CN108786381A - It is a kind of to absorb VOC and regeneration device using high boiling solvent - Google Patents

It is a kind of to absorb VOC and regeneration device using high boiling solvent Download PDF

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Publication number
CN108786381A
CN108786381A CN201810647277.1A CN201810647277A CN108786381A CN 108786381 A CN108786381 A CN 108786381A CN 201810647277 A CN201810647277 A CN 201810647277A CN 108786381 A CN108786381 A CN 108786381A
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CN
China
Prior art keywords
cooler
pipeline
valve
voc
refrigerant
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810647277.1A
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Chinese (zh)
Inventor
蒋国群
周卫强
史先桥
储鹏
戴玉明
程力伟
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Jiangsu Geely Amperex Technology Ltd
Original Assignee
Jiangsu Geely Amperex Technology Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Jiangsu Geely Amperex Technology Ltd filed Critical Jiangsu Geely Amperex Technology Ltd
Priority to CN201810647277.1A priority Critical patent/CN108786381A/en
Publication of CN108786381A publication Critical patent/CN108786381A/en
Pending legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/18Absorbing units; Liquid distributors therefor
    • B01D53/185Liquid distributors
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/1425Regeneration of liquid absorbents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/1487Removing organic compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/18Absorbing units; Liquid distributors therefor
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/70Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
    • B01D2257/708Volatile organic compounds V.O.C.'s
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/20Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Vaporization, Distillation, Condensation, Sublimation, And Cold Traps (AREA)

Abstract

The present invention relates to a kind of VOC and regeneration device are absorbed using high boiling solvent, it includes cooling blending tank, cooler I, cooler II and venturi mixer, they are connected by pipeline, are equipped with wire mesh demister in the cooling mixing upper end, refrigerant chuck is equipped with outside the cooling mixing tank, it is equipped with refrigerant inlet in refrigerant chuck lower part, top is equipped with refrigerant exit, and compressed gas source import is equipped at the refrigerant inlet, and steam inlet is equipped at the refrigerant exit.The present invention absorbs, whole continuous service reusable with solvent, operates steadily reliable, reduces cost.

