CN108773127A - A kind of resin regeneration gelling novel environment friendly plank and preparation method thereof - Google Patents
A kind of resin regeneration gelling novel environment friendly plank and preparation method thereof Download PDFInfo
- Publication number
- CN108773127A CN108773127A CN201810598641.XA CN201810598641A CN108773127A CN 108773127 A CN108773127 A CN 108773127A CN 201810598641 A CN201810598641 A CN 201810598641A CN 108773127 A CN108773127 A CN 108773127A
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- China
- Prior art keywords
- resin
- environment friendly
- novel environment
- preparation
- gelling
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Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/12—Layered products comprising a layer of synthetic resin next to a fibrous or filamentary layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B33/00—Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
- B32B5/028—Net structure, e.g. spaced apart filaments bonded at the crossing points
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
- C03C25/10—Coating
- C03C25/48—Coating with two or more coatings having different compositions
- C03C25/50—Coatings containing organic materials only
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2255/00—Coating on the layer surface
- B32B2255/02—Coating on the layer surface on fibrous or filamentary layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2255/00—Coating on the layer surface
- B32B2255/26—Polymeric coating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/10—Inorganic fibres
- B32B2262/101—Glass fibres
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)
Abstract
The present invention relates to a kind of novel environment friendly planks more particularly to a kind of resin regeneration gelling novel environment friendly plank and preparation method thereof.It can recycle the technical problem to be solved in the present invention is to provide a kind of, save the small resin regeneration of resource, environmental pollution and be gelled novel environment friendly plank and preparation method thereof.In order to solve the above-mentioned technical problem, the present invention provides such a resin regeneration gelling novel environment friendly planks and preparation method thereof, include glass fibre, thermosetting acrylic resin, pure phenolic resin and organic siliconresin, it is main shin bone using glass fibre, pure phenolic resin is uniformly smeared in glass fibre both sides, thermosetting acrylic resin is uniformly smeared in pure phenolic resin both sides, and organic siliconresin is bonded on the outside of thermosetting acrylic resin.Invention can largely energy saving, water resources and production auxiliary materials, reduction production cost be reduced environmental pollution compared with using Resources using regenerated resources.
Description
Technical field
The present invention relates to a kind of novel environment friendly plank more particularly to a kind of resin regeneration gelling novel environment friendly plank and its systems
Preparation Method.
Background technology
Resin typically refer to it is heated after be softened or melted range, there are liquidity preference, room temperature in when softening under external force
Under be solid-state, semisolid, can also be the organic polymer of liquid sometimes.In a broad aspect, plastic products processing can be used as former
Any high-molecular compound of material is referred to as resin.
In the age in last century 50-60, in order to solve the problems, such as that social goods and materials are seriously deficient, government advocates economy, receives energetically
Old profit is useless, it is established that more perfect waste and old material recovery system.Since the nineties in last century, in order to realize resource reutilization,
Mitigate environmental pollution, country successively releases a series of preferential support policies, and utilization of the recycling of renewable resources industry has obtained swift and violent hair
Exhibition.According to statistics, 2006-2011, China's recycle business total industrial output value annual average compound growth rate reach 50.49%.
The above regenerated resources enterprise of scale of 995, China realizes 2986.98 hundred million yuan of total industrial output value altogether within 2011.
But China's recycle business development also has prodigious gap compared with the developed countries such as America and Europe.China is useless at present
The rate of recovery of plastics is less than 25%；Reviver rate of consumption only 33%, and the U.S. has reached 82%.Just because of this China is sent out energetically
Opening up reproductive vibration has stronger newcoming advantage.
The utilization rate of plank has reached a peak at present, and plank scraps also very much, plank report because of reasons such as agings
If cannot be re-used after useless, huge waste, developed countries' phase such as China's renewable resource industry and America and Europe will result in
Than there is prodigious gap, therefore there is an urgent need for research and develop a kind of to recycle, save the small resin regeneration of resource, environmental pollution
Be gelled novel environment friendly plank and preparation method thereof.
Invention content
It can recycle the main purpose of the present invention is to provide a kind of, save the small resin of resource, environmental pollution
Regenerative gel novel environment friendly plank and preparation method thereof, can effectively solve the problems in background technology.
To achieve the above object, the technical solution that the present invention takes is：
A kind of resin regeneration gelling novel environment friendly plank and preparation method thereof, includes glass fibre, thermoset acrylics
Resin, pure phenolic resin and organic siliconresin are main shin bone using glass fibre, pure phenol are uniformly smeared in glass fibre both sides
Urea formaldehyde, pure phenolic resin both sides are uniformly smeared thermosetting acrylic resin, are bonded on the outside of thermosetting acrylic resin organic
Silicones.
