CN108774372B - Acrylonitrile modified wood powder reinforced wood-plastic foaming material - Google Patents
Acrylonitrile modified wood powder reinforced wood-plastic foaming material Download PDFInfo
- Publication number
- CN108774372B CN108774372B CN201810649474.7A CN201810649474A CN108774372B CN 108774372 B CN108774372 B CN 108774372B CN 201810649474 A CN201810649474 A CN 201810649474A CN 108774372 B CN108774372 B CN 108774372B
- Authority
- CN
- China
- Prior art keywords
- wood
- wood powder
- mixture
- acrylonitrile
- polyvinyl chloride
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000002023 wood Substances 0.000 title claims abstract description 75
- 239000000843 powder Substances 0.000 title claims abstract description 60
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 title claims abstract description 35
- 239000000463 material Substances 0.000 title claims abstract description 26
- 229920003023 plastic Polymers 0.000 title claims description 6
- 239000004033 plastic Substances 0.000 title claims description 6
- 238000005187 foaming Methods 0.000 title claims description 4
- 239000002984 plastic foam Substances 0.000 claims abstract description 17
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 15
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 31
- 239000004800 polyvinyl chloride Substances 0.000 claims description 31
- 239000000203 mixture Substances 0.000 claims description 30
- 239000011259 mixed solution Substances 0.000 claims description 20
- 239000011347 resin Substances 0.000 claims description 18
- 229920005989 resin Polymers 0.000 claims description 18
- 125000003118 aryl group Chemical group 0.000 claims description 15
- 125000000524 functional group Chemical group 0.000 claims description 15
- 239000000314 lubricant Substances 0.000 claims description 15
- 238000002156 mixing Methods 0.000 claims description 15
- 238000003756 stirring Methods 0.000 claims description 15
- 235000013312 flour Nutrition 0.000 claims description 12
- 239000008367 deionised water Substances 0.000 claims description 10
- 229910021641 deionized water Inorganic materials 0.000 claims description 10
- 238000010438 heat treatment Methods 0.000 claims description 10
- 239000003999 initiator Substances 0.000 claims description 10
- 239000004088 foaming agent Substances 0.000 claims description 7
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical group Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 5
- -1 ammonium peroxide Chemical class 0.000 claims description 5
- 125000003236 benzoyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C(*)=O 0.000 claims description 5
- 125000004432 carbon atom Chemical group C* 0.000 claims description 5
- 238000006243 chemical reaction Methods 0.000 claims description 5
- 238000004140 cleaning Methods 0.000 claims description 5
- 238000001035 drying Methods 0.000 claims description 5
- 238000001914 filtration Methods 0.000 claims description 5
- 238000002360 preparation method Methods 0.000 claims description 5
- 239000003381 stabilizer Substances 0.000 claims description 5
- BCNZYOJHNLTNEZ-UHFFFAOYSA-N tert-butyldimethylsilyl chloride Chemical compound CC(C)(C)[Si](C)(C)Cl BCNZYOJHNLTNEZ-UHFFFAOYSA-N 0.000 claims description 5
- 244000166124 Eucalyptus globulus Species 0.000 claims 1
- 238000010521 absorption reaction Methods 0.000 abstract description 3
- 241000219927 Eucalyptus Species 0.000 description 12
- 239000004604 Blowing Agent Substances 0.000 description 8
- 239000002131 composite material Substances 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 5
- 238000000034 method Methods 0.000 description 4
- 230000004048 modification Effects 0.000 description 4
- 238000012986 modification Methods 0.000 description 4
- 238000012545 processing Methods 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 239000000835 fiber Substances 0.000 description 2
- 240000002834 Paulownia tomentosa Species 0.000 description 1
- 235000010678 Paulownia tomentosa Nutrition 0.000 description 1
- 238000003490 calendering Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 230000009878 intermolecular interaction Effects 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/06—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent
- C08J9/10—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent developing nitrogen, the blowing agent being a compound containing a nitrogen-to-nitrogen bond
- C08J9/102—Azo-compounds
- C08J9/103—Azodicarbonamide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F289/00—Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds not provided for in groups C08F251/00 - C08F287/00
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0061—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof characterized by the use of several polymeric components
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/04—N2 releasing, ex azodicarbonamide or nitroso compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
- C08J2327/22—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers modified by chemical after-treatment
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2451/00—Characterised by the use of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
Abstract
The invention discloses an acrylonitrile modified wood powder reinforced wood-plastic foam material, and relates to the technical field of new materials, wherein the wood-plastic foam material contains acrylonitrile modified wood powder with the mass of 40.2-49.3%; the acrylonitrile modified wood powder reinforced wood plastic foam material prepared by the invention has good impact strength and greatly reduced water absorption.
