CN108784628A - A kind of cleaning roller - Google Patents
A kind of cleaning roller Download PDFInfo
- Publication number
- CN108784628A CN108784628A CN201811000572.4A CN201811000572A CN108784628A CN 108784628 A CN108784628 A CN 108784628A CN 201811000572 A CN201811000572 A CN 201811000572A CN 108784628 A CN108784628 A CN 108784628A
- Authority
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- China
- Prior art keywords
- cleaning
- adhesive tape
- layer
- mass parts
- film layer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000004140 cleaning Methods 0.000 title claims abstract description 151
- 239000002390 adhesive tape Substances 0.000 claims abstract description 105
- 239000010410 layer Substances 0.000 claims abstract description 72
- 239000000843 powder Substances 0.000 claims abstract description 45
- 229910052500 inorganic mineral Inorganic materials 0.000 claims abstract description 38
- 239000000945 filler Substances 0.000 claims abstract description 28
- 239000012790 adhesive layer Substances 0.000 claims abstract description 18
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 17
- 239000000463 material Substances 0.000 claims abstract description 17
- 239000003086 colorant Substances 0.000 claims abstract description 6
- 239000010408 film Substances 0.000 claims description 57
- -1 polyethylene Polymers 0.000 claims description 34
- 239000004743 Polypropylene Substances 0.000 claims description 24
- 229920001155 polypropylene Polymers 0.000 claims description 21
- 239000000203 mixture Substances 0.000 claims description 18
- 239000010409 thin film Substances 0.000 claims description 18
- 238000002156 mixing Methods 0.000 claims description 17
- 239000004698 Polyethylene Substances 0.000 claims description 15
- 229920000573 polyethylene Polymers 0.000 claims description 15
- 238000005266 casting Methods 0.000 claims description 13
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 12
- 239000002699 waste material Substances 0.000 claims description 11
- 235000013339 cereals Nutrition 0.000 claims description 10
- 238000002844 melting Methods 0.000 claims description 10
- 230000008018 melting Effects 0.000 claims description 10
- 239000004615 ingredient Substances 0.000 claims description 8
- 238000004519 manufacturing process Methods 0.000 claims description 8
- 239000003607 modifier Substances 0.000 claims description 8
- 239000000314 lubricant Substances 0.000 claims description 7
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 6
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 6
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 claims description 6
- 239000003245 coal Substances 0.000 claims description 6
- 239000011248 coating agent Substances 0.000 claims description 6
- 238000000576 coating method Methods 0.000 claims description 6
- 238000001035 drying Methods 0.000 claims description 6
- 235000013312 flour Nutrition 0.000 claims description 6
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 claims description 6
- 235000021355 Stearic acid Nutrition 0.000 claims description 5
- 150000001336 alkenes Chemical class 0.000 claims description 5
- 239000012760 heat stabilizer Substances 0.000 claims description 5
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 5
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims description 5
- 239000008117 stearic acid Substances 0.000 claims description 5
- 238000004804 winding Methods 0.000 claims description 5
- 239000011521 glass Substances 0.000 claims description 4
- 239000004831 Hot glue Substances 0.000 claims description 3
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 claims description 3
- 241000276489 Merlangius merlangus Species 0.000 claims description 3
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 3
- 239000000440 bentonite Substances 0.000 claims description 3
- 229910000278 bentonite Inorganic materials 0.000 claims description 3
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 3
- 239000011230 binding agent Substances 0.000 claims description 3
- 239000004566 building material Substances 0.000 claims description 3
- 238000001354 calcination Methods 0.000 claims description 3
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 claims description 3
- 230000018044 dehydration Effects 0.000 claims description 3
- 238000006297 dehydration reaction Methods 0.000 claims description 3
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims description 3
- 239000000428 dust Substances 0.000 claims description 3
- 238000005461 lubrication Methods 0.000 claims description 3
- 239000002245 particle Substances 0.000 claims description 3
- 229920001195 polyisoprene Polymers 0.000 claims description 3
- 238000012545 processing Methods 0.000 claims description 3
- 239000004576 sand Substances 0.000 claims description 3
- 238000007493 shaping process Methods 0.000 claims description 3
- 229910052709 silver Inorganic materials 0.000 claims description 3
- 239000004332 silver Substances 0.000 claims description 3
- 239000002893 slag Substances 0.000 claims description 3
- 239000001993 wax Substances 0.000 claims description 3
- 239000011787 zinc oxide Substances 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 2
- 238000005520 cutting process Methods 0.000 claims description 2
- 239000000155 melt Substances 0.000 claims description 2
- 238000010345 tape casting Methods 0.000 abstract description 3
- 230000000052 comparative effect Effects 0.000 description 20
- 238000002360 preparation method Methods 0.000 description 17
- 239000002994 raw material Substances 0.000 description 10
- 230000000694 effects Effects 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 229920001971 elastomer Polymers 0.000 description 5
- 229920003023 plastic Polymers 0.000 description 5
