CN108795226A - Poly- silicon ceramics Anti-ice paint and preparation method thereof - Google Patents
Poly- silicon ceramics Anti-ice paint and preparation method thereof Download PDFInfo
- Publication number
- CN108795226A CN108795226A CN201810419137.9A CN201810419137A CN108795226A CN 108795226 A CN108795226 A CN 108795226A CN 201810419137 A CN201810419137 A CN 201810419137A CN 108795226 A CN108795226 A CN 108795226A
- Authority
- CN
- China
- Prior art keywords
- poly
- ice
- preparation
- silicon ceramics
- mixed
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/14—Polycondensates modified by chemical after-treatment
- C08G59/1433—Polycondensates modified by chemical after-treatment with organic low-molecular-weight compounds
- C08G59/1477—Polycondensates modified by chemical after-treatment with organic low-molecular-weight compounds containing nitrogen
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/221—Oxides; Hydroxides of metals of rare earth metal
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The preparation method of poly- silicon ceramics Anti-ice paint provided by the invention obtains resin compound after stirring polysilane modified epoxy, titanium dioxide and mica powder；Component A is obtained after the resin compound, neopelex, nano oxidized erbium and nano lanthanum oxide are mixed；The component A and curing agent are mixed to get the poly- silicon ceramics Anti-ice paint, the poly- silicon ceramics Anti-ice paint that above-mentioned preparation method obtains, surface reactive material neopelex and oxide nano rare earth is added, interaction by each component and synergistic effect, so that coating is had, surface energy is low, corrosion resistance is high, it is big with basal body binding force, the comprehensive performances such as drag reduction is anti-freeze.
Description
Technical field
The present invention relates to anticorrosive paint technology fields, more particularly to a kind of poly- silicon ceramics Anti-ice paint and its preparation side
Method.
Background technology
Temperature is at 0 DEG C hereinafter, then extra steam is just sublimated on a surface of an as ice crystal, and here it is frosts.It freezes and claims to freeze
Knot, a kind of weather phenomenon refer to the surface of open water glaciation.Surface icing phenomenon is in addition to by temperature, this key factor is influenced it
Outside, the surface characteristic of frozen surface, especially surface energy, surface are to the adhesive force of ice and the hydrophobicity on surface to icing phenomenon
There is larger impact.Ice crystal can just be attached on frozen surface, and constantly deposit under adsorption force, the size of this adsorption capacity
Depending on the surface wettability between ice crystal and crystal surface, if it is the hydrophobic surface of low-surface-energy, so that it may be ice crystal with
It is in nonwetting state between surface, can greatly reduce the adsorption capacity to ice crystal, to effectively prevent from freezing.Anti-ice-and-snow applies
Material is a kind of infant industry coating haveing excellent performance, and is added by base-material and the high-activity nano Anti-ice-and-snow Jing Guo surface modification treatment
Agent forms, and so that the mechanical properties such as adhesive force, the hardness of coating is improved, in order to preferably clear up icing frosting, in pipeline, sets
The material surfaces brushing Anti-ice-and-snow paint such as standby, cooling tube, fiberglass, effectively prevent material surface icing frosting, avoids material surface
Corrosion.
Current Anti-ice paint coating contact angle is smaller, still has ice and snow to be adhered to above, be easy to cause corrosion.
Invention content
Based on this, it is necessary in view of the deficiencies in the prior art, provide it is a kind of can Anti-ice-and-snow attachment poly- silicon ceramics
Anti-ice paint.
To achieve the above object, the present invention uses following technical proposals：
A kind of preparation method of poly- silicon ceramics Anti-ice paint, includes the following steps：
Resin compound is obtained after polysilane modified epoxy, titanium dioxide and mica powder are stirred；
After the resin compound, neopelex, nano oxidized erbium and nano lanthanum oxide are mixed
To component A；And
The component A and curing agent are mixed to get the poly- silicon ceramics Anti-ice paint.
In some preferred embodiment, it is set after stirring polysilane modified epoxy, titanium dioxide and mica powder
In the step of lipoprotein mixture, the polysilane modified epoxy is prepared by following methods：
Silane KH-550 and epoxy resin are mixed, polysilane modified epoxy is formed.
In some preferred embodiment, the volume ratio of the silane and epoxy resin is 1：10-1：15.