Description
Technical Field
The invention belongs to the technical field of new materials, and particularly relates to an acrylonitrile modified wood powder reinforced wood plastic foam material.
Background
The PVC wood-plastic material belongs to a green environment-friendly material, can be processed into household or outdoor products such as floors, wallboards, door panels, profiles and the like through an extrusion mold, an injection mold and a calendering mold, does not contain benzene substances, and has the formaldehyde content of less than 0.2mg/cm3. The product made of the PVC wood-plastic material is moisture-proof and waterproof, can solve the problems that the solid wood board and the density board are easy to rot and expand and deform after absorbing water and being affected with damp in a humid and multi-water environment, and can be applied to the environment where the traditional wooden products cannot be applied.
However, in actual processing, the mechanical property of the prepared composite material is greatly reduced, so that the mechanical property of the composite material cannot meet the market demand.
Disclosure of Invention
The invention aims to solve the existing problems and provides an acrylonitrile modified wood powder reinforced wood plastic foam material.
The invention is realized by the following technical scheme:
an acrylonitrile modified wood powder reinforced wood-plastic foam material contains 40.2-49.3% of acrylonitrile modified wood powder by mass.
Further, the preparation method of the acrylonitrile modified wood powder comprises the following steps:
(1) mixing wood powder and deionized water according to the weight ratio of 100 g: mixing 500mL of the mixture according to a proportion, heating the mixture to 68 ℃, stirring the mixture for 30min at a rotating speed of 1200r/min to obtain a wood powder mixed solution, adding an initiator with the mass of 0.25% of the wood powder mixed solution, stirring the mixture uniformly, and then preserving the heat at 68 ℃;
(2) mixing acrylonitrile and tert-butyldimethylsilyl chloride according to the mass ratio of 20:1, heating to 55 ℃, and keeping the temperature for 15min to obtain a mixture;
(3) adding the mixture into the wood powder mixed solution according to the mass ratio of 1:15, adjusting the pH value of a reaction system to 5.5, adjusting the temperature to 86 ℃, stirring for 2 hours at the rotating speed of 120r/min, then filtering, cleaning by using deionized water, and drying in vacuum to constant weight to obtain the wood powder mixed solution.
Further, the wood flour is eucalyptus wood flour.
Further, the initiator is ammonium peroxide.
Further, the wood-plastic foam material also comprises the following components in parts by weight: modified polyvinyl chloride resin 90, foaming agent 1.2, lubricant 0.5 and stabilizer 1.3.
Further, the modified polyvinyl chloride resin is obtained by introducing an aromatic functional group having 25 carbon atoms as a graft chain into the main chain of polyvinyl chloride.
Further, the molar ratio of the grafted aromatic functional groups to the polyvinyl chloride units as the backbone is 1.2: 45.
further, the aromatic functional group is benzoyl.
Further, the blowing agent is an AC blowing agent.
Further, the lubricant is a lubricant of type G60.