- 239000004033 plastic Substances 0.000 description 5
- 239000005060 rubber Substances 0.000 description 5
- 238000010348 incorporation Methods 0.000 description 4
- 230000001965 increasing effect Effects 0.000 description 4
- 230000001154 acute effect Effects 0.000 description 3
- 238000007664 blowing Methods 0.000 description 3
- 230000015556 catabolic process Effects 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 238000006731 degradation reaction Methods 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 230000002708 enhancing effect Effects 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 238000010096 film blowing Methods 0.000 description 2
- 239000003292 glue Substances 0.000 description 2
- 239000008187 granular material Substances 0.000 description 2
- 229920001903 high density polyethylene Polymers 0.000 description 2
- 239000004700 high-density polyethylene Substances 0.000 description 2
- 229920001684 low density polyethylene Polymers 0.000 description 2
- 239000004702 low-density polyethylene Substances 0.000 description 2
- 239000012779 reinforcing material Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 238000012661 block copolymerization Methods 0.000 description 1
- 238000009933 burial Methods 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000012669 compression test Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 229920001179 medium density polyethylene Polymers 0.000 description 1
- 239000004701 medium-density polyethylene Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 238000005453 pelletization Methods 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 229920005629 polypropylene homopolymer Polymers 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 238000005057 refrigeration Methods 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 238000003900 soil pollution Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47L—DOMESTIC WASHING OR CLEANING; SUCTION CLEANERS IN GENERAL
- A47L25/00—Domestic cleaning devices not provided for in other groups of this subclass
- A47L25/005—Domestic cleaning devices not provided for in other groups of this subclass using adhesive or tacky surfaces to remove dirt, e.g. lint removers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29D—PRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
- B29D7/00—Producing flat articles, e.g. films or sheets
- B29D7/01—Films or sheets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/10—Homopolymers or copolymers of propene
- C08J2323/12—Polypropene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2423/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2423/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2423/04—Homopolymers or copolymers of ethene
- C08J2423/06—Polyethene
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Adhesive Tapes (AREA)
Abstract
The present invention provides a kind of cleaning rollers, which is characterized in that including:Tube filler, is cylindrical in shape and multiple cleaning adhesive tapes, successively in tube filler.Cleaning adhesive tape parallelogram has release layer, film layer and the adhesive-layer set gradually.Each cleaning adhesive tape, which is wound, forms the tubular with gap between screw to which in tube filler, the gap between screw of two neighboring cleaning adhesive tape mutually staggers, and the film layer that the film layer of two neighboring adhesive tape is different colours.Wherein, the film layer used in cleaning adhesive tape is prepared by inorganic mineral powder, high molecular material and auxiliary agent by the tape casting, is a kind of degradable film.
Description
Technical field
The present invention relates to a kind of cleaning rollers, and in particular to a kind of cleaning roller equipped with Environment protecting adhesive tape belongs to daily necessities
Field.
Background technology
Tape applications in daily life and industrial every aspect, wherein plastic adhesive tape be widely used, usage amount
Greatly, type it is various and it is easy mixed with Other Waste, therefore, it is difficult to recycle.If being carried out at burial or burning to this kind of adhesive tape
Reason, then will cause serious soil pollution or atmosphere pollution, pole to be unfavorable for environmental protection.On the other hand, the main original of plastic adhesive tape
Material is various high-molecular compounds, and main source is oil.However oil is non-renewable resources, therefore subtracting with resource
Few, the production cost of plastic adhesive tape is also constantly rising.
In order to reduce plastic adhesive tape to the pollution of environment and the consumption of limited resources, occurring some in the prior art can drop
Adhesive tape (such as line paper self-adhesive tape, PLA adhesive tapes etc.) is solved, primary raw material is that biodegradable material is made with plant fiber.
But the performances such as such degradable adhesive tape stability, tensile strength, with plastic adhesive tape gap, and such biology can drop
The material composition higher of solution limits the application range of such degradable adhesive tape.There are some Environment protecting adhesive tapes in the prior art,
Primary raw material is made of being mixed with by inorganic mineral powder and other high molecular materials.It gives up since building may be used in inorganic mineral powder
Material is used as raw material, belongs to waste utilization, therefore is good for the environment and cost is relatively low.However inorganic mineral powder is in preparation process
It is easy to happen shedding phenomenon, therefore such Environment protecting adhesive tape product equal defect in terms of intensity and appearance, it is difficult to be applied to pair
Intensity and appearance require on higher product.