In some preferred embodiment, it is set after stirring polysilane modified epoxy, titanium dioxide and mica powder
In the step of lipoprotein mixture, the mass ratio of the titanium dioxide, the mica powder and the polysilane modified epoxy is 1：2：
1-1：4：2.
In some preferred embodiment, after polysilane modified epoxy, titanium dioxide and mica powder are mixed
To in the step of resin compound, wherein the speed of stirring is 1000-1200rpm, mixing time 1-2h.
In some preferred embodiment, by the resin compound, neopelex, erbium oxide and lanthana
In the step of obtaining component A after mixing, wherein the neopelex, nano oxidized erbium, nano lanthanum oxide and
The mass ratio of polysilane modified epoxy is 1：1：1：3-2：2：1： 8.In some preferred embodiment,
Component A is obtained after the resin compound, neopelex, erbium oxide and lanthana are mixed
The step of in, the rotating speed of stirring is 1000-1500rpm, mixing time 1-2h.
In some preferred embodiment, the component A and curing agent are being mixed to get the poly- silicon ceramics Anti-ice-and-snow painting
In the step of material, the mass ratio of the component A and curing agent is 10：1-5:1.
In some preferred embodiment, the curing agent is diethylenetriamine.
In addition, the present invention also provides a kind of poly- silicon ceramics Anti-ice paint, by the poly- silicon ceramics Anti-ice paint
Preparation method be prepared.
The present invention uses above-mentioned technical proposal, advantage to be：
The preparation method of poly- silicon ceramics Anti-ice paint provided by the invention, by polysilane modified epoxy, titanium dioxide
And obtain resin compound after mica powder stirring；By the resin compound, neopelex, nano oxidized erbium and receive
Rice lanthana obtains component A after being mixed；The component A and curing agent are mixed to get the poly- silicon ceramics Anti-ice-and-snow to apply
Material, the poly- silicon ceramics Anti-ice paint that above-mentioned preparation method obtains, be added surface reactive material neopelex and
Oxide nano rare earth, the interaction by each component and synergistic effect, so that coating is had, surface energy is low, corrosion resistance is high,
It is big with basal body binding force, the comprehensive performances such as drag reduction is anti-freeze.
Poly- silicon ceramics Anti-ice paint provided by the invention can Anti-ice-and-snow attachment, while having anticorrosive, wear-resistant, anti-old
The complex functions such as change, clean surfaces, can be used for aircraft, ship, power line, and Telecommunication Lines etc. need Anti-ice-and-snow structure.
Specific implementation mode
It to facilitate the understanding of the present invention, below will be to invention is more fully described.The present invention can be with many not
With form realize, however it is not limited to embodiment described herein.Make to this on the contrary, purpose of providing these embodiments is
The understanding of the disclosure of invention is more thorough and comprehensive.
Unless otherwise defined, all of technologies and scientific terms used here by the article and belong to the technical field of the present invention
The normally understood meaning of technical staff is identical.Used term is intended merely to description tool in the description of the invention herein
The purpose of the embodiment of body, it is not intended that in the limitation present invention.Term " and or " used herein includes one or more phases
Any and all combinations of the Listed Items of pass.
The preparation method of poly- silicon ceramics Anti-ice paint provided by the invention, includes the following steps：
Step S110：Resin compound is obtained after polysilane modified epoxy, titanium dioxide and mica powder are stirred.
Specifically, with mixing speed it is being 1000-1500rpm by polysilane modified epoxy, titanium dioxide and mica powder
Resin compound is obtained after stirring 1-2h.
In some preferred embodiments, the polysilane modified epoxy is prepared by following methods：By silane KH-
550 are mixed with epoxy resin, form polysilane modified epoxy.
Specifically, it is that 500-1000rpm stirs 1-2h with speed of agitator by silane KH-550 and epoxy resin, obtains described
The volume ratio of polysilane modified epoxy, the silane and epoxy resin is 1：10-1：15.
In some preferred embodiments, the titanium dioxide, the mica powder and the polysilane modified epoxy
Mass ratio is 1：2：1-1：4：2.
Step S120：The resin compound, neopelex, nano oxidized erbium and nano lanthanum oxide are mixed
Component A is obtained after stirring；
Specifically, it is 1000- with rotating speed by the resin compound, neopelex, erbium oxide and lanthana
1500rpm stirs 1-2h, obtains component A.
In some preferred embodiments, the neopelex, nano oxidized erbium, nano lanthanum oxide and poly- silicon
The mass ratio of alkane modified epoxy is 1：1：1：3-2：2：1：8.