Preferably, further include having cullet steel resin, waste printed circuit board resin, useless anion-cation exchange resin and cured tree
Fat glue residue is uniformly mixed with cullet steel resin, waste printed circuit board resin, useless cation and anion exchange tree in organic siliconresin
Fat and cured resin glue residue.
Preferably, further include having epoxy resin and furane resins, head is coated with one layer of ring between every two layers of different materials
Oxygen resin and furane resins.
Compared with prior art, the present invention has the advantages that：
Largely energy saving, water resources and production auxiliary materials, reduction production cost it is dirty can to reduce environment using regenerated resources
Dye contributes greatly socio-economic development, recycles regenerated resources, not only there is preferable economic value, also considerable society
And environmental benefit, it is often more important that save the valuable land resource occupied because rubbish largely fills, reduce to air
Pollution.
Description of the drawings
Fig. 1 is the overall structure diagram of the present invention.
Fig. 2 is the schematic diagram of organic siliconresin of the present invention.
Fig. 3 is epoxy resin and furane resins structural schematic diagram of the present invention.
Label in attached drawing be：1- glass fibres, 2- pure phenolic resins, 3- thermosetting acrylic resins, 4- organosilicon trees
Fat, 21- epoxy resin, 22- furane resins, 41- cullet steel resins, 42- waste printed circuit board resins, 43- give up cation and anion exchange
Resin, the cured resin glue residues of 44-.
Specific implementation mode
To make the technical means, the creative features, the aims and the efficiencies achieved by the present invention be easy to understand, with reference to
Specific implementation mode, the present invention is further explained.
As shown in Figs. 1-3, a kind of resin regeneration gelling novel environment friendly plank and preparation method thereof, include glass fibre 1,
Thermosetting acrylic resin 3, pure phenolic resin 2 and organic siliconresin 4 are main shin bone, glass fibre 1 using glass fibre 1
It is arranged in net distribution, uniformly smears pure phenolic resin 2 in 1 both sides of glass fibre, thermosetting is uniformly smeared in 2 both sides of pure phenolic resin
Property acrylic resin 3, the outside of thermosetting acrylic resin 3 is bonded with organic siliconresin 4.
Further include having cullet steel resin 41, waste printed circuit board resin 42, useless anion-cation exchange resin 43 and cured tree
Fat glue residue 44, be uniformly mixed in organic siliconresin 4 cullet steel resin 41, waste printed circuit board resin 42, useless negative and positive from
Sub-exchange resin 43 and cured resin glue residue 44, wherein cullet steel resin 41, waste printed circuit board resin 42, useless negative and positive from
The use ratio of sub-exchange resin 43 and cured resin glue residue 44 is 1：2：1：3.
Further include having epoxy resin 21 and furane resins 22, one layer of asphalt mixtures modified by epoxy resin is all coated between every two layers of different materials
The mixture of fat 21 and furane resins 22.
Operation principle：Main shin bone is done with glass fibre 1, advantage is good insulating, heat resistance is strong, corrosion resistance is good, machine
Tool intensity is high, but the disadvantage is that property is crisp, wearability is poor, and pure phenolic resin 2 is uniformly smeared in both sides, has good water resistance,
Acid resistance, solvent resistance and electrical insulating property, while after drying, film is hard and flexible, adhesive force are good, can improve glass fibre
1 brittleness and wearability, color can deepen after baking, the shortcomings that can improving discoloration using thermosetting acrylic resin 3, with third
Olefin(e) acid ester system monomer is basis, crosslinked acrylic acid series polymeric compounds insoluble at network structure, not molten, superior plentiful
Degree, gloss, hardness, these three material advantages complementation non-discolouring in high-temperature baking, superior performance, outermost layer are equipped with organosilicon tree
Fat 4, waterproof is moisture-proof, and insulating properties is good.
The a variety of waste and old recycling resins of incorporation in organic siliconresin 4, merge the good characteristic of various resins, enhance organosilicon
The intensity and wearability of resin 4 are that plank is sturdy and durable, are provided simultaneously with a variety of excellent physical characteristics, are recycled to waste and old resin
It utilizes, reduces the waste of a large amount of physical resources, reduce expenses, reduce the cost in production process, scrap feed material mostly price is low
It is honest and clean, it is also possible to affect to environment if not carrying out recycling to these waste and old resins, this way can be significantly
Reduce pollution to environment, the stringent control of dosage of various waste and old resins can perform to the performance of various resins optimal, make
Plank is provided simultaneously with a series of excellent physical characteristics such as high temperature resistant, wear-resisting, insulation, intensity height, hardness height, enhances the reality of plank
The property used.