Most-often used hand-held cleaning roller requires all the strength character of used cleaning adhesive tape in household cleaning
It is relatively high.Cleaning roller is generally divided into tearing type cleaning roller and not tearing type cleaning roller.Tearing type cleaning roller does not pass through
Cleaning roller achievees the purpose that Reusability, but back roll surface, which is cleaned multiple times, can gradually lose viscosity, service life compared with
It is short.Tearing type cleaning roller is brought by the outermost cleaning rubber of roller of tearing successively achievees the purpose that keep roller viscosity, clearly
Clean adhesive tape use runs out of rear replaceable tube filler and is continuing with.It is divided into according to its structure and tears formula to be flat and tiltedly tear formula, put down that tear formula clear
Clean roller in use, tear outermost cleaning adhesive tape when, it is easy to while tearing and multiple cleaning adhesive tapes or causing
The damage of internal layer cleaning adhesive tape causes unnecessary waste.It tiltedly tears formula to tear formula effect compared to flat and make moderate progress, but was using
It is more difficult in journey quick and precisely to find outermost cleaning adhesive tape and torn, and be still easy while tearing more without solving
The problem of opening cleaning adhesive tape.On the other hand, the structure of one layer of release paper of tearing type cleaning roller generally use one layer tape, in a disguised form
The thickness for increasing cleaning roller reduces the utilization rate of cleaning roller.
Invention content
To solve the above problems, present invention employs following technical solutions:
The present invention provides a kind of cleaning rollers, which is characterized in that including:Tube filler, is cylindrical in shape and multiple cleaning adhesive tapes,
Successively in tube filler.Wherein, cleaning adhesive tape parallelogram has the release layer set gradually, film layer and glues
Glue-line.Each cleaning adhesive tape, which wind, forms the tubular with gap between screw thus in tube filler, two neighboring cleaning rubber
The gap between screw of band mutually staggers, and the film layer that the film layer of two neighboring adhesive tape is different colours.
The present invention provides a kind of cleaning rollers, can also have the feature that, wherein the bottom edge length of cleaning adhesive tape
For 150mm~550mm.The height of cleaning adhesive tape is equal with the height of tube filler.The sharp angle on cleaning adhesive tape bottom edge and side composition
It is 15 degree~70 degree.
The present invention provides a kind of cleaning rollers, can also have the feature that, wherein a bottom edge of cleaning adhesive tape
The either flush on concordant and another with the bottom surface of tube filler bottom edge and tube filler, two sides of cleaning adhesive tape after the completion of winding
Form gap between screw.
The present invention provides a kind of cleaning rollers, can also have the feature that, wherein release layer is release oil reservoir.
Adhesive-layer is aqueous glue-line, hot melt adhesive layer, caoutchouc layer or other adhesive layers.
The present invention provides a kind of cleaning rollers, can also have the feature that, wherein film layer is predetermined to be embedded with
The environment-friendlythin thin film of the inorganic mineral powder granular of grain size contains following ingredient:The inorganic mineral powder of 34~85 mass parts, 2~10 mass parts
Polyethylene, the polypropylene of 11~30 mass parts and the auxiliary agent of 1~5 mass parts.
The present invention provides a kind of cleaning rollers, can also have the feature that, wherein the manufacturing method packet of film layer
Include following steps:
Step S1 weighs the inorganic mineral powders of 34~85 mass parts, the polyethylene of 2~10 mass parts, 11~30 mass parts
Polypropylene and the auxiliary agent of 1~5 mass parts and sequentially add in mixing machine, with the rotating speed mixing 20 of 100~130r/min~
25 minutes so that obtain raw mixture.
Raw mixture is carried out melting mixing to obtain by step S2 by extruder with 180~250 DEG C of temperature conditions
Melting mixing object, and high-speed cutting is carried out to obtain agglomerate material to melting mixing object;
Step S3, carries out vacuum dehydration by agglomerate material and melts, and squeezes out and passes through through the vacuum pump in casting apparatus
Outflow is to obtain casting films in the gap of the die head front end of casting apparatus;
Casting films are carried out cooling and shaping and longitudinal stretching are to obtain film layer by step S4.
The present invention provides a kind of cleaning rollers, can also have the feature that, wherein the manufacture of the cleaning adhesive tape
Method includes the following steps:
Step S5, it is release oily to form release layer in the first working face coating of film layer;
Step S6, film layer the second working face coating binder to form adhesive layer;
Step S7, to by the step S5 and step S6 treated film layers carry out drying and processing and be cut and formed from
And obtain cleaning adhesive tape.
