CN108774912A - A kind of preparation method of restoring consciouness paper handkerchief - Google Patents
A kind of preparation method of restoring consciouness paper handkerchief Download PDFInfo
- Publication number
- CN108774912A CN108774912A CN201810388997.0A CN201810388997A CN108774912A CN 108774912 A CN108774912 A CN 108774912A CN 201810388997 A CN201810388997 A CN 201810388997A CN 108774912 A CN108774912 A CN 108774912A
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- CN
- China
- Prior art keywords
- added
- preparation
- paper handkerchief
- pulp
- restoring consciouness
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H15/00—Pulp or paper, comprising fibres or web-forming material characterised by features other than their chemical constitution
- D21H15/02—Pulp or paper, comprising fibres or web-forming material characterised by features other than their chemical constitution characterised by configuration
- D21H15/10—Composite fibres
-
- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47K—SANITARY EQUIPMENT NOT OTHERWISE PROVIDED FOR; TOILET ACCESSORIES
- A47K10/00—Body-drying implements; Toilet paper; Holders therefor
- A47K10/16—Paper towels; Toilet paper; Holders therefor
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/88—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds
- D01F6/92—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds of polyesters
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H11/00—Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H11/00—Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only
- D21H11/12—Pulp from non-woody plants or crops, e.g. cotton, flax, straw, bagasse
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H13/00—Pulp or paper, comprising synthetic cellulose or non-cellulose fibres or web-forming material
- D21H13/10—Organic non-cellulose fibres
- D21H13/20—Organic non-cellulose fibres from macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D21H13/24—Polyesters
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Textile Engineering (AREA)
- Health & Medical Sciences (AREA)
- Public Health (AREA)
- Manufacturing & Machinery (AREA)
- Paper (AREA)
- Medicines Containing Plant Substances (AREA)
Abstract
The present invention provides a kind of preparation method of restoring consciouness paper handkerchief, and potassium permanganate is added in ethanol solution, is stood after stirring, filters off precipitation, and activated carbon, filtering is added, and filtrate is filtered through silica gel, obtains the ethyl alcohol of purifying；Rose, ginseng, rhodiola root, Chinese herbaceous peony cleaning are smashed to pieces and be placed in water vapor generation device only, arrives mixed essential oil；Neral, muskone are added in ethyl alcohol after purification, mixed essential oil is added after 4-6 days in sealing, it is sealed and stored 3-5 days, beta cyclodextrin is added to stirring in warm water, saturated solution is made, mixed ethanol mixed liquor, heating stirring 1-2h is added according to proportioning, natural cooling precipitates crystal, it filters, dry 2h at 50 DEG C；Product is added in 10wt% PLA solutions, and composite polylactic acid fiber is obtained by electrostatic spinning, is then beaten softwood pulp, cotton pulp, hardwood pulp, composite polylactic acid fiber, through manufacturing paper with pulp, rewinding.The preparation method of paper handkerchief provided by the invention is easy to operate, at low cost, is easy large-scale production, has good application prospect.
Description
Technical field
The present invention relates to paper handkerchief preparing technical field more particularly to a kind of preparation methods of restoring consciouness paper handkerchief.
Background technology
It is well known that paper handkerchief is a kind of daily necessities, its ingredient has chlorine, bleaching powder, alcohol, wood pulp and renewable
Resource.Paper handkerchief type is varied, there is tissue, napkin paper, kitchen paper or cleansing tissue etc..Had using paper handkerchief relative to handkerchief
There are many benefits, it can be greatly reduced bacterium germ and be infected caused by reusing handkerchief；Secondly purposes is wide, some quality
Preferable paper handkerchief can be used, furthermore it is easy to carry with Wet-dry in addition to moisture absorption can also dip in water, small not take up space,
More meet the living habit of modern.Though current tissue products existing on the market are provided to the basic use needs of people,
But its own structure and use are had been found that in actual use with the increase of operating pressure with the improvement of people ' s living standards
Fail to reach best using effect and performance in performance, there are still there are many deficiencies, in addition to the material for paper handkerchief requires
Outside, it is also not being met to Functional Requirement subsidiary in paper handkerchief, such as the fragrance that possesses of paper handkerchief is pure and fresh refreshes oneself, additionally it is possible to have
There is clear refreshing, restoring consciouness function, and can ensure not injure human body, and existing paper handkerchief can not meet making for consumer
Use demand.