Compared with the prior art, the invention has the following advantages: according to the invention, through modification treatment on the polyvinyl chloride resin, the apparent viscosity of the melt of the modified polyvinyl chloride resin and acrylonitrile modified wood powder composite material can show a trend of obvious reduction along with the increase of the shear rate, so that the characteristic of shear thinning is shown, and a typical pseudoplastic fluid behavior is shown. This is because when the shear rate is increased, the entanglement points between the macromolecular chains of the modified polyvinyl chloride resin are disentangled, the disentanglement rate of the entanglement points is greater than the reconstitution rate, the number of the entanglement points is reduced, and the relative movement between the macromolecules of the modified polyvinyl chloride resin is easier, so that the apparent viscosity is also reduced. On the other hand, when the shear rate is increased, the molecular segments of the modified polyvinyl chloride resin are oriented in the flow field without being as much as possible to relax and shrink, so that intermolecular interaction between flow layers is reduced, and the flow resistance is lowered. Therefore, the processing stability is greatly improved in the processing process; the interface of the composite material is bonded most strongly through the synergistic effect between the modified polyvinyl chloride resin and the acrylonitrile modified wood powder, and when the composite material is acted by external force, the external force can be uniformly transmitted to the reinforced fibers through the interface, so that the external force is effectively buffered among the reinforced fibers, and the mechanical property of the composite material is improved accordingly; according to the invention, the eucalyptus wood powder is modified by acrylonitrile, and the acrylonitrile monomer and the eucalyptus wood powder are selected because a great deal of experimental research shows that the modification effect of the acrylonitrile monomer on the eucalyptus wood powder is the best, in the modification process, the grafting rate of the acrylonitrile monomer on the surface of the eucalyptus wood powder can be fast and stable, and in the modification process, the surface of the eucalyptus wood powder is grafted with more active points, so that the initiated active centers are increased, the surface performance of the wood powder modified by acrylonitrile is obviously improved, the compatibility between the wood powder and polyvinyl chloride molecules is obviously improved, meanwhile, the acrylonitrile modified wood powder is more uniformly dispersed in a complex system, the physical and mechanical properties of the composite material can be effectively improved, particularly, the impact strength is obviously improved, and meanwhile, the water absorption of the wood-plastic foam material can be effectively reduced.
Detailed Description
Example 1
An acrylonitrile modified wood powder reinforced wood-plastic foam material contains 40.2% of acrylonitrile modified wood powder by mass.
Further, the preparation method of the acrylonitrile modified wood powder comprises the following steps:
(1) mixing wood powder and deionized water according to the weight ratio of 100 g: mixing 500mL of the mixture according to a proportion, heating the mixture to 68 ℃, stirring the mixture for 30min at a rotating speed of 1200r/min to obtain a wood powder mixed solution, adding an initiator with the mass of 0.25% of the wood powder mixed solution, stirring the mixture uniformly, and then preserving the heat at 68 ℃;
(2) mixing acrylonitrile and tert-butyldimethylsilyl chloride according to the mass ratio of 20:1, heating to 55 ℃, and keeping the temperature for 15min to obtain a mixture;
(3) adding the mixture into the wood powder mixed solution according to the mass ratio of 1:15, adjusting the pH value of a reaction system to 5.5, adjusting the temperature to 86 ℃, stirring for 2 hours at the rotating speed of 120r/min, then filtering, cleaning by using deionized water, and drying in vacuum to constant weight to obtain the wood powder mixed solution.
Further, the wood flour is eucalyptus wood flour.
Further, the initiator is ammonium peroxide.
Further, the wood-plastic foam material also comprises the following components in parts by weight: modified polyvinyl chloride resin 90, foaming agent 1.2, lubricant 0.5 and stabilizer 1.3.
Further, the modified polyvinyl chloride resin is obtained by introducing an aromatic functional group having 25 carbon atoms as a graft chain into the main chain of polyvinyl chloride.
Further, the molar ratio of the grafted aromatic functional groups to the polyvinyl chloride units as the backbone is 1.2: 45.
further, the aromatic functional group is benzoyl.
Further, the blowing agent is an AC blowing agent.
Further, the lubricant is a lubricant of type G60.
Example 2
The acrylonitrile modified wood powder reinforced wood-plastic foam material contains 49.3% of acrylonitrile modified wood powder by mass.