The present invention provides a kind of cleaning rollers, can also have the feature that, wherein inorganic mineral powder include calcining or
Calcium carbonate, calcium sulfate, copper sulphate, bentonite, silver mountain flour, carclazyte, talcum powder, whiting, zinc oxide, the hollow glass that do not calcine
Glass microballon, grains of sand powder, waste coal ground-slag, waste coal spoil powder, useless building materials mountain flour, one kind in collection PM2.5 dust or arbitrary several
The mixture formed.
The present invention provides a kind of cleaning rollers, can also have the feature that, wherein the average diameter grain of inorganic mineral powder
For the mesh of 800 mesh~1200.
The present invention provides a kind of cleaning rollers, can also have the feature that, wherein the auxiliary agent changes comprising surface
Property agent PN-827, heat stabilizer BASF225, lubricant zinc stearate L-806, lubricant PP waxes, surface modifier stearic acid
One kind in 1801 or arbitrary several formed mixtures.
Invention effect
The cleaning roller of offer according to the present invention forms the cylinder with gap between screw since each cleaning adhesive tape is wound
Shape is to which in tube filler, the gap between screw of two neighboring cleaning adhesive tape mutually staggers, and the film of two neighboring adhesive tape
Therefore layer, which is the film layer of different colours, in use, can fast and accurately find outermost cleaning adhesive tape.Together
When since the sharp angle that the bottom edge of cleaning adhesive tape and side are formed is 15 degree~70 degree, in use if any need
It wants, easily outermost cleaning adhesive tape can be torn from acute angle and cannot be easily caused the damage of internal layer cleaning adhesive tape
It is bad.
Be in environment-friendlythin thin film used in film layer due to cleaning adhesive tape with the inorganic mineral powder of 34~85 mass parts, 2~
The polyethylene of 10 mass parts, 11~30 mass parts polypropylene prepared as primary raw material, therefore, which has good
Degradability.Due to the polypropylene containing 11~30 mass parts in environment-friendlythin thin film, and polypropylene can increase forming property,
So that cleaning adhesive tape is easier to shape in preparation process, the roughness that cleaning adhesive tape shows is reduced, ensure that cleaning
Shedding phenomenon will not occur in use for adhesive tape, to improve the service efficiency of cleaning roller.Due in environment-friendlythin thin film
Polyethylene containing 2~10 mass parts, and polyethylene can reinforcing material reinforce, therefore the stability of cleaning adhesive tape can be increased
And tensile strength, to improve the performance of cleaning roller.
Description of the drawings
Fig. 1 is the structural schematic diagram of the cleaning roller of the embodiment of the present invention one;
Fig. 2 be the embodiment of the present invention one cleaning roller in cleaning adhesive tape structural profile illustration;
Fig. 3 be the embodiment of the present invention one cleaning roller in cleaning adhesive tape structural plan schematic diagram.In figure, 10- tube fillers;
20- cleaning adhesive tapes;21- gap between screw;22- release layers;23- film layers;24- adhesive-layers.
Specific implementation mode
The present invention provides a kind of cleaning rollers, and the specific implementation mode of the present invention is illustrated below in conjunction with attached drawing.
<Embodiment one>
As shown in Figure 1, cleaning roller 100 includes in the present invention:Tube filler 10 and cleaning adhesive tape 20.
Tube filler 10 is cylindrical in shape, and the height of the tube filler is 120mm, overall diameter 50mm, thickness 1.5mm.
Multiple cleaning adhesive tapes 20, in tube filler 10.As shown in Fig. 2, having the release layer 22 set gradually, film layer
23 and adhesive-layer 24, thickness 0.03mm.
Wherein, release layer 22 is release oil reservoir.Film layer 23 is the environmental protection for the inorganic mineral powder granular for being embedded with predetermined particle diameter
Film.Adhesive layer 24 is aqueous glue-line.
Wherein, the film layer 23 of two adjacent cleaning adhesive tapes 20 is different colours.Due to release layer 22 and adhesive-layer 23
All it is the release oil reservoir of water white transparency and aqueous glue-line so that two neighboring cleaning adhesive tape 20 can pass through the difference of film layer 23
Color is distinguished.
Wherein, in two adjacent cleaning adhesive tapes 20, the release layer 22 of the cleaning adhesive tape 20 of outer layer is wound on the clear of internal layer
On the adhesive-layer 24 of clean adhesive tape 20.Due to the effect of release oil in release layer 22 so that two adjacent cleaning adhesive tapes 20 will not
Stick together phenomenon.