Invention content
The object of the invention is exactly to provide a kind of preparation method of restoring consciouness paper handkerchief to make up the defect of prior art.
The present invention is achieved by the following technical solutions：
A kind of preparation method of restoring consciouness paper handkerchief, including step in detail below：
(1) it will be added in ethanol solution after potassium permanganate distillation water dissolution, stand a period of time after rapid stirring, filter off
Activated carbon is added into solution for precipitation, filters, filtrate is filtered through silica gel, the ethyl alcohol purified is spare after placing 3-5 days；
(2) it smashs to pieces and is placed in water vapor generation device after cleaning up rose, ginseng, rhodiola root, Chinese herbaceous peony, be added one
It is heated to boiling after quantitative distilled water, when essential oil amount does not stop heating when increasing in reaction unit, the system of waiting for is cooled to often
By water-oil separating after temperature, oil reservoir is extracted with ethyl acetate rear rotary evaporation and obtains mixed essential oil；
(3) neral, muskone are added in the ethyl alcohol of step (1) after purification, step is added after placing 4-6 days in sealing
(2) mixed essential oil obtained continues to be sealed and stored 3-5 days, beta cyclodextrin is then added to stirring in warm water, saturated solution is made,
Above-mentioned mixed ethanol mixed liquor is added according to proportioning, heated constant temperature stirs 1-2h, and natural cooling precipitates crystal, and filters, in 50 DEG C
Lower dry 2h；
(4) product that step (3) is prepared is added in 10wt% PLA solutions, is obtained by electrostatic spinning compound
Acid fiber by polylactic, then softwood pulp, cotton pulp, hardwood pulp, composite polylactic acid fiber are added in trough-style pulp beater be beaten to
25-30SR ° of beating degree, most afterwards through manufacturing paper with pulp, rewinding.
The proportioning of a kind of preparation method of restoring consciouness paper handkerchief, potassium permanganate and ethanol solution described in step (1) is：
2.5-5g：250ml.
A kind of preparation method of restoring consciouness paper handkerchief, the quality of rose, ginseng, rhodiola root, Chinese herbaceous peony described in step (2)
Than for 4-6：2-3：7-9：4-6, wherein rose, ginseng, rhodiola root and the total weight of Chinese herbaceous peony and the proportioning of distilled water are 20-
22g：20-25ml.
A kind of preparation method of restoring consciouness paper handkerchief, neral, muskone, mixed essential oil and purifying described in step (3)
The volume proportion of ethyl alcohol is 3-5：1.6-2.2：5-7：90-110.
A kind of preparation method of restoring consciouness paper handkerchief, the heating stirring temperature 45 C described in step (3), mixing time 1-
The proportioning of 1.5h, beta cyclodextrin and alcohol mixed solution is 1g：0.1-0.4ml.
A kind of preparation method of restoring consciouness paper handkerchief, it is molten that the product prepared in (3) the step of described in step (4) accounts for polylactic acid
The 5-8% of liquid weight.
A kind of preparation method of restoring consciouness paper handkerchief, it is softwood pulp, cotton pulp, hardwood pulp described in step (4), compound poly-
The mass fraction ratio of acid fiber is 35-44：9-13：15-20：11-15.
The beneficial effects of the invention are as follows：
The present invention utilizes the good biocompatibility of acid fiber by polylactic, thermal stability, adsorptivity, biodegradability etc.
Advantage is added in the preparation process of paper handkerchief, assigns the advantage that tissue is soft, tension stress is strong, because of its hydrophobicity high pass and
Softwood pulp, cotton pulp, hardwood pulp proportioning mashing can improve hydrophily and dispersibility, secondly be obtained using extracted form natural plant
Blending is loaded to using beta cyclodextrin inclusion in polylactic acid, so that blending is evenly distributed in paper handkerchief, is not easy to dissipate, fragrance remaining time
It is long, by stimulating the respiratory center of people, promotes human body inspiration oxygen, carbon dioxide is discharged, brain obtains sufficient oxygen and supplies
It answers, generates vigorous energy, with the diffusion of fragrance, the cation in air increases, and adjusts the nervous system of human body, promotes blood
Liquid recycle, accelerate metabolism, so that human body corresponding organ is secreted out of wholesome hormone and body fluid, enhance human immunity and
Body energy has the function that refresh the mind, and is beneficial to the generation that sub-health population prevents various diseases, paper provided by the invention
The preparation method of handkerchief is easy to operate, at low cost, is easy large-scale production, has good application prospect.