Description

It is a kind of to absorb VOC and regeneration device using high boiling solvent
Technical field
The present invention relates to a kind of device for recycling exhaust gas, and in particular to a kind of VOC recycle devices.
Background technology
VOC is easy to form PM2.5 with steam, the microparticle etc. in air as volatile organic matter after evaporating into air Aerosol forms haze, larger destruction is caused to atmospheric environment, influences the health of the mankind.VOC mono- in industrial processes As be single volatile organic matter, if the discharge accumulated over a long period for a long time, very serious to atmosphere pollution, will also result in very big Waste.Currently, be typically all to the processing of VOC use solvent absorption, but its there are absorption solvents to reuse, production The shortcomings of raw secondary pollution, device are unable to continuous operation, and environmental protection treatment cost is higher.
Invention content
Goal of the invention:Purpose of the invention is to overcome the shortcomings in the prior art, and providing a kind of absorption solvent can It reuses, whole continuous service, operates steadily reliable, reduce cost absorbs VOC and regeneration using high boiling solvent Device.
Technical solution:In order to solve the above-mentioned technical problem, a kind of utilization high boiling solvent of the present invention absorbs VOC simultaneously Regeneration device, it includes cooling blending tank, and cooler I, cooler II and venturi mixer, they are connected by pipeline It connects, is equipped with wire mesh demister in the cooling mixing upper end, refrigerant chuck is equipped with outside the cooling mixing tank, Refrigerant chuck lower part be equipped with refrigerant inlet, top be equipped with refrigerant exit, at the refrigerant inlet be equipped with compressed gas source into Mouthful, it is equipped with steam inlet at the refrigerant exit, agitating device is equipped in the cooling blending tank, in the cooling mixing Pipeline between tank and cooler I is equipped with liquid pump, and refrigerant pipe is equipped between the cooler I and cooler II, The cooler II is equipped with cooler refrigerant inlet, and cooler refrigerant exit is equipped on cooler I, mixed in the venturi Clutch is equipped with the import of VOC gas source, and drain is equipped at the top of the wire mesh demister, mixed in the cooler II and cooling It is equipped with VOC distillation pipelines between conjunction tank, the outlets condensation VOC are equipped on the pipeline between the liquid pump and cooler I, each Valve is designed in connecting pipe.
The venturi mixer includes connecting tube, gas suction chamber is equipped in the connecting tube, in the connecting tube With in the gas suction chamber of gas suction chamber junction be equipped with conical nozzle, gas suction chamber rear end be equipped with converging transition, The converging transition is connected with trunnion section, and the trunnion section is connected with diffuser, and VOC gas source import is located at gas suction chamber On, the gas suction chamber, converging transition, trunnion section and diffuser length ratio be 30:10:7:75.
It is equipped with valve 1. on pipeline between the cooling blending tank and liquid pump, in the liquid pump and cooler I Between pipeline be equipped with valve 2., on the pipeline between the cooler II and venturi mixer be equipped with valve 3., Pipeline between the venturi mixer and cooling blending tank be equipped with valve 4. with valve 5., in the refrigerant inlet pipeline It is equipped with valve 6., valve is equipped with 7. on the refrigerant exit pipeline, valve is equipped on the compressed gas source inlet pipeline 8. being equipped with valve 9. on the steam inlet, valve is equipped with 10. on the VOC distillation pipelines, in the condensation VOC Outlet conduit is equipped with valve, and valve is equipped on the cooler refrigerant inlet pipeline, is gone out in the cooler refrigerant The pipeline of mouth is equipped with valve.
In the present invention, targetedly selection and the stronger high boiling solvent of ingredient intermiscibility in VOC exhaust gas, such as white The intermiscibilities such as oily, kerosene and hexane, hexamethylene are preferable;The intermiscibilities such as dimethylbenzene, butyl oxide and ethyl alcohol, ether, acetone are preferable;Second The intermiscibilities such as glycol and ethyl alcohol, acetone, water, inorganic salts are preferable.Using intermiscibility principle, suitable high boiling solvent is selected, or Person is reached to be completely covered and there may be using several high boiling solvents formation composite absorbers that does not react mutually and can dissolve VOC ingredients, reach the target of overall absorption VOC.