As shown in figure 3,20 parallelogram of cleaning adhesive tape, bottom edge length L is 320mm, high H and tube filler height phase
Together, it is 120mm.The sharp angle of bottom edge and side composition is 30 degree.One bottom edge of each cleaning adhesive tape 20 and tube filler 10
The either flush on bottom surface concordant and another bottom edge and tube filler 10, winding form the tubular with gap between screw, to roll up
It is wound in tube filler 10.After winding shaping, two sides of cleaning adhesive tape 20 form gap between screw 21, the width of gap between screw 21
For 1mm~2mm.
During the use of cleaning roller 100, user can by the different color of adjacent thin film layers 23 and mutually
The gap between screw 21 being staggered finds outermost cleaning adhesive tape 20, and will most from the acute angle that bottom edge and side form
The cleaning adhesive tape 20 of outer layer is torn.
Wherein, the film layer 22 of cleaning adhesive tape 20 is the environment-friendlythin thin film for the inorganic mineral powder granular for being embedded with predetermined particle diameter, is contained
There is following ingredient:The inorganic mineral powder of 34~85 mass parts, the polyethylene of 2~10 mass parts, 18~30 mass parts polypropylene with
And 1~5 mass parts auxiliary agent.
The preparation method of environment-friendlythin thin film such as following step used in film layer 23 in the present embodiment:
Step S1 weighs the inorganic mineral powders of 34~85 mass parts, the polyethylene of 2~10 mass parts, 18~30 mass parts
It polypropylene and the auxiliary agent of 1~5 mass parts and sequentially adds in mixing machine, and mixed with the rotating speed of 100r/min~130r/min
It closes 20~25 minutes, to obtain raw mixture.
Wherein, inorganic mineral powder include calcining or do not calcine calcium carbonate, calcium sulfate, copper sulphate, bentonite, silver mountain flour,
Carclazyte, talcum powder, whiting, zinc oxide, hollow glass micropearl, grains of sand powder, waste coal ground-slag, waste coal spoil powder, useless building materials mountain flour,
Collect one kind in PM2.5 dust or arbitrary several formed mixtures.The grain size of inorganic mineral powder granular is 800 mesh to 1200
Mesh.Polyethylene includes high density polyethylene (HDPE), medium density polyethylene, low density polyethylene (LDPE) and its mixture.Polypropylene uses homopolymerization
Polypropylene.Auxiliary agent includes surface modifier PN-827, heat stabilizer BASF225, lubricant zinc stearate L-806, lubricant PP
Wax, one kind in surface modifier stearic acid 1801 or arbitrary several formed mixtures.
Step S2 carries out melting to raw mixture under 180 DEG C~250 DEG C temperature conditions by continuous internal mixer and mixes
Refining, screw rod push raw mixture in feeder to head position in high-speed rotation, and powdery and granular material are melted rapidly
Change, carrying out high speed pelletizing by the edge of a knife after extrusion is made granular agglomerate material.
Step S3 carries out vacuum dehydration to agglomerate material by vacuum pump, and suppresses conveying through screw rod, and agglomerate material is melted
Melt, then flowed out by the gap of die head front end after the Twin-screw vacuum pump of casting apparatus squeezes out, forms melt film.
Step S4, the low temperature for reaching casting apparatus after allowing melt film to leave die head by a short gap are cast roll surface
And quick refrigeration is shaped, and vertically and horizontally stretching is carried out using the draw roll of casting apparatus and forms two-way film.Formed two-way film be
Environment-friendlythin thin film.
The preparation method such as following step of cleaning adhesive tape 20 used in the present embodiment:
Step S5 forms release layer 22 in the release oil of the first working face coating of environment-friendlythin thin film.
Step S6 forms adhesive layer 24 in the second working face coating binder of environment-friendlythin thin film.
Step S7, to carrying out drying and processing by step S5 and step S6 treated base materials and being cut and formed, to
To cleaning adhesive tape 20.
In the present embodiment, the actual conditions of each step are as follows:
The specific addition of each ingredient employed in step S1 is:The poly- second of the inorganic mineral powder of 71 mass parts, 5 mass parts
The auxiliary agent of alkene, the polypropylene of 20 mass parts and 4 mass parts, mixing rotating speed be 100r/min~130r/min, incorporation time 20~
25 minutes.Wherein, it is 1000 mesh that inorganic mineral powder, which selects calcium carbonate, grain size,.Added with heat stabilizer BASF225, lubrication in auxiliary agent
Agent zinc stearate L 1, surface modifier stearic acid 1801.
The melting mixing temperature condition of step S2 is 200~210 DEG C;
<Embodiment two>
In the present embodiment two, identical symbol is given for structure identical with embodiment one, method and condition, and save
Slightly identical explanation.