Further, the preparation method of the acrylonitrile modified wood powder comprises the following steps:
(1) mixing wood powder and deionized water according to the weight ratio of 100 g: mixing 500mL of the mixture according to a proportion, heating the mixture to 68 ℃, stirring the mixture for 30min at a rotating speed of 1200r/min to obtain a wood powder mixed solution, adding an initiator with the mass of 0.25% of the wood powder mixed solution, stirring the mixture uniformly, and then preserving the heat at 68 ℃;
(2) mixing acrylonitrile and tert-butyldimethylsilyl chloride according to the mass ratio of 20:1, heating to 55 ℃, and keeping the temperature for 15min to obtain a mixture;
(3) adding the mixture into the wood powder mixed solution according to the mass ratio of 1:15, adjusting the pH value of a reaction system to 5.5, adjusting the temperature to 86 ℃, stirring for 2 hours at the rotating speed of 120r/min, then filtering, cleaning by using deionized water, and drying in vacuum to constant weight to obtain the wood powder mixed solution.
Further, the wood flour is eucalyptus wood flour.
Further, the initiator is ammonium peroxide.
Further, the wood-plastic foam material also comprises the following components in parts by weight: modified polyvinyl chloride resin 90, foaming agent 1.2, lubricant 0.5 and stabilizer 1.3.
Further, the modified polyvinyl chloride resin is obtained by introducing an aromatic functional group having 25 carbon atoms as a graft chain into the main chain of polyvinyl chloride.
Further, the molar ratio of the grafted aromatic functional groups to the polyvinyl chloride units as the backbone is 1.2: 45.
further, the aromatic functional group is benzoyl.
Further, the blowing agent is an AC blowing agent.
Further, the lubricant is a lubricant of type G60.
Example 3
The acrylonitrile modified wood powder reinforced wood-plastic foam material contains 46.3% of acrylonitrile modified wood powder by mass.
Further, the preparation method of the acrylonitrile modified wood powder comprises the following steps:
(1) mixing wood powder and deionized water according to the weight ratio of 100 g: mixing 500mL of the mixture according to a proportion, heating the mixture to 68 ℃, stirring the mixture for 30min at a rotating speed of 1200r/min to obtain a wood powder mixed solution, adding an initiator with the mass of 0.25% of the wood powder mixed solution, stirring the mixture uniformly, and then preserving the heat at 68 ℃;
(2) mixing acrylonitrile and tert-butyldimethylsilyl chloride according to the mass ratio of 20:1, heating to 55 ℃, and keeping the temperature for 15min to obtain a mixture;
(3) adding the mixture into the wood powder mixed solution according to the mass ratio of 1:15, adjusting the pH value of a reaction system to 5.5, adjusting the temperature to 86 ℃, stirring for 2 hours at the rotating speed of 120r/min, then filtering, cleaning by using deionized water, and drying in vacuum to constant weight to obtain the wood powder mixed solution.
Further, the wood flour is eucalyptus wood flour.
Further, the initiator is ammonium peroxide.
Further, the wood-plastic foam material also comprises the following components in parts by weight: modified polyvinyl chloride resin 90, foaming agent 1.2, lubricant 0.5 and stabilizer 1.3.
Further, the modified polyvinyl chloride resin is obtained by introducing an aromatic functional group having 25 carbon atoms as a graft chain into the main chain of polyvinyl chloride.
Further, the molar ratio of the grafted aromatic functional groups to the polyvinyl chloride units as the backbone is 1.2: 45.
further, the aromatic functional group is benzoyl.
Further, the blowing agent is an AC blowing agent.
Further, the lubricant is a lubricant of type G60.
Comparative example 1: the only difference from example 1 is that the acrylonitrile-modified wood flour was replaced with unmodified eucalyptus wood flour.
Comparative example 2: the only difference from example 1 is that eucalyptus wood powder is replaced with tung wood powder.
Comparative example 3: only the difference from example 1 is that the application number: 201610468947.4 method for modifying eucalyptus powder.
