinding film wire, biomass and material block in moisture content be reduced to 6-12%;
In the present embodiment, it is timber, agricultural crop straw to select waste film wire and waste material block, the biomass material Deng.
(2) raw material after drying process is entered by the material elevator in the pre- agitating device and stirs 15- 20min obtains mixed raw material;The pre- agitating device is general stirring apparatus, it is preferable that the agitating device is to be suitble to solid The three-dimensional mixer or double-cone mixer of grain mixing.
The mixed raw material is entered into 300-5000 DEG C of temperature of progress in the cracker by the feeding equipment Thermal cracking processing;The mode of heating of the cracker is electrical heating;The electric energy conversion ratio of Electric heating is up to 95%, the energy Utilization rate is high.In the present embodiment, the cracking apparatus mode of heating can be other mode of heatings, such as microwave, superheated steam, red External heat and solar energy etc..
(4) cracker is internally provided with propeller structure, the propeller structure can both play augmentation of heat transfer, The purpose of slagging prevention, and the purpose of continuous discharge may be implemented.The solid product of the propeller structure discharge passes through institute Slag-draining device is stated to flow into the storage tank;Solid product carbon black after cracking can be used for making the additive of rubber product, also may be used It is used for industry heating with pressure ball burning, combustion heat value to be suitable with coal.
(5) due to containing the elements such as fluorine, nitrogen in cracking stock, a certain amount of sour gas is will produce in cracking gas, The cracking gas that the cracker generates, which enters by oil gas vent in the acid gas absorption tower, carries out acid gas removal;
(6) it is condensed to obtain liquid-fuel oil into the condenser by the cracking gas of the acid gas removal, The liquid-fuel oil flows into the accumulator tank;
(7) cracking gas not being condensed forms non-condensable gas, and the cracking gas not being condensed passes through the gs-oil separator After oil removing foam, power generation processing is carried out into the fuel gas generation device, is heated for cracking stock preheating and cracker.
In conclusion the thermal cracking liquefaction system of serialization of the present invention is greatly improved the waste film wire utilization of resources Rate reduces environmental pollution, and effectively reduces hand labor intensity;Meanwhile the present invention is to improve obtained by waste film wire Direct Pyrolysis The quality of fuel oil proposes biomass and waste film wire and material block being total to thermal cracking new process, improves cracking stock calorific value, to Condensed-nuclei aromatics content in Pyrolysis fuel oil PFO is reduced to a certain extent.
One of ordinary skill in the art will appreciate that:Attached drawing is the schematic diagram of one embodiment, module in attached drawing or Flow is not necessarily implemented necessary to the present invention.
Each embodiment in this specification is described in a progressive manner, identical similar portion between each embodiment Point just to refer each other, and each embodiment focuses on the differences from other embodiments.Especially for device or For system embodiment, since it is substantially similar to the method embodiment, so describing fairly simple, related place is referring to method The part of embodiment illustrates.Apparatus and system embodiment described above is only schematical, wherein the conduct The unit that separating component illustrates may or may not be physically separated, the component shown as unit can be or Person may not be physical unit, you can be located at a place, or may be distributed over multiple network units.It can root According to actual need that some or all of module therein is selected to achieve the purpose of the solution of this embodiment.Ordinary skill Personnel are without creative efforts, you can to understand and implement.
The foregoing is only a preferred embodiment of the present invention, but scope of protection of the present invention is not limited thereto, Any one skilled in the art in the technical scope disclosed by the present invention, the change or replacement that can be readily occurred in, It should be covered by the protection scope of the present invention.Therefore, protection scope of the present invention should be with scope of the claims Subject to.