In embodiment two, the structure of cleaning roller 100 is identical as embodiment one, the preparation method of cleaning adhesive tape also with implementation
Example one is identical, but raw material dosage and preparation condition are different, specially:
The specific addition of each ingredient employed in step S1 is:The poly- second of the inorganic mineral powder of 60 mass parts, 6 mass parts
The auxiliary agent of alkene, the polypropylene of 29 mass parts and 5 mass parts, mixing rotating speed be 115r/min~130r/min, incorporation time 20~
25 minutes.Wherein, it is 1000 mesh that inorganic mineral powder, which selects calcium carbonate, grain size,.Added with heat stabilizer BASF225, lubrication in auxiliary agent
Agent zinc stearate L 1, surface modifier stearic acid 1801.
The melting mixing temperature condition of step S2 is 220~230 DEG C.
<Embodiment three>
In the present embodiment three, identical symbol is given for structure identical with embodiment one, method and condition, and save
Slightly identical explanation.
In embodiment three, the structure of cleaning roller 100 is identical as embodiment one, the preparation method of cleaning adhesive tape also with implementation
Example one is identical, but raw material dosage and preparation condition are different, specially:
The specific addition of each ingredient employed in step S1 is:The poly- second of the inorganic mineral powder of 63 mass parts, 7 mass parts
The auxiliary agent of alkene, the polypropylene of 27 mass parts and 3 mass parts, mixing rotating speed be 100r/min~120r/min, incorporation time 20~
25 minutes.Wherein, it is 1000 mesh that inorganic mineral powder, which selects calcium carbonate, grain size,.Added with surface modifier PN -827, heat in auxiliary agent
Stabilizer BASF225, lubricant zinc stearate L 1, lubricant PP waxes.
The melting mixing temperature condition of step S2 is 230~250 DEG C.
<Comparative example one>
In this comparative example one, identical symbol is given for structure identical with embodiment one, method and condition, and save
Slightly identical explanation.
In comparative example one, the structure of cleaning roller 100 is identical as embodiment one, the preparation method of cleaning adhesive tape also with implementation
Example one is identical, and raw material dosage is also identical as embodiment one, but the preparation method of film layer is different, specially:
Step S3:By agglomerate material input by extruder and the extruder processed of O font mould mouth builders, extruder is controlled
Temperature makes granular material soften, and conveying is suppressed through screw rod, and melted material presses to film-blowing die head, and blowing mould die head makes film, with
This simultaneously, film-blowing die head rotation, film blows out under the action of the forces of the wind.
That is, this comparative example one is relative to embodiment one, difference lies in use blowing to manufacture film layer.
<Comparative example two>
In this comparative example two, identical symbol is given for structure identical with embodiment one, method and condition, and save
Slightly identical explanation.
In comparative example two, the structure of cleaning roller 100 is identical as embodiment one, the preparation method of cleaning adhesive tape also with implementation
Example one is identical, but raw material dosage and preparation condition are different, specially:
The specific addition of each ingredient employed in step S1 is:The inorganic mineral powder of 70 mass parts, 25 mass parts it is poly-
The auxiliary agent of ethylene and 5 mass parts, mixing rotating speed are 100r/min~130r/min, incorporation time 20~25 minutes.
That is, this comparative example two is relative to embodiment one, difference lies in be added without poly- third in two raw material of comparative example
Alkene.
Embodiment effect
The cleaning roller of offer according to the present invention, due to the film that the film layer of two neighboring adhesive tape is different colours
Layer, therefore, in use, can fast and accurately find outermost cleaning adhesive tape.
The tubular with gap between screw is formed since each cleaning adhesive tape is wound in tube filler, it is two neighboring
The gap between screw of cleaning adhesive tape mutually staggers, therefore, in use if it is desired, tearing by outermost cleaning adhesive tape
When, unnecessary waste will not be caused there is a situation where multiple cleaning adhesive tapes of once tearing.
Since the sharp angle that the bottom edge of cleaning adhesive tape and side are formed is 15 degree~70 degree, in use
If it is desired, easily outermost cleaning adhesive tape can be torn from acute angle and cannot be easily caused internal layer cleaning rubber
The damage of band.
Since the release layer of cleaning adhesive tape is release oil reservoir, adhesive-layer is aqueous glue-line, therefore, adjacent two cleaning rubbers
In band, the release layer of the cleaning adhesive tape of outer layer is on the adhesive-layer of the cleaning adhesive tape of internal layer so that two adjacent cleanings
Adhesive tape will not stick together phenomenon.Meanwhile release paper is covered without showing in cleaning adhesive tape in winding process, to increase
The quantity of cleaning adhesive tape on the cleaning roller of same thickness, improves cleaning roller service efficiency.