Advantageous effect:Compared with prior art, the present invention its remarkable advantage is:Overall structure setting of the present invention is reasonable, It is pumped into the organic matter with VOC gas source with medium for about mixing tank volume 60% in blending tank, opens stirring, opens chuck refrigerant Inlet and outlet, make blending tank temperature keep than 30 DEG C of volatile organic matter low boiling point or more, control organic matter volatilization as possible, and setting is cold But device I and cooler II make organic matter liquid be cooled to lower temperature, the spray that liquid passes through venturi mixer through double coolers Mouth accelerates to spray into blending tank, and certain negative pressure is laterally formed in venturi, and the volatile organic matter gas containing VOC is pumped into text Mixer enters blending tank in mound, and leaching property gas is not discharged through wire mesh demister, uses length ratio for 30:10:7:75 gas Suction chamber, converging transition, trunnion section and diffuser, make venturi laterally persistently form negative pressure, and ensure that negative pressure is larger, higher boiling A certain amount of VOC of solvent absorption reaches when tending to saturation, using boiling-point difference, passes through steam heating, cooler I and cooler II, the VOC being dissolved in high boiling solvent is distilled, high boiling solvent is made to recycle, present apparatus sustainable operation has Effect reduces pollution, at low cost.
Description of the drawings
Fig. 1 is the overall structure diagram of the present invention;
Fig. 2 is the structural schematic diagram of heretofore described venturi mixer.
Specific implementation mode
The present invention is further illustrated with reference to the accompanying drawings and examples.
As depicted in figs. 1 and 2, a kind of utilization high boiling solvent of the present invention absorbs VOC and regeneration device, it Including cooling blending tank 1, cooler I 2, cooler II 3 and venturi mixer 4, they are connected by pipeline, the venturi Mixer 4 includes connecting tube 20, and gas suction chamber 21 is equipped in the connecting tube 20, is sucked in the connecting tube 20 and gas It is equipped with conical nozzle 22 in the gas suction chamber 21 of 21 junction of room, converging transition 23 is equipped in 21 rear end of gas suction chamber, The converging transition 23 is connected with trunnion section 24, and the trunnion section 24 is connected with diffuser 25, and VOC gas source import 16 is located at On gas suction chamber 21, the gas suction chamber 21, converging transition 23, trunnion section 24 and diffuser 25 length ratio be 30:10:7: 75, it is equipped with wire mesh demister 5 on 1 top of cooling blending tank, refrigerant chuck is equipped with outside 1 tank body of cooling blending tank 6, it is equipped with refrigerant inlet 7 in 6 lower part of refrigerant chuck, top is equipped with refrigerant exit 8, and pressure is equipped at the refrigerant inlet 7 Contracting gas source inlet 9 is equipped with steam inlet 10 at the refrigerant exit 8, and agitating device is equipped in the cooling blending tank 1 11, liquid pump 12 is equipped on the pipeline between the cooling blending tank 1 and cooler I 2, in the cooler I 2 and cooler It is equipped with refrigerant pipe 13 between II 3, cooler refrigerant inlet 14 is equipped on the cooler II 3, is equipped on cooler I 2 Cooler refrigerant exit 15 is equipped with VOC gas source import 16 on the venturi mixer 4, is pushed up in the wire mesh demister 5 Portion is equipped with drain 17, VOC distillation pipelines 18 is equipped between the cooler II 3 and cooling blending tank 1, in the liquid pump Pipeline between 12 and cooler I 2 is equipped with the outlets condensation VOC 19, the pipe between the cooling blending tank 1 and liquid pump 12 Road is equipped with valve 1. 26, valve 2. 27 is equipped on the pipeline between the liquid pump 12 and cooler I 2, in the cooling Pipeline between device II 3 and venturi mixer 4 is equipped with valve 3. 28, in the venturi mixer 4 and cooling blending tank 1 Between pipeline be equipped with valve 4. 29 and valve 5. 30, valve 6. 31 is equipped on 7 pipeline of the refrigerant inlet, described cold Matchmaker exports 8 pipelines and is equipped with valve 7. 32, and valve 8. 33 is equipped on 9 pipeline of compressed gas source import, the steam into Mouthful 10 pipelines are equipped with valve 9. 34, valve 10. 35 are equipped on the VOC distillation pipelines 18, in the outlets the condensation VOC 19 Pipeline is equipped with valve 36, valve 37 is equipped on 14 pipeline of cooler refrigerant inlet, in the cooler refrigerant The pipeline of outlet 15 is equipped with valve 38.When regeneration of absorption solution, each valve is controlled, it will be in refrigerant chuck 6 by compressed air Refrigerant be fully transferred to cooling medium tank, then be passed through steam, mixed liquor made to heat up, absorbed the VOC of dissolving by thermal evaporation through cooling Enter VOC after device cooling and export 19 pipelines, when liquidus temperature is higher than 110 DEG C, vapor delivery line temperature is decreased below the main compositions of VOC Stop heating when 20 DEG C of boiling point, terminates regenerative process.
The present invention provides a kind of thinking and methods, and there are many method and the approach for implementing the technical solution, the above institute State only is the preferred embodiment of the present invention, it is noted that for those skilled in the art, is not being departed from Under the premise of the principle of the invention, several improvements and modifications can also be made, these improvements and modifications also should be regarded as the guarantor of the present invention Range is protected, all undefined components in this embodiment can be implemented in the prior art.