Comparative example 4: the only difference from example 1 is that the modified polyvinyl chloride resin was replaced with an unmodified treated polyvinyl chloride resin.
Control group: application No. 201410257524.9.
Test of
The processing technology is adopted to carry out performance detection on the wood-plastic foaming material samples with the same specification prepared in the embodiment and the comparative example, and the specific comparison data are shown in the following table 1:
TABLE 1
As can be seen from Table 1, the wood-plastic foam material prepared by the invention has good impact strength and low water absorption.
Claims (1)
1. The acrylonitrile modified wood powder reinforced wood-plastic foam material is characterized in that the wood-plastic foam material contains acrylonitrile modified wood powder with the mass of 40.2-49.3%; the preparation method of the acrylonitrile modified wood powder comprises the following steps:
(1) mixing wood powder and deionized water according to the weight ratio of 100 g: mixing 500mL of the mixture according to a proportion, heating the mixture to 68 ℃, stirring the mixture for 30min at a rotating speed of 1200r/min to obtain a wood powder mixed solution, adding an initiator with the mass of 0.25% of the wood powder mixed solution, stirring the mixture uniformly, and then preserving the heat at 68 ℃;
(2) mixing acrylonitrile and tert-butyldimethylsilyl chloride according to the mass ratio of 20:1, heating to 55 ℃, and keeping the temperature for 15min to obtain a mixture;
(3) adding the mixture into the wood powder mixed solution according to the mass ratio of 1:15, adjusting the pH value of a reaction system to 5.5, adjusting the temperature to 86 ℃, stirring for 2 hours at the rotating speed of 120r/min, then filtering, cleaning by using deionized water, and drying in vacuum to constant weight to obtain the wood powder mixed solution; the wood flour is eucalyptus wood flour; the initiator is ammonium peroxide; the wood-plastic foaming material also comprises the following components in parts by weight: 90 parts of modified polyvinyl chloride resin, 1.2 parts of foaming agent, 0.5 part of lubricant and 1.3 parts of stabilizer; the modified polyvinyl chloride resin is obtained by introducing an aromatic functional group having 25 carbon atoms as a graft chain into a main chain of polyvinyl chloride; the molar ratio of grafted aromatic functional groups to polyvinyl chloride units as backbone is 1.2: 45, a first step of; the aromatic functional group is benzoyl; the foaming agent is an AC foaming agent; the lubricant is a lubricant of type G60.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810649474.7A CN108774372B (en) | 2018-06-22 | 2018-06-22 | Acrylonitrile modified wood powder reinforced wood-plastic foaming material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810649474.7A CN108774372B (en) | 2018-06-22 | 2018-06-22 | Acrylonitrile modified wood powder reinforced wood-plastic foaming material |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN108774372A CN108774372A (en) | 2018-11-09 |
| CN108774372B true CN108774372B (en) | 2021-03-19 |
Family
ID=64025355
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810649474.7A Active CN108774372B (en) | 2018-06-22 | 2018-06-22 | Acrylonitrile modified wood powder reinforced wood-plastic foaming material |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108774372B (en) |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102837345B (en) * | 2012-09-14 | 2014-12-24 | 中南林业科技大学 | Preparation method of colored wood-plastic material |
| CN103665636B (en) * | 2013-11-27 | 2015-12-30 | 江阴匡时建材有限公司 | A kind of igelite building template |
| KR101799588B1 (en) * | 2015-01-15 | 2017-11-21 | 한남대학교 산학협력단 | A eco-friendly ductility composition for injection molding |
-
2018
- 2018-06-22 CN CN201810649474.7A patent/CN108774372B/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| CN108774372A (en) | 2018-11-09 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Balart et al. | Processing and characterization of high environmental efficiency composites based on PLA and hazelnut shell flour (HSF) with biobased plasticizers derived from epoxidized linseed oil (ELO) | |