By the film (environment-friendlythin thin film of i.e. uncoated adhesive and release oil) of gained in the various embodiments described above and comparative example
Carry out compression test, heatproof test and degradation test.Its performance parameter is as shown in table 1 below.
The performance parameter of 1 film of table
Compared with each embodiment and comparative example, in embodiment one be added inorganic mineral powder amount it is more, degradation time compared with
It is short, illustrate that inorganic mineral powder has the function of enhancing degradation property.
Compared with each embodiment and comparative example, the amount that polyethylene is added in embodiment three is more, and resistance to tensile strength is also high
In other embodiment, illustrate that polyethylene has the function of increasing film strength.
Compared with each embodiment and comparative example, comparative example one is formed a film using blowing, and shedding rate is very high, and explanation is adopted
Shedding phenomenon can preferably be inhibited by carrying out film preparation with the tape casting and casting apparatus, improve the forming effect of film.
Compared with each embodiment and comparative example, polypropylene is not added in comparative example two, shedding rate is higher, temperature tolerance
It is poor.Meanwhile inventor also found, compared with each embodiment, the film surface of comparative example two is more coarse, and when translumination observation is interior
Portion also has coarse uneven texture, illustrates that polypropylene has the function of enhancing forming property, reduces shedding.
As it can be seen that according to the cleaning adhesive tape that one~embodiment of above-described embodiment three provides, due to ring used in its film layer
The inorganic mineral powder containing 34~85 mass parts in film is protected, the mass content for being equivalent to wherein inorganic mineral powder reaches 70% or more,
Therefore, which has good degradability, and environmental pollution is small, is good for the environment.Meanwhile inorganic mineral powder is useless to build
Material is used as raw material, is consequently belonging to waste utilization and significantly reduces the production cost of environment-friendlythin thin film, thereby reduces clear
The production cost of clean roller.
Since inorganic mineral powder is formed in the form of embedded in film layer, so that inorganic mineral powder is firmly combined with, it is not easy
Shedding, while film layer appearance also being allowed to show smooth state.
Due to the polypropylene containing 11~30 mass parts in environment-friendlythin thin film, and polypropylene can increase the forming of product
Performance, to reduce the roughness on cleaning adhesive tape surface, is protected so that environment-friendlythin thin film is easier to shape in preparation process
It has demonstrate,proved cleaning roller and has been less likely to occur shedding phenomenon in use, improved the service efficiency of cleaning roller.
Due to the polyethylene containing 2~10 mass parts in environment-friendlythin thin film, and polyethylene can reinforcing material intensity, therefore energy
The stability and tensile strength for enough increasing cleaning adhesive tape, to improve the performance of cleaning roller.
Due to containing polyethylene and polypropylene in environment-friendlythin thin film, and the two ratio is appropriate, thus can by the tape casting and
Prepared by casting apparatus, so as to further increase formability of the environment-friendlythin thin film in preparation process, preferably inhibit
Shedding phenomenon, improves the service efficiency of cleaning roller.
Since cleaning adhesive tape is combined inorganic mineral powder film and water-based glue in preparation process, cleaning rubber belt
There are lower drying temperature and bondline thickness.Its reason is that the micropore on the surface of inorganic mineral powder film itself can be better
It is binded with glue-line, and its more gas permeability of the natural ore powder ingredient contained in it are preferable, contribute to the progress of drying course;And
The characteristic that the drying temperature that aqueous glue-line has itself is low and colloidality is good is played with the inorganic mineral powder film and is mutually promoted
Effect.
The preferred embodiment of the present invention has been described in detail above.It should be appreciated that the ordinary skill of this field is without wound
The property made labour, which according to the present invention can conceive, makes many modifications and variations.Therefore, all technician in the art
Pass through the available technology of logical analysis, reasoning, or a limited experiment on the basis of existing technology under this invention's idea
Scheme, all should be in the protection domain being defined in the patent claims.
For example, the tube filler height of cleaning roller is 120mm, overall diameter 50mm in above-described embodiment and comparative example, it is applicable in
In cleaning smaller article, such as knapsack, back cushion and pet adhesive hair etc..In cleaning roller provided by the present invention, may be used also
According to the height of different tube fillers, overall diameter, to be suitable for cleaning various articles.
For example, the polypropylene used in cleaning adhesive tape preparation process in above-described embodiment and comparative example is homopolypropylene.
In cleaning roller provided by the present invention, polypropylene can also use block copolymerization polypropylene.