Claims (10)

1. a kind of thermal cracking liquefaction system of serialization, which is characterized in that including material elevator, pre- agitating device, charging dress It sets, cracker, acid gas absorption tower, condenser, gs-oil separator, accumulator tank and fuel gas generation device;
The material elevator is connect with the pre- agitating device, and the pre- agitating device is connect with the feeding equipment, described Feeding equipment is connect with the cracker, and the cracker is connect with the acid gas absorption tower, the sour gas Absorption tower is connect with the condenser, and the condenser is connect with the accumulator tank, the accumulator tank and the gs-oil separator Connection, the gs-oil separator are connect with the fuel gas generation device, and the fuel gas generation device is connect with the cracker.
2. thermal cracking liquefaction system according to claim 1, which is characterized in that the cracker is equipped with motor and deslagging Device, the slag-draining device are helical structure, and the screw diameter of the slag-draining device is gradually reduced, and the slag-draining device is equipped with storage Tank.
3. thermal cracking liquefaction system according to claim 1, which is characterized in that the cracker is internally provided with spiral and pushes away Into structure, the propeller structure includes impeller, and blow vent is provided on the impeller.
4. thermal cracking liquefaction system according to claim 1, which is characterized in that the pre- agitating device is three-dimensional mixer Or double-cone mixer.
5. thermal cracking liquefaction system according to claim 1, which is characterized in that the acid gas absorption tower is packed tower Or spray column.
6. thermal cracking liquefaction system according to claim 1, which is characterized in that the feeding equipment is helical structure, institute The screw diameter for stating feeding equipment is gradually reduced.
7. a kind of oil-producing technique of the thermal cracking liquefaction system as described in claim any one of 1-6, which is characterized in that including as follows Step:
(1) using film wire, biomass and material the equal cutting and grinding of block at setting grain size particle as raw material, the raw material is done Dry processing;
(2) raw material after drying process is entered stirring setting time in the pre- agitating device by the material elevator to obtain To mixed raw material;
(3) mixed raw material is entered in the cracker by the feeding equipment at the thermal cracking for carrying out set temperature Reason;
(4) cracker is internally provided with propeller structure, and the solid product of the propeller structure discharge passes through institute Slag-draining device is stated to flow into the storage tank;
(5) cracking gas that the cracker generates, which enters by oil gas vent in the acid gas absorption tower, carries out sour gas Body removes;
(6) it is condensed to obtain liquid-fuel oil into the condenser by the cracking gas of the acid gas removal, it is described Liquid-fuel oil flows into the accumulator tank;
(7) cracking gas not being condensed generates electricity after the gs-oil separator oil removing foam into the fuel gas generation device Processing is heated for cracking stock preheating and cracker.
8. oil-producing technique according to claim 7, which is characterized in that (1) includes:
By film wire, the equal cutting and grinding of biomass at the particle that grain size is 1.0-3.0mm, it is 5- that panel cutting, which is ground into grain size, The particle of 10mm, by after cutting and grinding film wire, biomass and material block in moisture content be reduced to 6-12%.
9. oil-producing technique according to claim 7, which is characterized in that (2) include:
Raw material after drying process is entered stirring 15-20min in the pre- agitating device by the material elevator to obtain Mixed raw material, the pre- agitating device are three-dimensional mixer or double-cone mixer.
10. oil-producing technique according to claim 7, which is characterized in that (3) include:
The thermal cracking temperature of the cracker is 300-5000 DEG C, and the mode of heating of the cracker is electrical heating.
CN201810414951.1A 2018-05-03 2018-05-03 A kind of the thermal cracking liquefaction system and its oil-producing technique of serialization Pending CN108795472A (en)

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN2223297Y (en) * 1995-08-18 1996-03-27 周鼎力 Apparatus for producing gasoline diesel oil and carbon black from waste rubber
CN1392224A (en) * 2001-06-14 2003-01-22 上海市环境工程设计科学研究院 Oil refining process of waste plastic and equipment
CN101074385A (en) * 2007-04-28 2007-11-21 牛斌 Waste-plastic continuous cracking process and cracker
CN106398740A (en) * 2016-10-28 2017-02-15 厦门高龙朝环保科技股份有限公司 Plastic waste thermal cracking gas treatment apparatus and method

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN2223297Y (en) * 1995-08-18 1996-03-27 周鼎力 Apparatus for producing gasoline diesel oil and carbon black from waste rubber
CN1392224A (en) * 2001-06-14 2003-01-22 上海市环境工程设计科学研究院 Oil refining process of waste plastic and equipment
CN101074385A (en) * 2007-04-28 2007-11-21 牛斌 Waste-plastic continuous cracking process and cracker
CN106398740A (en) * 2016-10-28 2017-02-15 厦门高龙朝环保科技股份有限公司 Plastic waste thermal cracking gas treatment apparatus and method

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Application publication date: 20181113