Step S130：The component A and curing agent are mixed to get the poly- silicon ceramics Anti-ice paint.
In some preferred embodiments, the curing agent is diethylenetriamine, wherein the component A and the solidification
The mass ratio of agent is 5：1-10：1.
The preparation method of poly- silicon ceramics Anti-ice paint provided by the invention, by polysilane modified epoxy, titanium dioxide
And obtain resin compound after mica powder stirring；By the resin compound, neopelex, nano oxidized erbium and receive
Rice lanthana obtains component A after being mixed；The component A and curing agent are mixed to get the poly- silicon ceramics Anti-ice-and-snow to apply
Material, the poly- silicon ceramics Anti-ice paint that above-mentioned preparation method obtains, be added surface reactive material neopelex and
Oxide nano rare earth, the interaction by each component and synergistic effect, so that coating is had, surface energy is low, corrosion resistance is high,
It is big with basal body binding force, the comprehensive performances such as drag reduction is anti-freeze.
Polysilane ceramics Anti-ice paint provided by the invention, hydrophobic angle are more than 150 degree, and surface is big to the contact angle of water
In 110 degree, surface energy is less than 10X10-3N/m；Hardness reaches 8H, and salt spray resistance is more than 10000h, and wet-heat resisting is more than 5000h, resistance to
10%H2SO4 1000d, the 1000d of resistance to 10%NaOH, compactness is 0.65 X 10-3mg/(cm2.d)；And its solid content is big
In 98%, non-volatility organic matter is very environmentally friendly.
Poly- silicon ceramics Anti-ice paint provided by the invention can Anti-ice-and-snow attachment, while having anticorrosive, wear-resistant, anti-old
The complex functions such as change, clean surfaces, can be used for aircraft, ship, power line, and Telecommunication Lines etc. need Anti-ice-and-snow structure.
Above-mentioned technical proposal of the present invention is described in detail below in conjunction with specific embodiment.
Embodiment 1
10g silane KH550 is added in 100g epoxy resin, 1h is stirred under 1000rpm, forms polysilane asphalt mixtures modified by epoxy resin
Fat；100g titanium dioxides, 200g mica powders are added, 1500rpm stirs 1h；Continuously add 30g neopelexes, 30g
Nano oxidized erbium, 15g nano lanthanum oxides, stirring 1h obtains component A under 1500rpm；By component A and curing agent (divinyl three
Amine) according to mass ratio 5：1 proportioning uses.
Embodiment 2
5g silane KH550 is added in 100g epoxy resin, 1h is stirred under 1000rpm, forms polysilane epoxy resin；
100g titanium dioxides, 400g mica powders are added, 1500rpm stirs 2h；25g neopelexes are continuously added, 25g receives
Rice erbium oxide, 15g nano lanthanum oxides, stirring 1h obtains component A under 1500rpm；By component A and curing agent (diethylenetriamine)
According to mass ratio 5：1 proportioning uses.
Embodiment 3
10g silane KH550 is added in 100g epoxy resin, 1h is stirred under 1000rpm, forms polysilane asphalt mixtures modified by epoxy resin
Fat；100g titanium dioxides, 400g mica powders are added, 1500rpm stirs 2h；Continuously add 30g neopelexes, 30g
Nano oxidized erbium, 30g nano lanthanum oxides, stirring 1h obtains component A under 2000rpm；By component A and curing agent (divinyl three
Amine) according to mass ratio 5：1 proportioning uses.
Each technical characteristic of embodiment described above can be combined arbitrarily, to keep description succinct, not to above-mentioned reality
It applies all possible combination of each technical characteristic in example to be all described, as long as however, the combination of these technical characteristics is not deposited
In contradiction, it is all considered to be the range of this specification record.
Several embodiments of the invention above described embodiment only expresses, the description thereof is more specific and detailed, but simultaneously
It cannot therefore be construed as limiting the scope of the patent.It should be pointed out that coming for those of ordinary skill in the art
It says, without departing from the inventive concept of the premise, various modifications and improvements can be made, these belong to the protection of the present invention
Range.Therefore, the protection domain of patent of the present invention should be determined by the appended claims.