For example, adhesive-layer is aqueous glue-line in cleaning adhesive tape in above-described embodiment and comparative example.Provided by the present invention
In cleaning roller, adhesive-layer can also be hot melt adhesive layer, caoutchouc layer or other adhesive layers.
Claims (10)
1. a kind of cleaning roller, which is characterized in that including:
Tube filler is cylindrical in shape;And
Multiple cleaning adhesive tapes, successively in the tube filler,
Wherein, the cleaning adhesive tape parallelogram has release layer, film layer and the adhesive-layer set gradually,
Each cleaning adhesive tape, which wind, forms the tubular with gap between screw thus in the tube filler, two neighboring
The gap between screw of the cleaning adhesive tape mutually staggers, and the film layer of the two neighboring adhesive tape is different colours
Film layer.
2. cleaning roller according to claim 1, it is characterised in that:
Wherein, the bottom edge length of the cleaning adhesive tape is 150mm~550mm;
The height of the cleaning adhesive tape is equal with the height of the tube filler;
The sharp angle of the cleaning adhesive tape bottom edge and side composition is 15 degree~70 degree.
3. cleaning roller according to claim 2, it is characterised in that:
Wherein, concordant and another with the bottom surface of the tube filler of the bottom edge bottom edge of each cleaning adhesive tape and the cylinder
The either flush of core, two sides of the cleaning adhesive tape form the gap between screw after the completion of winding.
4. cleaning roller according to claim 1, it is characterised in that:
Wherein, the release layer is release oil reservoir;
The adhesive-layer is aqueous glue-line, hot melt adhesive layer or caoutchouc layer.
5. cleaning roller according to claim 1, it is characterised in that:
Wherein, the film layer is the environment-friendlythin thin film for the inorganic mineral powder granular for being embedded with predetermined particle diameter, contains following ingredient:
The inorganic mineral powder of 34~85 mass parts;
The polyethylene of 2~10 mass parts;
The polypropylene of 11~30 mass parts;And
The auxiliary agent of 1~5 mass parts.
6. cleaning roller according to claim 5, it is characterised in that:
Wherein, the manufacturing method of the film layer includes the following steps:
Step S1, weigh the inorganic mineral powder of 34~85 mass parts, the polyethylene of 2~10 mass parts, 18~30 mass parts poly- third
It alkene and the auxiliary agent of 1~5 mass parts and sequentially adds in mixing machine, 20~25 points is mixed with the rotating speed of 100~130r/min
Clock is to obtain raw mixture;
The raw mixture is carried out melting mixing to obtain by step S2 by extruder with 180~250 DEG C of temperature conditions
Melting mixing object, and high-speed cutting is carried out to obtain the agglomerate material to the melting mixing object;
Step S3, carries out vacuum dehydration by the agglomerate material and melts, and squeezes out and passes through through the vacuum pump in casting apparatus
Outflow is to obtain casting films in the gap of the die head front end of the casting apparatus;
The casting films are carried out cooling and shaping and longitudinal stretching are to obtain the film layer by step S4.
7. cleaning roller according to claim 5, it is characterised in that:
Wherein, the manufacturing method of the cleaning adhesive tape includes the following steps:
Step S5, it is release oily to form the release layer in the first working face coating of the film layer;
Step S6, the film layer the second working face coating binder to form the adhesive layer;
Step S7, to treated that the film layer carries out drying and processing and cuts by the step S5 and step S6
Shape is to obtain the cleaning adhesive tape.
8. cleaning roller according to claim 5, it is characterised in that:
Wherein, the inorganic mineral powder include calcining or do not calcine calcium carbonate, calcium sulfate, copper sulphate, bentonite, silver mountain flour,
Carclazyte, talcum powder, whiting, zinc oxide, hollow glass micropearl, grains of sand powder, waste coal ground-slag, waste coal spoil powder, useless building materials mountain flour,
Collect one kind in PM2.5 dust or arbitrary several formed mixtures.
9. cleaning roller according to claim 5, it is characterised in that:
Wherein, the average diameter grain of the inorganic mineral powder is the mesh of 800 mesh~1200.
10. cleaning roller according to claim 5, it is characterised in that:
Wherein, the auxiliary agent includes surface modifier PN-827, heat stabilizer BASF225, lubricant zinc stearate L-806, profit
Lubrication prescription PP waxes, one kind in surface modifier stearic acid 1801 or arbitrary several formed mixtures.
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CN201811000572.4A CN108784628A (en) | 2018-08-30 | 2018-08-30 | A kind of cleaning roller |
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CN201811000572.4A CN108784628A (en) | 2018-08-30 | 2018-08-30 | A kind of cleaning roller |
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