Claims (3)

1. a kind of absorbing VOC and regeneration device using high boiling solvent, it is characterised in that:It includes cooling blending tank(1), Cooler I(2), cooler II(3)And venturi mixer(4), they are connected by pipeline, in the cooling blending tank(1) Top is equipped with wire mesh demister(5), in the cooling blending tank(1)Refrigerant chuck is equipped with outside tank body(6), pressed from both sides in the refrigerant Set(6)Lower part is equipped with refrigerant inlet(7), top is equipped with refrigerant exit(8), in the refrigerant inlet(7)Place is equipped with compressed gas source Import(9), in the refrigerant exit(8)Place is equipped with steam inlet(10), in the cooling blending tank(1)It is interior to be equipped with agitating device (11), in the cooling blending tank(1)With cooler I(2)Between pipeline be equipped with liquid pump(12), in the cooler I (2)With cooler II(3)Between be equipped with refrigerant pipe(13), in the cooler II(3)It is equipped with cooler refrigerant inlet (14), in cooler I(2)It is equipped with cooler refrigerant exit(15), in the venturi mixer(4)It is equipped with VOC gas Source import(16), in the wire mesh demister(5)Top is equipped with drain(17), in the cooler II(3)It is mixed with cooling Tank(1)Between be equipped with VOC distillation pipelines(18), in the liquid pump(12)With cooler I(2)Between pipeline be equipped with condensation VOC is exported(19), valve is designed in each connecting pipe.
2. according to claim 1 absorb VOC and regeneration device using high boiling solvent, it is characterised in that:It is described Venturi mixer(4)Including connecting tube(20), in the connecting tube(20)It is equipped with gas suction chamber(21), in the connection Pipe(20)With gas suction chamber(21)The gas suction chamber of junction(21)It is interior to be equipped with conical nozzle(22), sucked in the gas Room(21)Rear end is equipped with converging transition(23), the converging transition(23)With trunnion section(24)It is connected, the trunnion section(24)With diffusion Section(25)It is connected, VOC gas source import(16)It is located at gas suction chamber(21)On, the gas suction chamber(21), it is tapered Section(23), trunnion section(24)And diffuser(25)Length ratio be 30:10:7:75.
3. according to claim 1 absorb VOC and regeneration device using high boiling solvent, it is characterised in that:Institute State cooling blending tank(1)And liquid pump(12)Between pipeline be equipped with valve 1.(26), in the liquid pump(12)And cooling Device I(2)Between pipeline be equipped with valve 2.(27), in the cooler II(3)And venturi mixer(4)Between pipeline It is equipped with valve 3.(28), in the venturi mixer(4)With cooling blending tank(1)Between pipeline be equipped with valve 4. (29)5. with valve(30), in the refrigerant inlet(7)6. pipeline is equipped with valve(31), in the refrigerant exit(8)Pipeline It is equipped with valve 7.(32), in the compressed gas source import(9)8. pipeline is equipped with valve(33), in the steam inlet(10) 9. pipeline is equipped with valve(34), in the VOC distillation pipelines(18)It is equipped with valve 10.(35), exported in the condensation VOC (19)Pipeline is equipped with valve(36), in the cooler refrigerant inlet(14)Pipeline is equipped with valve(37), described Cooler refrigerant exit(15)Pipeline be equipped with valve(38).
CN201810647277.1A 2018-06-22 2018-06-22 It is a kind of to absorb VOC and regeneration device using high boiling solvent Pending CN108786381A (en)

Priority Applications (1)

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CN201810647277.1A CN108786381A (en) 2018-06-22 2018-06-22 It is a kind of to absorb VOC and regeneration device using high boiling solvent

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Application Number Priority Date Filing Date Title
CN201810647277.1A CN108786381A (en) 2018-06-22 2018-06-22 It is a kind of to absorb VOC and regeneration device using high boiling solvent

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114225651A (en) * 2021-11-23 2022-03-25 安徽金禾实业股份有限公司 Device and method for recovering sucralose esterification solvent cyclohexane

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Publication number Priority date Publication date Assignee Title
JP2010022959A (en) * 2008-07-22 2010-02-04 Kinji Takeuchi Deodorization apparatus
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CN205700046U (en) * 2016-04-29 2016-11-23 红板(江西)有限公司 A kind of VOCs controlling device
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Publication number Priority date Publication date Assignee Title
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CN205700046U (en) * 2016-04-29 2016-11-23 红板(江西)有限公司 A kind of VOCs controlling device
CN206184218U (en) * 2016-08-11 2017-05-24 上海睿思化工科技有限公司 Get rid of volatile organic compounds's in gas device
CN206152611U (en) * 2016-10-19 2017-05-10 中冶焦耐(大连)工程技术有限公司 Processing system who contains VOCs industrial waste gas
CN208711379U (en) * 2018-06-22 2019-04-09 江苏昌吉利新能源科技有限公司 It is a kind of to absorb VOC and regeneration device using high boiling solvent

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114225651A (en) * 2021-11-23 2022-03-25 安徽金禾实业股份有限公司 Device and method for recovering sucralose esterification solvent cyclohexane

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