Specific implementation mode
In order to make the technical means, the creative features, the aims and the efficiencies achieved by the present invention be easy to understand, tie below
Specific embodiment is closed, the present invention is further explained, but following embodiments are only the preferred embodiment of the present invention, and not all.
Based on the implementation example in the implementation mode, those skilled in the art's obtained other realities without making creative work
Example is applied, protection scope of the present invention is belonged to.Experimental method in following embodiments is unless otherwise specified conventional method,
The materials, reagents and the like used in the following examples is commercially available unless otherwise specified.
A kind of preparation method of restoring consciouness paper handkerchief, including step in detail below：
(1) it will be added in ethanol solution after potassium permanganate distillation water dissolution, wherein being added in per 250mL ethanol solutions
The potassium permanganate of 2.8-3.2g stands a period of time after rapid stirring, filters off precipitation, activated carbon is added into solution, places 3-5
It filters, filtrate is filtered through silica gel, the ethyl alcohol purified is spare after it；
(2) according to 4 after rose, ginseng, rhodiola root, Chinese herbaceous peony being cleaned up：2：8：5 parts by weight mixing, which is smashed to pieces, to be placed in
In water vapor generation device, according to 20g：Distilled water is added in the proportioning of 23ml, is heated to boiling, when essential oil amount is not in reaction unit
Stop heating when increasing, by water-oil separating after system is cooled to room temperature, oil reservoir is extracted with ethyl acetate rear rotary evaporation and obtains
To mixed essential oil；
(3) neral, muskone are added in the ethyl alcohol of step (1) after purification, step is added after placing 4-6 days in sealing
(2) mixed essential oil obtained, wherein neral, muskone, mixed essential oil and purifying ethanol weight part ratio be 3.5：1.6：6：
97, continue to be sealed and stored 3-5 days, beta cyclodextrin is then added to stirring in 45 DEG C of warm water, saturated solution is made, according to every 1g β rings
The above-mentioned mixed ethanol mixed liquors of 0.4ml are added dropwise in dextrin, constant temperature stirs 1-2h at 45 DEG C, and natural cooling precipitates crystal, and filters, in
Dry 2h at 50 DEG C；
(4) product that step (3) is prepared is added in 10wt% PLA solutions, wherein step (3) product accounts for
The 7% of 10% PLA solution weight obtains composite polylactic acid fiber by electrostatic spinning, then by softwood pulp, cotton pulp, wealthy
Leaf wood pulp, composite polylactic acid fiber are according to mass fraction than 38：11：16：12 are added in trough-style pulp beater mashing to 25-30SR °
Beating degree, most afterwards through manufacturing paper with pulp, rewinding.
The foregoing is merely the specific implementation modes of the present invention, are not intended to limit the scope of protection of the present invention, all
Within the spirit and principles in the present invention, any modification, equivalent substitution, improvement and etc. done should be included in the guarantor of the present invention
Within the scope of shield.
Claims (7)
1. a kind of preparation method of restoring consciouness paper handkerchief, which is characterized in that including step in detail below：
(1) it will be added in ethanol solution after potassium permanganate distillation water dissolution, stand a period of time after rapid stirring, it is heavy to filter off
It forms sediment, activated carbon is added into solution, filter, filtrate is filtered through silica gel, the ethyl alcohol purified is spare after placing 3-5 days；
(2) it smashs to pieces and is placed in water vapor generation device after cleaning up rose, ginseng, rhodiola root, Chinese herbaceous peony, is added a certain amount of
Distilled water after be heated to boiling, when in reaction unit essential oil amount not increase when stop heating, after system is cooled to room temperature
By water-oil separating, oil reservoir is extracted with ethyl acetate rear rotary evaporation and obtains mixed essential oil；
(3) neral, muskone are added in the ethyl alcohol of step (1) after purification, sealing is added step (2) after placing 4-6 days and obtains
The mixed essential oil arrived, continue be sealed and stored 3-5 days, then by beta cyclodextrin be added in warm water stir saturated solution is made, according to
Than above-mentioned mixed ethanol mixed liquor is added, heated constant temperature stirs 1-2h, and natural cooling precipitates crystal, and filters, dry at 50 DEG C
2h；
(4) product that step (3) is prepared is added in 10wt% PLA solutions, compound poly- breast is obtained by electrostatic spinning
Then softwood pulp, cotton pulp, hardwood pulp, composite polylactic acid fiber are added in trough-style pulp beater and are beaten to 25- by sour fiber
30SR ° of beating degree, most afterwards through manufacturing paper with pulp, rewinding.