Claims (10)
1. a kind of preparation method of poly- silicon ceramics Anti-ice paint, which is characterized in that include the following steps：
Resin compound is obtained after polysilane modified epoxy, titanium dioxide and mica powder are stirred；
Group is obtained after the resin compound, neopelex, nano oxidized erbium and nano lanthanum oxide are mixed
Divide A；And
The component A and curing agent are mixed to get the poly- silicon ceramics Anti-ice paint.
2. the preparation method of poly- silicon ceramics Anti-ice paint according to claim 1, which is characterized in that change by polysilane
Property epoxy resin, after titanium dioxide and mica powder stirring in the step of obtaining resin compound, the polysilane modified epoxy
It is prepared by following methods：
Silane KH-550 and epoxy resin are mixed, polysilane modified epoxy is formed.
3. the preparation method of poly- silicon ceramics Anti-ice paint according to claim 2, which is characterized in that the silane and ring
The volume ratio of oxygen resin is 1：10-1：15.
4. the preparation method of poly- silicon ceramics Anti-ice paint according to claim 2, which is characterized in that change by polysilane
Property epoxy resin, after titanium dioxide and mica powder stirring in the step of obtaining resin compound, the titanium dioxide, the mica powder and
The mass ratio of the polysilane modified epoxy is 1：2：1-1：4：2.
5. the preparation method of poly- silicon ceramics Anti-ice paint according to claim 1, which is characterized in that change by polysilane
Property epoxy resin, titanium dioxide and mica powder the step of obtaining resin compound after being mixed in, wherein the speed of stirring is
1000-1500rpm, mixing time 1-2h.
6. the preparation method of poly- silicon ceramics Anti-ice paint according to claim 2, which is characterized in that by the resin
In the step of mixture, neopelex, erbium oxide and lanthana obtain component A after being mixed, wherein described ten
The mass ratio of dialkyl benzene sulfonic acids sodium, nano oxidized erbium, nano lanthanum oxide and polysilane modified epoxy is 1：1：1：3-2：
2：1：8.
7. the preparation method of poly- silicon ceramics Anti-ice paint according to claim 6, which is characterized in that by the resin
In the step of mixture, neopelex, erbium oxide and lanthana obtain component A after being mixed, the rotating speed of stirring
For 1000-1500rpm, mixing time 1-2h.
8. the preparation method of poly- silicon ceramics Anti-ice paint according to claim 1, which is characterized in that by the component
In the step of A is mixed to get the poly- silicon ceramics Anti-ice paint with curing agent, the mass ratio of the component A and curing agent is
10：1-5:1.
9. the preparation method of poly- silicon ceramics Anti-ice paint according to claim 1, which is characterized in that the curing agent is
Diethylenetriamine.
10. a kind of poly- silicon ceramics Anti-ice paint, which is characterized in that prevented by the poly- silicon ceramics of claim 1-9 any one of them
The preparation method of ice and snow coating is prepared.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810419137.9A CN108795226A (en) | 2018-05-04 | 2018-05-04 | Poly- silicon ceramics Anti-ice paint and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810419137.9A CN108795226A (en) | 2018-05-04 | 2018-05-04 | Poly- silicon ceramics Anti-ice paint and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108795226A true CN108795226A (en) | 2018-11-13 |
Family
ID=64093271
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810419137.9A Pending CN108795226A (en) | 2018-05-04 | 2018-05-04 | Poly- silicon ceramics Anti-ice paint and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108795226A (en) |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105176307A (en) * | 2015-09-24 | 2015-12-23 | 天津米一科技有限公司 | Silylation blended epoxy group low surface treatment coating |
| CN106497323A (en) * | 2016-10-21 | 2017-03-15 | 过冬 | A kind of non-solvent epoxy pipeline coating and preparation method thereof |
| CN106867357A (en) * | 2015-12-11 | 2017-06-20 | 中国航空工业集团公司北京航空材料研究院 | A kind of nanometer modified high-solid body point epoxy primer |
| CN106893452A (en) * | 2017-03-15 | 2017-06-27 | 包头稀土研究院 | Nano rare earth modified epoxy anticorrosive paint and preparation method thereof |
| CN107141968A (en) * | 2017-06-27 | 2017-09-08 | 过春明 | A kind of resin base ceramic coating composition and preparation method thereof |