| CN103146049A (en) | preparation method and application of acrylate wood-plastic composite compatibilization modifier | |
| JPH0948023A (en) | Miscibility improved polymer wood fiber composite material | |
| CN104672697A (en) | Wood-plastic composite material | |
| CN102558679A (en) | Novel bamboo fiber/polypropylene composite material and method for preparing same | |
| CN101353180B (en) | Grafting nano-titania particle and preparation thereof | |
| Hon et al. | Composites from benzylated wood and polystyrenes: their processability and viscoelastic properties | |
| CN108774372B (en) | Acrylonitrile modified wood powder reinforced wood-plastic foaming material | |
| Fu et al. | Influence of core–shell particles structure on the morphology and brittle‐ductile transition of PBT/ABS‐g‐GMA blends | |
| CN107418084A (en) | A kind of PVC wood plastic composite decorating board | |
| CN108384208B (en) | PET-based wood-plastic composite material and preparation method thereof | |
| CN110746730A (en) | Biodegradable starch-based preservative film for microwave oven and preparation method thereof | |
| CN102558697A (en) | Preparation method of ultrahigh-toughness polystyrene resin | |
| CN106497118B (en) | A kind of wood plastic composite, preparation method and the profiled sheeting made of the composite material | |
| CN111073327A (en) | Light high-strength ABS (acrylonitrile butadiene styrene) wood-plastic foamed board and preparation method thereof | |
| JPS6137297B2 (en) | ||
| CN107057394A (en) | Pvc wood plastic composite material and its preparation method and application | |
| CN107216478B (en) | Polyvinyl chloride resin with surface modified by ethylene-vinyl acetate copolymer emulsion and surface modification method thereof | |
| CN107201051B (en) | Method for modifying polyvinyl chloride resin on surface of ethylene-vinyl acetate-vinyl chloride copolymer emulsion | |
| CN108659367B (en) | Composition for transparent washing machine cover and preparation method | |
| Lu et al. | Preparation of soft wood–plastic composites | |
| CN107286468B (en) | Preparation method of high-load wood-plastic floor | |
| CN113072786A (en) | Nano calcium carbonate master batch, preparation method thereof and application of nano calcium carbonate master batch in UPVC (unplasticized polyvinyl chloride) reinforcement and toughening | |
| CN107177141B (en) | Method for modifying surface of polyvinyl chloride resin by propylene-vinyl chloride copolymer emulsion | |
| CN118459902B (en) | Preparation method of high-elongation-at-break chlorinated polyethylene |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20220908 Address after: Northeast of the intersection of Hongshan Road and Shuangying Road, Wuyi Town, Nanqiao District, Chuzhou City, Anhui Province 239000 Patentee after: Anhui Dongsen Smart Home Co.,Ltd. Address before: 239500 Quanjiao Economic Development Zone, Anhui, Chuzhou Patentee before: ANHUI SOYA DECORATIVE MATERIALS Co.,Ltd. |
|
| TR01 | Transfer of patent right | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: A Kind of Acrylonitrile Modified Wood Powder Reinforced Wood Plastic Foam Material Effective date of registration: 20230728 Granted publication date: 20210319 Pledgee: Chuzhou Wandong Rural Commercial Bank Co.,Ltd. Changjiang Branch Pledgor: Anhui Dongsen Smart Home Co.,Ltd. Registration number: Y2023980050256 |
|
| PC01 | Cancellation of the registration of the contract for pledge of patent right | ||
| PC01 | Cancellation of the registration of the contract for pledge of patent right |
Granted publication date: 20210319 Pledgee: Chuzhou Wandong Rural Commercial Bank Co.,Ltd. Changjiang Branch Pledgor: Anhui Dongsen Smart Home Co.,Ltd. Registration number: Y2023980050256 |
|
| PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: A Acrylonitrile Modified Wood Powder Reinforced Wood Plastic Foam Material Granted publication date: 20210319 Pledgee: Chuzhou Wandong Rural Commercial Bank Co.,Ltd. Changjiang Branch Pledgor: Anhui Dongsen Smart Home Co.,Ltd. Registration number: Y2024980039359 |