Epoxy resin 21 and furane resins 22 are added thereto as adhesive, can enhance the bonding effect between layers of material
Fruit melts furane resins 22 in 130 degrees Celsius of environment, and epoxy resin 21 is added in uncured furane resins 22 and adds
With modification, the erosion of furane resins 22 resistance to strong acid, highly basic and organic solvent after solidification is still very stable at high temperature, usually may be used
It is used for a long time at 150 DEG C or so, ensures that adhesive strength at high temperature between each layer, epoxy resin 21 can improve furane resins
22, enhance processing performance when mechanical property and the preparation of composite material.
It should be noted that；
The above shows and describes the basic principles and main features of the present invention and the advantages of the present invention.The technology of the industry
Personnel are it should be appreciated that the present invention is not limited to the above embodiments, and the above embodiments and description only describe this
The principle of invention, without departing from the spirit and scope of the present invention, various changes and improvements may be made to the invention, these changes
Change and improvement all fall within the protetion scope of the claimed invention.The claimed scope of the invention by appended claims and its
Equivalent thereof.
Claims (3)
1. a kind of resin regeneration gelling novel environment friendly plank and preparation method thereof, which is characterized in that include glass fibre (1),
Thermosetting acrylic resin (3), pure phenolic resin (2) and organic siliconresin (4) they are main shin bone using glass fibre (1),
Pure phenolic resin (2) is uniformly smeared in glass fibre (1) both sides, and thermoset acrylics tree is uniformly smeared in pure phenolic resin (2) both sides
Fat (3), thermosetting acrylic resin (3) outside are bonded with organic siliconresin (4).
2. a kind of resin regeneration gelling novel environment friendly plank according to claim 1 and preparation method thereof, which is characterized in that
Further include having cullet steel resin (41), waste printed circuit board resin (42), useless anion-cation exchange resin (43) and cured resin
Glue residue (44) is uniformly mixed with cullet steel resin (41) in organic siliconresin (4), waste printed circuit board resin (42), gives up
Anion-cation exchange resin (43) and cured resin glue residue (44).
3. a kind of resin regeneration gelling novel environment friendly plank according to claim 1 and preparation method thereof, which is characterized in that
Further include having epoxy resin (21) and furane resins (22), head is coated with one layer of epoxy resin between every two layers of different materials
(21) and furane resins (22).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810598641.XA CN108773127A (en) | 2018-06-12 | 2018-06-12 | A kind of resin regeneration gelling novel environment friendly plank and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810598641.XA CN108773127A (en) | 2018-06-12 | 2018-06-12 | A kind of resin regeneration gelling novel environment friendly plank and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108773127A true CN108773127A (en) | 2018-11-09 |
Family
ID=64025024
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810598641.XA Pending CN108773127A (en) | 2018-06-12 | 2018-06-12 | A kind of resin regeneration gelling novel environment friendly plank and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108773127A (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20120061005A1 (en) * | 2010-09-10 | 2012-03-15 | Windsor Chou | Recycle skiboard fabrication method |
| CN104085156A (en) * | 2014-06-27 | 2014-10-08 | 优利康达（天津）科技有限公司 | Cabin cover and manufacturing method thereof |
| CN204471997U (en) * | 2015-01-16 | 2015-07-15 | 东莞市诺方斯电子科技有限公司 | Environment-friendly type wear-resistant composite board |
| CN105570657A (en) * | 2014-10-09 | 2016-05-11 | 南京建辉复合材料有限公司 | Glass reinforced plastic pultrusion profile |
-
2018
- 2018-06-12 CN CN201810598641.XA patent/CN108773127A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20120061005A1 (en) * | 2010-09-10 | 2012-03-15 | Windsor Chou | Recycle skiboard fabrication method |
| CN104085156A (en) * | 2014-06-27 | 2014-10-08 | 优利康达（天津）科技有限公司 | Cabin cover and manufacturing method thereof |
| CN105570657A (en) * | 2014-10-09 | 2016-05-11 | 南京建辉复合材料有限公司 | Glass reinforced plastic pultrusion profile |
| CN204471997U (en) * | 2015-01-16 | 2015-07-15 | 东莞市诺方斯电子科技有限公司 | Environment-friendly type wear-resistant composite board |
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| PB01 | Publication | ||
| PB01 | Publication | ||
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| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20181109 |
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| RJ01 | Rejection of invention patent application after publication |