| KR101776150B1 (en) * | 2017-05-31 | 2017-09-08 | 김영규 | Environmental friendly process for coating steel-structure using metal-zinc anti-rust primer and ceramic-urethane coating materials |
| CN107163699A (en) * | 2017-06-30 | 2017-09-15 | 周远华 | A kind of corrosion-resistant ceramic coating composition and preparation method thereof |
-
2018
- 2018-05-04 CN CN201810419137.9A patent/CN108795226A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105176307A (en) * | 2015-09-24 | 2015-12-23 | 天津米一科技有限公司 | Silylation blended epoxy group low surface treatment coating |
| CN106867357A (en) * | 2015-12-11 | 2017-06-20 | 中国航空工业集团公司北京航空材料研究院 | A kind of nanometer modified high-solid body point epoxy primer |
| CN106497323A (en) * | 2016-10-21 | 2017-03-15 | 过冬 | A kind of non-solvent epoxy pipeline coating and preparation method thereof |
| CN106893452A (en) * | 2017-03-15 | 2017-06-27 | 包头稀土研究院 | Nano rare earth modified epoxy anticorrosive paint and preparation method thereof |
| KR101776150B1 (en) * | 2017-05-31 | 2017-09-08 | 김영규 | Environmental friendly process for coating steel-structure using metal-zinc anti-rust primer and ceramic-urethane coating materials |
| CN107141968A (en) * | 2017-06-27 | 2017-09-08 | 过春明 | A kind of resin base ceramic coating composition and preparation method thereof |
| CN107163699A (en) * | 2017-06-30 | 2017-09-15 | 周远华 | A kind of corrosion-resistant ceramic coating composition and preparation method thereof |
Non-Patent Citations (2)
| Title |
|---|
| 中国有色金属工业协会专家委员会: "《中国钼业》", 31 August 2013, 冶金工业出版社 * |
| 化工百科全书》编辑委员会: "《化工百科全书》", 31 December 1997, 化学工业出版社 * |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Tong et al. | Mechanically robust superhydrophobic coating for aeronautical composite against ice accretion and ice adhesion | |
| CN102618165B (en) | Nanometer polysiloxane nontoxic low-surface-energy ship antifouling coating and preparation method thereof | |
| CN102827537B (en) | Aqueous normal temperature curing peelable paint and preparation method of paint | |
| CN102838931B (en) | Epoxy modified polysiloxane low surface energy antifouling coating and preparation method thereof | |
| CN104762008B (en) | A kind of bi-component waterborne is wear-resisting, low ice adhesion anti-icing paint, coating and preparation method and application | |
| CN101955716B (en) | Zinc-rich steel structure anti-corrosion primer based on epoxy resin and preparation method thereof | |
| CN103820007B (en) | A kind of elastic anti-slip deck composition and preparation method thereof | |
| CN103805059A (en) | Slow-release three-component road de-icing and snow-melting coating and preparation method thereof | |
| CN103788833A (en) | Organosilicon antiskid anticorrosion deck coating and preparation method thereof | |
| CN105802462B (en) | A kind of MODIFIED PP material polyurethane paint and preparation method thereof | |
| CN104774526A (en) | Room temperature-curing two-component aqueous epoxy zinc-rich primer | |
| CN102807802A (en) | Super-hydrophobic surface coating material and preparation method thereof | |
| CN109943128A (en) | A kind of thin graphene aqueous slurry, preparation method and application | |
| CN104725969B (en) | Water-based anti-corrosion floating type aluminium powder paint and preparation method thereof | |
| WO2021068506A1 (en) | Water-based anticorrosive coating based on graphene oxide and preparation method therefor | |
| CN104277516A (en) | Waterproof film spraying material, and preparation method and application thereof | |
| CN108795226A (en) | Poly- silicon ceramics Anti-ice paint and preparation method thereof | |
| CN101255290B (en) | Marine reinforced concrete anticorrosion paint and preparation method thereof | |
| CN107312460A (en) | A kind of long-acting type aqueous corrosion resisting paint without need of cleaning rust and preparation method thereof | |
| CN102559042B (en) | Nano modified polysiloxane paint and preparation method thereof | |
| CN108610780A (en) | A kind of fluorocarbon resin coating and preparation method thereof | |
| CN102190935A (en) | Anti-icing coating and use thereof | |
| CN109679391A (en) | A kind of macromolecular antiseptic water-repellent paint for concrete structure | |
| RU2156786C2 (en) | Composition for antiicing coating | |
| CN104293068A (en) | Tough and wear-resistant bituminous insulating paint and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20181113 |
|
| RJ01 | Rejection of invention patent application after publication |