2. a kind of preparation method of restoring consciouness paper handkerchief according to claim 1, which is characterized in that described in step (1)
The proportioning of potassium permanganate and ethanol solution is：2.5-5g：250ml.
3. a kind of preparation method of restoring consciouness paper handkerchief according to claim 1, which is characterized in that described in step (2)
Rose, ginseng, rhodiola root, Chinese herbaceous peony mass ratio be 4-6：2-3：7-9：4-6, wherein rose, ginseng, rhodiola root and Chinese herbaceous peony
Total weight and distilled water proportioning be 20-22g：20-25ml.
4. a kind of preparation method of restoring consciouness paper handkerchief according to claim 1, which is characterized in that described in step (3)
Neral, muskone, mixed essential oil and purifying ethanol volume proportion be 3-5：1.6-2.2：5-7：90-110.
5. a kind of preparation method of restoring consciouness paper handkerchief according to claim 1, which is characterized in that described in step (3)
The proportioning of heating stirring temperature 45 C, mixing time 1-1.5h, beta cyclodextrin and alcohol mixed solution is 1g：0.1-0.4ml.
6. a kind of preparation method of restoring consciouness paper handkerchief according to claim 1, which is characterized in that described in step (4)
The product prepared in step (3) accounts for the 5-8% of PLA solution weight.
7. a kind of preparation method of restoring consciouness paper handkerchief according to claim 1, which is characterized in that described in step (4)
Softwood pulp, cotton pulp, hardwood pulp, composite polylactic acid fiber mass fraction ratio be 35-44：9-13：15-20：11-15.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810388997.0A CN108774912A (en) | 2018-04-27 | 2018-04-27 | A kind of preparation method of restoring consciouness paper handkerchief |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810388997.0A CN108774912A (en) | 2018-04-27 | 2018-04-27 | A kind of preparation method of restoring consciouness paper handkerchief |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108774912A true CN108774912A (en) | 2018-11-09 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810388997.0A Pending CN108774912A (en) | 2018-04-27 | 2018-04-27 | A kind of preparation method of restoring consciouness paper handkerchief |
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| Country | Link |
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| CN (1) | CN108774912A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111979839A (en) * | 2020-07-30 | 2020-11-24 | 安徽瑞莱尔仪表有限公司 | Medical tissue and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0499181A2 (en) * | 1991-02-13 | 1992-08-19 | Tree Extracts Research Association | Gradual fragrance-emitting textile material |
| CN103265795A (en) * | 2013-04-19 | 2013-08-28 | 江南大学 | Preparation method of degradable and radiation-protection computer screen film with rose fragrance |
| CN104213460A (en) * | 2014-08-05 | 2014-12-17 | 江守仲 | Smoke-content-reducing fragrant base paper of tipping paper with addition of nano kieselguhr and preparation method thereof |
| CN104452433A (en) * | 2014-11-24 | 2015-03-25 | 杭州新兴纸业有限公司 | Raw paper for dispersed wet tissues and production method for raw paper |
| CN106283887A (en) * | 2016-08-17 | 2017-01-04 | 安庆市新宜纸业有限公司 | A kind of preparation method of the napkin with stimulating effect |
-
2018
- 2018-04-27 CN CN201810388997.0A patent/CN108774912A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0499181A2 (en) * | 1991-02-13 | 1992-08-19 | Tree Extracts Research Association | Gradual fragrance-emitting textile material |
| CN103265795A (en) * | 2013-04-19 | 2013-08-28 | 江南大学 | Preparation method of degradable and radiation-protection computer screen film with rose fragrance |
| CN104213460A (en) * | 2014-08-05 | 2014-12-17 | 江守仲 | Smoke-content-reducing fragrant base paper of tipping paper with addition of nano kieselguhr and preparation method thereof |
| CN104452433A (en) * | 2014-11-24 | 2015-03-25 | 杭州新兴纸业有限公司 | Raw paper for dispersed wet tissues and production method for raw paper |
| CN106283887A (en) * | 2016-08-17 | 2017-01-04 | 安庆市新宜纸业有限公司 | A kind of preparation method of the napkin with stimulating effect |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111979839A (en) * | 2020-07-30 | 2020-11-24 | 安徽瑞莱尔仪表有限公司 | Medical tissue and preparation method thereof |
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| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20181109 |
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| RJ01 | Rejection of invention patent application after publication |